CN109082887A - A kind of fabric softening agent - Google Patents

A kind of fabric softening agent Download PDF

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Publication number
CN109082887A
CN109082887A CN201810640671.2A CN201810640671A CN109082887A CN 109082887 A CN109082887 A CN 109082887A CN 201810640671 A CN201810640671 A CN 201810640671A CN 109082887 A CN109082887 A CN 109082887A
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China
Prior art keywords
softening agent
parts
fabric softening
fragrant
fabric
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Application number
CN201810640671.2A
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Chinese (zh)
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CN109082887B (en
Inventor
龚亚丽
徐涛
余守洪
高京华
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Hubei Healthy Guest Daily Chemical Co Ltd
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Hubei Healthy Guest Daily Chemical Co Ltd
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Priority to CN201810640671.2A priority Critical patent/CN109082887B/en
Publication of CN109082887A publication Critical patent/CN109082887A/en
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Publication of CN109082887B publication Critical patent/CN109082887B/en
Expired - Fee Related legal-status Critical Current
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005Compositions containing perfumes; Compositions containing deodorants
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/328Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/352Heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/09Cellulose ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12Processes in which the treating agent is incorporated in microcapsules
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of fabric softening agent, the component including following mass parts: 3~15 parts of ester based quaternary ammonium salt, 1~5 part of water soluble polyether silicone oil, 2~10 parts of amido silicon oil, 0.2~0.8 part of EDC, 0.02~0.1 part of NHS, 70~80 parts of deionized water.When fabric softening agent of the invention is the advantages of playing the good flexibility of amido silicon oil and slippery of high ammonia value, discoloration can be effectively reduced, to fabric fanout free region after use, flexibility, the gas permeability that fabric can be increased, after washing, fabric rewettability is good, it is antistatic, not yellowing, fragrance is simple and elegant idle, and lasting is lasting.

Description

A kind of fabric softening agent
Technical field
The invention belongs to daily chemical product technical field, in particular to a kind of fabric softening agent technical field.
Background technique
Fabric softening agent is also fabric care agent, is a kind of washing and nursing article, can be on the surface of fabric fibre Adhere to layer protecting film evenly, fiber surface is reduced due to having adsorbed softening agent, interfibrous coefficient of friction, moved so as to enhance Dynamic property, at the same fiber it is intrinsic it is smooth, extend, compression performance is also restored, so fabric becomes more soft, fluffy It is loose, flexible.
One of primary activity composition of the existing fabric softening agent in market is amido silicon oil, due to amino in amido silicon oil Polarity can make siloxane main chain oriented attachment in fiber surface with hydroxyl, the carboxyl of fiber surface etc. by chemical bonding, from And the coefficient of friction between fiber is reduced, it can make to generate sliding between fiber with the power of very little, show soft, smooth spy Property, so amido silicon oil is for that can assign excellent flexibility, slipping, elasticity, crease-resistant, washable, anti-tear after textile finishing It splits and forms a film with the performances such as comfortable and easy to wear, silicone molecule in fabric surface, make fabric that there is good elasticity, substantially increase to knitting The finishing effect of object, amido silicon oil are widely used in fabric softening agent by its above-mentioned advantage.
But amido silicon oil is because of amino and reactive hydrogen atom on its side switch, easily raw under the influence of illumination, warm and ultraviolet light At azo group chromophore, arrangement light color or white fabrics is caused to will appear different journeys after high temperature bakes or wears for a long time The Yellowing of degree, so that existing fabric softening agent is dfficult to apply to light color or white and high-end fabric.It is generally believed that ammonia The ammonia value of base silicone oil is higher, and the flexibility and slippery of fabric are better, but xanthochromia also can be bigger.
Summary of the invention
The present invention is to overcome problems of the prior art, provides a kind of fabric softening agent, in the ammonia for playing high ammonia value When the advantages of good flexibility of base silicone oil and slippery, discoloration can be effectively reduced.
The present invention is to solve above-mentioned problems of the prior art, is adopted the following technical scheme that.
A kind of fabric softening agent, which is characterized in that the fabric softening agent includes the component of following mass parts: ester group quaternary ammonium 3~15 parts of salt, 1~5 part of water soluble polyether silicone oil, 2~10 parts of amido silicon oil, 0.2~0.8 part of EDC, NHS 0.02~0.1 Part, 70~80 parts of deionized water.
Further, the ammonia value of the amido silicon oil is 0.55~1.1.
Further, the fabric softening agent further includes the viscosity stabiliser of 2~8 parts of mass parts.
Further, the viscosity stabiliser is the one or two of carboxymethyl cellulose, hydroxyethyl cellulose.
Further, the fabric softening agent further includes fragrant fragrant 0.5~3 part of microcapsules.
Further, the fragrant fragrant microcapsules are rose fragrant sweet smell microcapsules, the fragrant fragrant microcapsules of Christian Dior, the fragrant fragrant microcapsules of precious jasmine One or more of.
Compared with the existing technology, the present invention achieve it is following the utility model has the advantages that
1, fabric softening agent of the invention can increase flexibility, the gas permeability of fabric, wash to fabric fanout free region after use After washing, fabric rewettability is good, and antistatic, not yellowing, fragrance is simple and elegant idle, and lasting is lasting.
2, fabric softening agent of the invention, the middle tool of EDC (1- (3- dimethylamino-propyl) -3- ethyl-carbodiimide hydrochloride) Being formed to be coupled between fiber molecule and amido silicon oil molecule bridging reaction, the netted knot of formation can occur for some active groups Structure is more continuous and stablizes, and dye for fabrics can only move in fiber molecule gap, fiber cannot be still detached from, so fabric discoloration It is low;In addition, NHS (n-hydroxysuccinimide) and EDC is combined, the connection efficiency of EDC bridging reaction can further improve, on a small quantity Addition can substantially reduce fabric discoloration.
3, in the prior art, generally lower applied to the ammonia value of the amido silicon oil in fabric softening agent is only 0.1~0.3, And the ammonia value of the amido silicon oil for the fabric softening agent that this hair has may be up to 0.55~1.1, EDC component and knit amido silicon oil molecule Crosslinking inside and outside object and fiber is more abundant, and structure is more stable, in the good flexibility of amido silicon oil and slippery for playing high ammonia value The advantages of when, discoloration can be effectively reduced.
4, fabric softening agent of the invention is glued using one or two kinds of be used as of carboxymethyl cellulose, hydroxyethyl cellulose Spending stabilizer can also be in the work in EDC when carboxymethyl cellulose or hydroxyethyl cellulose are used to adjust the viscosity of fabric softening agent Property group effect is lower that bridging reaction occurs between amido silicon oil molecule, further increase amido silicon oil molecule in fabric and fiber The inside and outside degree of cross linking, structure are more stable.
Specific embodiment
The technical solution in embodiment will be clearly and completely described below.Obviously, described embodiment is only It is a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiment of the present invention, ordinary skill people Member's every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
One, embodiment
Embodiment 1
Fabric softening agent includes the component of following mass parts:
9 parts of ester based quaternary ammonium salt, 3 parts of water soluble polyether silicone oil, 10 parts of amido silicon oil, 0.8 part of EDC, 0.02 part of NHS, perfume It is 2 parts, 70 parts of deionized water fragrant.
Wherein, the ammonia value of amido silicon oil is 0.55.
Embodiment 2
Fabric softening agent includes the component of following mass parts:
15 parts of ester based quaternary ammonium salt, 1 part of water soluble polyether silicone oil, 6 parts of amido silicon oil, 0.6 part of EDC, 0.1 part of NHS, fragrant sweet smell 0.5 part, 75 parts of deionized water.
Wherein, the ammonia value of amido silicon oil is 0.8.
Embodiment 3
Fabric softening agent includes the component of following mass parts:
3 parts of ester based quaternary ammonium salt, 10 parts of amido silicon oil, 0.2 part of EDC, 0.06 part of NHS, glues 5 parts of water soluble polyether silicone oil Spend 8 parts of stabilizer, fragrant 3 parts, 70 parts of deionized water of sweet smell.
Wherein, the ammonia value of amido silicon oil is 1.1, and viscosity stabiliser is carboxymethyl cellulose.
Embodiment 4
Fabric softening agent includes the component of following mass parts:
9 parts of ester based quaternary ammonium salt, 3 parts of water soluble polyether silicone oil, 2 parts of amido silicon oil, 0.6 part of EDC, 0.06 part of NHS, viscosity 2 parts of stabilizer, fragrant 3 parts, 80 parts of deionized water of sweet smell.
Wherein, the ammonia value of amido silicon oil is 0.8, and viscosity stabiliser is carboxymethyl cellulose.
Embodiment 5
Fabric softening agent includes the component of following mass parts:
3 parts of ester based quaternary ammonium salt, 5 parts of water soluble polyether silicone oil, 6 parts of amido silicon oil, 0.8 part of EDC, 0.02 part of NHS, viscosity 6 parts of stabilizer, fragrant 2 parts, 80 parts of deionized water of sweet smell.
Wherein, the ammonia value of amido silicon oil is 0.8, and viscosity stabiliser is the combination of carboxymethyl cellulose and hydroxyethyl cellulose The mass ratio of the composition of object, carboxymethyl cellulose and hydroxyethyl cellulose is 5:5.
Embodiment 6
Fabric softening agent includes the component of following mass parts:
15 parts of ester based quaternary ammonium salt, 1 part of water soluble polyether silicone oil, 2 parts of amido silicon oil, 0.2 part of EDC, 0.1 part of NHS, viscosity 6 parts of stabilizer, fragrant 0.5 part, 75 parts of deionized water of sweet smell.
Wherein, the ammonia value of amido silicon oil is 1.1, and viscosity stabiliser is the combination of carboxymethyl cellulose and hydroxyethyl cellulose The mass ratio of the composition of object, carboxymethyl cellulose and hydroxyethyl cellulose is 8:2.
Two, test example
Take fabric softening agent and the 2 sections of commercially available situation of selling well amido silicon oil softeners of the proportion preparation of the present embodiment 1~6 (right respectively The ammonia value of ratio 1 is 0.2;The ammonia value of comparative example 2 is that 0.3) processing assesses its xanthochromia degree with a collection of white fabrics as a comparison case And pliability.
1, xanthochromia is tested
The fabric softening agent of the proportion preparation of the present embodiment 1~6 and the softener of comparative example 1 and 2 are taken respectively, and processing is same respectively Money white cotton towels dry 6 hours, change feelings with the yellowing of Datacolor colour photometer test brightened goods and benchmark sample cloth Condition, positive value show that xanthochromia is bigger more greatly.
2, flexibility test
The fabric softening agent of the proportion preparation of the present embodiment 1~6 and the softener of comparative example 1 and 2 are taken respectively, and processing is same respectively Money white cotton towels select 10 professionals to carry out touching test, and 1 point is worst for pliability, and 10 points are best for pliability, According to marking, results are averaged.
Correlation test result is as follows:
Sample Xanthochromia value Pliability scoring
Embodiment 1 0.10 7.1
Embodiment 2 0.08 8.2
Embodiment 3 0.06 9
Embodiment 4 0.02 7.8
Embodiment 5 0.05 8.2
Embodiment 6 0.04 8.6
Comparative example 1 (ammonia value is 0.2) 0.12 5.6
Comparative example 2 (ammonia value is 0.3) 0.15 6.2
As can be seen from the above table, (1) though fabric softening agent of the invention ammonia value up to 0.55~1.1, through at it For the more commercially available softener of the fabric of reason, xanthochromia value is significantly less than comparative example, and the fabric of all embodiments processing Pliability is substantially better than comparative example, illustrates fabric softening agent of the invention in the good flexibility of amido silicon oil for playing high ammonia value And when the advantages of slippery, discoloration can be effectively reduced.

Claims (6)

1. a kind of fabric softening agent, which is characterized in that the fabric softening agent includes the component of following mass parts: ester based quaternary ammonium salt 3~15 parts, 1~5 part of water soluble polyether silicone oil, 2~10 parts of amido silicon oil, 0.2~0.8 part of EDC, 0.02~0.1 part of NHS, 70~80 parts of deionized water.
2. fabric softening agent according to claim 1, which is characterized in that the ammonia value of the amido silicon oil is 0.55~1.1.
3. fabric softening agent according to claim 1, which is characterized in that the fabric softening agent further includes 2~8 parts of matter Measure the viscosity stabiliser of part.
4. fabric softening agent according to claim 1, which is characterized in that the viscosity stabiliser be carboxymethyl cellulose, The one or two of hydroxyethyl cellulose.
5. fabric softening agent according to claim 1, which is characterized in that the fabric softening agent further includes fragrant fragrant micro- glue 0.5~3 part of capsule.
6. fabric softening agent according to claim 1, which is characterized in that the fragrant fragrant microcapsules are the fragrant micro- glue of rose fragrant One or more of the fragrant fragrant microcapsules of capsule, Christian Dior, the fragrant fragrant microcapsules of precious jasmine.
CN201810640671.2A 2018-06-21 2018-06-21 Fabric softener Expired - Fee Related CN109082887B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810640671.2A CN109082887B (en) 2018-06-21 2018-06-21 Fabric softener

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Application Number Priority Date Filing Date Title
CN201810640671.2A CN109082887B (en) 2018-06-21 2018-06-21 Fabric softener

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CN109082887B CN109082887B (en) 2020-11-27

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102505498A (en) * 2011-11-01 2012-06-20 吴江市北厍盛源纺织品助剂厂 Preparation method of anti-yellowing organic silicon modified polyurethane softening agents
CN103031714A (en) * 2012-12-30 2013-04-10 浙江喜得宝丝绸科技有限公司 Silk afterfinishing compound softening agent and preparation method
CN103642044A (en) * 2013-12-05 2014-03-19 宁波润禾化学工业有限公司 Preparation method of high-activity anti-yellowing modified amino silicon oil
CN104894856A (en) * 2015-05-19 2015-09-09 东华大学 Processing method for improving mechanical properties of silk fibroin nanofiber
CN106868872A (en) * 2017-03-13 2017-06-20 广东得到宝贝科技有限公司 A kind of fabric softener

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102505498A (en) * 2011-11-01 2012-06-20 吴江市北厍盛源纺织品助剂厂 Preparation method of anti-yellowing organic silicon modified polyurethane softening agents
CN103031714A (en) * 2012-12-30 2013-04-10 浙江喜得宝丝绸科技有限公司 Silk afterfinishing compound softening agent and preparation method
CN103642044A (en) * 2013-12-05 2014-03-19 宁波润禾化学工业有限公司 Preparation method of high-activity anti-yellowing modified amino silicon oil
CN104894856A (en) * 2015-05-19 2015-09-09 东华大学 Processing method for improving mechanical properties of silk fibroin nanofiber
CN106868872A (en) * 2017-03-13 2017-06-20 广东得到宝贝科技有限公司 A kind of fabric softener

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李国英等: "《胶原化学》", 30 April 2013, 中国轻工业出版社 *

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