CN109082003A - A kind of plastic film with strong tensile resistance - Google Patents

A kind of plastic film with strong tensile resistance Download PDF

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Publication number
CN109082003A
CN109082003A CN201810518806.8A CN201810518806A CN109082003A CN 109082003 A CN109082003 A CN 109082003A CN 201810518806 A CN201810518806 A CN 201810518806A CN 109082003 A CN109082003 A CN 109082003A
Authority
CN
China
Prior art keywords
parts
plastic film
tensile resistance
strong tensile
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810518806.8A
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Chinese (zh)
Inventor
李峰
郑志龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Original Assignee
ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd filed Critical ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Priority to CN201810518806.8A priority Critical patent/CN109082003A/en
Publication of CN109082003A publication Critical patent/CN109082003A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2463/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds
    • C08K2003/166Magnesium halide, e.g. magnesium chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/26Silicon- containing compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a kind of plastic films with strong tensile resistance, it is divided into according to raw material weight component, 44-46 parts of acrylic resin, 35-37 parts of epoxy resin, 52-54 parts of glycol monoethyl ether, 46-48 parts of ethylene glycol monoethyl ether, 6-8 parts of magnesium chloride, 11-13 parts of flyash, 8-10 parts of precipitated calcium carbonate, 5-7 parts of toughener, 3-5 parts of plasticizer, 2-4 parts of stabilizer.Using technical solution of the present invention, the present invention is using acrylic resin, raw material production based on epoxy resin, and it joined the fillers such as magnesium chloride, flyash, precipitated calcium carbonate and make prepared plastic film that there is stronger tensile resistance, it can be to avoid being torn when using plastic film the case where, can widely be promoted the use of.

Description

A kind of plastic film with strong tensile resistance
Technical field
The present invention relates to the technical field of plastic film more particularly to a kind of plastic films with strong tensile resistance.
Background technique
Plastic film is mainly used for packing and being used as coating layer.Plastics package and plastic packet product are shared on the market Share it is increasing, especially composite plastic flexible package has been widely used for the fields such as food, medicine, chemical industry, wherein It is again maximum with food packaging proportion, such as beverage packaging, quick-frozen food packaging, cooking food packaging, fast food packaging It all brings great convenience to people's life Deng, these products.But the tensile resistance of existing plastic film and rigidity all compared with Difference is easily broken when so as to cause the foreign object for carrying constant weight, and makes troubles to routine use.For this purpose, it is proposed that one Kind has the plastic film of strong tensile resistance.
Summary of the invention
For the defect for solving prior art, the invention discloses a kind of plastic films with strong tensile resistance.
The invention discloses a kind of plastic films with strong tensile resistance, are divided into according to raw material weight component, and poly- third 44-46 parts of olefine resin, 35-37 parts of epoxy resin, 52-54 parts of glycol monoethyl ether, 46-48 parts of ethylene glycol monoethyl ether, magnesium chloride 6-8 parts, 11-13 parts of flyash, 8-10 parts of precipitated calcium carbonate, 5-7 parts of toughener, 3-5 parts of plasticizer, 2-4 parts of stabilizer.
Preferably, a kind of plastic film with strong tensile resistance, is divided into, acrylic resin according to raw material weight component 45 parts, 36 parts of epoxy resin, 53 parts of glycol monoethyl ether, 47 parts of ethylene glycol monoethyl ether, 7 parts of magnesium chloride, 12 parts of flyash, lightweight 9 parts of calcium carbonate, 6 parts of toughener, 4 parts of plasticizer, 3 parts of stabilizer.
Preferably, the toughener is nitrile rubber, hydroxyl terminated butyl nitrile (HTBN) rubber, the one kind for holding mercapto nitrile rubber Or a variety of mixtures.
Preferably, the plasticizer is one or more mixtures of epoxy methyl esters, chloro methyl esters, polyester plasticizer.
Preferably, the stabilizer is phosphite-type stabilisers.
A kind of plastic film with strong tensile resistance, it is specific the preparation method is as follows:
S1, according to parts by weight than weighing each raw material component;
S2, the raw material in step S1 is put into homogenizer, at 90-95 DEG C, homogeneous stirring turns the control of homogenizer temperature Speed obtains homogeneous mixture at 2000-3000 revs/min, homogenization 2-3h;
S3, the homogeneous mixture in step S2 is taken out and is added into extruder, extrusion forming, it is cooling, obtain plastic film Finished product.
Beneficial effect is: the present invention joined chlorination using acrylic resin, raw material production based on epoxy resin The fillers such as magnesium, flyash, precipitated calcium carbonate make prepared plastic film have stronger tensile resistance, can keep away Exempt from the case where tearing when using plastic film, can widely be promoted the use of.
Specific embodiment
Embodiment 1
The invention discloses a kind of plastic films with strong tensile resistance, are divided into according to raw material weight component, polypropylene tree It is 44 parts of rouge, 35 parts of epoxy resin, 52 parts of glycol monoethyl ether, 46 parts of ethylene glycol monoethyl ether, 6 parts of magnesium chloride, 11 parts of flyash, light 8 parts of matter calcium carbonate, 5 parts of toughener, 3 parts of plasticizer, 2 parts of stabilizer.
The toughener is nitrile rubber, hydroxyl terminated butyl nitrile (HTBN) rubber, holds the one or more of mercapto nitrile rubber Mixture.
The plasticizer is one or more mixtures of epoxy methyl esters, chloro methyl esters, polyester plasticizer.
The stabilizer is phosphite-type stabilisers.
A kind of plastic film with strong tensile resistance, it is specific the preparation method is as follows:
S1, according to parts by weight than weighing each raw material component;
S2, the raw material in step S1 is put into homogenizer, homogenizer temperature is controlled at 90 DEG C, and homogeneous speed of agitator exists 2000 revs/min, homogenization 2h, obtain homogeneous mixture;
S3, the homogeneous mixture in step S2 is taken out and is added into extruder, extrusion forming, it is cooling, obtain plastic film Finished product.
Embodiment 2
The invention discloses a kind of plastic films with strong tensile resistance, are divided into according to raw material weight component, polypropylene tree It is 45 parts of rouge, 36 parts of epoxy resin, 53 parts of glycol monoethyl ether, 47 parts of ethylene glycol monoethyl ether, 7 parts of magnesium chloride, 12 parts of flyash, light 9 parts of matter calcium carbonate, 6 parts of toughener, 4 parts of plasticizer, 3 parts of stabilizer.
The toughener is nitrile rubber, hydroxyl terminated butyl nitrile (HTBN) rubber, holds the one or more of mercapto nitrile rubber Mixture.
The plasticizer is one or more mixtures of epoxy methyl esters, chloro methyl esters, polyester plasticizer.
The stabilizer is phosphite-type stabilisers.
A kind of plastic film with strong tensile resistance, it is specific the preparation method is as follows:
S1, according to parts by weight than weighing each raw material component;
S2, the raw material in step S1 is put into homogenizer, homogenizer temperature is controlled at 93 DEG C, and homogeneous speed of agitator exists 2500 revs/min, homogenization 2.5h, obtain homogeneous mixture;
S3, the homogeneous mixture in step S2 is taken out and is added into extruder, extrusion forming, it is cooling, obtain plastic film Finished product.
Embodiment 3
The invention discloses a kind of plastic films with strong tensile resistance, are divided into according to raw material weight component, polypropylene tree It is 46 parts of rouge, 37 parts of epoxy resin, 54 parts of glycol monoethyl ether, 48 parts of ethylene glycol monoethyl ether, 8 parts of magnesium chloride, 13 parts of flyash, light 10 parts of matter calcium carbonate, 7 parts of toughener, 5 parts of plasticizer, 4 parts of stabilizer.
The toughener is nitrile rubber, hydroxyl terminated butyl nitrile (HTBN) rubber, holds the one or more of mercapto nitrile rubber Mixture.
The plasticizer is one or more mixtures of epoxy methyl esters, chloro methyl esters, polyester plasticizer.
The stabilizer is phosphite-type stabilisers.
A kind of plastic film with strong tensile resistance, it is specific the preparation method is as follows:
S1, according to parts by weight than weighing each raw material component;
S2, the raw material in step S1 is put into homogenizer, homogenizer temperature is controlled at 95 DEG C, and homogeneous speed of agitator exists 3000 revs/min, homogenization 3h, obtain homogeneous mixture;
S3, the homogeneous mixture in step S2 is taken out and is added into extruder, extrusion forming, it is cooling, obtain plastic film Finished product.
Finally, it should be noted that above embodiments are only to illustrate the present invention and not limit technology described in the invention Scheme;Therefore, although this specification is referring to above-mentioned each embodiment, the present invention has been described in detail, this Field it is to be appreciated by one skilled in the art that still can modify to the present invention or equivalent replacement;And all do not depart from this The technical solution and its improvement of the spirit and scope of invention, should all cover within the scope of the claims of the present invention.

Claims (6)

1. a kind of plastic film with strong tensile resistance, it is characterised in that: be divided into according to raw material weight component, polypropylene tree 44-46 parts of rouge, 35-37 parts of epoxy resin, 52-54 parts of glycol monoethyl ether, 46-48 parts of ethylene glycol monoethyl ether, magnesium chloride 6-8 Part, 11-13 parts of flyash, 8-10 parts of precipitated calcium carbonate, 5-7 parts of toughener, 3-5 parts of plasticizer, 2-4 parts of stabilizer.
2. a kind of plastic film with strong tensile resistance according to claim 1, it is characterised in that: according to raw material weight Amount component is divided into, 45 parts of acrylic resin, 36 parts of epoxy resin, 53 parts of glycol monoethyl ether, 47 parts of ethylene glycol monoethyl ether, chlorination 7 parts of magnesium, 12 parts of flyash, 9 parts of precipitated calcium carbonate, 6 parts of toughener, 4 parts of plasticizer, 3 parts of stabilizer.
3. a kind of plastic film with strong tensile resistance according to claim 1, it is characterised in that: the toughener For nitrile rubber, hydroxyl terminated butyl nitrile (HTBN) rubber, the one or more mixtures for holding mercapto nitrile rubber.
4. a kind of plastic film with strong tensile resistance according to claim 1, it is characterised in that: the plasticizer For epoxy methyl esters, chloro methyl esters, polyester plasticizer one or more mixtures.
5. a kind of plastic film with strong tensile resistance according to claim 1, it is characterised in that: the stabilizer For phosphite-type stabilisers.
6. a kind of plastic film with strong tensile resistance according to claim 1, it is characterised in that: its specific system Preparation Method is as follows:
S1, according to parts by weight than weighing each raw material component;
S2, the raw material in step S1 is put into homogenizer, at 90-95 DEG C, homogeneous stirring turns the control of homogenizer temperature Speed obtains homogeneous mixture at 2000-3000 revs/min, homogenization 2-3h;
S3, the homogeneous mixture in step S2 is taken out and is added into extruder, extrusion forming, it is cooling, obtain plastic film Finished product.
CN201810518806.8A 2018-05-25 2018-05-25 A kind of plastic film with strong tensile resistance Pending CN109082003A (en)

Priority Applications (1)

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CN201810518806.8A CN109082003A (en) 2018-05-25 2018-05-25 A kind of plastic film with strong tensile resistance

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Application Number Priority Date Filing Date Title
CN201810518806.8A CN109082003A (en) 2018-05-25 2018-05-25 A kind of plastic film with strong tensile resistance

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Publication Number Publication Date
CN109082003A true CN109082003A (en) 2018-12-25

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112693203A (en) * 2020-12-28 2021-04-23 黄山源点新材料科技有限公司 Winding film and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942130A (en) * 2009-07-06 2011-01-12 北京华通博奥科贸有限责任公司 Thermoplastic composite material and preparation method thereof as well as cable channel and preparation method thereof
CN102295793A (en) * 2011-07-07 2011-12-28 宋旭 Highly extended oxidation-degradable high-molecular packaging material and preparation method thereof
CN102391557A (en) * 2011-07-07 2012-03-28 宋旭 High-filling controllable oxidative degradation packaging material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942130A (en) * 2009-07-06 2011-01-12 北京华通博奥科贸有限责任公司 Thermoplastic composite material and preparation method thereof as well as cable channel and preparation method thereof
CN102295793A (en) * 2011-07-07 2011-12-28 宋旭 Highly extended oxidation-degradable high-molecular packaging material and preparation method thereof
CN102391557A (en) * 2011-07-07 2012-03-28 宋旭 High-filling controllable oxidative degradation packaging material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112693203A (en) * 2020-12-28 2021-04-23 黄山源点新材料科技有限公司 Winding film and preparation method thereof

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Application publication date: 20181225