CN109096943A - A kind of novel belt glue conductive fabric - Google Patents

A kind of novel belt glue conductive fabric Download PDF

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Publication number
CN109096943A
CN109096943A CN201810882944.4A CN201810882944A CN109096943A CN 109096943 A CN109096943 A CN 109096943A CN 201810882944 A CN201810882944 A CN 201810882944A CN 109096943 A CN109096943 A CN 109096943A
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China
Prior art keywords
powder
polyester
particle
nanoparticle
nickel
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CN201810882944.4A
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CN109096943B (en
Inventor
潘荣德
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SUZHOU BECKLOS ELECTRONIC TECHNOLOGY Co.,Ltd.
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Wuzhou Xing Neng Agriculture Science And Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/314—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials
    • C09J2400/16—Metal
    • C09J2400/163—Metal in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00—Presence of halogenated polymer
    • C09J2427/006—Presence of halogenated polymer in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

This application involves a kind of novel belt glue conductive fabrics, including polyester fiber base (1) and adhesive sticker adhesion coating (2), the layer of polyester fiber (1) is made of polyester fiber, and the polyester fiber is to melt blended be prepared with polyester master particle A, polyester master particle B and polyester slice.

Description

A kind of novel belt glue conductive fabric
Technical field
This application involves conductive fabric technical field more particularly to a kind of novel belt glue conductive fabrics.
Background technique
Band glue conductive fabric is suitable for all kinds of electric equipment products such as photoelectricity, computer, electric wire, cable and connector, main to make Be in high-frequency transmission masking or isolating electromagnetic or radio wave interference.With good electric conductivity, anti-friction property and Inoxidizability.Traditional is made of with glue conductive fabric conductive fabric and the electroconductive binder being coated on conductive fabric, is relatively good screen Material is covered, when electromagnetic wave encounters electricity conductive cloth tape, most of electromagnetic wave can be reflected back by electricity conductive cloth tape.But this band The anti-friction of glue conductive fabric, antioxygenic property are poor, and in the case of a high temperature, and shielding properties is easy to decline, and can also make At being cracked and falling off, it is unable to satisfy requirement, most importantly conductive fabric generally directlys adopt metallic film and attaches, this Kind structure can also unevenly reach conductive fabric electric conductivity and screen due to calenderability in edge crimping easy to form or thorn side etc. Performance unevenness is covered, it is impossible to meet actual design requirements, and as being made of direct attach, often in practical applications It can be only a kind of metal composition, have the defects that on electric conductivity and shielding properties certain.
Summary of the invention
The present invention is intended to provide a kind of novel belt glue conductive fabric, set forth above to solve the problems, such as.
A kind of novel belt glue conductive fabric, including polyester fiber base (1) and adhesive sticker are provided in the embodiment of the present invention Nickel particle (3) is adsorbed in such a way that chemical precipitation or metal physics are shifted by adhesion coating (2) on polyester fiber base (1) In polyester fiber base (1), in nickel particle (3) outer surface by being electroplate with layers of copper (4), layers of copper (4) outer surface is also electroplated Have nickel layer (5), the adhesive sticker adhesion coating (2) includes adhesive sticker overlay (6), and the adhesive sticker overlay (6) is applied directly to Nickel layer (5) outer surface, the adhesive sticker overlay (6), which also passes through chemical precipitation, nickel particle (3), and in adhesive sticker overlay (6) outer surface is carved with nickel bar line (7), and the nickel bar line (7) is in netted intertexture shape, in nickel layer (5) outer surface and not of the other side It is fixedly installed with frosted layer (8) and PVC film (9) respectively on dry glue adhesion coating (2) outer surface；The layer of polyester fiber (1) is by gathering Ester fiber is constituted, and the polyester fiber is to melt blended be prepared with polyester master particle A, polyester master particle B and polyester slice.
The technical solution that the embodiment of the present invention provides can include the following benefits:
1, the present invention is by polyester fiber base, by nickel particle in such a way that chemical precipitation or metal physics are shifted It is adsorbed in polyester fiber base, then plates the layers of copper of high conductivity in nickel particle outer surface, the oxygen in re-plating in layers of copper The etch-proof nickel metal of change machine, copper and mickel combine and provide splendid electric conductivity and good effectiveness, and at edge Upper to have smooth edge by primary cutting and polishing treatment, cutting passes through chemical precipitation and electricity without flash and Ci Bian The method of plating carries out metal coat, forms uniform stable outer surface structure, and can largely improve resistance, energy The destruction to electroplated layer etc. such as high temperature is enough prevented, further, in the nickel particle of adhesive sticker adhesion coating internal precipitate and on surface The nickel bar line of formation is all to have good conductive capability, can be improved the conductive capability of adhesive sticker adhesion coating.
2, polyester fiber of the invention is by the improvement to polyester master particle, so that the antibiotic effect and electric conductivity of polyester fiber Balance can be obtained, there is good antibacterial, antistatic property.
The additional aspect of the application and advantage will be set forth in part in the description, and will partially become from the following description It obtains obviously, or recognized by the practice of the application.It should be understood that above general description and following detailed description are only Be it is exemplary and explanatory, the application can not be limited.
Detailed description of the invention
The present invention will be further described with reference to the accompanying drawings, but the embodiment in attached drawing is not constituted to any limit of the invention System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings Other attached drawings.
Fig. 1 is schematic structural view of the invention；
Fig. 2 is adhesive sticker adhesion coating structural schematic diagram of the present invention.
In figure: 1- polyester fiber base；2- adhesive sticker adhesion coating；3- nickel particle；4- layers of copper；5- nickel layer；The coating of 6- adhesive sticker Layer；7- nickel bar line；8- frosted layer；9-PVC film.
Specific embodiment
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment Described in embodiment do not represent all embodiments consistented with the present invention.On the contrary, they be only with it is such as appended The example of device and method being described in detail in claims, some aspects of the invention are consistent.
Embodiments herein is related to a kind of novel belt glue conductive fabric, as depicted in figs. 1 and 2, including polyester fiber base 1 With adhesive sticker adhesion coating 2, nickel particle 3 is adsorbed in such a way that chemical precipitation or metal physics are shifted in polyester fiber base 1 In polyester fiber base 1, in 3 outer surface of nickel particle by being electroplate with layers of copper 4,4 outer surface of layers of copper is also electroplate with nickel layer 5, the adhesive sticker adhesion coating 2 includes adhesive sticker overlay 6, and the adhesive sticker overlay 6 is applied directly to 5 outer surface of nickel layer, institute Stating adhesive sticker overlay 6 and also passing through chemical precipitation has nickel particle 3, and is carved with nickel bar line 7, institute in 6 outer surface of adhesive sticker overlay Nickel bar line 7 is stated in netted intertexture shape, is fixedly mounted respectively on 2 outer surface of 5 outer surface of nickel layer and adhesive sticker adhesion coating of the other side There are frosted layer 8 and PVC film 9, the PVC film 9 is in the strip of equal in width, and each PVC film 9 is applied with adhesive sticker 6 edge oblique of layer, convenient for the PVC film for protection of tearing as needed.
Preferably, the nickel particle 3 is micron order, and maximum 3 partial size of nickel particle is not more than 10um, the nickel particle 3 Absorption filling 1 surface layer of polyester fiber base forms flat configuration, and particle is smaller, can preferably form adsorption effect, and have There is smaller grain structure to be capable of providing better surface texture, prevents from being formed crude.
It may further be preferable that the polyester fiber base 1, nickel particle 3, layers of copper 4 and nickel layer 5 form integral structure, And there is smooth edge, cut without flash and Ci Bian by primary cutting and polishing treatment at the edge of integral structure.
The main characteristic of the invention lies in that the present invention is by polyester fiber base, with chemical precipitation or metal object Nickel particle is adsorbed in polyester fiber base by the mode of reason transfer, then plates the layers of copper of high conductivity in nickel particle outer surface, The anti-oxidation etch-proof nickel metal of machine in re-plating in layers of copper, copper and mickel combine and provide splendid electric conductivity and good electricity Magnetic Shielding Effectiveness, and there is smooth edge by primary cutting and polishing treatment on edge, it cuts without flash and Ci Bian, And metal coat is carried out by chemical precipitation and electric plating method, form uniform stable outer surface structure, and can be with Resistance is largely improved, the destruction to electroplated layer etc. such as high temperature can be prevented, further, is sunk inside adhesive sticker adhesion coating The nickel particle in shallow lake and the nickel bar line formed on surface, are all to have good conductive capability, can be improved adhesive sticker adhesion coating Conductive capability.
Preferably, the polyester fiber base 1 is made of polyester fiber, in the present invention, by the improvement to polyester master particle, So that the antibiotic effect and electric conductivity of polyester fiber obtain balance, there is good antibacterial, antistatic property.Polyester fiber letter Claim PET fiber, typically refer to polyethylene terephthalate through fiber made from melt spinning, have at low cost, intensity is high, The advantages of rapid-curing cutback and stable structure.Polyester fiber is the first big kind of current synthetic fibers, is taken in fiber various, polyester Fiber applications are extensive.With the continuous improvement of people's living standards, consumer also changes the demand of textile garment therewith, open Begin the textile material for being intended to environmental protection, health.Wherein, antibiotic property is one be often taken into account based on textile use habit Characteristic, the primary efficacy of antibacterial polyester fibre is antibacterial, the procreation for inhibiting bacterium, to achieve the purpose that protect user；In addition, In conjunction with electric conductivity, it can be avoided textile and generate electrostatic phenomenon.In existing functional polyalkylene ester fiber, antibiotic property and electric conductivity knot Merge unobvious, technical effect is bad.
Preferably, the polyester fiber is prepared so that the melting of polyester master particle A, polyester master particle B and polyester slice is blended 's.It is mixed by melting in disclosed technique scheme in conjunction with polyester master particle A and polyester master particle B using existing melt spinning method It spins, polyester master particle A and polyester master particle B is enabled to cooperate with and play a role, while keeping antibacterial effect, enhance polyester fibre The antistatic property of dimension.
Further, in the polyester fiber, the quality accounting of polyester master particle A, polyester master particle B and polyester slice are respectively 14-19%, 6-21%, 60-80%.
Further, in the polyester fiber, the matter of polyester slice, graphene polyester master particle and anion polyester master particle Measuring accounting is respectively 17%, 15%, 68%.
Wherein, the polyester master particle A is obtained by mixing, being granulated with polyester powder by powder A；In polyester master particle A The mass content of powder A is 10-20%；The polyester master particle B is obtained by mixing, being granulated with polyester powder by powder B； The mass content of powder B is 6-25% in polyester master particle B.
Wherein, powder A is made of the mixing of Mg-ZnO nanoparticle, MgO nanoparticle and graphene；Powder B by graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and ZnO nanoparticle composition.
Powder A is to be mixed to obtain through wet grinding technique by Mg-ZnO nanoparticle, MgO nanoparticle and graphene. Wherein, zinc oxide is a kind of common chemical addition agent, is widely used in plastics, silicate product, synthetic rubber, lubrication In the production of the products such as oil, paint, ointment, adhesive, food, battery, fire retardant.The band gap and exciton beam of zinc oxide Tiing up can be larger, and transparency is high, has excellent room temperature luminescent properties, in the liquid crystal display, thin film transistor (TFT), hair of semiconductor field There is application in the products such as optical diode；And ZnO nanoparticle is a kind of traditional inorganic, metal oxide antibacterial agent, by right ZnO nanoparticle adulterates Mg, increases its antibacterial effect, in combination with MgO nanoparticle and graphene as carrier, for anti- Good effect is played in the increase of bacterium effect.It is similar, powder B be by graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, Electrically conductive graphite, CaCO3What nanoparticle and ZnO nanoparticle mixing were obtained through wet grinding technique.Wherein, graphene is a kind of The flat film being made of carbon atom.With perfect two dimensional crystal structure, its lattice is six surrounded by six carbon atoms Side shape, with a thickness of an atomic layer.In graphene, each carbon atom has the p electronics of a non-bonding, these p electronics can To move freely in crystal, and movement velocity is up to the 1/300 of the light velocity, imparts the good electric conductivity of graphene.The disclosure In technical solution, by by graphene and AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and ZnO nanoparticle mixing constitutes powder B, enables to powder B to give full play to electric conductivity, by its CaCO3Nanoparticle and ZnO receive Rice corpuscles plays unexpected beneficial effect as dispersing agent, for the performance of powder B electric conductivity uniformity.
Preferably, in powder A, the mass ratio of Mg-ZnO nanoparticle, MgO nanoparticle and graphene is 5:1:4；Institute Stating Mg-ZnO nano particle diameter is 200nm；The MgO nano particle diameter is 100nm；The partial size of the powder A is less than 1 μ m；
Preferably, in powder B, graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanometer Particle and the mass ratio of ZnO nanoparticle are 7:2:1:4:3:1；The grain of the AZO nanometer conductive powder, ATO nanometer conductive powder Diameter is 100nm；The CaCO3The partial size of nanoparticle is 500nm；The partial size of the ZnO nanoparticle is 50nm；The powder The partial size of body B is less than 2 μm；
In another preferred embodiment, in powder A and powder B it is described it is graphene-supported have a Fe and Cu, load capacity difference It is 4%, 1%.
The preparation method of the polyester fiber is also disclosed below:
Embodiment 1
A kind of polyester fiber, the polyester fiber are to melt blended preparation with polyester master particle A, polyester master particle B and polyester slice It obtains；Wherein, the quality accounting of polyester master particle A, polyester master particle B and polyester slice are respectively 14%, 6%, 80%.
Above-mentioned polyester master particle A is obtained by mixing, being granulated with polyester powder by powder A；Wherein, polyester master particle A The mass content of middle powder A is 10-20%；Above-mentioned polyester master particle B is by mixing, being granulated with polyester powder by powder B It arrives；Wherein, the mass content of powder B is 6-25% in polyester master particle B；
Wherein, powder A is made of the mixing of Mg-ZnO nanoparticle, MgO nanoparticle and graphene, wherein Mg-ZnO receives The mass ratio of rice corpuscles, MgO nanoparticle and graphene is 5:1:4；The Mg-ZnO nano particle diameter is 200nm；Institute Stating MgO nano particle diameter is 100nm；The partial size of the powder A is less than 1 μm；
Wherein, powder B is by graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle It is formed with ZnO nanoparticle；Wherein, graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanometer Particle and the mass ratio of ZnO nanoparticle are 7:2:1:4:3:1；The grain of the AZO nanometer conductive powder, ATO nanometer conductive powder Diameter is 100nm；The CaCO3The partial size of nanoparticle is 500nm；The partial size of the ZnO nanoparticle is 50nm；The powder The partial size of body B is less than 2 μm.
It the following is the preparation method of the present embodiment polyester fiber:
S1, the zinc acetate of the magnesium acetate of 0.01mol and 0.01mol is added in 10ml distilled water, is stirred continuously, then The ethyl alcohol of 90ml is added, is ultrasonically treated 30min, the ammonium hydroxide of 28wt.% is added in reaction system, adjusting pH value is 9.2, with Ultrasound assisted chemical reacts afterwards, after reaction 2 hours, collects Mg-ZnO nanoparticle by high speed centrifugation, receives what is be collected by centrifugation It is dry after rice corpuscles cleaning；Mg-ZnO nanoparticle, MgO nanoparticle and graphene are mixed by ball mill grinding, mistake Sieve, by after sieving powder and corundum ball, water be made into 1: 1: 4 slurries, and 0.5% chelating type lactic acid titanium salt or single alkane is added Oxygen type titanate esters are ground 20 hours in rotary mill, and the slurries after grinding are squeezed into rotation ball mill, and grinding matter is changed to zirconium Ball, rotation grinding 60 hours slough slurry moisture in 110 DEG C~200 DEG C dryings, the powder of drying disperses in airflow mill, It crushes, grinding, obtains powder A；Powder A is mixed with polyester powder, is granulated to obtain polyester master particle A through screw rod；
S2, pass through the following substance of ball mill grinding: graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, conductive stone Ink, CaCO3Nanoparticle and ZnO nanoparticle, are then sieved, by after sieving powder and corundum ball, water be made into 1: 1: 4 slurry Liquid, and 0.7% chelating type lactic acid titanium salt or Monoalkoxy-titanates is added, it grinds 22 hours, will grind in rotary mill Slurries afterwards are squeezed into rotation ball mill, and grinding matter is changed to zirconium ball, and rotation grinding 50 hours takes off in 110 DEG C~200 DEG C dryings Slurry moisture is removed, the powder of drying disperses in airflow mill, crushes, grinds, and obtains powder B；Powder B is mixed with polyester powder It closes, be granulated to obtain polyester master particle B through screw rod；
S3, according to mass ratio, polyester master particle A and polyester master particle B and polyester slice are subjected to combination drying；Drying is true It carries out in empty rotary drum dryer, extracts moisture with air by vacuum system, drying temperature is 130 DEG C；After drying Melt of the raw material under screw extruder effect after melting is pumped in homogeneous removal of impurities blender through melt and carries out homogenization removal of impurities Processing, melt are 30min~90min in the residence time of homogeneous removal of impurities blender；Polyester fondant after homogeneous removal of impurities is through melt It is pumped to secondary filter, filtered melt enters spinning manifold, spinning box temperature after being set the blend melt on pipeline Degree control is at 250~280 DEG C；Fiber after spinning is carried out drawing-off to process to get the polyester fiber.
Measure the anti-microbial property of polyester fiber in the present embodiment:
Antibiotic property test be according to national standard GB/T 20944.3-2008 " evaluation of antibacterial textile performance " Part III, Antibacterial test is carried out to fiber, control sample uses 100% pure cotton fabric, and strain selects staphylococcus aureus ATCC 6538, greatly Enterobacteria 8099, Candida albicans ATCC 10231, sample sterilization method are the 15min that sterilizes at 121 DEG C of high steam, calculate suppression Bacterium rate formula are as follows: Y=(WT- QT)/WT× 100%, wherein Y is the bacteriostasis rate of sample, WTAfter control sample 18h concussion contact The average value of viable bacteria concentration, Q in flaskTFor the average value of viable bacteria concentration in flask after test sample 18h concussion contact.
Test result shows the polyester fiber of the present embodiment to staphylococcus aureus, Escherichia coli and Candida albicans Bacteriostasis rate reach 99%, standard provides bacteriostasis rate >=70% to staphylococcus aureus and Escherichia coli, or to white When the bacteriostasis rate of candida albicans >=60%, sample has antibacterial effect, from test result it can be concluded that, the polyester in the present embodiment Fiber has good fungistatic effect；
Measure the performance of polyester fiber in the present embodiment:
Wherein, filament number 1.7dtex, breaking strength 3.9CN/dtex, elongation at break 43%, resistivity reaches To 105 Ω .cm.
Embodiment 2
A kind of polyester fiber, the polyester fiber are to melt blended preparation with polyester master particle A, polyester master particle B and polyester slice It obtains；Wherein, the quality accounting of polyester master particle A, polyester master particle B and polyester slice are respectively 19%, 21%, 60%.
Above-mentioned polyester master particle A is obtained by mixing, being granulated with polyester powder by powder A；Wherein, polyester master particle A The mass content of middle powder A is 10-20%；
Powder A is made of the mixing of Mg-ZnO nanoparticle, MgO nanoparticle and graphene, wherein Mg-ZnO nanoparticle The mass ratio of son, MgO nanoparticle and graphene is 5:1:4；The Mg-ZnO nano particle diameter is 200nm；The MgO Nano particle diameter is 100nm；The partial size of the powder A is less than 1 μm；
Above-mentioned polyester master particle B is obtained by mixing, being granulated with polyester powder by powder B；Wherein, polyester master particle B The mass content of middle powder B is 6-25%；
Powder B is by graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and ZnO Nanoparticle composition；Wherein, graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and The mass ratio of ZnO nanoparticle is 7:2:1:4:3:1；The AZO nanometer conductive powder, ATO nanometer conductive powder partial size be 100nm；The CaCO3The partial size of nanoparticle is 500nm；The partial size of the ZnO nanoparticle is 50nm；The powder B's Partial size is less than 2 μm.
It the following is the preparation method of the present embodiment polyester fiber:
S1, the zinc acetate of the magnesium acetate of 0.01mol and 0.01mol is added in 10ml distilled water, is stirred continuously, then The ethyl alcohol of 90ml is added, is ultrasonically treated 30min, the ammonium hydroxide of 28wt.% is added in reaction system, adjusting pH value is 9.2, with Ultrasound assisted chemical reacts afterwards, after reaction 2 hours, collects Mg-ZnO nanoparticle by high speed centrifugation, receives what is be collected by centrifugation It is dry after rice corpuscles cleaning；Mg-ZnO nanoparticle, MgO nanoparticle and graphene are mixed by ball mill grinding, mistake Sieve, by after sieving powder and corundum ball, water be made into 1: 1: 4 slurries, and 0.5% chelating type lactic acid titanium salt or single alkane is added Oxygen type titanate esters are ground 20 hours in rotary mill, and the slurries after grinding are squeezed into rotation ball mill, and grinding matter is changed to zirconium Ball, rotation grinding 60 hours slough slurry moisture in 110 DEG C~200 DEG C dryings, the powder of drying disperses in airflow mill, It crushes, grinding, obtains powder A；Powder A is mixed with polyester powder, is granulated to obtain polyester master particle A through screw rod；
S2, pass through the following substance of ball mill grinding: graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, conductive stone Ink, CaCO3Nanoparticle and ZnO nanoparticle, are then sieved, by after sieving powder and corundum ball, water be made into 1: 1: 4 slurry Liquid, and 0.7% chelating type lactic acid titanium salt or Monoalkoxy-titanates is added, it grinds 22 hours, will grind in rotary mill Slurries afterwards are squeezed into rotation ball mill, and grinding matter is changed to zirconium ball, and rotation grinding 50 hours takes off in 110 DEG C~200 DEG C dryings Slurry moisture is removed, the powder of drying disperses in airflow mill, crushes, grinds, and obtains powder B；Powder B is mixed with polyester powder It closes, be granulated to obtain polyester master particle B through screw rod；
S3, according to mass ratio, polyester master particle A and polyester master particle B and polyester slice are subjected to combination drying；Drying is true It carries out in empty rotary drum dryer, extracts moisture with air by vacuum system, drying temperature is 130 DEG C；After drying Melt of the raw material under screw extruder effect after melting is pumped in homogeneous removal of impurities blender through melt and carries out homogenization removal of impurities Processing, melt are 30min~90min in the residence time of homogeneous removal of impurities blender；Polyester fondant after homogeneous removal of impurities is through melt It is pumped to secondary filter, filtered melt enters spinning manifold, spinning box temperature after being set the blend melt on pipeline Degree control is at 250~280 DEG C；Fiber after spinning is carried out drawing-off to process to get the polyester fiber.
Measure the anti-microbial property of polyester fiber in the present embodiment:
Antibiotic property test be according to national standard GB/T 20944.3-2008 " evaluation of antibacterial textile performance " Part III, Antibacterial test is carried out to fiber, control sample uses 100% pure cotton fabric, and strain selects staphylococcus aureus ATCC 6538, greatly Enterobacteria 8099, Candida albicans ATCC 10231, sample sterilization method are the 15min that sterilizes at 121 DEG C of high steam, calculate suppression Bacterium rate formula are as follows: Y=(WT- QT)/WT× 100%, wherein Y is the bacteriostasis rate of sample, WTAfter control sample 18h concussion contact The average value of viable bacteria concentration, Q in flaskTFor the average value of viable bacteria concentration in flask after test sample 18h concussion contact.
Test result shows the polyester fiber of the present embodiment to staphylococcus aureus, Escherichia coli and Candida albicans Bacteriostasis rate reach 99%, standard provides bacteriostasis rate >=70% to staphylococcus aureus and Escherichia coli, or to white When the bacteriostasis rate of candida albicans >=60%, sample has antibacterial effect, from test result it can be concluded that, the polyester in the present embodiment Fiber has good fungistatic effect；
Measure the performance of polyester fiber in the present embodiment:
Wherein, filament number 1.6dtex, breaking strength 3.4CN/dtex, elongation at break 41%, resistivity reaches To 98 Ω .cm.
Embodiment 3
A kind of polyester fiber, the polyester fiber are to melt blended preparation with polyester master particle A, polyester master particle B and polyester slice It obtains；Wherein, the quality accounting of polyester master particle A, polyester master particle B and polyester slice are respectively 17%, 15%, 68%.
Above-mentioned polyester master particle A is obtained by mixing, being granulated with polyester powder by powder A；Wherein, polyester master particle A The mass content of middle powder A is 10-20%；
Powder A is made of the mixing of Mg-ZnO nanoparticle, MgO nanoparticle and graphene, wherein Mg-ZnO nanoparticle The mass ratio of son, MgO nanoparticle and graphene is 5:1:4；The Mg-ZnO nano particle diameter is 200nm；The MgO Nano particle diameter is 100nm；The partial size of the powder A is less than 1 μm；
Above-mentioned polyester master particle B is obtained by mixing, being granulated with polyester powder by powder B；Wherein, polyester master particle B The mass content of middle powder B is 6-25%；
Powder B is by graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and ZnO Nanoparticle composition；Wherein, graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and The mass ratio of ZnO nanoparticle is 7:2:1:4:3:1；The AZO nanometer conductive powder, ATO nanometer conductive powder partial size be 100nm；The CaCO3The partial size of nanoparticle is 500nm；The partial size of the ZnO nanoparticle is 50nm；The powder B's Partial size is less than 2 μm.
It the following is the preparation method of the present embodiment polyester fiber:
S1, the zinc acetate of the magnesium acetate of 0.01mol and 0.01mol is added in 10ml distilled water, is stirred continuously, then The ethyl alcohol of 90ml is added, is ultrasonically treated 30min, the ammonium hydroxide of 28wt.% is added in reaction system, adjusting pH value is 9.2, with Ultrasound assisted chemical reacts afterwards, after reaction 2 hours, collects Mg-ZnO nanoparticle by high speed centrifugation, receives what is be collected by centrifugation It is dry after rice corpuscles cleaning；Mg-ZnO nanoparticle, MgO nanoparticle and graphene are mixed by ball mill grinding, mistake Sieve, by after sieving powder and corundum ball, water be made into 1: 1: 4 slurries, and 0.5% chelating type lactic acid titanium salt or single alkane is added Oxygen type titanate esters are ground 20 hours in rotary mill, and the slurries after grinding are squeezed into rotation ball mill, and grinding matter is changed to zirconium Ball, rotation grinding 60 hours slough slurry moisture in 110 DEG C~200 DEG C dryings, the powder of drying disperses in airflow mill, It crushes, grinding, obtains powder A；Powder A is mixed with polyester powder, is granulated to obtain polyester master particle A through screw rod；
S2, pass through the following substance of ball mill grinding: graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, conductive stone Ink, CaCO3Nanoparticle and ZnO nanoparticle, are then sieved, by after sieving powder and corundum ball, water be made into 1: 1: 4 slurry Liquid, and 0.7% chelating type lactic acid titanium salt or Monoalkoxy-titanates is added, it grinds 22 hours, will grind in rotary mill Slurries afterwards are squeezed into rotation ball mill, and grinding matter is changed to zirconium ball, and rotation grinding 50 hours takes off in 110 DEG C~200 DEG C dryings Slurry moisture is removed, the powder of drying disperses in airflow mill, crushes, grinds, and obtains powder B；Powder B is mixed with polyester powder It closes, be granulated to obtain polyester master particle B through screw rod；
S3, according to mass ratio, polyester master particle A and polyester master particle B and polyester slice are subjected to combination drying；Drying is true It carries out in empty rotary drum dryer, extracts moisture with air by vacuum system, drying temperature is 130 DEG C；After drying Melt of the raw material under screw extruder effect after melting is pumped in homogeneous removal of impurities blender through melt and carries out homogenization removal of impurities Processing, melt are 30min~90min in the residence time of homogeneous removal of impurities blender；Polyester fondant after homogeneous removal of impurities is through melt It is pumped to secondary filter, filtered melt enters spinning manifold, spinning box temperature after being set the blend melt on pipeline Degree control is at 250~280 DEG C；Fiber after spinning is carried out drawing-off to process to get the polyester fiber.
Measure the anti-microbial property of polyester fiber in the present embodiment:
Antibiotic property test be according to national standard GB/T 20944.3-2008 " evaluation of antibacterial textile performance " Part III, Antibacterial test is carried out to fiber, control sample uses 100% pure cotton fabric, and strain selects staphylococcus aureus ATCC 6538, greatly Enterobacteria 8099, Candida albicans ATCC 10231, sample sterilization method are the 15min that sterilizes at 121 DEG C of high steam, calculate suppression Bacterium rate formula are as follows: Y=(WT- QT)/WT× 100%, wherein Y is the bacteriostasis rate of sample, WTAfter control sample 18h concussion contact The average value of viable bacteria concentration, Q in flaskTFor the average value of viable bacteria concentration in flask after test sample 18h concussion contact.
Test result shows the polyester fiber of the present embodiment to staphylococcus aureus, Escherichia coli and Candida albicans Bacteriostasis rate reach 99%, standard provides bacteriostasis rate >=70% to staphylococcus aureus and Escherichia coli, or to white When the bacteriostasis rate of candida albicans >=60%, sample has antibacterial effect, from test result it can be concluded that, the polyester in the present embodiment Fiber has good fungistatic effect；
Measure the performance of polyester fiber in the present embodiment:
Wherein, filament number 1.8dtex, breaking strength 4.2CN/dtex, elongation at break 45%, resistivity reaches To 107 Ω .cm.
Embodiment 4
The present embodiment be based on embodiment 3, the difference is that, in powder A and powder B it is described it is graphene-supported have Fe and Cu, load capacity are respectively 4%, 1%.
Wherein, graphene preparation process is loaded are as follows:
Ferric nitrate and copper nitrate are added in 50ml deionized water, is completely dissolved, then will be dissolved with ferric nitrate and nitric acid The deionized water solution of copper is added in the ethylene glycol of 200ml, obtains mixed liquor, and mixed liquor and graphene oxide suspension are added Enter into four-hole bottle, under 50 DEG C of water bath with thermostatic control environment, strong stirring 3h obtains reaction solution；400ml deionized water is taken again, Sodium hydroxide is added thereto, makes pH value of solution 10, sodium borohydride is then added, the sodium borohydride that 0.1mol/L is made is water-soluble Liquid, and be slowly added in reaction solution, reflux unit is added, is heated to reflux 2h at 120 DEG C, reaction is obtained by filtration and produces Reaction product is cleaned with deionized water, then be dry, pulverize by object, obtains load graphene powder.
Measure the anti-microbial property of polyester fiber in the present embodiment:
Antibiotic property test be according to national standard GB/T 20944.3-2008 " evaluation of antibacterial textile performance " Part III, Antibacterial test is carried out to fiber, control sample uses 100% pure cotton fabric, and strain selects staphylococcus aureus ATCC 6538, greatly Enterobacteria 8099, Candida albicans ATCC 10231, sample sterilization method are the 15min that sterilizes at 121 DEG C of high steam, calculate suppression Bacterium rate formula are as follows: Y=(WT- QT)/WT× 100%, wherein Y is the bacteriostasis rate of sample, WTAfter control sample 18h concussion contact The average value of viable bacteria concentration, Q in flaskTFor the average value of viable bacteria concentration in flask after test sample 18h concussion contact.
Test result shows the polyester fiber of the present embodiment to staphylococcus aureus, Escherichia coli and Candida albicans Bacteriostasis rate reach 99%, standard provides bacteriostasis rate >=70% to staphylococcus aureus and Escherichia coli, or to white When the bacteriostasis rate of candida albicans >=60%, sample has antibacterial effect, from test result it can be concluded that, the polyester in the present embodiment Fiber has good fungistatic effect；
Measure the performance of polyester fiber in the present embodiment:
Wherein, filament number 1.8dtex, breaking strength 4.3CN/dtex, elongation at break 45%, resistivity reaches To 108 Ω .cm.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of novel belt glue conductive fabric, including polyester fiber base (1) and adhesive sticker adhesion coating (2), it is characterised in that: in polyester Nickel particle (3) is adsorbed on polyester fiber base (1) in such a way that chemical precipitation or metal physics are shifted on fibrous base layers (1) On, in nickel particle (3) outer surface by being electroplate with layers of copper (4), layers of copper (4) outer surface is also electroplate with nickel layer (5), it is described not Dry glue adhesion coating (2) includes adhesive sticker overlay (6), and the adhesive sticker overlay (6) is applied directly to nickel layer (5) outer surface, institute Stating adhesive sticker overlay (6) and also passing through chemical precipitation has nickel particle (3), and is carved with nickel bar in adhesive sticker overlay (6) outer surface Line (7), the nickel bar line (7) is in netted intertexture shape, in nickel layer (5) outer surface and adhesive sticker adhesion coating (2) outer surface of the other side It is upper to be fixedly installed with frosted layer (8) and PVC film (9) respectively；The layer of polyester fiber (1) is made of polyester fiber, described poly- Ester fiber is to melt blended be prepared with polyester master particle A, polyester master particle B and polyester slice.
2. a kind of novel belt glue conductive fabric according to claim 1, which is characterized in that the nickel particle (3) is micron order, And maximum nickel particle (3) partial size is not more than 10um, described nickel particle (3) absorption filling polyester fiber base (1) surface layer forms flat Whole structure.
3. a kind of novel belt glue conductive fabric according to claim 1, which is characterized in that the polyester fiber base (1), nickel Particle (3), layers of copper (4) and nickel layer (5) form integral structure, and by primary cutting and throw at the edge of integral structure Light processing.
4. a kind of novel belt glue conductive fabric according to claim 1, which is characterized in that the PVC film (9) is in wide The strip of degree, and each PVC film (9) with adhesive sticker overlay (6) edge oblique.
5. a kind of novel belt glue conductive fabric according to claim 1, which is characterized in that the polyester master particle A be pass through by Powder A mixes with polyester powder, is granulated and obtains；The mass content of powder A is 10-20% in polyester master particle A；The polyester is female Grain B is obtained by mixing, being granulated with polyester powder by powder B；The mass content of powder B is 6-25% in polyester master particle B.
6. a kind of novel belt glue conductive fabric according to claim 5, which is characterized in that the powder A is by Mg-ZnO nanometers Particle, MgO nanoparticle and graphene mixing composition；The powder B is by graphene, AZO nanometer conductive powder, ATO conductive nano Powder, electrically conductive graphite, CaCO3Nanoparticle and ZnO nanoparticle composition.
7. a kind of novel belt glue conductive fabric according to claim 6, which is characterized in that Mg-ZnO nanometers described in powder A The mass ratio of particle, MgO nanoparticle and graphene is 5:1:4；The Mg-ZnO nano particle diameter is 200nm；It is described MgO nano particle diameter is 100nm；The partial size of the powder A is less than 1 μm.
8. a kind of novel belt glue conductive fabric according to claim 6, which is characterized in that in powder B, the graphene, AZO Nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3Nanoparticle and the mass ratio of ZnO nanoparticle are 7:2: 1:4:3:1；The AZO nanometer conductive powder, ATO nanometer conductive powder partial size be 100nm；The CaCO3The grain of nanoparticle Diameter is 500nm；The partial size of the ZnO nanoparticle is 50nm；The partial size of the powder B is less than 2 μm.
9. a kind of novel belt glue conductive fabric according to claim 6, which is characterized in that the polyester master particle A, polyester master particle B is obtained by the following method:
Polyester master particle A:
The zinc acetate of the magnesium acetate of 0.01mol and 0.01mol is added in 10ml distilled water, is stirred continuously, is then added The ethyl alcohol of 90ml is ultrasonically treated 30min, the ammonium hydroxide of 28wt.% is added in reaction system, and adjusting pH value is 9.2, then super Sound assisted chemical reactions after reaction 2 hours, collect Mg-ZnO nanoparticle, the nanoparticle that will be collected by centrifugation by high speed centrifugation It is dry after son cleaning；Mg-ZnO nanoparticle, MgO nanoparticle and graphene are mixed by ball mill grinding, are sieved, it will Powder and corundum ball, water after sieving are made into 1: 1: 4 slurries, and 0.5% chelating type lactic acid titanium salt or single alkoxy type is added Titanate esters are ground 20 hours in rotary mill, and the slurries after grinding are squeezed into rotation ball mill, and grinding matter is changed to zirconium ball, Rotation grinding 60 hours sloughs slurry moisture in 110 DEG C~200 DEG C dryings, and the powder of drying disperses in airflow mill, powder Broken, grinding, obtains powder A；Powder A is mixed with polyester powder, is granulated to obtain polyester master particle A through screw rod；
Polyester master particle B:
Pass through the following substance of ball mill grinding: graphene, AZO nanometer conductive powder, ATO nanometer conductive powder, electrically conductive graphite, CaCO3It receives Rice corpuscles and ZnO nanoparticle, are then sieved, and the powder after sieving are made into 1: 1: 4 slurries with corundum ball, water, and be added 0.7% chelating type lactic acid titanium salt or Monoalkoxy-titanates grinds 22 hours in rotary mill, the slurries after grinding is beaten Entering to rotate in ball mill, grinding matter is changed to zirconium ball, and rotation grinding 50 hours in 110 DEG C~200 DEG C dryings, sloughs slurry moisture, The powder of drying disperses in airflow mill, crushes, grinds, and obtains powder B；Powder B is mixed with polyester powder, is made through screw rod Grain obtains polyester master particle B.
10. a kind of novel belt glue conductive fabric according to claim 1, which is characterized in that in the polyester fiber, polyester is female The quality accounting of grain A, polyester master particle B and polyester slice is respectively 14-19%, 6-21%, 60-80%.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016692A (en) * 2007-01-26 2007-08-15 北京工业大学 Organic fiber conductive powder and preparing method thereof
US20140083635A1 (en) * 2012-03-31 2014-03-27 Ningbo Asia Pulp & Paper Co., Ltd. Process of making antibacterial coating and antibacterial paper with same, and antibacterial paper
CN107119342A (en) * 2017-06-05 2017-09-01 上海帕吉索纳米技术有限公司 A kind of superelevation conductive graphene polyester fiber and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016692A (en) * 2007-01-26 2007-08-15 北京工业大学 Organic fiber conductive powder and preparing method thereof
US20140083635A1 (en) * 2012-03-31 2014-03-27 Ningbo Asia Pulp & Paper Co., Ltd. Process of making antibacterial coating and antibacterial paper with same, and antibacterial paper
CN107119342A (en) * 2017-06-05 2017-09-01 上海帕吉索纳米技术有限公司 A kind of superelevation conductive graphene polyester fiber and preparation method thereof

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