CN109098034A - Carbonless copying paper microcapsule and preparation method thereof, carbonless paper and its coating - Google Patents
Carbonless copying paper microcapsule and preparation method thereof, carbonless paper and its coating Download PDFInfo
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- CN109098034A CN109098034A CN201810718105.9A CN201810718105A CN109098034A CN 109098034 A CN109098034 A CN 109098034A CN 201810718105 A CN201810718105 A CN 201810718105A CN 109098034 A CN109098034 A CN 109098034A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Color Printing (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
This application discloses carbonless copying paper microcapsule and preparation method thereof, carbonless paper and its coating, the carbonless paper environmental-friendly microcapsule, based on parts by weight, carbonless paper environmental-friendly microcapsule includes 2-6 parts of leuco dyes, 50-100 parts of solvent naphthas, 3-8 parts of emulsifiers, 7-20 parts of wall materials, 30-100 parts of water；Wherein, wall material is the more carbon dialdehyde performed polymers of melamine.By the above-mentioned means, the application can reduce the pollution to environment, paper is avoided pollution, reduces use cost.
Description
Technical field
This application involves pulp technology for making paper, more particularly to carbonless copying paper microcapsule and preparation method thereof, carbon-free
Carbon paper and its coating.
Background technique
Carbonless paper (NCR) is a kind of procrypsis carbon paper, has the function of directly making carbon copies, directly develop the color, is mainly used for
Multiple part form, bill, wealth ticket etc..Currently, client is gradually to nothing with the enhancing of people's environmental consciousness and the variation of the market demand
More stringent requirements are proposed for the performance of carbon carbon paper, especially pollutes (post office and tax reciept paper to the microcapsules feature of environmental protection and paper
It is especially prominent) propose higher requirement.
Present inventor has found in current techniques, carbonless paper microcapsules are general in long-term R&D process
Using melamine resin and polyurethane resin as wall material, the two contains formaldehyde and isocyanates respectively, has to environment
Different degrees of pollution is easy pollution paper, and the latter's higher cost.
Summary of the invention
The application is mainly solving the technical problems that provide carbonless copying paper microcapsule and preparation method thereof, carbonless copying
Paper and its coating can reduce the pollution to environment, avoid pollution paper, reduce use cost.
In order to solve the above technical problems, the technical solution that the application uses is: providing a kind of carbonless paper ring
Microcapsules are protected, based on parts by weight, carbonless paper environmental-friendly microcapsule includes 2-6 parts of leuco dyes, 50-100 parts of solvents
Oil, 3-8 parts of emulsifiers, 7-20 parts of wall materials, 30-100 parts of water；Wherein, the wall material is the more carbon dialdehyde performed polymers of melamine.
In order to solve the above technical problems, another technical solution that the application uses is: providing a kind of carbonless paper painting
Material, based on parts by weight, carbon-free copying paper paint include above-mentioned carbonless paper with 50-100 parts of environmental-friendly microcapsule, interval dose
20-80 parts, 5-25 parts of adhesive, 0-3 parts of thickener, the 0-3 of resistance to hydrated agent parts, 0-1 parts of interfacial agent.
In order to solve the above technical problems, another technical solution that the application uses is: providing a kind of carbonless paper, nothing
Carbon carbon paper includes: body paper；A surface of body paper is arranged in back coating；Back coating is coated with by carbon-free copying paper paint,
In, based on parts by weight, carbon-free copying paper paint includes carbonless paper with 50-100 parts of environmental-friendly microcapsule, interval dose 20-80
Part, 5-25 parts of adhesive, 0-3 parts of thickener, the 0-3 of resistance to hydrated agent parts, 0-1 parts of interfacial agent.
In order to solve the above technical problems, another technical solution that the application uses is: providing a kind of carbonless paper use
The preparation method of environmental-friendly microcapsule, is used to prepare above-mentioned carbonless paper environmental-friendly microcapsule, and preparation method includes: with weight
2-6 parts of leuco dyes are dissolved in 50-100 parts of solvent naphtha under heating conditions, obtain core material by number meter；By 50-
It is added in 30-100 parts of water in 100 parts of core materials and 3-8 parts of emulsifiers, carries out primary emulsifying after being sufficiently stirred, reach default grain
7-20 parts of wall materials are added after diameter, are sufficiently stirred to obtain lotion；Lotion is gradually warming up in the case of stirring 75-110 DEG C into
Carbonless paper environmental-friendly microcapsule is made in row curing molding；PH adjusting agent is added by carbonless paper environmental-friendly microcapsule
PH saves stand-by after adjusting to 8-10.
The beneficial effect of the application is: being in contrast to the prior art, the application is pre- using the more carbon dialdehyde of melamine
Aggressiveness is as wall material, since the carbon atom number connected between the melamine rings in the more carbon dialdehyde performed polymers of melamine increases,
Therefore, increase the flexibility of wall material, the brittleness for reducing wall shell avoids micro- during transportation to promote the toughness of microcapsules
The pollution of paper caused by capsules break, reduces use cost.Simultaneously as the preparation of the more carbon dialdehyde performed polymers of melamine not with
Formaldehyde is to prepare raw material, therefore, can reduce the pollution to environment.
Detailed description of the invention
In order to more clearly explain the technical solutions in the embodiments of the present application, make required in being described below to embodiment
Attached drawing is briefly described, it should be apparent that, the drawings in the following description are only some examples of the present application, for
For those of ordinary skill in the art, without creative efforts, it can also be obtained according to these attached drawings other
Attached drawing.Wherein:
Fig. 1 is a kind of flow diagram of one embodiment of preparation method of carbonless copying paper microcapsule of the application.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present application, technical solutions in the embodiments of the present application carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of embodiments of the present application, rather than whole embodiments.Based on this
Embodiment in application, those of ordinary skill in the art are obtained every other under the premise of not making creative labor
Embodiment shall fall in the protection scope of this application.
Carbonless paper is a kind of procrypsis carbon paper, has the function of directly making carbon copies, directly develop the color.Its colour developing is main
It is: under external force, the quick pigment of the power in microcapsules (i.e. leuco dye) and oil solution (i.e. solvent naphtha) is made to overflow and develop the color
Staining reaction occurs after agent contact, to play the role of manifolding.It is mainly used for multiple part form, bill, continuous wealth ticket, general industry
Business wealth ticket etc..There are two types of coating in carbonless paper: the CF layer (code name CF, i.e. Coated Front) containing color developing agent and containing
There is the CB layer (code name CB, i.e. Coated Back) of colour former.Colour former is a kind of special leuco dye, is dissolved in non-volatile
Solvent naphtha in, it is microencapsulated by 3-7 μm.The surge firmly write and printed can crush microcapsules, make
Leuco dye solution outflow is contacted with color developing agent, chemical reaction occurs, colored graph text is presented, to achieve the purpose that manifolding.With three
For the carbonless paper receipt of connection, paper, middle paper, lower paper can be divided into.Upper paper is also known as carried on the back and applies paper (code name CB), the back side of paper
It is coated with the microcapsules of the quick pigment oil containing power；Middle paper is also known as positive and negative double paintings paper (code name CFB, i.e. Coated Frontand Back),
Recto is coated with color developing agent, and the back side is coated with the microcapsules of the quick pigment oil containing power；Lower paper is also known as face and applies paper (code name CF), and paper is only
It is coated with color developing agent.
Microcapsules are the important components of carbonless paper, largely control the quality of carbonless paper.
The preparation method of microcapsules is usually using natural or synthetic macromolecule filming material finely dispersed solid particle, liquid
Or gas coats to form minute solid particles.Wherein, it is wrapped in the substance inside microcapsules and is known as core material, the packet outside microcapsules
Overlay film is known as wall material.
Wherein, core material is leuco dye and solvent naphtha, and leuco dye is dissolved in solvent naphtha.Write or printing when generate compared with
Big pressure, microcapsules are crushed, and so that the solvent naphtha containing leuco dye is flowed out and is absorbed by the coating on lower layer's paper, in turn
It is contacted with color developing agent, chromogenic reaction occurs, to achieve the purpose that manifolding.
In current techniques, carbonless paper microcapsules generally use melamine resin and polyurethane resin as wall
Material, the two contain formaldehyde and isocyanates respectively, there is different degrees of pollution, and the latter's higher cost to environment.Therefore, exist
Domestic 95% or more carbonless paper uses melamine resin.Present inventor is in long-term R&D process, discovery
Melamine resin is because of only one carbon body paper connection between melamine rings, and rigidity is larger, and the brittleness of wall shell is big, is transporting
It is easily broken during defeated, is easy to produce paper pollution problem.Meanwhile preparing melamine resin using formaldehyde as raw material,
Therefore, production process and not environmentally, and the microcapsules produced may contain residues of formaldehyde object, to mucocutaneous irritating
Effect.
In view of the above-mentioned problems, the application provides a kind of carbonless paper environmental-friendly microcapsule, it is based on parts by weight, carbon-free multiple
Writing paper environmental-friendly microcapsule includes 50-100 parts of leuco dye 2-6 parts (such as 2 parts, 3 parts, 4 parts, 5 parts or 6 parts), solvent naphtha (examples
Such as 50 parts, 60 parts, 70 parts, 80 parts or 100 parts), 7-20 parts of 3-8 parts of emulsifier (such as 3 parts, 5 parts, 7 parts or 8 parts), wall material (examples
Such as 7 parts, 11 parts, 15 parts or 20 parts), 30-100 parts of water (such as 30 parts, 50 parts, 70 parts or 100 parts).Wherein, wall material is trimerization
The more carbon dialdehyde performed polymers of cyanamide.
Specifically, the carbon atom number of the more carbon dialdehyde performed polymers of melamine is 2-10 (such as 2,4,6,8 or 10).Its
In, the more carbon dialdehyde performed polymers of melamine can be the more carbon dialdehyde performed polymers of hexa methoxy melamine, hexa methoxy melamine
The more carbon of amine one of more carbon octanal performed polymers of aldehyde performed polymer, hexa methoxy melamine or a variety of.The more carbon two of melamine
Aldehyde performed polymer can carry out synthetic reaction with more carbon dialdehyde by melamine and its derivative and be prepared, for example, melamine
Melamine glyoxal resin or hexa methoxy melamine is prepared in amine and glyoxal and pregnancy is prepared in suberic aldehyde
Oxygroup melamine suberic aldehyde urea formaldehyde etc..Due to what is connected between the melamine rings in the more carbon dialdehyde performed polymers of melamine
Carbon atom number increases, and therefore, increases the flexibility of wall material, the brittleness for reducing wall shell avoids to promote the toughness of microcapsules
Paper caused by microcapsules rupture pollutes in transportational process, reduces use cost.Simultaneously as the more carbon dialdehyde pre-polymerizations of melamine
The preparation of body is not to prepare raw material with formaldehyde, therefore, can reduce the pollution to environment.
Wherein, microcapsules may include: oil soluble interfacial activating agent, which can be oleic acid diethyl
Alkylolamides, dioctyl sodium sulfosuccinate, sorbitan mono-laurate (Span-20), sorbitan monopalmitate
(Span-40), sorbitan monostearate (Span-60), sorbitan monooleate (Span-80), polyoxyethylene
Sorbitan mono-laurate (Tween-20), polyoxyethylene 20 sorbitan monopalmitate (Tween-40), polyoxy second
In alkene sorbitan monostearate (Tween-60), polyoxyethylene 20 sorbitan monooleate (Tween-80) at least
It is a kind of；In an application scenarios, above-mentioned oil soluble interfacial activating agent can be in the core material of microcapsules, in other application scenarios
In, can also microcapsules other structures it is medium；When making above-mentioned microcapsules rupture by certain pressure, oil soluble interfacial activity
The presence of agent can reduce the surface tension of the core material of outflow, promote the spreadability of core material, so that the lines displayed
Width increases.
Specifically, it is in solid state that pigment (such as leuco dye etc.) is most of at room temperature in microcapsules, can not with it is aobvious
Toner chemically reacts, and solvent naphtha is needed to dissolve in advance；In an application scenarios, solvent naphtha include diarylethane,
At least one in isopropyl naphthalene, isopropyl biphenyl, soybean oil, peanut oil, castor oil, coconut oil, palm oil and its modified product
Kind.
Leuco dye is the substance chemically reacted with color developing agent, including anilino fluorane type dye, phthalide type dye
At least one of.Emulsifier includes at least one of polyacrylate, polystyrene maleic anhydride salt or polyamide salt.
Based on parts by weight, the ingredient of carbonless paper environmental-friendly microcapsule further include 0.2-2 parts of pH adjusting agents (such as
0.2 part, 0.4 part, 0.8 part, 1.5 parts or 2 parts).PH adjusting agent is mainly used for the pH value of regulation system, such as ties up system pH
It holds in 8-10 (such as 8,8.5,9.5 or 10), microcapsules can be made convenient for saving, pH adjusting agent includes sodium hydroxide, ammonium hydroxide, carbon
At least one of sour hydrogen trisodium, disodium hydrogen phosphate.
The application also provides a kind of coating of carbonless paper, and based on parts by weight, which includes nothing as described above
Carbon carbon paper is with 50-100 parts of environmental-friendly microcapsule (such as 50 parts, 60 parts, 70 parts, 80 parts or 100 parts), 20-80 parts of (examples of interval dose
Such as 20 parts, 40 parts, 60 parts, 70 parts or 80 parts), 5-25 parts of adhesive (such as 5 parts, 10 parts, 15 parts, 20 parts or 25 parts), thickening
0-3 parts of agent (such as 0 part, 1 part, 2 parts or 3 parts), the 0-3 of resistance to hydrated agent parts (such as 0 part, 1 part, 2 parts or 3 parts), interfacial agent
0-1 parts (such as 0 part, 0.2 part, 0.4 part, 0.6 part or 1 part).Introduction in relation to carbonless paper environmental-friendly microcapsule, herein not
It carries out going to live in the household of one's in-laws on getting married again and chat, details refer to explanation above.
Microcapsules are influenced in coating process or by external force and are ruptured too early in order to prevent, and interval dose is in coating can not
Lack.Interval dose can for potato starch, cornstarch, tapioca, wheaten starch or cellulose, the dosage of interval dose
For 20-80 parts by weight.
The effect of adhesive is to be bonded together microcapsules and interval dose with paper.Adhesive can be esterification starch, gather
Vinyl alcohol, potato starch, cornstarch, tapioca, wheaten starch, carboxymethylcellulose sodium, modified starch, one in latex
Kind is a variety of.Modified starch includes phosphoric acid modification starch, acetic acid modified starch etc., and latex includes styrene-acrylic latex, styrene-butadiene latex.Glue
The dosage of glutinous agent is 5-25 parts by weight, and dosage influences to develop the color and aggravate the warpage of coating paper too much, and dosage does not have bonding very little
Effect generates picking (microcapsules and interval dose being coated on paper fall off), also will affect the use of paper when serious.
Resistance to hydrated agent can be the poly- urea of polyamide (PAPU), potassium zirconium carbonate (KZC), zirconium carbonate ammonium (AZC), polyamine polycyclic
Oxygen type resin (PAPE), Lauxite, glyoxal or melamine resin.Tackifier can be modified ammonia polyol carboxylic acid salt
With Sodium Polyacrylate copolymer.Interfacial agent can for one of sulfosuccinate, acetylene ethylene glycol or more than one
Coating provided by the present application includes carbonless paper environmental-friendly microcapsule, in carbonless paper environmental-friendly microcapsule
In ingredient, using the more carbon dialdehyde performed polymers of melamine as wall material, due to the trimerization in the more carbon dialdehyde performed polymers of melamine
The carbon atom number connected between cyanamide ring increases, and therefore, increases the flexibility of wall material, the brittleness of wall shell is reduced, to be promoted micro-
The toughness of capsule avoids paper caused by microcapsules rupture during transportation from polluting, and reduces use cost.Simultaneously as three
The preparation of the more carbon dialdehyde performed polymers of poly cyanamid is not to prepare raw material with formaldehyde, therefore, can reduce the pollution to environment.
The application also provides a kind of carbonless paper, and carbonless paper includes: body paper；The one of body paper is arranged in back coating
Surface.Back coating is coated with by carbon-free copying paper paint as described above, wherein based on parts by weight, carbonless paper applies
Material, with 50-100 parts of environmental-friendly microcapsule, 20-80 parts of interval dose, 5-25 parts of adhesive, increases comprising carbonless paper as described above
Thick dose 0-3 parts, the 0-3 of resistance to hydrated agent parts, 0-1 parts of interfacial agent.In relation to carbon-free copying paper paint and carbonless paper environmental protection
The introduction of microcapsules no longer carries out going to live in the household of one's in-laws on getting married herein and chat, and details refer to explanation above.
The application also provides a kind of preparation method of carbonless copying paper microcapsule.Refering to fig. 1, Fig. 1 is the application one kind
The flow diagram of one embodiment of preparation method of carbonless copying paper microcapsule.The preparation method the following steps are included:
Step S11: based on parts by weight, it is dissolved in 50-100 parts molten under heating conditions by 2-6 parts of leuco dye
In agent oil, core material is obtained.
Specifically, based on parts by weight, by 2-6 parts of leuco dye (such as 2 parts, 3 parts, 4 parts, 5 parts or 6 parts) in heating
Under the conditions of be dissolved in the solvent naphtha of 50-100 parts (such as 50 parts, 60 parts, 70 parts, 80 parts or 100 parts), obtain core material.
Step S12: it will be added in 30-100 parts of water, be sufficiently stirred laggard in 50-100 parts of core materials and 3-8 parts of emulsifiers
Row is primary emulsifying, and 7-20 parts of wall materials are added after reaching predetermined size, are sufficiently stirred to obtain lotion.
Specifically, by the emulsifier of 3-8 parts by weight (such as 3 parts, 5 parts, 7 parts or 8 parts) and 50-100 parts by weight (such as 50
Part, 60 parts, 70 parts, 80 parts or 100 parts) core material be added in 30-100 parts of (such as 30 parts, 50 parts, 70 parts or 100 parts) water,
It is mixed, is then emulsified under certain revolving speed, obtain (2 μm -7 μm, such as 2 μm, 3 μm, 4 μm, 5 μm or 7 of predetermined size
μm) lotion.The wall material of 7-20 parts by weight (such as 7 parts, 11 parts, 15 parts or 20 parts) is slowly added into while stirring
In the good lotion of above-mentioned emulsification, stir evenly.
Step S13: lotion is gradually warming up to 75-110 DEG C of progress curing molding in the case of stirring, is made carbon-free multiple
Write paper environmental-friendly microcapsule.
Specifically, it is gradually warming up to 75-110 DEG C (such as 75 DEG C, 80 DEG C, 85 DEG C, 90 DEG C or 100 DEG C) and keeps the temperature 3-5 hours
(such as 3 hours, 4 hours or 5 hours), carbonless paper environmental-friendly microcapsule is made in curing molding.
Step S14: it is added after pH adjusting agent adjusts the pH of carbonless paper environmental-friendly microcapsule to 8-10 and saves for use.
Specifically, for the ease of the storage of microcapsules, the subsequent pH value that pH adjusting agent regulation system is just added will be carbon-free multiple
The pH for writing paper environmental-friendly microcapsule is adjusted to 8-10 (such as 8,8.5,9.5 or 10).PH adjusting agent include sodium hydroxide, ammonium hydroxide,
At least one of sodium sesquicarbonate, disodium hydrogen phosphate.
Carbonless copying paper microcapsule of the invention is described further below by specific embodiment.
Embodiment 1
The carbonless paper microcapsule formula of embodiment 1 is referring specifically to table 1:
1 carbonless paper microcapsule formula of table
The preparation method of the carbonless copying paper microcapsule of embodiment 1 includes the following steps:
Step 1-1: the leuco dye of 5 parts by weight is dissolved in the solvent naphtha of 70 parts by weight under conditions of addition and is obtained
Core material；
Step 1-2: the emulsifier of 3 parts by weight being added in above-mentioned core material, is emulsified after being sufficiently stirred, partial size control
System is at 2 μm -7 μm (such as 2 μm, 3 μm, 4 μm, 5 μm or 7 μm)；
Step 1-3: the wall material of 13 parts by weight is added in the lotion of step 1-2, and is stirred evenly；
Step 1-4: it is gradually warming up to 85 DEG C in the case of stirring and is solidified, carbonless copying paper microcapsule is made；
Step 1-5: it is saved after carbonless paper is adjusted to 8-10 with microcapsule emulsion pH stand-by.
The formula of the coating containing the carbonless copying paper microcapsule of embodiment 1: contain in the coating of the carbonless paper
60 parts of environment-friendly toughened capsule, 70 parts of the modified wheat starch for thering is embodiment 1 to prepare, 15 parts of adhesive, sodium carboxymethylcellulose 1
Part, 1 part, 0.8 part of interfacial agent of the resistance to hydrated agent of PAPU.It is 30% that said components, which are added water and stirred rear adjusting coating solid content,
One surface of body paper is coated in the case where Coating Speed is the curtain coating mode of 1100m/min speed, it is carbon-free multiple to prepare
Write paper.
Embodiment 2
The carbonless paper microcapsule formula of embodiment 2 is referring specifically to table 2:
2 carbonless paper microcapsule formula of table
The preparation method of the carbonless copying paper microcapsule of embodiment 2 includes the following steps:
Step 2-1: the leuco dye of 5 parts by weight is dissolved in the solvent naphtha of 70 parts by weight under conditions of addition and is obtained
Core material；
Step 2-2: the emulsifier of 3 parts by weight being added in above-mentioned core material, is emulsified after being sufficiently stirred, partial size control
System is at 2 μm -7 μm (such as 2 μm, 3 μm, 4 μm, 5 μm or 7 μm)；
Step 2-3: the wall material of 15 parts by weight is added in the lotion of step 2-2, and is stirred evenly；
Step 2-4: it gradually heats up 95 DEG C solidified in the case of stirring, carbonless copying paper microcapsule is made；
Step 2-5: it is saved after carbonless paper is adjusted to 8-10 with microcapsule emulsion pH stand-by.
The formula of the coating containing the carbonless copying paper microcapsule of embodiment 2: contain in the coating of the carbonless paper
60 parts of environment-friendly toughened capsule, 70 parts of the modified wheat starch for thering is embodiment 2 to prepare, 15 parts of adhesive, sodium carboxymethylcellulose 1
Part, 1 part, 0.8 part of interfacial agent of the resistance to hydrated agent of PAPU.It is 30% that said components, which are added water and stirred rear adjusting coating solid content,
One surface of body paper is coated in the case where Coating Speed is the curtain coating mode of 1100m/min speed, it is carbon-free multiple to prepare
Write paper.
Embodiment 3
The carbonless paper microcapsule formula of embodiment 3 is referring specifically to table 3:
3 carbonless paper microcapsule formula of table
The preparation method of the environmental-friendly microcapsule of embodiment 3 includes the following steps:
Step 3-1: the leuco dye of 5 parts by weight is dissolved in the solvent naphtha of 70 parts by weight under conditions of addition and is obtained
Core material；
Step 3-2: the emulsifier of 3 parts by weight being added in above-mentioned core material, is emulsified after being sufficiently stirred, partial size control
System is at 2 μm -7 μm (such as 2 μm, 3 μm, 4 μm, 5 μm or 7 μm)；
Step 3-3: the wall material of 18 parts by weight is added in the lotion of step 3-2, and is stirred evenly；
Step 3-4: it gradually heats up 110 DEG C solidified in the case of stirring, carbonless copying paper microcapsule is made；
Step 3-5: it is saved after carbonless paper is adjusted to 8-10 with microcapsule emulsion pH stand-by.
The formula of the coating containing the carbonless copying paper microcapsule of embodiment 3: it is prepared in the coating containing embodiment 3
60 parts of environmentally friendly capsule, 70 parts of modified wheat starch, 15 parts of adhesive, 1 part of sodium carboxymethylcellulose, 1 part of the resistance to hydrated agent of PAPU,
0.8 part of interfacial agent.It is 30% that said components, which are added water and stirred rear adjusting coating solid content, is 1100m/ in Coating Speed
A surface of body paper is coated under the curtain coating mode of min speed, to prepare carbonless paper.
In above-described embodiment, wall material uses melamine resin, and solvent naphtha is all made of phenyl xylyl ethylbenzene, leads to
The carbonless paper microcapsule formula using above-described embodiment is crossed, prepares microcapsules and coating, and be coated to body paper, with
Carbonless paper is prepared, and the chromophoric characteristic of carbonless paper is tested, chromophoric characteristic comparing result refers to table 4.By
Table 4 as can be seen that with it is traditional using hexa methoxy melamine resin performed polymer as the microcapsules of wall material compared with, make
The carbonless paper paper cleannes prepared with carbonless copying paper microcapsule are obviously improved, this illustrates carbonless paper with micro-
Capsule not only has the effect of environmental protection, while having preferable toughening effect.
The comparison of 4 chromophoric characteristic of table
The above is only presently filed embodiments, are not intended to limit the scope of the patents of the application, all to utilize the application
Equivalent structure or equivalent flow shift made by specification and accompanying drawing content is applied directly or indirectly in other relevant technologies
Field similarly includes in the scope of patent protection of the application.
Claims (10)
1. a kind of carbonless paper environmental-friendly microcapsule, which is characterized in that based on parts by weight, the carbonless paper environmental protection
Microcapsules include 2-6 parts of leuco dyes, 50-100 parts of solvent naphthas, 3-8 parts of emulsifiers, 7-20 parts of wall materials, 30-100 parts of water；
Wherein, the wall material is the more carbon dialdehyde performed polymers of melamine.
2. carbonless paper environmental-friendly microcapsule according to claim 1, which is characterized in that the more carbon two of melamine
The carbon atom number of aldehyde performed polymer is 2-10；
Wherein, the more carbon dialdehyde performed polymers of the melamine are the more carbon dialdehyde performed polymers of hexa methoxy melamine, hexa methoxy
The more carbon of melamine one of more carbon octanal performed polymers of aldehyde performed polymer, hexa methoxy melamine or a variety of.
3. carbonless paper environmental-friendly microcapsule according to claim 1, which is characterized in that the emulsifier is polyphenyl second
At least one of alkene maleic anhydride salt or polyacrylate.
4. carbonless paper environmental-friendly microcapsule according to claim 1, which is characterized in that based on parts by weight, described
The ingredient of carbonless paper environmental-friendly microcapsule further includes 0.2-2 parts of pH adjusting agents.
5. a kind of carbon-free copying paper paint, which is characterized in that based on parts by weight, the carbon-free copying paper paint includes such as right
It is required that the described in any item carbonless paper of 1-4 are with 50-100 parts of environmental-friendly microcapsule, 20-80 parts of interval dose, 5-25 parts of adhesive,
0-3 parts of thickener, the 0-3 of resistance to hydrated agent parts, 0-1 parts of interfacial agent.
6. carbon-free copying paper paint according to claim 4, which is characterized in that the interval dose is wheaten starch and its changes
One of property product is a variety of；The adhesive is esterification starch, one of styrene-butadiene latex, styrene-acrylic latex, polyvinyl alcohol
Or it is a variety of.
7. a kind of carbonless paper, which is characterized in that the carbonless paper includes:
Body paper；
A surface of the body paper is arranged in back coating；
The back coating is coated with by carbon-free copying paper paint, wherein based on parts by weight, the carbon-free copying paper paint packet
It is 0-3 parts of thickener, water-fast containing carbonless paper with 50-100 parts of environmental-friendly microcapsule, 20-80 parts of interval dose, 5-25 parts of adhesive
0-3 parts of agent, 0-1 parts of interfacial agent.
8. carbonless paper according to claim 7, which is characterized in that based on parts by weight, the carbonless paper is used
Environmental-friendly microcapsule includes 2-6 parts of leuco dyes, 50-100 parts of solvent naphthas, 3-8 parts of emulsifiers, 7-20 parts of wall materials, 30-100 parts of water；
Wherein, the wall material is the more carbon dialdehyde performed polymers of melamine,.
9. carbonless paper according to claim 8, which is characterized in that the carbon of the more carbon dialdehyde performed polymers of melamine
Atom number is 2-10；
Wherein, the more carbon dialdehyde performed polymers of the melamine are the more carbon dialdehyde performed polymers of hexa methoxy melamine, hexa methoxy
The more carbon of melamine one of more carbon octanal performed polymers of aldehyde performed polymer, hexa methoxy melamine or a variety of.
10. a kind of preparation method of carbonless paper environmental-friendly microcapsule, which is characterized in that be used to prepare such as claim 1-3
Described in any item carbonless paper environmental-friendly microcapsules, the preparation method include:
Based on parts by weight, 2-6 parts of leuco dyes are dissolved under heating conditions in 50-100 parts of solvent naphtha, obtain core
Material；
It will be added in 30-100 parts of water in the 50-100 parts of core material and 3-8 parts of emulsifiers, preliminary cream carried out after being sufficiently stirred
Change, 7-20 parts of wall materials are added after reaching predetermined size, are sufficiently stirred to obtain lotion；
The lotion is gradually warming up to 75-110 DEG C of progress curing molding in the case of stirring, carbonless paper ring is made
Protect microcapsules；
It is added after pH adjusting agent adjusts the pH of carbonless paper environmental-friendly microcapsule to 8-10 and saves for use.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810718105.9A CN109098034A (en) | 2018-07-03 | 2018-07-03 | Carbonless copying paper microcapsule and preparation method thereof, carbonless paper and its coating |
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| CN201810718105.9A CN109098034A (en) | 2018-07-03 | 2018-07-03 | Carbonless copying paper microcapsule and preparation method thereof, carbonless paper and its coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110607711A (en) * | 2019-08-02 | 2019-12-24 | 金华盛纸业（苏州工业园区）有限公司 | Carbonless copy paper, coating, microcapsule for carbonless copy paper and preparation method thereof |
| CN111304961A (en) * | 2020-02-25 | 2020-06-19 | 金华盛纸业（苏州工业园区）有限公司 | Microcapsule for carbonless copy paper, preparation method of microcapsule, carbonless copy paper and coating of carbonless copy paper |
| CN115748297A (en) * | 2021-05-26 | 2023-03-07 | 刘兴发 | Carbon paper with flame retardant property |
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| CN104936573A (en) * | 2012-11-27 | 2015-09-23 | 国际香料和香精公司 | Dispersed capsules in lyotropic or lyotropic liquid crystal surfactant phases for enhanced capsule deposition |
| CN106320081A (en) * | 2016-08-24 | 2017-01-11 | 金华盛纸业（苏州工业园区）有限公司 | Environment-friendly microcapsule of carbonless copy paper and preparing method thereof, coating of carbonless copy paper |
| CN107787215A (en) * | 2015-06-30 | 2018-03-09 | 弗门尼舍有限公司 | Improve the delivery system of deposition |
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| CN104936573A (en) * | 2012-11-27 | 2015-09-23 | 国际香料和香精公司 | Dispersed capsules in lyotropic or lyotropic liquid crystal surfactant phases for enhanced capsule deposition |
| CN107787215A (en) * | 2015-06-30 | 2018-03-09 | 弗门尼舍有限公司 | Improve the delivery system of deposition |
| CN106320081A (en) * | 2016-08-24 | 2017-01-11 | 金华盛纸业（苏州工业园区）有限公司 | Environment-friendly microcapsule of carbonless copy paper and preparing method thereof, coating of carbonless copy paper |
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| CN110607711A (en) * | 2019-08-02 | 2019-12-24 | 金华盛纸业（苏州工业园区）有限公司 | Carbonless copy paper, coating, microcapsule for carbonless copy paper and preparation method thereof |
| CN111304961A (en) * | 2020-02-25 | 2020-06-19 | 金华盛纸业（苏州工业园区）有限公司 | Microcapsule for carbonless copy paper, preparation method of microcapsule, carbonless copy paper and coating of carbonless copy paper |
| CN115748297A (en) * | 2021-05-26 | 2023-03-07 | 刘兴发 | Carbon paper with flame retardant property |
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Application publication date: 20181228 |