CN109098011A - A method of utilizing natural indigo dye denim yarn - Google Patents
A method of utilizing natural indigo dye denim yarn Download PDFInfo
- Publication number
- CN109098011A CN109098011A CN201810946792.XA CN201810946792A CN109098011A CN 109098011 A CN109098011 A CN 109098011A CN 201810946792 A CN201810946792 A CN 201810946792A CN 109098011 A CN109098011 A CN 109098011A
- Authority
- CN
- China
- Prior art keywords
- leuco compound
- concentration
- yarn
- sodium
- dye liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 59
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 title claims abstract description 49
- COHYTHOBJLSHDF-BUHFOSPRSA-N indigo dye Chemical compound N\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-BUHFOSPRSA-N 0.000 title claims abstract description 23
- 150000001875 compounds Chemical class 0.000 claims abstract description 117
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 75
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims abstract description 70
- 238000004043 dyeing Methods 0.000 claims abstract description 44
- 239000003381 stabilizer Substances 0.000 claims abstract description 35
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 230000003647 oxidation Effects 0.000 claims abstract description 28
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims abstract description 26
- 229940097275 indigo Drugs 0.000 claims abstract description 26
- 230000000149 penetrating effect Effects 0.000 claims abstract description 23
- 238000002203 pretreatment Methods 0.000 claims abstract description 20
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 10
- 230000001590 oxidative effect Effects 0.000 claims abstract description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 8
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- 229920000742 Cotton Polymers 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 142
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 239000012452 mother liquor Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 13
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 10
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 10
- 150000004056 anthraquinones Chemical class 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 6
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 238000009738 saturating Methods 0.000 claims 1
- 230000009467 reduction Effects 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 238000002386 leaching Methods 0.000 abstract 1
- 238000012805 post-processing Methods 0.000 abstract 1
- 241001062009 Indigofera Species 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 6
- 239000008103 glucose Substances 0.000 description 6
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 6
- 238000013112 stability test Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 238000009970 yarn dyeing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/228—Indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65112—Compounds containing aldehyde or ketone groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/6025—Natural or regenerated cellulose using vat or sulfur dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of methods using natural indigo dye denim yarn, oxidizing process is repeatedly padded using leuco compound to dye cowboy's cotton, stock vatting under the conditions of 40 ~ 50 DEG C, natural indigo 0.5 ~ 2g/L, 1.5 ~ 4.5g/L of sodium hydroxide, 0.75 ~ 1.8 g/L of sodium hydrosulfite, 0.25 ~ 0.6g/L of sodium hydrosulfite stabilizer, 10 ~ 15g/L of accelerant sodium chloride or sodium sulphate, penetrating agent JFC 2g/L, denim yarn is dyed according to yarn dye pre-treatment → dyeing → oxidation → dyeing → oxidation → dyeing → oxidation → dyeing → oxidation → dyeing → oxidation → dyeing → oxidation → post-processing technique, the present invention is using repeatedly leaching, it rolls, the dyefastness of denim yarn can be improved in the colouring method of oxidation, dyeing, oxidation can be in room temperature condition Lower progress, is not required to heat, energy conservation and environmental protection, is restored using sodium hydrosulfite method, and rate of reduction is high, and dyeing effect is stablized.
Description
Technical field
The invention belongs to the staining technique fields of fabric, and in particular to a kind of side using natural indigo dye denim yarn
Method.
Background technique
Natural pigment is born in nature finally naturally, being compatible with the environment property is good, biodegradable, will not generate toxic object
Matter, will not be to skin irritant, more without carcinogenicity.Naturally indigo is to contain Yin with indigo plant, woaded blue, the wooden indigo plant, acanthaceous indigo etc.
It is a kind of reducing dye made of the plant leaf fermentation of diindyl sour component, it is not soluble in water, there is no affinity to fiber.When dyeing,
Indigo reduction need to can be just dissolved in water at leuco compound, have affinity to fiber, dye fiber can be gone up.Indigo restoring method has
Fermentation method, sodium hydrosulfite method, thiourea dioxide method etc..Wherein, fermentation method application is earliest, its advantage is that equipment is simple, production cost
It is cheap；The disadvantage is that needing a large amount of cumbersome manual operations, and reduction is slow, it usually needs procrypsis could be formed within 7 ~ 10 days
Body, production efficiency is low, is unable to continuous production.Thiourea dioxide method stability is poor, easily generation over reduction, causes under dye-uptake
Drop.Sodium hydrosulfite method reduction rate is fast, easy to operate, but sodium hydrosulfite stability is poor, meets water reaction acutely, generates a large amount of invalid point
Solution, need to often be excessively used, sodium hydrosulfite stabilizer is the compound of a variety of reducing agents, and sulfur-bearing, not tasteless, can be had in process of production
Effect reduces the decomposition of sodium hydrosulfite, therefore, sodium hydrosulfite reduction method is used in the present patent application, is taken a policy in reduction system
Powder stabilizer significantly reduces the dosage of sodium hydrosulfite, reaches save the cost, the purpose improved efficiency.
Indigo leuco compound is low to the affinity of cotton fiber, and dye-uptake is low, using the side for improving dye liquor concentration and dyeing temperature
Method promotes to contaminate on leuco compound, it may appear that the problems such as colour brightness is deteriorated, reproducibility is poor, poor color fastness.Therefore, of the invention
It is dyed in application using low concentration, room temperature, denim yarn is dyed by the method repeatedly soaked, roll, aoxidized.
Summary of the invention
Aiming at the problems existing in the prior art, the present invention provides a kind of method using natural indigo dye denim yarn,
Meet demand of the people to environmental protection and health.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A method of using natural indigo dye denim yarn, oxidizing process repeatedly being padded to cowboy's cotton using leuco compound dye liquor
It is dyed, steps are as follows:
(1) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 60 ~ 65%；
(2) dye: by through contaminate pre-treatment denim yarn be put into leuco compound dye liquor, under the conditions of 20 ~ 35 DEG C impregnate 10 ~
After 15min, padding machine roll compacting；
(3) it aoxidizes: denim yarn air oxidation under the conditions of 20 ~ 35 DEG C after dyeing；
(4) (2) are repeated, (3) operate 5 times；
(5) it post-processes: the yarn after oxidation being washed, squezzing, drying.
The leuco compound dye liquor includes that the raw material of following portions by weight is made: natural indigo 0.5 ~ 2g/L, sodium hydroxide 1.5
~ 4.5g/L, 0.75 ~ 1.8 g/L of sodium hydrosulfite, 0.25 ~ 0.6g/L of sodium hydrosulfite stabilizer, penetrating agent JFC 2g/L, accelerant 10 ~
15g/L。
The sodium hydrosulfite stabilizer is made of the component that following weight matches: glucose 40% ~ 50%, sodium hypophosphite 30% ~
40%, surplus is anthraquinone.
The accelerant is sodium chloride or sodium sulphate.
The preparation step of the leuco compound dye liquor is as follows:
A, dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
After mixing evenly, the insurance of formula ratio 2/3 is added in the 1/3 of the total liquid measure of leuco compound dye liquor, the sodium hydroxide that formula ratio 2/3 is added
Powder, the sodium hydrosulfite stabilizer of full dose, restores dyestuff sufficiently, and leuco compound mother liquor is made；
B, prepared by dye liquor: the water of surplus is added in dyeing cup, remaining sodium hydroxide and sodium hydrosulfite is added, is sufficiently stirred, dissolves,
Leuco compound mother liquor made from addition penetrating agent JFC, accelerant and step a, reaches the total liquid measure of leuco compound dye liquor, stirs evenly, and makes
Obtain leuco compound dye liquor.
Natural indigo concentration is that be equivalent to the concentration in leuco compound dye liquor be 0.5 ~ 2g/ to 1.5 ~ 6g/L(in the step a
L), it is 1 ~ 3g/L that 3 ~ 9g/L(of concentration of sodium hydroxide, which is equivalent to the concentration in leuco compound dye liquor), the concentration 1.5 ~ 3.6 of sodium hydrosulfite
It is 0.5 ~ 1.2 g/L that g/L(, which is equivalent to the concentration in leuco compound dye liquor), 0.75 ~ 1.8g/L(of concentration of sodium hydrosulfite stabilizer is suitable
In in leuco compound dye liquor concentration be 0.25 ~ 0.6g/L).
The concentration of sodium hydroxide is that 0.75 ~ 2.25g/L(is equivalent to hidden when leuco compound mother liquor not being added in the step b
Concentration is 0.5 ~ 1.5 g/L in colour solid dye liquor), the concentration of sodium hydrosulfite is that 0.375 ~ 0.9 g/L(is equivalent in leuco compound dye liquor
Concentration is 0.25 ~ 0.6 g/L), the concentration of penetrating agent JFC is that be equivalent to the concentration in leuco compound dye liquor be 2g/L to 3g/L(), promote
It is 10 ~ 15g/L that 15 ~ 22.5 g/L(of concentration of stain, which is equivalent to the concentration in leuco compound dye liquor).
The leuco compound repeatedly pads the pick-up 70% ~ 75% in oxidizing process step (2).
It is 1.5 ~ 2 min that the leuco compound, which repeatedly pads oxidization time in oxidizing process step (3),.
It is 40 ~ 50 DEG C that the leuco compound, which repeatedly pads the washing temperature in oxidizing process step (5), is washed 2 ~ 3 times, pick-up
60~65%。
Beneficial effects of the present invention: being dyed using room temperature, the colour brightness of dyeing product can be improved, dyeing reappears
Property, the dyefastness of denim yarn can be improved using the colouring method for repeatedly soaking, rolling, aoxidizing, dyeing, oxidation can be in rooms
It is carried out under the conditions of temperature, is not required to heat, energy conservation and environmental protection, restored using sodium hydrosulfite method, rate of reduction is high, and dyeing effect is stablized, insurance
The addition of powder stabilizer significantly improves the utilization rate and reducing power of sodium hydrosulfite, effectively reduces the decomposition of sodium hydrosulfite, is added
A small amount of sodium hydrosulfite stabilizer can reduce sodium hydrosulfite dosage 50%, and when reaching and sodium hydrosulfite stabilizer is not added, 100% dosage is protected
The almost consistent dyeing effect of dangerous powder.The aqueous solution containing bleeding agent is padded before dye, is made yarn wetting, extruding, is conducive to impregnate
Diffusion of the dyestuff to fibrous inside when dye liquor improves dyeing rate, be added in dye liquor accelerant can reduce leuco dye with
Repulsion effect between cellulose fibre, improves dye-uptake, penetrating agent JFC is added in dye liquor, is conducive to dye liquor to denim yarn
Internal infiltration improves fastness to rubbing, is not necessarily to soap after realizing denim yarn dyeing, greatly reduces water consumption.Pre-treatment is contaminated,
Bleeding agent and accelerant act synergistically in dye liquor, greatly reduce natural indigo dosage, realize extremely low concentration dyeing
Obtain the effect in darker pool.
Specific embodiment
Combined with specific embodiments below, the present invention will be further described.It should be understood that following embodiment is merely to illustrate this
The person skilled in the art of the range of invention and is not intended to limit the present invention, the field can make one according to the content of foregoing invention
A little nonessential modifications and adaptations.
Embodiment 1
The method of the natural indigo dye denim yarn of the utilization of the present embodiment, steps are as follows:
(1) dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
To the 1/3 of total liquid measure, at this point, it is 0.5 g/L that natural indigo concentration, which is the concentration that 1.5g/L(is equivalent in leuco compound dye liquor),
It is 1 g/L that sodium hydroxide 3g/L(, which is added, and is equivalent to the concentration in leuco compound dye liquor), 1.5 g/L(of sodium hydrosulfite is equivalent to hidden
Concentration in colour solid dye liquor is 0.5 g/L), the concentration that 0.75 g/L(of sodium hydrosulfite stabilizer is equivalent in leuco compound dye liquor is
0.25g/L), it restores dyestuff sufficiently, leuco compound mother liquor is made；Wherein sodium hydrosulfite stabilizer is by following weight
The component of proportion is made: glucose 40%, sodium hypophosphite 30%, surplus are anthraquinone；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 0.75g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 0.5g/L), sodium hydrosulfite 0.375g/L(be equivalent to the concentration in leuco compound dye liquor be 0.25g/L), be sufficiently stirred,
Dissolution is added penetrating agent JFC 3g/L(and is equivalent to the concentration in leuco compound dye liquor as 2g/L), accelerant sodium chloride 15g/L
(being equivalent to the concentration in leuco compound dye liquor is 10g/L), leuco compound mother liquor, stir evenly, leuco compound dye liquor are made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 60%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 10min under the conditions of 20 DEG C, roll
Vehicle roll compacting, pick-up 70%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 2min under the conditions of 20 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 2 times under the conditions of 40 DEG C, then pick-up 60% is dried.
Embodiment 2
The method of the natural indigo dye denim yarn of the utilization of the present embodiment, steps are as follows:
(1) dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
To the 1/3 of total liquid measure, at this point, it is 2 g/L that natural indigo concentration, which is the concentration that 6g/L(is equivalent in leuco compound dye liquor), it is added
It is 3 g/L that sodium hydroxide 9g/L(, which is equivalent to the concentration in leuco compound dye liquor), 3.6 g/L(of sodium hydrosulfite is equivalent in leuco compound
Concentration in dye liquor is 1.2 g/L), it is 0.6 g/ that 1.8 g/L(of sodium hydrosulfite stabilizer, which is equivalent to the concentration in leuco compound dye liquor,
L), restore dyestuff sufficiently, leuco compound mother liquor is made；Wherein sodium hydrosulfite stabilizer is matched by following weight
Component is made: glucose 50%, sodium hypophosphite 40%, surplus are anthraquinone；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 2.25g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 1.5g/L), sodium hydrosulfite 0.9g/L(be equivalent to the concentration in leuco compound dye liquor be 0.6g/L), be sufficiently stirred, be molten
Solution is added penetrating agent JFC 3g/L(and is equivalent to the concentration in leuco compound dye liquor as 2g/L), accelerant sodium sulphate 22.5g/L
(being equivalent to the concentration in leuco compound dye liquor is 15g/L), leuco compound mother liquor, stir evenly, leuco compound dye liquor are made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 65%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 15min under the conditions of 35 DEG C, roll
Vehicle roll compacting, pick-up 75%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 1.5min under the conditions of 35 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 3 times under the conditions of 50 DEG C, then pick-up 65% is dried.
Embodiment 3
The method of the natural indigo dye denim yarn of the utilization of the present embodiment, steps are as follows:
(1) dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
To the 1/3 of total liquid measure, at this point, it is 1.3 g/L that natural indigo concentration, which is the concentration that 3.9g/L(is equivalent in leuco compound dye liquor),
It is 2g/L that sodium hydroxide 6g/L(, which is added, and is equivalent to the concentration in leuco compound dye liquor), 2.4 g/L(of sodium hydrosulfite is equivalent in procrypsis
Concentration in body dye liquor is 0.8 g/L), it is 0.4 that 1.2 g/L(of sodium hydrosulfite stabilizer, which is equivalent to the concentration in leuco compound dye liquor,
G/L), restore dyestuff sufficiently, leuco compound mother liquor is made；Wherein sodium hydrosulfite stabilizer is matched by following weight
Component be made: glucose 40%, sodium hypophosphite 40%, surplus are anthraquinone；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 1.5g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 1g/L), sodium hydrosulfite 0.6g/L(be equivalent to the concentration in leuco compound dye liquor be 0.4g/L), be sufficiently stirred, dissolve,
It is suitable for 2g/L), accelerant sodium chloride 19.5g/L(that addition penetrating agent JFC 3g/L(is equivalent to the concentration in leuco compound dye liquor
It is 13g/L), leuco compound mother liquor in the concentration in leuco compound dye liquor, stirs evenly, leuco compound dye liquor is made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 63%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 13min under the conditions of 30 DEG C, roll
Vehicle roll compacting, pick-up 73%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 1.8min under the conditions of 30 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 2 times under the conditions of 45 DEG C, then pick-up 63% is dried.
Embodiment 4
The method of the natural indigo dye denim yarn of the utilization of the present embodiment, steps are as follows:
(1) dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
To the 1/3 of total liquid measure, at this point, it is 0.9 g/L that natural indigo concentration, which is the concentration that 2.7g/L(is equivalent in leuco compound dye liquor),
It is 1.6g/L that sodium hydroxide 4.8g/L(, which is added, and is equivalent to the concentration in leuco compound dye liquor), 1.8 g/L(of sodium hydrosulfite is equivalent to
Concentration in leuco compound dye liquor is 0.6 g/L), the concentration that 0.9 g/L(of sodium hydrosulfite stabilizer is equivalent in leuco compound dye liquor is
0.3g/L), it restores dyestuff sufficiently, leuco compound mother liquor is made；Wherein sodium hydrosulfite stabilizer is by following weight
The component of proportion is made: glucose 45%, sodium hypophosphite 35%, surplus are anthraquinone；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 1.2g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 0.8g/L), sodium hydrosulfite 0.45g/L(be equivalent to the concentration in leuco compound dye liquor be 0.3g/L), be sufficiently stirred, be molten
Solution is added penetrating agent JFC 3g/L(and is equivalent to the concentration in leuco compound dye liquor as 2g/L), accelerant sodium sulphate 18g/L(phase
When being 12g/L), leuco compound mother liquor in the concentration in leuco compound dye liquor, stirs evenly, leuco compound dye liquor is made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 62%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 12min under the conditions of 25 DEG C, roll
Vehicle roll compacting, pick-up 72%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 1.5min under the conditions of 25 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 3 times under the conditions of 43 DEG C, then pick-up 62% is dried.
Embodiment 5
The method of the natural indigo dye denim yarn of the utilization of the present embodiment, steps are as follows:
(1) dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
To the 1/3 of total liquid measure, at this point, it is 1.6 g/L that natural indigo concentration, which is the concentration that 4.8g/L(is equivalent in leuco compound dye liquor),
It is 2.4g/L that sodium hydroxide 7.2g/L(, which is added, and is equivalent to the concentration in leuco compound dye liquor), 3 g/L(of sodium hydrosulfite is equivalent to hidden
Concentration in colour solid dye liquor is 1 g/L), it is 0.5 that 1.5 g/L(of sodium hydrosulfite stabilizer, which is equivalent to the concentration in leuco compound dye liquor,
G/L), restore dyestuff sufficiently, leuco compound mother liquor is made；Wherein sodium hydrosulfite stabilizer is matched by following weight
Component be made: glucose 50%, sodium hypophosphite 30%, surplus are anthraquinone；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 1.8g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 1.2g/L), sodium hydrosulfite 0.75g/L(be equivalent to the concentration in leuco compound dye liquor be 0.5g/L), be sufficiently stirred, be molten
Solution is added penetrating agent JFC 3g/L(and is equivalent to the concentration in leuco compound dye liquor as 2g/L), accelerant sodium sulphate 21g/L(phase
When being 14g/L), leuco compound mother liquor in the concentration in leuco compound dye liquor, stirs evenly, leuco compound dye liquor is made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 65%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 14min under the conditions of 32 DEG C, roll
Vehicle roll compacting, pick-up 74%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 1.5min under the conditions of 32 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 2 times under the conditions of 48 DEG C, then pick-up 65% is dried.
The measurement of fabric apparent shade depth K/S value: being measured with CE-7000A SCT high-precision colour photometer, using D65 light source and
10 ° of viewing angles, each sample are surveyed 4 times, are averaged.
Colour fastness to rubbing: it is carried out referring to GB/T 3920-2008 " textile color stability test colour fastness to rubbing "
Test.
Fastness to soaping: it is surveyed referring to GB/T 3921-2008 " textile color stability test fastness to soaping "
Examination.
Colour fastness to perspiration: it is surveyed referring to GB/T 3922-2013 " textile color stability test colour fastness to perspiration "
Examination.
Color fastness to daylight: referring to GB/T 8427-2008 " textile color stability test the color fastness of resistance to artificial light: xenon arc " into
Row test.
The K/S value and color fastness of denim yarn after table 1 is dyed according to embodiment 3
The K/S value and color fastness of denim yarn after table 2 is dyed according to embodiment 4
The color fastness for the dyeing denim yarn that table 1 is measured into table 2 is able to satisfy the requirement of denim fabric.
Comparative example 1
Sodium hydrosulfite stabilizer is not added according to the prescription of embodiment 4, with 2 times of sodium hydrosulfite amount, utilizes natural indigo dye denim yarn
Method, steps are as follows:
Then plus water (1) dyestuff prereduction: natural bipseudoindoxyl dye is put into beaker, and a small amount of alcohol is added and water is mixed well, and, is stirred
It mixes, reaches the 1/3 of total liquid measure, at this point, natural bipseudoindoxyl dye concentration is that the concentration that 2.7g/L(is equivalent in leuco compound dye liquor is
0.9 g/L), it is 1.6g/L that sodium hydroxide 4.8g/L(, which is added, and is equivalent to the concentration in leuco compound dye liquor), 3.6 g/L of sodium hydrosulfite
(being equivalent to the concentration in leuco compound dye liquor is 1.2 g/L), restores dyestuff sufficiently, it is female that leuco compound is made
Liquid；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 1.2g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 0.8g/L), sodium hydrosulfite 0.9g/L(be equivalent to the concentration in leuco compound dye liquor be 0.6g/L), be sufficiently stirred, be molten
Solution is added penetrating agent JFC 3g/L(and is equivalent to the concentration in leuco compound dye liquor as 2g/L), accelerant sodium sulphate 18g/L(phase
When being 12g/L), leuco compound mother liquor in the concentration in leuco compound dye liquor, stirs evenly, leuco compound dye liquor is made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 62%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 12min under the conditions of 25 DEG C, roll
Vehicle roll compacting, pick-up 72%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 1.5min under the conditions of 25 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 3 times under the conditions of 43 DEG C, then pick-up 62% is dried.
The K/S value and color fastness of denim yarn after subordinate list 1 is dyed according to comparative example 1
Sodium hydrosulfite dosage increases 1 times it can be seen from subordinate list 1, and sodium hydrosulfite stabilizer is not added, and (insures with sodium hydrosulfite stabilizer is added
Powder dosage does not increase) it compares, the K/S value of dyeing gained denim yarn is very close, and color fastness is consistent.This is because sodium hydrosulfite is steady
The effect for determining agent is to effectively improve the utilization rate and reducing power of sodium hydrosulfite, reduces the decomposition of sodium hydrosulfite, to significantly drop
Low sodium hydrosulfite dosage.
Comparative example 2
According to the prescription of embodiment 4, sodium hydrosulfite stabilizer all uses glucose, utilizes the side of natural indigo dye denim yarn
Method, steps are as follows:
(1) dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
To the 1/3 of total liquid measure, at this point, it is 0.9 g/L that natural indigo concentration, which is the concentration that 2.7g/L(is equivalent in leuco compound dye liquor),
It is 1.6g/L that sodium hydroxide 4.8g/L(, which is added, and is equivalent to the concentration in leuco compound dye liquor), 1.8 g/L(of sodium hydrosulfite is equivalent to
Concentration in leuco compound dye liquor is 0.6 g/L), 0.9 g/L(of sodium hydrosulfite stabilizer of single reducing component is equivalent in leuco compound
Concentration in dye liquor is 0.3g/L), it restores dyestuff sufficiently, leuco compound mother liquor is made；
(2) prepared by dye liquor: the water of surplus being added in dyeing cup, sodium hydroxide 1.2g/L(is added and is equivalent in leuco compound dye liquor
Concentration be 0.8g/L), sodium hydrosulfite 0.45g/L(be equivalent to the concentration in leuco compound dye liquor be 0.3g/L), be sufficiently stirred, be molten
Solution is added penetrating agent JFC 3g/L(and is equivalent to the concentration in leuco compound dye liquor as 2g/L), accelerant sodium sulphate 18g/L(phase
When being 12g/L), leuco compound mother liquor in the concentration in leuco compound dye liquor, stirs evenly, leuco compound dye liquor is made；
(3) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 62%；
(4) it dyes: the denim yarn through contaminating pre-treatment is put into leuco compound dye liquor, after impregnating 12min under the conditions of 25 DEG C, roll
Vehicle roll compacting, pick-up 72%；
(5) it aoxidizes: denim yarn after the dyeing air oxidation 1.5min under the conditions of 25 DEG C；
(6) (4) are repeated, (5) operate 5 times；
(7) post-process: the yarn after oxidation is washed 3 times under the conditions of 43 DEG C, then pick-up 62% is dried.
The K/S value and color fastness of denim yarn after subordinate list 2 is dyed according to comparative example 2
Comparative example 3
According to the prescription of embodiment 4, sodium hydrosulfite stabilizer all uses sodium hypophosphite, and the K/S value of denim yarn is after dyeing
4.8。
Comparative example 4
According to the prescription of embodiment 4, sodium hydrosulfite stabilizer all uses anthraquinone, and the K/S value of denim yarn is 5.4 after dyeing.
Comparative example 5
According to the prescription of embodiment 4, sodium hydrosulfite stabilizer all uses glucose and sodium hypophosphite, denim yarn after dyeing
K/S value is 6.9.
Comparative example 6
According to the prescription of embodiment 4, sodium hydrosulfite stabilizer all uses glucose and anthraquinone, the K/S value of denim yarn after dyeing
It is 7.1.
Comparative example 7
According to the prescription of embodiment 4, sodium hydrosulfite stabilizer all uses sodium hypophosphite and anthraquinone, the K/ of denim yarn after dyeing
S value is 6.5.
Sodium hydrosulfite stabilizer changes into containing one of or two kinds of reduction it can be seen from the coloration result of comparative example 2-7
Agent ingredient, dyeing gained denim yarn K/S value reduce, contaminate yarn color is shallower.This is because in sodium hydrosulfite stabilizer
Three kinds of reducing agents can act synergistically, effectively improve the utilization rate and reducing power of sodium hydrosulfite, reduce invalid point of sodium hydrosulfite
Solution cannot give full play to the synergistic effect of reduction components, lead to natural indigo reduction not after changing one of or two kinds of ingredients into
Sufficiently, dye utilization rate reduces, and yarn color is shallow after dyeing.
Basic principles and main features and advantages of the present invention of the invention have been shown and described above.The skill of the industry
Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe
The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these
Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and
Its equivalent thereof.
Claims (10)
1. a kind of method using natural indigo dye denim yarn, it is characterised in that: repeatedly pad oxidation using leuco compound dye liquor
Method dyes cowboy's cotton, and steps are as follows:
(1) yarn contaminates pre-treatment: being padded with the aqueous solution containing penetrating agent JFC 2g/L, pick-up 60 ~ 65%；
(2) dye: by through contaminate pre-treatment denim yarn be put into leuco compound dye liquor, under the conditions of 20 ~ 35 DEG C impregnate 10 ~
After 15min, padding machine roll compacting；
(3) it aoxidizes: denim yarn air oxidation under the conditions of 20 ~ 35 DEG C after dyeing；
(4) (2) are repeated, (3) operate 5 times；
(5) it post-processes: the yarn after oxidation being washed, squezzing, drying.
2. the method according to claim 1 using natural indigo dye denim yarn, it is characterised in that: the leuco compound dye
Liquid includes that the raw material of following portions by weight is made: natural indigo 0.5 ~ 2g/L, 1.5 ~ 4.5g/L of sodium hydroxide, sodium hydrosulfite 0.75 ~
1.8 g/L, 0.25 ~ 0.6g/L of sodium hydrosulfite stabilizer, penetrating agent JFC 2g/L, 10 ~ 15g/L of accelerant.
3. the method according to claim 1 using natural indigo dye denim yarn, it is characterised in that: the sodium hydrosulfite is steady
Determine agent to be made of the component that following weight matches: glucose 40% ~ 50%, sodium hypophosphite 30% ~ 40%, surplus are anthraquinone.
4. the method according to claim 1 using natural indigo dye denim yarn, it is characterised in that: the accelerant is
Sodium chloride or sodium sulphate.
5. according to the method for the natural indigo dye denim yarn of any utilization of claim 2-4, it is characterised in that: described hidden
The preparation step of colour solid dye liquor is as follows:
A, dyestuff prereduction: being put into naturally indigo in beaker, a small amount of alcohol be added and water is mixed well, and then plus water, stirring reach
After mixing evenly, the insurance of formula ratio 2/3 is added in the 1/3 of the total liquid measure of leuco compound dye liquor, the sodium hydroxide that formula ratio 2/3 is added
Powder, the sodium hydrosulfite stabilizer of full dose, restores dyestuff sufficiently, and leuco compound mother liquor is made；
B, prepared by dye liquor: the water of surplus is added in dyeing cup, remaining sodium hydroxide and sodium hydrosulfite is added, is sufficiently stirred, dissolves,
Leuco compound mother liquor made from addition penetrating agent JFC, accelerant and step a, reaches the total liquid measure of leuco compound dye liquor, stirs evenly, and makes
Obtain leuco compound dye liquor.
6. the method according to claim 5 using natural indigo dye denim yarn, it is characterised in that: in the step a
Natural indigo concentration is 1.5 ~ 6g/L, 3 ~ 9g/L of concentration of sodium hydroxide, 1.5 ~ 3.6 g/L of concentration of sodium hydrosulfite, sodium hydrosulfite
0.75 ~ 1.8g/L of concentration of stabilizer.
7. the method according to claim 5 using natural indigo dye denim yarn, it is characterised in that: in the step b
The concentration of sodium hydroxide is 0.75 ~ 2.25g/L when leuco compound mother liquor not being added, and the concentration of sodium hydrosulfite is 0.375 ~ 0.9 g/L, is seeped
The concentration of saturating agent JFC is 3g/L, 15 ~ 22.5 g/L of concentration of accelerant.
8. the method according to claim 1 using natural indigo dye denim yarn, it is characterised in that: the leuco compound is more
The secondary pick-up 70% ~ 75% padded in oxidizing process step (2).
9. the method according to claim 1 using natural indigo dye denim yarn, it is characterised in that: the leuco compound is more
The secondary oxidization time that pads in oxidizing process step (3) is 1.5 ~ 2 min.
10. the method according to claim 1 using natural indigo dye denim yarn, it is characterised in that: the leuco compound
Repeatedly padding the washing temperature in oxidizing process step (5) is 40 ~ 50 DEG C, is washed 2 ~ 3 times, pick-up 60 ~ 65%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810946792.XA CN109098011B (en) | 2018-08-20 | 2018-08-20 | Method for dyeing jean yarns by using natural indigo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810946792.XA CN109098011B (en) | 2018-08-20 | 2018-08-20 | Method for dyeing jean yarns by using natural indigo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109098011A true CN109098011A (en) | 2018-12-28 |
| CN109098011B CN109098011B (en) | 2020-07-31 |
Family
ID=64850399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810946792.XA Active CN109098011B (en) | 2018-08-20 | 2018-08-20 | Method for dyeing jean yarns by using natural indigo |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109098011B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016816A (en) * | 2019-03-13 | 2019-07-16 | 广东前进牛仔布有限公司 | A kind of indigo dyeing method |
| CN110130122A (en) * | 2019-06-14 | 2019-08-16 | 佛山市南海亿棉染织有限公司 | A kind of water-saving colouring method and vulcanization dyeing apparatus of sulfur dye |
| CN111395013A (en) * | 2020-06-02 | 2020-07-10 | 佛山市南海区今易德纺织有限公司 | Rapid dyeing process of denim fabric |
| CN114086405A (en) * | 2021-12-22 | 2022-02-25 | 中纺院（浙江）技术研究院有限公司 | Biological reducing agent and method for applying biological reducing agent to plant indigo dyed yarn |
| CN114481651A (en) * | 2021-12-31 | 2022-05-13 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
| CN115538191A (en) * | 2022-09-21 | 2022-12-30 | 南通东屹高新纤维科技有限公司 | Dyeing method of degradable yarns |
| CN116556082A (en) * | 2023-05-22 | 2023-08-08 | 佛山纳纤科技有限公司 | Anhydrous supercritical dyed jean textile and process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789513A (en) * | 2005-12-13 | 2006-06-21 | 金国周 | Production method of indigo cheese |
| CN103882638A (en) * | 2014-03-18 | 2014-06-25 | 山东万泰创业投资有限公司 | Producing technology for jean bundle-shaped thread super blue dyeing |
| CN104294671A (en) * | 2014-10-13 | 2015-01-21 | 濮阳宏业汇龙化工有限公司 | Reducing agent for dyeing reduced dyes |
| CN105442224A (en) * | 2016-01-09 | 2016-03-30 | 海宁牛仔织造有限公司 | Indigo-blue jean dyeing machine |
-
2018
- 2018-08-20 CN CN201810946792.XA patent/CN109098011B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789513A (en) * | 2005-12-13 | 2006-06-21 | 金国周 | Production method of indigo cheese |
| CN103882638A (en) * | 2014-03-18 | 2014-06-25 | 山东万泰创业投资有限公司 | Producing technology for jean bundle-shaped thread super blue dyeing |
| CN104294671A (en) * | 2014-10-13 | 2015-01-21 | 濮阳宏业汇龙化工有限公司 | Reducing agent for dyeing reduced dyes |
| CN105442224A (en) * | 2016-01-09 | 2016-03-30 | 海宁牛仔织造有限公司 | Indigo-blue jean dyeing machine |
Non-Patent Citations (2)
| Title |
|---|
| 上海市纺织工业局供销处主编: "《纺织企业物资管理》", 30 April 1985, 北京：纺织工业出版社 * |
| 裔旻: "单一和复合添加剂对保险粉水溶液的稳定作用研究", 《江苏大学硕士学位论文》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016816A (en) * | 2019-03-13 | 2019-07-16 | 广东前进牛仔布有限公司 | A kind of indigo dyeing method |
| CN110130122A (en) * | 2019-06-14 | 2019-08-16 | 佛山市南海亿棉染织有限公司 | A kind of water-saving colouring method and vulcanization dyeing apparatus of sulfur dye |
| CN111395013A (en) * | 2020-06-02 | 2020-07-10 | 佛山市南海区今易德纺织有限公司 | Rapid dyeing process of denim fabric |
| CN111395013B (en) * | 2020-06-02 | 2020-10-27 | 佛山市南海区今易德纺织有限公司 | Rapid dyeing process of denim fabric |
| CN114086405A (en) * | 2021-12-22 | 2022-02-25 | 中纺院（浙江）技术研究院有限公司 | Biological reducing agent and method for applying biological reducing agent to plant indigo dyed yarn |
| CN114086405B (en) * | 2021-12-22 | 2024-02-13 | 中纺院（浙江）技术研究院有限公司 | Biological reducing agent and method for applying biological reducing agent to plant indigo dyed yarns |
| CN114481651A (en) * | 2021-12-31 | 2022-05-13 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
| CN114481651B (en) * | 2021-12-31 | 2024-02-02 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
| CN115538191A (en) * | 2022-09-21 | 2022-12-30 | 南通东屹高新纤维科技有限公司 | Dyeing method of degradable yarns |
| CN115538191B (en) * | 2022-09-21 | 2023-12-29 | 南通东屹高新纤维科技有限公司 | Dyeing method of degradable yarn |
| CN116556082A (en) * | 2023-05-22 | 2023-08-08 | 佛山纳纤科技有限公司 | Anhydrous supercritical dyed jean textile and process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109098011B (en) | 2020-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109098011A (en) | A method of utilizing natural indigo dye denim yarn | |
| CN105803828B (en) | Scattered/active Graft versus host disease dyestuff of one kind and its printing technology | |
| CN104233581B (en) | The preparation method of the fire-retardant camouflage printing fabric of a kind of waterproof antistatic | |
| CN103740136B (en) | A kind of high fastness disperses bright blue dye composite | |
| EP1913195B1 (en) | Process for introducing vat dyes and chemicals into textiles | |
| CN106192470B (en) | A kind of reactive dyes dyeing method of high colour-fast rate | |
| CN102936854B (en) | A kind of cold dyeing being applicable to all-cotton fabric printing with reactive dye directly prints technique | |
| CN103184697A (en) | One-bath dyeing and anti-mosquito finishing method of aramid fiber disperse dye | |
| CN103255648A (en) | Method for improving pad dyeing fixation rate of textile | |
| CN105064085A (en) | Novel levelling agent for dyeing pure cotton and dyeing method thereof | |
| CN102493223B (en) | A kind of composition of aqueous solution of reactive dye for pad dyeing and compound method | |
| CN105926316A (en) | Novel environment-friendly dyeing method for jeans apparel | |
| CN107794787A (en) | A kind of acid dyes light fastness elevator and its application | |
| CN105821683A (en) | Method for preventing printing-free areas of positive-ion-modified cotton fabric from staining | |
| CN103074785A (en) | Ecological dyeing method for traditional Chinese medicine dye of silk fabric | |
| CN104805706B (en) | Reduction system for vat dye or sulfur dyestuff dyeing and reduction method | |
| CN109281208A (en) | A kind of cotton fabric low temperature white discharge method | |
| CN109295760A (en) | A kind of polyester-cotton blend disperse dyes and the novel two bath process technique of reactive dye | |
| CN101302661A (en) | Preparation of coloured antibiotic viscose fiber | |
| KR20120076096A (en) | Jean for fabrics dyeing method use natural indigo powder | |
| CN102372932A (en) | Disperse red dye composition | |
| DE10349435A1 (en) | Process for the continuous dyeing of cellulosic fiber fabrics and blended fabrics containing cellulosic fibers | |
| CN106758395A (en) | A kind of multifunctional low-temperature dyeing assistant and colouring method | |
| Xin et al. | Colour variation in the dyeing of denim yarn with indigo | |
| CN109667162A (en) | The method that reactive dye carry out salt-free dyeing to un-scoured and unbleached cotton textile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210519 Address after: 456750 west of the middle section of Heqi Avenue, Qi County, Hebi City, Henan Province Patentee after: Hebi xingeyuan Daning Technology Co.,Ltd. Address before: 451191 Xianghe Road, Longhu Town, Zhengzhou City, Henan Province Patentee before: HENAN INSTITUTE OF ENGINEERING |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 456750 west of the middle section of Heqi Avenue, Qi County, Hebi City, Henan Province Patentee after: Henan Xinrun Textile Co.,Ltd. Country or region after: China Address before: 456750 west of the middle section of Heqi Avenue, Qi County, Hebi City, Henan Province Patentee before: Hebi xingeyuan Daning Technology Co.,Ltd. Country or region before: China |