CN109085313A - A kind of gas detection method and gas detecting instrument - Google Patents

A kind of gas detection method and gas detecting instrument Download PDF

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Publication number
CN109085313A
CN109085313A CN201811294975.4A CN201811294975A CN109085313A CN 109085313 A CN109085313 A CN 109085313A CN 201811294975 A CN201811294975 A CN 201811294975A CN 109085313 A CN109085313 A CN 109085313A
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gas
sensor
array
signal
module
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王大平
董承智
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Fujian Bokai Technology Co Ltd
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Fujian Bokai Technology Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0031General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array
    • G01N33/0032General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array using two or more different physical functioning modes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
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  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

The present invention relates to a kind of gas detection method and gas detecting instruments, the gas detection method of the technical program, it is that gas detection module provides detection gas in the case where guaranteeing that detection environment is constant by gas collection module, and using in detection module, gas with various sensor provides integrated data group to the sensibility of gas with various, with the mixing of the gas with various in corresponding detected place, to improve the detection accuracy of gas detecting instrument.

Description

A kind of gas detection method and gas detecting instrument
Technical field
The invention belongs to air detection technical fields, particularly relate to the gas that unknown gas is detected in a kind of pair of air Detection method and gas detecting instrument.
Background technique
In order to whether have polluted gas or toxic and harmful gas in clear current environment, it is required in many places to working as Gas in preceding place is detected, to realize certain specific demands.
For example, needing to detect in passenger baggage case whether have volatile materials, in places such as airport, stations to avoid right The harm of the vehicles such as remaining passenger or aircraft, train and influence public safety.In usual household, need to detect Whether indoor environment detects because of the exceeded of the pernicious gases such as formaldehyde caused by the reasons such as finishing, or in industrial enterprise Whether flammable explosive gas is exceeded and jeopardizes normal production and personal safety.
The detecting instrument that existing technology uses, the target of detection is substantially determining, for example detection alcohol gas is true It is fixed whether the detector of drunk driving, it is only sensitive to alcohol gas, and other gases cannot be detected, therefore, now often report by mistake The exceeded phenomenon of alcohol gas.For another example H2S detector, it is only sensitive to hydrogen sulfide gas, and to simultaneously with other When the gases such as gas, such as methane, sulfur dioxide, will not substantially it detected.
Reality is that in most cases, a certain specific place, may need to detect in different times is not Same gas, such as airport or station;In the case of another, in home environment, pollutant is not single formaldehyde, it is also possible to It is to have certain toxic action to human body including toluene, ethylbenzene and more benzene ring compounds.In mine, it is not only single Gas further includes the gas that other many can set off an explosion.This allows for corresponding in order to be equipped with to different gas detections Detecting instrument, or multiple and different gas detecting instruments are used side by side, the detection at existing airport or station is exactly using multiple inspections Instrument is surveyed side by side using being directed to different gas.And the quantity that this phenomenon results in the need for detecting instrument is more, detection is inconvenient And increase the investment of cost.
Summary of the invention
The object of the present invention is to provide a kind of gas detection method and gas detecting instruments, to solve the detector of the prior art The problem of being only capable of detection pure gas, and mixed gas cannot be detected.
The present invention is achieved by the following technical solutions:
A kind of gas detection method, comprising the following steps:
1) prepare the gas sensor group of the variety classes gas sensor including design quantity;
2) prepare the sample of design detection gas, sample size is Yn, and n is natural number;
3) control gas N0 is provided to the gas sensor group, the gas passes each of in the gas sensor group Sensor exports corresponding control signal to control module, and the control module exports the control signal soft to abview Part, the control signal of all gas sensors form different peak values on the curve of abview software, and corresponding peak value is total With composition control signal array H0, and save;
4) selecting step 2) in sample Y1, and be supplied to the gas sensor group;In the gas sensor group Each gas sensor exports corresponding data-signal to the control module, and the control module believes the data Abview software is given in number output, and the data-signal of all gas sensors forms different peaks on the curve of abview software Value, corresponding peak value collectively constitute array H1, save array H1 and corresponding sample composition;
5) step 3) is repeated, control signal array H01 is obtained and is compared with control signal array H0, if in design model In enclosing, then step 6) is carried out, otherwise, repeats step 3);
6) sample Y2 is chosen from the step 2), repeats step 4), obtains array H2, saves array H2 and corresponding sample Product composition;
7) step 5) and step 6) are repeated, until sample Yn, and array Hn is obtained, save array Hn and corresponding sample sets At;
8) by array H1 and corresponding sample composition, array H2 and corresponding sample composition until array Hn and corresponding sample Product composition sets up database;
9) gas to be detected is supplied to the gas sensor group, the gas each of in the gas sensor group Sensor exports corresponding data-signal to the control module, the control module by the data-signal export to Abview software, the data-signal of all gas sensors form different peak values on the curve of abview software, corresponding Peak value collectively constitute gas array to be detected, the gas array to be detected is compared with the array in database, most connects Array corresponding to sample composition be gas composition to be detected.
Gas sensor group includes nine kinds of sensors sensitive to gas with various, respectively first sensor, the second sensing Device, 3rd sensor, the 4th sensor, the 5th sensor, the 6th sensor, the 7th sensor, the 8th sensor and the 9th pass Sensor.
Comparison in step 5) includes the independent comparison between the control signal of each gas sensor, also includes control letter The comparison of the integrated value of the integrated value and control signal array H01 of number group H0.
Comparison in step 9) includes the data-signal gas corresponding with array each in database of each gas sensor The comparison of the data-signal of body sensor, also including gas array to be detected integrated value and data be in each array synthesis The comparison of value.
For the abview software installation on external equipment, the external equipment is computer or central processing unit.
A kind of gas detecting instrument, including gas collection module, gas detection module, power supply module, control module and outside Equipment;
The gas collection module includes air pump, gas chamber, air intake duct, exhaust pipe and connection tracheae;The air intake duct enters Outlet with environmental communication to be measured, the air intake duct is connect with the entrance of the gas chamber;It is described connection tracheae entrance with it is described The outlet of gas chamber connects, and the outlet of the connection tracheae is connect with the entrance of the air pump;The entrance of the exhaust pipe with it is described The outlet of air pump connects, the outlet of the exhaust pipe and the environmental communication to be measured;
The gas detection module is made of gas sensor group, and the gas sensor group includes two or more Gas sensor;The gas sensor is set side by side, and the gas sensor group is set in the gas chamber;
Each gas sensor corresponds signal with the control module input port and connect;
The power supply module is electrically connected with the air pump, the gas sensor and the control module respectively;It is described outer Portion's equipment is connect with the control module signal.
The gas sensor group includes nine kinds of sensors sensitive to gas with various, respectively first sensor, second Sensor, 3rd sensor, the 4th sensor, the 5th sensor, the 6th sensor, the 7th sensor, the 8th sensor and Nine sensors.
It is all the same to the gas flow rate of each sensor offer in the gas chamber.
The power supply module includes power supply and voltage changing module;The gas sensor group is connect with the power lead;
The power supply is connect with the voltage changing module conducting wire, and the air pump is connect with the voltage changing module conducting wire;
The control module is connect with power lead or the control module is connect by USB interface with external power supply.
It is provided with memory module on the control module.
The beneficial effects of the present invention are:
The gas detection method of the technical program is that gas detection module is guaranteeing to detect environment by gas collection module Detection gas are provided in the case where constant, and using in detection module, gas with various sensor proposes the sensibility of gas with various It is accurate with the detection for improving gas detecting instrument with the mixing of the gas with various in corresponding detected place for integrated data group Degree.
Detailed description of the invention
Fig. 1 is the schematic diagram of detector of the present invention;
Fig. 2 is that schematic diagram is arranged in blank control in labview;
Fig. 3 is that schematic diagram is arranged in data collection in labview;
Fig. 4 is detector neural metwork training lab diagram;
Fig. 5 is detector predicted value and actual comparison data schematic table.
Specific embodiment
Carry out the technical solution that the present invention will be described in detail by the following examples, embodiment below is merely exemplary, only It can be used to explanation and illustration technical solution of the present invention, and be not to be construed as the limitation to technical solution of the present invention.
The application provides a kind of gas detection method, comprising the following steps:
1) prepare the gas sensor group of the variety classes gas sensor including design quantity;In the present embodiment, gas Body sensor group includes nine kinds of sensors sensitive to gas with various, respectively first sensor, second sensor, third sensing Device, the 4th sensor, the 5th sensor, the 6th sensor, the 7th sensor, the 8th sensor and the 9th sensor.In this Shen In other embodiments please, the gas sensor type in each gas sensor group can be more than nine kinds or less than nine Kind, it is preferred that being nine kinds of gas sensors, this nine kinds of gas sensors are that each gas sensor is to one or two Gas sensitization.
2) prepare the sample of design detection gas, sample size is Yn, and n is natural number;According to the difference of sample, data Library is not identical, and can increase in the case where increasing sample database, can also be by using self study function Can, increase the array amount of database.
3) control gas N0 is provided to gas sensor group, each gas sensor in gas sensor group is to control Module exports corresponding control signal, and control module, which exports control signal, gives abview software, all gas sensors Control signal forms different peak values on the curve of abview software, and corresponding peak value collectively constitutes control signal array H0, And it saves;In this application, control gas is usually air, but also be can according to need using other gases, such as inertia Gas, hydrogen etc., it is preferred to use air.
In the other embodiments of the application, the control signal that control module obtains can also be exported to external equipment In, such as in chromatograph or labview software, to obtain the data such as corresponding curve and peak value.
4) selecting step 2) in sample Y1, and be supplied to gas sensor group;Each gas in gas sensor group Sensor exports corresponding data-signal to control module, and data-signal is exported and gives abview software by control module, owns The data-signal of gas sensor different peak values is formed on the curve of abview software, corresponding peak value collectively constitutes number Group H1, saves array H1 and corresponding sample composition;Gas sensor exports the susceptibility of gas with various according to it corresponding Data-signal, data-signal can be the existing convenient value such as concentration percentage composition, molar concentration, volume content, herein without Detailed description.
In the other embodiments of the application, the control signal that control module obtains can also be exported to external equipment In, such as in chromatograph or labview software, to obtain the data such as corresponding curve and peak value.
5) step 3) is repeated, control signal array H01 is obtained and is compared with control signal array H0, if in design model In enclosing, then step 6) is carried out, otherwise, repeats step 3);Compare between the control signal including each gas sensor Individually comparison, the also comparison of the integrated value including control signal array H0 and the integrated value of control signal array H01.Integrated value is adopted It is calculated with conventional mathematical function algorithm.
6) sample Y2 is chosen from step 2), repeats step 4), obtains array H2, saves array H2 and corresponding sample sets At.
7) step 5) and step 6) are repeated, until sample Yn, and array Hn is obtained, save array Hn and corresponding sample sets At.
8) by array H1 and corresponding sample composition, array H2 and corresponding sample composition until array Hn and corresponding sample Product composition sets up database, and database is stored in control module, or is stored in external equipment.
9) gas to be detected is supplied to gas sensor group, each gas sensor in gas sensor group is to control Molding block exports corresponding data-signal, and control module, which exports data-signal, gives abview software, all gas sensors Data-signal different peak values is formed on the curve of abview software, corresponding peak value collectively constitutes gas number to be detected Group, gas array to be detected are compared with the array in database, and sample composition corresponding to the array most connect is as to be checked Survey gas composition.
Compare the data-signal gas sensor corresponding with array each in database including each gas sensor The comparison of data-signal, also including gas array to be detected integrated value and data be in each array integrated value comparison. Integrated value is calculated using conventional mathematical function algorithm.
For abview software installation on external equipment, external equipment is computer or central processing unit.
Gas sensor group includes nine kinds of sensors sensitive to gas with various, respectively first sensor, the second sensing Device, 3rd sensor, the 4th sensor, the 5th sensor, the 6th sensor, the 7th sensor, the 8th sensor and the 9th pass Sensor.
The application provides a kind of gas detecting instrument, a kind of gas detecting instrument, including gas collection module, gas detection mould Block, power supply module, control module and external equipment.
As shown in Figure 1, gas collection module includes air pump, gas chamber, air intake duct, exhaust pipe and connection tracheae;Air intake duct Enter and is connected with environmental communication to be measured, the outlet of air intake duct and the entrance of gas chamber;The outlet for connecting the entrance and gas chamber of tracheae connects, The entrance of the outlet and air pump that connect tracheae connects;The outlet of the entrance of exhaust pipe and air pump connects, the outlet of exhaust pipe with to Survey environmental communication.
In this application, the purpose of gas chamber is to provide same gas stream for all gas sensor in gas collection module The air-flow of amount, to guarantee detection data property really, shape or structure for gas chamber etc. and without specifically requiring, as long as energy It is enough to realize that the gas flow rate provided each sensor is all the same.
In the present embodiment, as shown in Figures 2 to 5, environment to be measured is simulated using gas bottle, and calibrating gas is added to It in gas bottle, is stoppered using rubber stopper, the outlet end of the arrival end of air intake duct and exhaust pipe is passed through into rubber stopper and gas bottle Connection realizes the stabilization for collecting data in this way, guaranteeing to run in closed circulation system after opening air pump.
Gas detection module is made of gas sensor group, and gas sensor group includes that two or more gas passes Sensor;Gas sensor is set side by side, and gas sensor group is set in gas chamber.
Gas sensor group includes nine kinds of sensors sensitive to gas with various, respectively first sensor, the second sensing Device, 3rd sensor, the 4th sensor, the 5th sensor, the 6th sensor, the 7th sensor, the 8th sensor and the 9th pass Sensor.In this application, each gas sensor output data is analog signal.
In the present embodiment, gas sensor group by nine kinds respectively the sensor sensitive to gas with various form, still, one When a gas sensor is to specific gas sensitization, other gas sensors are although insensitive to the gas, but there is also Certain response numerical value, and the different and different gas concentration of response numerical value of remaining eight kinds of gas sensor Under, the response numerical value of remaining eight kinds of gas sensor may have different variations, these different responses are collected to be formed Each array, each array represent the gas of certain concentration.
Herein by taking alcohol gas as an example, in gas sensor group, alcohol gas sensor is most sensitive to alcohol gas, The peak of curve highest being shown on labview;And other eight kinds of gas sensors are also individually present centainly on labview Peak value, therefore, will after the data collection of each peak value in this nine kinds of gas sensors formed an array;When change ethanol gas When the concentration of body, the peak value of each sensor has corresponding variation, these new peak values form a new array after collecting.
By repeatedly, multiple types data collection, form database about alcohol gas after training, when unknown at certain Gas in, when containing certain density alcohol gas, formed practical array can have centainly with the data in database Matching, such signal export when, can accurately detect the alcohol gas and concentration in unknown gas;Equally, for Other gases also can accurately detected.
By multiple array set formed database, by database purchase in control module, when gas sensor group again into When row is actually detected, each gas sensor passes to control by signal for the data response numerical value of the gas in detection place After module, practical array is formed within the control module, is compared with database, to determine the real gas kind in detection place Class.
Each gas sensor corresponds signal with control module input port and connect.
Power supply module is electrically connected with air pump, gas sensor and control module respectively.
External equipment is connect with control module signal, and for abview software installation on external equipment, external equipment is computer Or central processing unit.
In the present embodiment, power supply is mobile power source, output voltage 5V, every kind of gas sensor in gas sensor group Operating voltage be 5V;The operating voltage of air pump is 12V;The operating voltage of control module is 3.3V-5V.
Power supply module includes power supply and voltage changing module;Gas sensor group is connect with power lead.Gas sensor group Each gas sensor is connected in parallel on power supply.
Power supply is connect with voltage changing module conducting wire, and air pump is connect with voltage changing module conducting wire.
Control module is connect with power lead or control module is connect with external power supply;Specially control module can be straight It connects and connects to power supply, realize the independence of detecting instrument;On the other hand, when detecting instrument when detecting, can with external power supply, For example connect by USB interface with computer, then computer directly can provide power supply for control module, and can be carried out data transmission.
Memory module is provided in control module;Control module is Arduino-leo plate.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And deformation, the scope of the present invention are extremely equally limited by appended claims.

Claims (10)

1. a kind of gas detection method, which comprises the following steps:
1) prepare the gas sensor group of the variety classes gas sensor including design quantity;
2) prepare the sample of design detection gas, sample size is Yn, and n is natural number;
3) control gas N0, the gas sensor each of in the gas sensor group are provided to the gas sensor group Corresponding control signal is exported to control module, the control module, which exports the control signal, gives abview software, institute The control signal of some gas sensors forms different peak values on the curve of abview software, and corresponding peak value collectively constitutes Control signal array H0, and save;
4) selecting step 2) in sample Y1, and be supplied to the gas sensor group;Each of in the gas sensor group The gas sensor exports corresponding data-signal to the control module, and the control module is defeated by the data-signal Abview software is given out, the data-signal of all gas sensors forms different peak values on the curve of abview software, Corresponding peak value collectively constitutes array H1, saves array H1 and corresponding sample composition;
5) step 3) is repeated, control signal array H01 is obtained and is compared with control signal array H0, if in scope of design It is interior, then step 6) is carried out, otherwise, repeats step 3);
6) sample Y2 is chosen from the step 2), repeats step 4), obtains array H2, saves array H2 and corresponding sample sets At;
7) step 5) and step 6) are repeated, until sample Yn, and array Hn is obtained, save array Hn and corresponding sample composition;
8) by array H1 and corresponding sample composition, array H2 and corresponding sample composition until array Hn and corresponding sample sets At establishment database;
9) gas to be detected is supplied to the gas sensor group, the gas sensing each of in the gas sensor group Device exports corresponding data-signal to the control module, and the control module exports the data-signal soft to abview Part, the data-signal of all gas sensors form different peak values on the curve of abview software, and corresponding peak value is total With gas array to be detected is formed, the gas array to be detected is compared with the array in database, the array institute most connect Corresponding sample composition is gas composition to be detected.
2. gas detection method according to claim 1, which is characterized in that gas sensor group includes nine kinds to different gas The sensor of body sensitivity, respectively first sensor, second sensor, 3rd sensor, the 4th sensor, the 5th sensor, 6th sensor, the 7th sensor, the 8th sensor and the 9th sensor.
3. gas detection method according to claim 1, which is characterized in that the comparison in step 5) includes that each gas passes Independent comparison between the control signal of sensor, also the integrated value including control signal array H0 is with control signal array H01's The comparison of integrated value.
4. gas detection method according to claim 1, which is characterized in that the comparison in step 9) includes that each gas passes The comparison of the data-signal of the data-signal of sensor gas sensor corresponding with array each in database also includes to be detected The integrated value of gas array and data be in each array integrated value comparison.
5. gas detection method according to claim 1, which is characterized in that the abview software installation is in external equipment On, the external equipment is computer or central processing unit.
6. a kind of gas detecting instrument, which is characterized in that including gas collection module, gas detection module, power supply module, control mould Block and external equipment;
The gas collection module includes air pump, gas chamber, air intake duct, exhaust pipe and connection tracheae;The air intake duct enter with to Environmental communication is surveyed, the outlet of the air intake duct is connect with the entrance of the gas chamber;The entrance and the gas chamber of the connection tracheae Outlet connection, it is described connection tracheae outlet connect with the entrance of the air pump;The entrance of the exhaust pipe and the air pump Outlet connection, the outlet of the exhaust pipe and the environmental communication to be measured;
The gas detection module is made of gas sensor group, and the gas sensor group includes two or more gas Body sensor;The gas sensor is set side by side, and the gas sensor group is set in the gas chamber;
Each gas sensor corresponds signal with the control module input port and connect;
The power supply module is electrically connected with the air pump, the gas sensor and the control module respectively;The outside is set It is standby to be connect with the control module signal.
7. gas detecting instrument according to claim 6, which is characterized in that the gas sensor group includes nine kinds to difference The sensor of gas sensitization, respectively first sensor, second sensor, 3rd sensor, the 4th sensor, the 5th sensing Device, the 6th sensor, the 7th sensor, the 8th sensor and the 9th sensor.
8. gas detecting instrument according to claim 6, which is characterized in that provide in the gas chamber each sensor Gas flow rate it is all the same.
9. gas detecting instrument according to claim 6, which is characterized in that the power supply module includes power supply and transformation mould Block;The gas sensor group is connect with the power lead;
The power supply is connect with the voltage changing module conducting wire, and the air pump is connect with the voltage changing module conducting wire;
The control module is connect with power lead or the control module is connect by USB interface with external power supply.
10. gas detecting instrument according to claim 6, which is characterized in that be provided with storage mould on the control module Block.
CN201811294975.4A 2018-11-01 2018-11-01 A kind of gas detection method and gas detecting instrument Pending CN109085313A (en)

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Publication number Priority date Publication date Assignee Title
CN113267533A (en) * 2021-05-18 2021-08-17 浙江大学 Device and method for dynamically monitoring VOCs (volatile organic chemicals) on line by self-calibration gas sensor array

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Publication number Priority date Publication date Assignee Title
CN113267533A (en) * 2021-05-18 2021-08-17 浙江大学 Device and method for dynamically monitoring VOCs (volatile organic chemicals) on line by self-calibration gas sensor array

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