CN109098005A - A kind of coating and preparation method thereof for shell fabric for fire garment - Google Patents
A kind of coating and preparation method thereof for shell fabric for fire garment Download PDFInfo
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- CN109098005A CN109098005A CN201810856617.1A CN201810856617A CN109098005A CN 109098005 A CN109098005 A CN 109098005A CN 201810856617 A CN201810856617 A CN 201810856617A CN 109098005 A CN109098005 A CN 109098005A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/065—Insulating
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- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
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- D06N2209/00—Properties of the materials
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- D06N2209/142—Hydrophobic
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- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
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- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
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- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
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- D06N2211/00—Specially adapted uses
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Abstract
The invention discloses a kind of coating for shell fabric for fire garment, raw material including following parts by weight: 20~30 parts of styrene-acrylic emulsion, 15~25 parts of epoxy emulsion, 10~20 parts of polyaminoester emulsion, 7~11 parts of terpene resin, 6~14 parts of acrylic resin, 6~9 parts of modified talc powder, 4~7 parts of attapulgite, 3~6 parts of Kynoar, 4~8 parts of hollow float bead, 2~5 parts of polyvinyl alcohol, 4~9 parts of modified Nano expanded vermiculite, 2~3 parts of ethyl cellulose, 3~6 parts of reinforcing fiber, 2~4 parts of calcium stearate, 2~3 parts of thickener, 3~4 parts of fire retardant, 1~2 part of nano-silver ionic fungicide.Coating of the present invention for shell fabric for fire garment has good waterproof performance, heat-proof quality and fire protecting performance, and safety in utilization is strong, and its wearability is fine, soft light, convenient for operation.
Description
Technical field
The invention belongs to fire-entry suit technical fields, and in particular to a kind of for the coating of shell fabric for fire garment and its preparation side
Method.
Background technique
Fire-entry suit is that protection is active in one of important equipment product of fire fighter's personal safety of fire-fighting First Line, it is not only
It is the indispensable necessary article of fire salvation scene, and the fire prevention apparatus that protection fire fighter's body escapes injury.
Fire-entry suit is in carrying out firefighting activities, and fire fighter is used to protect the important tool of body.Therefore, it must have
Standby following characteristics:
(1) consider from protective, it is necessary to have fire resistance, heat resistance and thermal insulation will also have obdurability, prevent knife-edge
Impact, collision of body etc..In addition, also to have the performance for the injury that chemical substance can be prevented to skin；
(2) variation for adapting to the environment such as extraneous changes in temperature, wind and rain, is able to maintain physical strength and vigorous energy；
(3) from the aspect of operating efficiency, fire-entry suit should have move place, as far as possible the selection good material of telescopicing performance in operation
Material, in addition, the quality and shape of dress material, construction etc. also will be studied conscientiously；
(4) consider on safety management and army are planned as a whole, want effective between the superior and the subordinate, it is ensured that it is due that fire-entry suit plays its
Effect.
Existing fire-entry suit can mostly be equipped with multiple precoats such as waterproof layer, thermal insulation layer, so that fire-entry suit is than cumbersome,
It is not easy to operate.
Authorization Notice No. CN104060465B discloses a kind of shell fabric for fire garment coating, it is by following weight parts
Raw material composition: polypropylene 72-80, carbon fibre 4-5, bauxite 3-5, graphite powder 10-13, dibatyl phithalate 10-
16, guar gum 3-5, sodium potassium tartrate tetrahydrate 1-2, dibutyl ester 7-9, aluminium hydroxide 2-3, cetomacrogol 1000 5-6, Kynoar
2-4, itaconate 3-5, chitosan 0.6-1, crosslinking agent TAC0.2-0.3, compounded mix 12-18；Coating above-mentioned coating can subtract
The precoat of few fire-entry suit, but simultaneously but also the waterproof of fire-entry suit, fire protecting performance decline.
Summary of the invention
The coating and preparation method thereof that the present invention provides a kind of for shell fabric for fire garment, solves in background technique
Problem, the coating of the present invention for shell fabric for fire garment have good waterproof performance, heat-proof quality and fire protecting performance,
Safety in utilization is strong, and its wearability is fine, soft light, convenient for operation.
It is of the existing technology in order to solve the problems, such as, it adopts the following technical scheme that
A kind of coating for shell fabric for fire garment, the raw material including following parts by weight: 20~30 parts of styrene-acrylic emulsion, epoxy emulsion
15~25 parts, 10~20 parts of polyaminoester emulsion, 7~11 parts of terpene resin, 6~14 parts of acrylic resin, modified talc powder 6~9
Part, the expansion of 4~7 parts of attapulgite, 3~6 parts of Kynoar, 4~8 parts of hollow float bead, 2~5 parts of polyvinyl alcohol, modified Nano
4~9 parts of vermiculite, 2~3 parts of ethyl cellulose, 3~6 parts of reinforcing fiber, 2~4 parts of calcium stearate, 2~3 parts of thickener, fire retardant
3~4 parts, 1~2 part of nano-silver ionic fungicide.
Preferably, the coating for shell fabric for fire garment, the raw material including following parts by weight: styrene-acrylic emulsion 23~28
Part, is modified 17~22 parts of epoxy emulsion, 13~19 parts of polyaminoester emulsion, 8~10 parts of terpene resin, 7~10 parts of acrylic resin
7~8 parts of talcum powder, 4~5 parts of Kynoar, 5~7 parts of hollow float bead, 3~4 parts of polyvinyl alcohol, changes 5~6 parts of attapulgite
5~8 parts of property nanometer expanded vermiculite, 2.3~2.7 parts of ethyl cellulose, 4~5 parts of reinforcing fiber, 2.8~3.3 parts of calcium stearate,
2.4~2.9 parts of thickener, 3.2~3.8 parts of fire retardant, 1.3~1.8 parts of nano-silver ionic fungicide.
Preferably, the coating for shell fabric for fire garment, the raw material including following parts by weight: 25 parts of styrene-acrylic emulsion,
20 parts of epoxy emulsion, 16 parts of polyaminoester emulsion, 9 parts of terpene resin, 8 parts of acrylic resin, 7.4 parts of modified talc powder, concave convex rod
5.3 parts of soil, 4.7 parts of Kynoar, 6 parts of hollow float bead, 3.3 parts of polyvinyl alcohol, 6 parts of modified Nano expanded vermiculite, ethyl are fine
2.4 parts of dimension element, 4.5 parts of reinforcing fiber, 3.1 parts of calcium stearate, 2.8 parts of thickener, 3.4 parts of fire retardant, nano-silver ionic sterilization
1.7 parts of agent.
Preferably, the modified Nano expanded vermiculite the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
Preferably, the modified talc powder the preparation method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
Preferably, the reinforcing fiber is the mixture of glass fibre, metallic fiber and silicon carbide fibre, and the enhancing is fine
Dimension is that the mass ratio of glass fibre, metallic fiber and silicon carbide fibre is 1:2:1.
Preferably, the thickener is hydroxyethyl ether cellulose.
Preferably, the fire retardant is the mixture of antimony oxide, magnesium hydroxide and aluminium hydroxide, three oxidation two
The mass ratio of antimony, magnesium hydroxide and aluminium hydroxide is 2:1:1.
A method of preparing the coating for being used for shell fabric for fire garment, comprising the following steps:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) by styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin be placed in kneading machine be kneaded 40~
60 minutes, melting temperature was 80~90 DEG C, obtained mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
20~40 minutes, add modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite, high speed dispersion 10~20
Minute, obtain mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
Preferably, the time of the microwave treatment is 10 minutes.
Compared with prior art, the present invention it has the advantages that
Coating of the present invention for shell fabric for fire garment has good waterproof performance, heat-proof quality and fire protecting performance,
Safety in utilization is strong, and its wearability is fine, soft light, specific as follows convenient for operation:
(1) present invention using styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified talc powder,
It is attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, reinforcing fiber, hard
Resin acid calcium, thickener, fire retardant, nano-silver ionic fungicide etc. are used as raw material, mutually act synergistically, prepare between raw material
The coating good water-proof effect that coating is coated in fire-entry suit fabric, it is wear-resisting, and fire resisting, it is heat-insulated；
(2) present invention is added to the originals such as modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite in the feed
Material, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite etc. are wear-resisting, heat-insulated, noninflammable material, with benzene
The synergistic effect such as acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, thus it is possible to vary styrene-acrylic emulsion, ring
The wearability of the substances such as oxygen lotion, polyaminoester emulsion, terpene resin, acrylic resin, thermal insulation and its fire resistance, to mention
The wearability of high product, thermal insulation and its fire resistance；
(3) present invention also added reinforcing fiber in the feed, and the reinforcing fiber is glass fibre, metallic fiber and silicon carbide
The mixture of fiber, the glass fibre, metallic fiber and silicon carbide fibre are dispersed in coating, and coating can be improved and exist
The impact resistance and tensile strength for the coating that garment material surface is formed.
Specific embodiment
Present invention will be further explained below with reference to specific examples.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
The present embodiment is related to a kind of coating for shell fabric for fire garment, the raw material including following parts by weight: 20 parts of styrene-acrylic emulsion,
15 parts of epoxy emulsion, 10 parts of polyaminoester emulsion, 7 parts of terpene resin, 6 parts of acrylic resin, 6 parts of modified talc powder, attapulgite 4
Part, increases 3 parts of Kynoar, 4 parts of hollow float bead, 2 parts of polyvinyl alcohol, 4 parts of modified Nano expanded vermiculite, 2 parts of ethyl cellulose
Strong 3 parts of fiber, 2 parts of calcium stearate, 2 parts of thickener, 3 parts of fire retardant, 1 part of nano-silver ionic fungicide.
Wherein, the modified Nano expanded vermiculite the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
Wherein, the modified talc powder the preparation method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
Wherein, the reinforcing fiber is the mixture of glass fibre, metallic fiber and silicon carbide fibre, the reinforcing fiber
Mass ratio for glass fibre, metallic fiber and silicon carbide fibre is 1:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose.
Wherein, the fire retardant is the mixture of antimony oxide, magnesium hydroxide and aluminium hydroxide, three oxidation two
The mass ratio of antimony, magnesium hydroxide and aluminium hydroxide is 2:1:1.
A method of preparing the coating for being used for shell fabric for fire garment, comprising the following steps:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin are placed in kneading machine and are kneaded 40 points
Clock, melting temperature are 80 DEG C, obtain mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
20 minutes, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite are added, high speed dispersion 10 minutes, is obtained
Mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
Wherein, the time of the microwave treatment is 10 minutes.
Embodiment 2
The present embodiment is related to a kind of coating for shell fabric for fire garment, the raw material including following parts by weight: 30 parts of styrene-acrylic emulsion,
25 parts of epoxy emulsion, 20 parts of polyaminoester emulsion, 11 parts of terpene resin, 14 parts of acrylic resin, 9 parts of modified talc powder, concave convex rod
Native 7 parts, 6 parts of Kynoar, 8 parts of hollow float bead, 5 parts of polyvinyl alcohol, 9 parts of modified Nano expanded vermiculite, ethyl cellulose 3
Part, 6 parts of reinforcing fiber, 4 parts of calcium stearate, 3 parts of thickener, 4 parts of fire retardant, 2 parts of nano-silver ionic fungicide.
Wherein, the modified Nano expanded vermiculite the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
Wherein, the modified talc powder the preparation method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
Wherein, the reinforcing fiber is the mixture of glass fibre, metallic fiber and silicon carbide fibre, the reinforcing fiber
Mass ratio for glass fibre, metallic fiber and silicon carbide fibre is 1:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose.
Wherein, the fire retardant is the mixture of antimony oxide, magnesium hydroxide and aluminium hydroxide, three oxidation two
The mass ratio of antimony, magnesium hydroxide and aluminium hydroxide is 2:1:1.
A method of preparing the coating for being used for shell fabric for fire garment, comprising the following steps:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin are placed in kneading machine and are kneaded 60 points
Clock, melting temperature are 90 DEG C, obtain mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
40 minutes, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite are added, high speed dispersion 20 minutes, is obtained
Mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
Wherein, the time of the microwave treatment is 10 minutes.
Embodiment 3
The present embodiment is related to a kind of coating for shell fabric for fire garment, the raw material including following parts by weight: 23 parts of styrene-acrylic emulsion,
17 parts of epoxy emulsion, 13 parts of polyaminoester emulsion, 8 parts of terpene resin, 7 parts of acrylic resin, 7 parts of modified talc powder, attapulgite 5
Part, 4 parts of Kynoar, 5 parts of hollow float bead, 3 parts of polyvinyl alcohol, 5 parts of modified Nano expanded vermiculite, 2.3 parts of ethyl cellulose,
4 parts of reinforcing fiber, 2.8 parts of calcium stearate, 2.4 parts of thickener, 3.2 parts of fire retardant, 1.3 parts of nano-silver ionic fungicide.
Wherein, the modified Nano expanded vermiculite the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
Wherein, the modified talc powder the preparation method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
Wherein, the reinforcing fiber is the mixture of glass fibre, metallic fiber and silicon carbide fibre, the reinforcing fiber
Mass ratio for glass fibre, metallic fiber and silicon carbide fibre is 1:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose.
Wherein, the fire retardant is the mixture of antimony oxide, magnesium hydroxide and aluminium hydroxide, three oxidation two
The mass ratio of antimony, magnesium hydroxide and aluminium hydroxide is 2:1:1.
A method of preparing the coating for being used for shell fabric for fire garment, comprising the following steps:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin are placed in kneading machine and are kneaded 45 points
Clock, melting temperature are 82 DEG C, obtain mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
25 minutes, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite are added, high speed dispersion 13 minutes, is obtained
Mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
Wherein, the time of the microwave treatment is 10 minutes.
Embodiment 4
The present embodiment is related to a kind of coating for shell fabric for fire garment, the raw material including following parts by weight: 28 parts of styrene-acrylic emulsion,
22 parts of epoxy emulsion, 19 parts of polyaminoester emulsion, 10 parts of terpene resin, 10 parts of acrylic resin, 8 parts of modified talc powder, concave convex rod
Native 6 parts, 5 parts of Kynoar, 7 parts of hollow float bead, 4 parts of polyvinyl alcohol, 8 parts of modified Nano expanded vermiculite, ethyl cellulose 2.7
Part, 5 parts of reinforcing fiber, 3.3 parts of calcium stearate, 2.9 parts of thickener, 3.8 parts of fire retardant, 1.8 parts of nano-silver ionic fungicide.
Wherein, the modified Nano expanded vermiculite the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
Wherein, the modified talc powder the preparation method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
Wherein, the reinforcing fiber is the mixture of glass fibre, metallic fiber and silicon carbide fibre, the reinforcing fiber
Mass ratio for glass fibre, metallic fiber and silicon carbide fibre is 1:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose.
Wherein, the fire retardant is the mixture of antimony oxide, magnesium hydroxide and aluminium hydroxide, three oxidation two
The mass ratio of antimony, magnesium hydroxide and aluminium hydroxide is 2:1:1.
A method of preparing the coating for being used for shell fabric for fire garment, comprising the following steps:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin are placed in kneading machine and are kneaded 50 points
Clock, melting temperature are 85 DEG C, obtain mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
30 minutes, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite are added, high speed dispersion 15 minutes, is obtained
Mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
Wherein, the time of the microwave treatment is 10 minutes.
Embodiment 5
The present embodiment is related to a kind of coating for shell fabric for fire garment, the raw material including following parts by weight: 25 parts of styrene-acrylic emulsion,
20 parts of epoxy emulsion, 16 parts of polyaminoester emulsion, 9 parts of terpene resin, 8 parts of acrylic resin, 7.4 parts of modified talc powder, concave convex rod
5.3 parts of soil, 4.7 parts of Kynoar, 6 parts of hollow float bead, 3.3 parts of polyvinyl alcohol, 6 parts of modified Nano expanded vermiculite, ethyl are fine
2.4 parts of dimension element, 4.5 parts of reinforcing fiber, 3.1 parts of calcium stearate, 2.8 parts of thickener, 3.4 parts of fire retardant, nano-silver ionic sterilization
1.7 parts of agent.
Wherein, the modified Nano expanded vermiculite the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
Wherein, the modified talc powder the preparation method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
Wherein, the reinforcing fiber is the mixture of glass fibre, metallic fiber and silicon carbide fibre, the reinforcing fiber
Mass ratio for glass fibre, metallic fiber and silicon carbide fibre is 1:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose.
Wherein, the fire retardant is the mixture of antimony oxide, magnesium hydroxide and aluminium hydroxide, three oxidation two
The mass ratio of antimony, magnesium hydroxide and aluminium hydroxide is 2:1:1.
A method of preparing the coating for being used for shell fabric for fire garment, comprising the following steps:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin are placed in kneading machine and are kneaded 55 points
Clock, melting temperature are 87 DEG C, obtain mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
35 minutes, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite are added, high speed dispersion 18 minutes, is obtained
Mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
Wherein, the time of the microwave treatment is 10 minutes.
Comparative example
Authorization Notice No. CN104060465B discloses a kind of shell fabric for fire garment coating.
Coating described in Examples 1 to 5, comparative example is coated on to the surface of shell fabric for fire garment respectively, and it is formed
The performance of coating tested, test result is as follows table:
From above-mentioned data, it can be seen that coating property of the present invention is better than comparative example.
To sum up, the coating of the present invention for shell fabric for fire garment has good waterproof performance, thermal insulation
Energy and fire protecting performance, safety in utilization is strong, and its wearability is fine, soft light, specific as follows convenient for operation:
(1) present invention using styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified talc powder,
It is attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, reinforcing fiber, hard
Resin acid calcium, thickener, fire retardant, nano-silver ionic fungicide etc. are used as raw material, mutually act synergistically, prepare between raw material
The coating good water-proof effect that coating is coated in fire-entry suit fabric, it is wear-resisting, and fire resisting, it is heat-insulated；
(2) present invention is added to the originals such as modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite in the feed
Material, modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite etc. are wear-resisting, heat-insulated, noninflammable material, with benzene
The synergistic effect such as acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, thus it is possible to vary styrene-acrylic emulsion, ring
The wearability of the substances such as oxygen lotion, polyaminoester emulsion, terpene resin, acrylic resin, thermal insulation and its fire resistance, to mention
The wearability of high product, thermal insulation and its fire resistance；
(3) present invention also added reinforcing fiber in the feed, and the reinforcing fiber is glass fibre, metallic fiber and silicon carbide
The mixture of fiber, the glass fibre, metallic fiber and silicon carbide fibre are dispersed in coating, and coating can be improved and exist
The impact resistance and tensile strength for the coating that garment material surface is formed.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring substantive content of the invention.
Claims (10)
1. a kind of coating for shell fabric for fire garment, which is characterized in that the raw material including following parts by weight: styrene-acrylic emulsion 20~
30 parts, 15~25 parts of epoxy emulsion, 10~20 parts of polyaminoester emulsion, 7~11 parts of terpene resin, 6~14 parts of acrylic resin, change
6~9 parts of talcum powder of property, 4~7 parts of attapulgite, 3~6 parts of Kynoar, 4~8 parts of hollow float bead, 2~5 parts of polyvinyl alcohol,
4~9 parts of modified Nano expanded vermiculite, 2~3 parts of ethyl cellulose, 3~6 parts of reinforcing fiber, 2~4 parts of calcium stearate, thickener 2
~3 parts, 3~4 parts of fire retardant, 1~2 part of nano-silver ionic fungicide.
2. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the original including following parts by weight
Material: 23~28 parts of styrene-acrylic emulsion, 17~22 parts of epoxy emulsion, 13~19 parts of polyaminoester emulsion, 8~10 parts of terpene resin, propylene
7~10 parts of acid resin, 7~8 parts of modified talc powder, 5~6 parts of attapulgite, 4~5 parts of Kynoar, hollow float bead 5~7
Part, 3~4 parts of polyvinyl alcohol, 5~8 parts of modified Nano expanded vermiculite, 2.3~2.7 parts of ethyl cellulose, 4~5 parts of reinforcing fiber,
2.8~3.3 parts of calcium stearate, 2.4~2.9 parts of thickener, 3.2~3.8 parts of fire retardant, nano-silver ionic fungicide 1.3~1.8
Part.
3. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the original including following parts by weight
Material: 25 parts of styrene-acrylic emulsion, 20 parts of epoxy emulsion, 16 parts of polyaminoester emulsion, 9 parts of terpene resin, 8 parts of acrylic resin, modified cunning
7.4 parts of mountain flour, 5.3 parts of attapulgite, 4.7 parts of Kynoar, 6 parts of hollow float bead, 3.3 parts of polyvinyl alcohol, modified Nano are swollen
6 parts of swollen vermiculite, 2.4 parts of ethyl cellulose, 4.5 parts of reinforcing fiber, 3.1 parts of calcium stearate, 2.8 parts of thickener, fire retardant 3.4
Part, 1.7 parts of nano-silver ionic fungicide.
4. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the modified Nano expands leech
Stone the preparation method is as follows:
Expanded vermiculite is soaked in the sodium alginate colloidal sol prepared in advance, using vacuum impregnation absorbing process, keeps nanometer extra large
Mosanom colloidal sol sucks in expanded perlite cavity, forms gel, and after to be aging, by normal pressure classification, dry, hydrophobic handles shape
At modified Nano expanded vermiculite.
5. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the system of the modified talc powder
Preparation Method is as follows:
By weight 6:3:2:1 weigh talcum powder, bentonite, jade powder, boron mud be uniformly mixed, be added 1.5% triethanolamine,
2% Sodium Polyacrylate, 1.5% calcium lignosulfonate, 0.6% vinyl three ('beta '-methoxy ethyoxyl) silane, 2000rpm
High speed grinding 15min is dried, and is crushed, and crosses 400 meshes to get modified talc powder.
6. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the reinforcing fiber is glass
The mixture of fiber, metallic fiber and silicon carbide fibre, the reinforcing fiber are glass fibre, metallic fiber and silicon carbide fibre
Mass ratio be 1:2:1.
7. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the thickener is ethoxy
Cellulose ether.
8. the coating according to claim 1 for shell fabric for fire garment, which is characterized in that the fire retardant is three oxidations
The mass ratio of the mixture of two antimony, magnesium hydroxide and aluminium hydroxide, the antimony oxide, magnesium hydroxide and aluminium hydroxide is 2:
1:1。
9. a kind of method prepared described in any one of claim 1~8 for the coating of shell fabric for fire garment, which is characterized in that
The following steps are included:
(1) styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin, modified cunning are weighed by above-mentioned formula
Mountain flour, attapulgite, Kynoar, hollow float bead, polyvinyl alcohol, modified Nano expanded vermiculite, ethyl cellulose, enhancing are fine
Dimension, calcium stearate, thickener, fire retardant, nano-silver ionic fungicide, it is spare；
(2) by styrene-acrylic emulsion, epoxy emulsion, polyaminoester emulsion, terpene resin, acrylic resin be placed in kneading machine be kneaded 40~
60 minutes, melting temperature was 80~90 DEG C, obtained mixture A；
(3) calcium stearate, Kynoar, ethyl cellulose and polyvinyl alcohol, first mechanical stirring are sequentially added into mixture A
20~40 minutes, add modified talc powder, attapulgite, hollow float bead, modified Nano expanded vermiculite, high speed dispersion 10~20
Minute, obtain mixture B；
(4) surplus stock is added into mixture B, is uniformly mixed, then microwave treatment is used for firefighter uniform to get described
The coating of fabric.
10. preparation method according to claim 9, which is characterized in that the time of the microwave treatment is 10 minutes.
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| CN113461966A (en) * | 2021-08-23 | 2021-10-01 | 濮阳市盛源能源科技股份有限公司 | Flame-retardant unsaturated polyester resin and preparation method thereof |
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Application publication date: 20181228 |