CN109094956A - A kind of mark printing method, packaging material, packing box and beverage filling plant - Google Patents
A kind of mark printing method, packaging material, packing box and beverage filling plant Download PDFInfo
- Publication number
- CN109094956A CN109094956A CN201810942177.1A CN201810942177A CN109094956A CN 109094956 A CN109094956 A CN 109094956A CN 201810942177 A CN201810942177 A CN 201810942177A CN 109094956 A CN109094956 A CN 109094956A
- Authority
- CN
- China
- Prior art keywords
- packaging material
- packing box
- fate
- laser irradiation
- mark
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B3/00—Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
- B65B3/04—Methods of, or means for, filling the material into the containers or receptacles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B61/00—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages
- B65B61/26—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages for marking or coding completed packages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/20—External fittings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/02—Wrappers or flexible covers
Abstract
The invention discloses a kind of mark printing method, a kind of beverage filling plant, a kind of packaging material and a kind of packing box, solve in the prior art the later period printing identification inconvenient on product packing box the technical issues of.The mark printing method is the following steps are included: step 1) prints fate on packaging material semi-finished product using color shifting ink;Step 2) protective mulch on packaging material semi-finished product;Step 3) uses laser irradiation fate, and illuminated area discoloration forms mark in fate.Printing method of the invention is easy to implement, and can be firmly combined with packing box easily in packing box surface later period printing identification, be not easy to be destroyed, while also improve the aesthetics of product.
Description
Technical field
The present invention relates to a kind of mark printing methods, for the printing identification on packaging material or product packing box.The present invention is also
It is related to a kind of packaging material, a kind of packing box, a kind of beverage filling plant.
Background technique
In liquid beverage packaging field, it is typically used for brick packet, pillow packet, the packing box for boring the types such as packet, the packet of these types
Mounted box be formed during beverage filling using band-like packaging material made from, packaging material needs to carry out by special production equipment
Manufacture.
In order to identify product, there are the contents such as pattern, identification code in the surface printing of packing box, such as identification code can be item
Shape code or two dimensional code, for tracing the production information of product, such as date of manufacture, product batch number.
The outermost layer of product packing box is usually PE protective layer, and the coding printed on outer layer PE is easy to be tampered, modification
The case where date of manufacture may cause the case where selling expired beverage generation, and modification product batch number may cause falsifying generation etc..
After packaging material manufacture is completed, it is difficult to realize if rethinking and printing more complex pattern, such as want on packing box
The two dimensional code or trade mark for increasing new commercial use, generally use paster stickup mode, the two dimensional code formed in this way or
Trade mark is not beautiful enough, also not too strong, it is difficult to achieve the desired results.
Some clients can also propose customization demand, such as printing postcard, photo, active theme to product packing box
Deng these items realize on product packing box with regard to more difficult.
Summary of the invention
For the above-mentioned problems in the prior art, the present invention provides a kind of mark printing methods, use discoloration oil
Ink prints fate on packaging material, then forms mark using laser irradiation color shifting ink, improves packing box later period mark print
Technique processed.
The present invention additionally provides a kind of packaging material, a kind of packing box, a kind of beverage filling plant simultaneously.
In order to achieve the above object, the technical scheme of the present invention is realized as follows:
The present invention provides a kind of mark printing method, manufacture packaging material semi-finished product, method first is further comprising the steps of:
Step 1) prints fate on packaging material semi-finished product using color shifting ink;
Step 2) protective mulch on packaging material semi-finished product;
Step 3) uses laser irradiation fate, and illuminated area discoloration forms mark in fate.
Preferably, color shifting ink uses photosensitive colour-changing ink or heat-sensitive colour-changing ink.
Preferably, later period printing tag slot has been reserved in fate.
Preferably, it is identified as any one in text, number, pattern, bar code or two dimensional code, or any several
Combination.
Preferably, the joint length for identifying packaging material, without laser irradiation in the joint length of packaging material.
Preferably, two pieces or more of fate is printed on packaging material semi-finished product, packaging material is shaped to after packing box, predetermined position
In the front of packing box, reverse side, side or top surface.
The present invention also provides a kind of packaging materials, are made by above-described mark printing method.
The present invention also provides a kind of packing boxes, are made by above-described mark printing method.
The present invention also provides a kind of beverage filling plants, including packaging material storing unit, packaging material feedway, beverage filling
Device, packing box molding machine, beverage product conveying device, further include laser irradiation device;
Laser irradiation device is mounted on packaging material feedway packaging material or packing box in perhaps beverage product conveying device
When passing through from laser irradiation device position, laser irradiation device to the color shifting ink fate on packaging material or packing box into
Row laser irradiation allows illuminated area discoloration in fate to form mark.
Preferably, packaging material feedway is equipped with laser irradiation device more than two, respectively corresponds different positions on packaging material
Several fates set.
Preferably, beverage product conveying device is equipped with laser irradiation device more than two, respectively corresponds packing box
Fate on front, reverse side, side or top surface.
Preferably, sensor is set in beverage product conveying device, and sensor, which detects, starts laser when packing box passes through
Irradiation unit carries out laser irradiation to color shifting ink fate.
Preferably, packaging material feedway includes several propelling sheaves, and packaging material is directed to beverage filling from packaging material storing unit
Device.
It is had the advantage that using the mark printing method of above-mentioned technological means
Printing method of the invention prints fate using color shifting ink on packaging material semi-finished product, then passes through laser irradiation
Color shifting ink is allowed to change colour to form mark, printing method is easy, can implement easily in packing box surface later period printing identification
Simplicity is firmly combined with packing box, not easily modified or destruction, while also improving the aesthetics of product.
It is had the advantage that using the beverage filling plant of above-mentioned technological means
Beverage filling plant of the invention can be obtained by the simple transformation to existing beverage filling plant, be easy to real
Existing, improvement cost is low.
Detailed description of the invention
Fig. 1 is the flow chart of mark printing method in the embodiment of the present invention 1;
Fig. 2 is the structural schematic diagram of packaging material manufacturing equipment in the embodiment of the present invention 5;
Fig. 3 is the structural schematic diagram of beverage filling plant in the embodiment of the present invention 3;
Fig. 4 is the structural schematic diagram of beverage filling plant in the embodiment of the present invention 4;
Fig. 5 is the structural schematic diagram with mark packing box in the embodiment of the present invention 1;
Fig. 6 is the structural schematic diagram with mark packing box in the embodiment of the present invention 1;
Fig. 7 is the structural schematic diagram with mark packing box in the embodiment of the present invention 2;
Fig. 8 is the structural schematic diagram with mark packaging material in the embodiment of the present invention 1.
In figure: 1. packing boxes;2. fate;3. the later period prints tag slot;4. packaging material.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with attached drawing to embodiment party of the present invention
Formula is described in further detail.
Embodiment 1
It is as shown in Figure 1 the embodiment of the present invention 1, in the present embodiment, a kind of mark printing method, first manufacture packaging material half
Finished product, packaging material semi-finished product are the packaging materials for having been provided with paper base and printing layer, at this time there are no composite protection layer (also cry outermost layer or
Person's waterproof layer), next to print color shifting ink in printing layer.It is glued as hot sealing layer, the first adhesive layer, aluminium foil, second
The composite steps of layer are tied, can before printing, it can also be after composite protection layer, preferably after the printing, complex protection
Before layer.
Mark printing method further includes following steps:
Step 1) prints fate on packaging material semi-finished product using color shifting ink;
Step 2) protective mulch on packaging material semi-finished product;
Step 3) uses laser irradiation fate, and illuminated area discoloration forms mark in fate.
Because every volume packaging material can form connector with other packaging material continued accesses on head and tail portion during beverage filling,
The packing box that packaging material in joint length is formed can be rejected as useless packet, so if before using laser irradiation fate,
It can use the joint length of other technological means identification packaging materials, without laser irradiation in the joint length of packaging material, in this way
It, will not be useless because of being imprinted on especially when being identified as prize drawing, the picture in groups of integral mark or customization, postcard, photo etc.
It wraps and cancels, lacks or omit.
The structure identified in the present embodiment is as shown in figure 5,1 upper left corner rectangular area of packing box is the predetermined of printing in Fig. 5
Area 2, the packing box 1 in left side have not gone through laser irradiation, and fate 2 not yet forms mark, and the packing box 1 on right side passes through laser
Irradiation, the discoloration of fate 2 form mark.
The color shifting ink used in the present embodiment can use heat-sensitive colour-changing ink according to discoloration technology type, by laser
Can change colour (laser irradiation can heat fate) after heating, or use photosensitive colour-changing ink, by laser irradiation
After can change colour.Laser irradiation formation mark is usually irreversible, namely the mark formed is non-erasable and modification.
Laser irradiation special material, which changes colour, to be formed the principle of mark and can not be explained herein with reference to the prior art.
Current main-stream mode is got on color shifting ink by many tiny laser beams, and the ink point got to generates discoloration.Certainly originally
Field technical staff understands that any laser irradiation discoloration mode is suitable for the present invention.The light that laser projection goes out is by computer control
System, can arbitrarily change, meet various types of mark demands.Laser irradiation speed is very fast, carrier, that is, packaging material of fate 2
Or laser irradiation can be completed in lasting traveling process and form mark for packing box.
One piece of fate 2 can be only printed on packaging material semi-finished product, fate 2 is located at front, reverse side, the side of packing box 1
Or top surface can be with.
Two pieces or more of fate 2 can also be printed on packaging material semi-finished product, such as first fate 2 is located at packing box
1 front, second fate 2 are located at the reverse side of packing box 1, and third fate 2 is located at the top surface of packing box 1.
Fate 2, which can be printed in printing layer, arbitrarily needs position, such as after packing box 1 forms, fate 2
In the positive upper left corner of packing box 1, the lower left corner, the upper right corner, the lower right corner.
Fate 2 can be arbitrary shape, such as rectangle, circle, ellipse, other polygons etc..
Protective layer not only covers fate 2 using polyethylene (PE) or polypropylene (PP), protective layer, substantially covers
Whole extexines of packaging material, to packaging material play protection, isolation, waterproof effect.
Step 3) carries out usually after beverage filling, and packing box 1 has formed at this time, makes outside packing box 1 immediately
It makes a check mark.
By above-mentioned mark printing method, can be easy to implement easily in 1 surface later period of packing box printing identification,
And printing is beautiful, is firmly combined with packing box 1, is not easy to be destroyed.Mark is located at printing layer surface and protective layer (waterproof layer)
Positioned at this composite construction of printing layer and mark top, so that otherwise mark can not be distorted except non-demolition packaging structure, that is, energy
It is enough to realize the purpose for forbidding mark to be tampered.
As shown in figure 5, the present embodiment additionally provides a kind of tagged packing box 1 of band, printed by above-described mark
Method processed is made, and the positive upper left corner of packing box 1 is printed with the fate 2 of rectangle, and fate 2 changes colour to form mark through laser irradiation
Know, mark is specially Text region code.
As shown in fig. 6, the positive upper left corner of packing box 1 is printed with circular fate 2, fate 2 becomes through laser irradiation
Color forms mark, and mark is specially pattern.
Certainly, step 3) can also carry out before beverage filling, and packaging material is unfolded in packaging material feedway at this time,
It is prepared to enter into beverage filling device and packing box molding machine, makes mark on packaging material immediately.Packaging material feedway
Refer to and guide the device that packaging material advances in beverage filling plant, is provided with the components such as propelling sheave, tensioning wheel.
The structure of packaging material is as shown in figure 8, be printed with multiple fates 2, the packet in left side in the present embodiment on packaging material 4 in Fig. 8
Material 4 has not gone through laser irradiation, and fate 2 not yet forms mark, and the packaging material 4 on right side passes through laser irradiation, and fate 2 changes colour
Form mark.The color shifting ink fate 2 of different location on packaging material 4, respectively appear in the future the front of packing box 1, reverse side,
Side or top surface.
Embodiment 2
It is illustrated in figure 7 the embodiment of the present invention 2, with embodiment 1 the difference is that mark printing method in the present embodiment
Later period printing tag slot 3 is reserved in fate 2, instant packed 1 later period of box makes the mark of other purposes again.
Printing identification usually occurs after beverage products produce again in later period printing tag slot 3, the printing step
The retailer two dimensional code or trade mark that increase new commercial use can be given, sufficiently large area is reserved in later period printing tag slot 3
When domain, postcard, photo, active theme etc. can also be printed, facilitates retailer's sales promotion beverage products.
Other steps of mark printing method are in the same manner as in Example 1 in the present embodiment, are not repeated to describe herein.
Embodiment 3
It is illustrated in figure 3 the embodiment of the present invention 3, present embodiments provides a kind of beverage filling plant, in the present embodiment,
Beverage filling plant include packaging material storing unit, packaging material feedway, beverage filling device, packing box molding machine, beverage at
Product conveying device and laser irradiation device.
Laser irradiation device is mounted in beverage product conveying device, if Fig. 5, Fig. 6, packing box shown in Fig. 71 are from laser
When irradiation unit position passes through, laser irradiation device carries out laser irradiation to color shifting ink fate 2 on packaging material, allows predetermined
Illuminated area discoloration forms mark in area 2.
The light that laser irradiation device is projected out is controlled by computer, can arbitrarily be changed, and various types of marks are met
Demand.Laser irradiation speed is very fast, and the carrier, that is, packaging material or packing box of fate 2 can be completed sharp in lasting traveling process
Light irradiates and forms mark.
Laser irradiation device can be set more than two, respectively correspond on front, reverse side, side or the top surface of packing box 1
Fate 2.
Sensor is set in beverage product conveying device, sensor detect packing box 1 by when starting laser irradiation dress
It sets and laser irradiation is carried out to color shifting ink fate.
Sensor can use the types such as photoelectric sensor or magnetic proximity sensor.
Above-mentioned packaging material storing unit, packaging material feedway, beverage filling device, packing box molding machine and beverage product
Original relevant device in beverage filling plant in the prior art can be used in conveying device.In beverage product conveying device again
Increase by one group or several groups laser irradiation device, is easily achieved in this way, improvement cost is low.
Embodiment 4
It is illustrated in figure 4 the embodiment of the present invention 4, with embodiment 3 the difference is that in the present embodiment, laser irradiation fills
It sets and is mounted on packaging material feedway, packaging material is unfolded in packaging material feedway at this time, is prepared to enter into beverage filling device
In packing box molding machine.Packaging material feedway, which refers to, guides the device that packaging material advances in beverage filling plant, provided with leading
Packaging material is directed to beverage filling device from packaging material storing unit by the components such as running wheel, tensioning wheel.
When packaging material passes through from laser irradiation device position, laser irradiation device is to color shifting ink fate on packaging material
2 carry out laser irradiation, and illuminated area discoloration in fate 2 is allowed to form mark.
Laser irradiation device can be set more than two, respectively correspond the color shifting ink fate 2 of different location on packaging material,
The color shifting ink fate of these different locations respectively appears in front, reverse side, side or the top surface of packing box 12 future.
Above-mentioned packaging material storing unit, packaging material feedway, beverage filling device, packing box molding machine and beverage product
Original relevant device in beverage filling plant in the prior art can be used in conveying device.It is further added by packaging material feedway
One group or several groups laser irradiation device, are easily achieved, improvement cost is low in this way.
Embodiment 5
Present embodiment discloses a kind of packaging material manufacturing equipments, shown in structural reference Fig. 2, can provide and be printed with for the present invention
The packaging material of color shifting ink fate 2.
Packaging material manufacturing equipment includes: that color shifting ink printing equipment, protective layer overlay device, packaging material winding apparatus and packaging material are cut
Cut equipment.
Pass through packet between color shifting ink printing equipment, protective layer overlay device, packaging material winding apparatus and packaging material shearing equipment
Material conveying device is sequentially connected, and band-like packaging material can be sent to another equipment from an equipment by packaging material conveying device.
Color shifting ink printing equipment prints fate 2 using color shifting ink on packaging material semi-finished product, in Fig. 5, Fig. 6, Fig. 7
Fate 2.
Protective layer overlay device is laid with protective layer covering packaging material and fate 2 on packaging material semi-finished product.
Color shifting ink printing equipment can be set more than two, and it is pre- that the different location on packaging material semi-finished product prints several
Determine area 2, the color shifting ink fate of these different locations respectively appears in front, reverse side, side or the top of packing box 12 future
Face.
It is raw that packaging material in the prior art can be used in above-mentioned protective layer overlay device, packaging material winding apparatus and packaging material shearing equipment
Produce original relevant device in equipment, color shifting ink printing equipment can be used in packaging material production equipment original printing equipment into
Row is transformed, such as is further added by a set of printing equipment dedicated for printing color shifting ink, is easily achieved in this way, improvement cost
It is low.
The packaging material technological process of production in the prior art generally includes following steps: rolling up, prints on printing production line, receives
The coiled material for completing printing is transported to composite production line, upper volume by volume, other compound layers wind, the coiled material for completing compound is transported to and is cut
Production line is cut, is cut.
Color shifting ink printing equipment in the present embodiment can be set in printing production line, protective layer overlay device and packaging material
Winding apparatus can be set in composite production line, and packaging material shearing equipment can be set in cutting production line.Packaging material conveying device
There are many types, has both included the conveying device inside each production line, also includes the conveying device between each production line.
The above is only a specific embodiment of the invention, and under above-mentioned introduction of the invention, those skilled in the art can be with
Other improvement or deformation are carried out on the basis of the above embodiments.It will be understood by those skilled in the art that above-mentioned specifically retouches
It states and only preferably explains that the purpose of the present invention, protection scope of the present invention should be subject to the protection scope in claims.
Claims (12)
1. a kind of mark printing method, first manufacture packaging material semi-finished product, which is characterized in that the method also includes following steps:
Step 1) prints fate on the packaging material semi-finished product using color shifting ink;
Step 2) protective mulch on the packaging material semi-finished product;
Step 3) uses fate described in laser irradiation, and illuminated area discoloration forms mark in the fate.
2. mark printing method as described in claim 1, which is characterized in that the color shifting ink using photosensitive colour-changing ink or
Heat-sensitive colour-changing ink.
3. mark printing method as described in claim 1, which is characterized in that reserved later period printing mark in the fate
Area.
4. mark printing method as described in claim 1, which is characterized in that described to be identified as text, number, pattern, bar shaped
Any one in code or two dimensional code, or any several combination.
5. mark printing method as described in claim 1, which is characterized in that the joint length for identifying packaging material, in the packaging material
Joint length in without laser irradiation.
6. mark printing method as described in claim 1, which is characterized in that print two pieces or more on the packaging material semi-finished product
The fate, packaging material are shaped to after packing box, and the fate is located at front, reverse side, side or the top of the packing box
Face.
7. a kind of packaging material, which is characterized in that be made by mark printing method described in any one of claims 1-6.
8. a kind of packing box, which is characterized in that be made by mark printing method described in any one of claims 1-6.
9. a kind of beverage filling plant, including the molding of packaging material storing unit, packaging material feedway, beverage filling device, packing box
Device, beverage product conveying device, which is characterized in that further include laser irradiation device;
The laser irradiation device is mounted on packaging material feedway packaging material or packing box in perhaps beverage product conveying device
When passing through from the laser irradiation device position, the laser irradiation device is to the color shifting ink on packaging material or packing box
Fate carries out laser irradiation, and illuminated area discoloration in the fate is allowed to form mark.
10. beverage filling plant as claimed in claim 9, which is characterized in that the packaging material feedway be equipped with two groups with
On the laser irradiation device, respectively correspond several described fates of different location on the packaging material.
11. beverage filling plant as claimed in claim 9, which is characterized in that the beverage product conveying device is equipped with two
Group or more the laser irradiation device, respectively correspond described predetermined on front, reverse side, side or the top surface of the packing box
Area.
12. the beverage filling plant as described in claim 9 or 11, which is characterized in that set in the beverage product conveying device
Sensor is set, the sensor, which detects, starts the laser irradiation device to the color shifting ink fate when packing box passes through
Carry out laser irradiation.
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Cited By (1)
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CN109774330A (en) * | 2019-03-20 | 2019-05-21 | 江苏天顺印业有限公司 | A kind of preparation method and device of laser induced discoloration heat transfer film |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109774330A (en) * | 2019-03-20 | 2019-05-21 | 江苏天顺印业有限公司 | A kind of preparation method and device of laser induced discoloration heat transfer film |
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