CN109081946B - Light absorbing material composition and product using same - Google Patents
Light absorbing material composition and product using same Download PDFInfo
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- CN109081946B CN109081946B CN201710449088.9A CN201710449088A CN109081946B CN 109081946 B CN109081946 B CN 109081946B CN 201710449088 A CN201710449088 A CN 201710449088A CN 109081946 B CN109081946 B CN 109081946B
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Abstract
The invention provides a light absorption material composition and a product using the same. The light absorbing material composition includes: a composite absorber comprising a nanomaterial and a first light absorber bonded by chemisorption and/or physisorption; a second light absorber, the first light absorber and the second light absorber being different in polarity; and one end of the surface modification group is physically or chemically adsorbed on the surface of the nano material, and the other end of the surface modification group is physically or chemically adsorbed on the surface of the second light absorbent. The uniform and stable compounding with the first light absorbent is realized by utilizing the nanometer characteristics of the nanometer material, namely high specific surface area and high adsorption force. Meanwhile, the surface modification group is adopted to ensure that the composite absorbent and the second light absorption are in physical or chemical adsorption connection, so that the two light absorbers are uniformly dispersed in the same dispersant or dispersion medium, and a uniform and stable product can be obtained through a one-time film forming process.
Description
Technical Field
The invention relates to the field of optical materials, in particular to a light absorption material composition and a product using the same.
Background
The metal oxide light absorber is widely used in the preparation of various glass filters, and along with the rapid development of electronic products and sensors towards lightness, thinness and flexibility, glass is gradually replaced by plastic base materials due to the fragility, difficult processing and the like. The metal oxide light absorber is difficult to be applied to the field of plastic substrate optical filters due to the high temperature required for film forming processing, mismatch of polarity with plastic substrates and the like.
In contrast, the wavelength absorption peak range of a general non-metal oxide light absorber, especially a light absorber material such as an organic material or an organic metal chelate, is relatively narrow, and the approximate range is 60 to 100nm, and especially a light absorber material with a deep cut-off has a much narrower wavelength absorption peak range (20 to 50 nm). In order to expand the wavelength absorption peak range, 2 or more than 2 kinds of light absorption materials with different wavelength absorption peak ranges are often adopted for mixing and overlapping, so that the purpose of expanding the wavelength absorption peak range is achieved.
However, the above-mentioned method is very difficult to be implemented in the practical application of the plastic substrate optical filter. The main reasons are as follows: (1) The traditional inorganic metal oxide infrared absorbent has the advantages of broad-spectrum absorption and high cut-off degree on infrared rays, but the conventional plastic substrate cannot bear the temperature required by processing because the high temperature is required for processing the conventional inorganic metal oxide infrared absorbent into the optical filter; (2) When the metal oxide light absorbent is uniformly dispersed in the plastic base material or the glue by using a physical method, the phenomenon of non-uniform dispersion can occur; (3) The light absorbent materials such as organic matters and organic metal chelates need to be mixed for use due to the narrow wavelength absorption range, and the uneven mixing greatly reduces the transmittance of visible light or other utilization field wavelengths, so that the use requirements cannot be met; as described above, when light-absorbing materials such as inorganic metal oxides, organic compounds, and organic metal chelates are mixed, the materials are not well dispersed with each other due to a large difference in polarity, and thus the film formation is not uniform.
Disclosure of Invention
The invention mainly aims to provide a light absorbing material composition and a product using the same, so as to solve the problem of uneven dispersion of mixed materials formed by light absorbers with different polarities in the prior art.
In order to achieve the above object, according to one aspect of the present invention, there is provided a light absorbing material composition comprising: a composite absorber comprising a nanomaterial and a first light absorber bonded by chemisorption and/or physisorption; a second light absorber, the first light absorber and the second light absorber being different in polarity; and one end of the surface modification group is physically or chemically adsorbed on the surface of the nano material, and the other end of the surface modification group is physically or chemically adsorbed on the surface of the second light absorbent.
Further, the chemical adsorption is selected from one or more of electrostatic adsorption, ionic bond adsorption, covalent bond adsorption and hydrogen bond adsorption.
Further, the weight ratio of the nanomaterial, the second light absorber and the first light absorber is 1-500: 0.01 to 200:1, preferably, the weight ratio of the nano material to the first light absorbent is 20-100: 1, more preferably, the weight ratio of the second light absorber to the first light absorber is 0.05 to 100:1.
the nanomaterial is one or more of inorganic particles, organic particles, and particles of an organic-inorganic composite having a dispersion size of 150nm or less, and preferably one or more of silica particles, alumina particles, acryl particles, polyurethane particles, silicone particles, and organic aluminum particles.
Further, the first light absorber and the second light absorber are each independently selected from any one or more of an inorganic light absorber, an organic light absorber, and an organic-inorganic composite light absorber, preferably, the inorganic light absorber is a metal oxide or a metal salt, wherein a metal in the metal oxide or the metal salt is copper, chromium, iron, or cadmium, preferably, the organic light absorber is phthalocyanine, porphyrin, or azo, the organic-inorganic composite light absorber is phthalocyanine metal chelate, porphyrin metal chelate, or azo metal chelate, and more preferably, the absorption spectra of the first light absorber and the second light absorber overlap.
Further, the above-mentioned first light absorber and second light absorber are each independently selected from any one of the light absorbers of types ABS-642, ABS-626, FDR-004 and FDR-005.
Further, the above light absorption material composition has a 50% absorption band width of a light absorption peak of more than 30nm, and preferably has a 50% absorption band width of a light absorption peak of 40 to 500nm.
According to another aspect of the present application, there is provided an optical filter including a light absorption film prepared using the light absorption material composition of any one of the above.
Further, the optical filter further includes a refractive material layer disposed on one surface or opposite surfaces of the light absorption film.
According to a further aspect of the present application, there is provided an optical product comprising an optical filter, the optical filter being any of the optical filters described above.
Further, the optical product is an electronic consumer product, a sensor or an optical imaging system.
By applying the technical scheme of the invention, the uniform and stable composition with the first light absorbent is realized by utilizing the nanometer characteristics of the nanometer material, namely high specific surface area and high adsorption force. Meanwhile, the surface modification group is adopted to ensure that the composite absorbent and the second light absorption are connected in a physical or chemical adsorption manner, so that the two light absorbers are uniformly dispersed in the same dispersant or dispersion medium, and then a uniform and stable product can be obtained by a one-time film forming process, namely, the problem of nonuniform dispersion of the light absorbers with different polarities in the prior art is solved, and the film forming uniformity of the composition containing the light absorbers with different polarities is improved. The surface modification group can be provided by a coupling agent or a surfactant, one end of the surface modification group is a hydrophilic end, and the other end of the surface modification group is a lipophilic end, so that the surface modification group can adsorb two substances with different polarities, and the two ends of the surface modification group can adsorb nano materials with different polarities and second light absorption, so that the uniform mixing of the first light absorbent and the second light absorbent is realized.
Detailed Description
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict. The present invention will be described in detail with reference to examples.
As described in the background art, when organic compounds and organic metal chelates are mixed with inorganic metal oxide light-absorbing materials, the materials are not well dispersed with each other due to a large difference in polarity, resulting in non-uniform film formation. In order to solve the above problems, the present application provides a light absorbing material composition and a product using the same.
In an exemplary embodiment of the present application, there is provided a light absorbing material composition including a composite absorber including a nanomaterial bound and/or physisorbed by chemisorption and a first light absorber, a second light absorber, and a surface modification group; the first light absorbent and the second light absorbent have different polarities, and one end of the surface modification group is physically or chemically adsorbed on the surface of the nano material, and the other end of the surface modification group is physically or chemically adsorbed on the surface of the second light absorbent.
The application utilizes the nanometer characteristics of the nanometer material, namely high specific surface area and high adsorption force, and realizes uniform and stable compounding with the first light absorbent. Meanwhile, the surface modification group is adopted to ensure that the composite absorbent and the second light absorption are connected in a physical or chemical adsorption manner, so that the two light absorbers are uniformly dispersed in the same dispersant or dispersion medium, and then a uniform and stable product can be obtained by a one-time film forming process, namely, the problem of nonuniform dispersion of the light absorbers with different polarities in the prior art is solved, and the film forming uniformity of the composition containing the light absorbers with different polarities is improved. The surface modification group can be provided by a coupling agent or a surfactant, one end of the surface modification group is a hydrophilic end, and the other end of the surface modification group is a lipophilic end, so that the surface modification group can adsorb two substances with different polarities, and the two ends of the surface modification group can adsorb nano materials with different polarities and second light absorption, so that the uniform mixing of the first light absorbent and the second light absorbent is realized. As the coupling agent, various commercially available products such as organic branched siloxane, titanoxane and aluminoxane can be used, and as the surfactant, various commercially available surfactants such as carbonate anion and ammonium salt cation can be used.
Based on the effects of the nano material, the organic light absorber, the inorganic metal oxide light absorber or the inorganic-organic composite light absorber can be mixed as required, so that the light absorption effect is ensured, various materials for dispersing the organic light absorption material in the prior art are avoided, and the transmittance of visible light and other useful light is ensured.
In order to better solve the problem of uneven dispersion of the light absorbers having different polarities and to expand the light absorption range of the composition, the weight ratio of the nanomaterial, the second light absorber, and the first light absorber is preferably 1 to 500:0.01 to 200:1, more preferably, the weight ratio of the nanomaterial to the first light absorber is 20 to 100:1, it is further preferable that the weight ratio of the second light absorber to the first light absorber is from 0.05 to 100:1. the absorption range of the mixture is expanded by utilizing the mutual superposition effect of the absorption of the first light absorbent and the second light absorbent in the group. If the above ratio is exceeded, the effect of mutual addition of the absorptions may not be significant because the content of the first light-absorbing agent or the second light-absorbing agent is too small.
The chemisorption may be conventionally used, and preferably the chemisorption is one or more selected from the group consisting of electrostatic adsorption, ionic bond adsorption, covalent bond adsorption and hydrogen bond adsorption.
In order to facilitate the preparation of the nanomaterial and the stability thereof, the nanomaterial is preferably one or more of inorganic particles, organic particles, and particles of an organic-inorganic composite having a maximum dispersion size of 150nm or less, and preferably one or more of silica particles, alumina particles, acryl particles, polyurethane particles, silicone particles, and alumina particles.
The first light absorber and the second light absorber may each be a single light absorber or a mixture of a plurality of light absorbers, and preferably, the first light absorber and the second light absorber are each independently selected from one or more of an inorganic light absorber, an organic light absorber, and an organic-inorganic composite light absorber, and preferably, the inorganic light absorber is a metal oxide or a metal salt, wherein the metal in the metal oxide or the metal salt is copper, chromium, iron, or cadmium. Preferably, the organic light absorber is a phthalocyanine, porphyrin or azo. Preferably, the organic-inorganic composite light absorber is phthalocyanine metal chelate, porphyrin metal chelate or azo metal chelate. More preferably, the absorption spectra of the first light absorber and the second light absorber have an overlap.
The light absorption material composition of the application is compounded with a plurality of light absorbers, so the absorption bandwidth of the light absorption peak can be flexibly adjusted, preferably, the 50% absorption bandwidth of the light absorption peak of the light absorption material composition is more than 30nm, and preferably, the 50% absorption bandwidth of the light absorption peak is 40-500 nm. Wherein the 50% absorption bandwidth of the light absorption peak is the 50% absorption bandwidth of the left and right of the maximum absorption peak.
In still another exemplary embodiment of the present application, there is provided an optical filter including a light absorption film prepared using any one of the light absorption material compositions.
Because the light absorption material composition of this application has contained the not equidistance's of homodisperse light absorber of co-polar to solved organic inorganic light absorber among the prior art and dispersed inhomogeneous problem, and then improved the homogeneity of its light absorption membrane under the prerequisite of having guaranteed the extinction effect, avoided simultaneously using prior art to disperse multiple material of organic light absorption material, guaranteed the transmittance of the visible light and other useful lights of the light filter that has it.
The light absorption film can be prepared by adopting a liquid film forming method such as suspension coating, micro-concave, slit and the like.
In still another preferred embodiment of the present application, the optical filter further includes a refractive material layer disposed on one surface or opposite surfaces of the light absorption film.
The refractive material layer may be prepared by overlapping high and low refractive index materials using liquid multi-layer coating or deposition methods such as CVD, PVD, PECVD, etc.
In another exemplary embodiment of the present application, there is provided an optical product including the optical filter, which is the optical filter described above. The obtained optical product has the advantages of broad-spectrum absorption and large cut-off degree. Preferably, the optical product is an electronic consumer product, a sensor or an optical imaging system.
The advantageous effects of the present application will be further described below with reference to examples and comparative examples.
Example 1
9.8wt% Tetraethoxysilane (TEOS) is completely hydrolyzed in isopropanol solvent under the catalysis of acid (molar ratio TEOS: H) 2 O =1: 4) Reaction to give a transparent nano-colloidal polymer solution (i.e., silica polymer), to which 0.1 part by weight of a first light was added (100 parts by weight, theoretical nano-colloidal polymer content: 5 wt%)The absorbent ABS-642 (light absorbent manufactured by Exciton) was dissolved by stirring, and then heated and refluxed at 30 ℃ for 3 hours to form a nano-colloid composite absorbent stably existing by electrostatic adsorption. The nano colloid composite absorbent is modified by adding a silicon coupling agent (the dosage is less, and the composition of a finally obtained composition cannot be obviously influenced), so that the modified nano colloid composite absorbent after physical adsorption is obtained. Then, the solvent substitution was performed, and the isopropyl alcohol solvent was substituted for the methyl ethyl ketone solvent (as complete substitution as possible), to obtain a methyl ethyl ketone solution of the modified nano-colloid composite absorbent.
0.3 part by weight of a second light absorber ABS-626 (light absorber from Exciton, inc.) was added to 100 parts by weight of a 10wt% butanone solution of an epoxy resin and dissolved by stirring to obtain an epoxy resin solution of ABS-626. Gradually adding 50 parts by weight of the butanone solution of the nano-colloid composite absorbent into 50 parts by weight of the butanone solution of the ABS-626, and fully stirring and mixing to obtain a coating liquid of the light absorbing material, wherein the weight ratio of the silica polymer to the second light absorbent to the first light absorbent is 50:3:1. one end of the silane coupling agent is physically adsorbed on the composite absorbent, and the other end of the silane coupling agent is physically or chemically adsorbed on the ABS-626 light absorbent, so that the ABS-642 light absorbent and the ABS-626 light absorbent are uniformly compounded.
The polarity strength judging method of the ABS-642 and the ABS-626 comprises the following steps: ABS-642 is soluble in isopropanol, and ABS-626 is soluble in toluene, because isopropanol has stronger polarity than toluene, according to the principle of similar compatibility, the polarity of ABS-642 is stronger than that of ABS-626.
The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1.
Example 2
0.1 part by weight of a first light absorber ABS-642 was added to a 5wt% isopropanol solution of a transparent aluminum hydroxide nano-colloid polymer (i.e., hydrated alumina polymer) (100 parts by weight), and after fully stirred and dissolved, the solution was heated and refluxed at 30 ℃ for 3 hours to form a hydrogen bond-electrostatically adsorbed nano-colloid composite absorbent. The modified nano colloid composite absorbent which is mainly processed by chemical bonds is obtained after the nano colloid composite absorbent is modified by adding a silicon coupling agent. Then, solvent replacement is carried out, and the isopropanol solvent is replaced by butanone solvent, so as to obtain butanone solution of the modified nano-colloid composite absorbent.
0.3 part by weight of a second light absorber ABS-626 was added to 100 parts by weight of a 10wt% butanone solution of epoxy resin and dissolved by stirring to obtain an epoxy resin solution of ABS-626.
Gradually adding 50 parts by weight of the butanone solution of the nano-colloid composite absorbent into 50 parts by weight of the butanone solution of the ABS-626, and fully stirring and mixing to obtain a coating liquid of the light absorbing material, wherein the weight ratio of the alumina polymer to the second light absorbent to the first light absorbent is 50:3:1. one end of the silane coupling agent is physically adsorbed on the composite absorbent, and the other end of the silane coupling agent is physically or chemically adsorbed on the ABS-626 light absorbent, so that the ABS-642 light absorbent and the ABS-626 light absorbent are uniformly compounded.
The polarity strength judging method of the ABS-642 and the ABS-626 comprises the following steps: ABS-642 is soluble in isopropanol, and ABS-626 is soluble in toluene, because isopropanol has stronger polarity than toluene, according to the principle of similar compatibility, the polarity of ABS-642 is stronger than that of ABS-626. The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1.
Example 3
The difference from example 1 is that the weight ratio of the silica polymer, the second light absorber and the first light absorber is 20:3:1.
example 4
The difference from example 1 is that the weight ratio of the silica polymer, the second light absorber and the first light absorber is 100:3:1.
example 5
The difference from example 1 is that the weight ratio of the silica polymer, the second light absorber and the first light absorber is 50:0.05:1.
example 6
The difference from example 1 is that the weight ratio of the silica polymer, the second light absorber and the first light absorber is 50:100:1.
example 7
The difference from example 1 is that the weight ratio of the silica polymer, the second light absorber and the first light absorber is 500:200:1.
example 8
The difference from example 1 is that the weight ratio of the silica polymer, the second light absorber and the first light absorber is 50:0.01:1.
example 9
0.1 part by weight of a first light absorber ABS-642 (Exciton) was added to 100 parts by weight of isopropyl alcohol (5 wt% in Nissan chemical) dispersion of silica having a dispersion particle diameter of 20nm, and after sufficient stirring, the mixture was heated and refluxed at 30 ℃ for 3 hours, and then subjected to electrostatic and physical adsorption, thereby forming a stable nanocomposite absorber. The nano composite absorbent is modified by adding a silicon coupling agent to obtain the nano composite absorbent modified by physical adsorption and chemical bonds. Then, the solvent replacement is carried out, and the isopropanol solvent is replaced by the butanone solvent, so as to obtain the butanone dispersion liquid of the modified nano composite absorbent.
To 100 parts by weight of a 10wt% butanone solution of an epoxy resin, 0.3 part by weight of a second light absorber ABS-626 (Exciton) was added and dissolved by stirring to obtain an epoxy resin solution of ABS-626.
Gradually adding 50 parts by weight of the butanone dispersion liquid of the nano composite absorbent into 50 parts by weight of an epoxy resin butanone solution of ABS-626, and fully stirring and mixing to obtain a coating liquid of the light absorbing material, wherein the weight ratio of the silicon oxide to the second light absorbent to the first light absorbent is 50:3:1. one end of the silane coupling agent is physically adsorbed on the composite absorbent, and the other end of the silane coupling agent is physically or chemically adsorbed on the ABS-626 light absorbent, so that the ABS-642 light absorbent and the ABS-626 light absorbent are uniformly compounded.
The polarity strength judging method of the ABS-642 and the ABS-626 comprises the following steps: ABS-642 is soluble in isopropanol, and ABS-626 is soluble in toluene, because isopropanol has stronger polarity than toluene, according to the principle of similar compatibility, the polarity of ABS-642 is stronger than that of ABS-626. The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1.
Example 10
The difference from example 9 is that the weight ratio of the silicon oxide, the second light absorber and the first light absorber is 1:20:1.
example 11
The difference from example 9 is that the weight ratio of the silicon oxide, the second light absorber and the first light absorber is 500:100:1.
example 12
The difference from example 9 is that the weight ratio of the silicon oxide, the second light absorber and the first light absorber is 20:0.01:1.
example 13
The difference from example 9 is that the weight ratio of the silicon oxide, the second light absorber and the first light absorber is 100:200:1.
example 14
The difference from example 9 is that the weight ratio of the silicon oxide, the second light absorber and the first light absorber is 50:0.05:1.
example 15
The difference from example 9 is that the weight ratio of the silicon oxide, the second light absorber and the first light absorber is 50:220:1.
example 16
The difference from example 9 is that the nanoparticles are acryl particles having a dispersion size of less than 150 nm.
Example 17
The difference from the example 9 is that the nano particles are polyurethane and alumina particles with the dispersed size of less than 150nm, and the volume ratio of the polyurethane to the alumina is 1:1.
Example 18
Adding 0.1 weight part of FDR-004 of a first light absorbing agent in Shantian chemical industry into silicon oxide (5 wt% of daily chemical) butanone (100 weight parts) with the dispersion particle size of 20nm, fully stirring, maintaining the temperature for heating and refluxing for 3 hours, performing electrostatic and physical adsorption to form a stable modified nano composite absorbent, and performing modification treatment by adding a silicon coupling agent to the nano composite absorbent to obtain the physically adsorbed modified nano composite absorbent.
To 100 parts by weight of a 10wt% toluene solution of an epoxy resin, 0.3 part by weight of FDR-005 of the second light absorber, shantian chemical industry, was added and dissolved with stirring to obtain an epoxy resin solution of FDR-005.
Gradually adding 50 parts by weight of the butanone dispersion liquid serving as the nano composite absorbent into 50 parts by weight of an FDR-005 epoxy resin toluene solution, and fully stirring and mixing to obtain a coating liquid of the light absorption material, wherein the weight ratio of the silicon oxide to the second light absorber to the first light absorber is 50:3:1. one end of the silane coupling agent is physically adsorbed on the composite absorbent, and the other end of the silane coupling agent is physically or chemically adsorbed on the FDR-005 light absorbent, so that the FDR-004 light absorbent and the FDR-005 light absorbent are uniformly compounded.
The polarity strength judgment method of FDR-004 and FDR-005 comprises the following steps: FDR-004 is dissolved in butanone, FDR-005 is dissolved in toluene, the butanone has stronger polarity than toluene, and the FDR-004 has stronger polarity than FDR-005 according to the similar intermiscibility principle.
The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1.
Comparative example 1
0.3 part by weight of a second light absorber ABS-626 is added to 100 parts by weight of a 10wt% butanone solution of epoxy resin and stirred to dissolve, thus obtaining an epoxy resin solution of ABS-626.
The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1.
Comparative example 2
0.1 part by weight of a second light absorber ABS-642 was added to 100 parts by weight of a 10wt% isopropyl alcohol solution of an epoxy resin and dissolved by stirring to obtain an epoxy resin solution of ABS-642.
The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1.
Comparative example 3
0.3 part by weight of a second light absorber ABS-626 is added to 100 parts by weight of a 10wt% butanone solution of epoxy resin and stirred to dissolve, thus obtaining an epoxy resin solution of ABS-626.
0.1 part by weight of a second light absorber ABS-642 was added to 100 parts by weight of a 10wt% isopropyl alcohol solution of an epoxy resin and dissolved by stirring to obtain an epoxy resin solution of ABS-642.
The epoxy resin solution of ABS-626 and the epoxy resin solution of ABS-642 were mixed by stirring in an amount of 50 parts by weight, respectively, to obtain a coating solution of a light-absorbing material.
The coating liquid was coated on a transparent PET substrate and dried to obtain a light-absorbing film. The evaluation results of the film are shown in Table 1. The evaluation method comprises the following steps: the haze was evaluated with NDH-2000 haze meter, the adhesion with a hundred grid knife and tape, and the absorption bandwidth and transmittance were measured with a spectrophotometer lambda 950. The 450-500 nm transmittance is the average value of the transmittances in the range measured by a spectrophotometer, and the 50% absorption bandwidth is the wavelength range corresponding to the 50% transmittance on the left and right of the maximum absorption peak in the spectrum.
TABLE 1
According to the comparison of the effects of the above examples and comparative examples, it can be seen that the light absorption film of the present application has uniform film formation, high light transmittance, low haze and significantly increased absorption bandwidth of 50% before cross-compounding, which indicates that the first light absorber and the second light absorber in the light absorption film are not only uniformly dispersed, but also have significant synergistic effect of light absorption effect.
From the above description, it can be seen that the above-described embodiments of the present invention achieve the following technical effects:
the application utilizes the nanometer characteristics of the nanometer material, namely high specific surface area and high adsorption force, and realizes uniform and stable compounding with the first light absorbent. Meanwhile, the surface modification group is adopted to ensure that the composite absorbent and the second light absorption are connected in a physical or chemical adsorption manner, so that the two light absorbers are uniformly dispersed in the same dispersant or dispersion medium, and then a uniform and stable product can be obtained by a one-time film forming process, namely, the problem of nonuniform dispersion of the light absorbers with different polarities in the prior art is solved, and the film forming uniformity of the composition containing the light absorbers with different polarities is improved. The surface modification group can be provided by a coupling agent or a surfactant, one end of the surface modification group is a hydrophilic end, the other end of the surface modification group is a lipophilic end, and the surface modification group can adsorb two substances with different polarities, so that the adsorption of the two ends of the surface modification group on the nano material with different polarities and the second light absorber is depended, and the uniform mixing of the first light absorber and the second light absorber is realized.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (18)
1. A light absorbing material composition, comprising:
a composite absorber comprising a nanomaterial and a first light absorber bonded by chemisorption and/or physisorption;
a second light absorber, the first light absorber and the second light absorber being of different polarity;
and one end of the surface modification group is physically or chemically adsorbed on the surface of the nano material, and the other end of the surface modification group is physically or chemically adsorbed on the surface of the second light absorbent.
2. A light absorbing material composition in accordance with claim 1, wherein the chemisorption is selected from any one or more of electrostatic adsorption, ionic bond adsorption, covalent bond adsorption and hydrogen bond adsorption.
3. The light absorbing material composition according to claim 1, wherein the weight ratio of the nanomaterial, the second light absorber, and the first light absorber is 1 to 500:0.01 to 200:1.
4. the light absorbing material composition according to claim 3, wherein the weight ratio of the nanomaterial to the first light absorber is 20 to 100:1.
5. the light absorbing material composition according to claim 3, wherein the weight ratio of the second light absorbing agent to the first light absorbing agent is from 0.05 to 100:1.
6. a light-absorbing material composition according to claim 1, wherein the nanomaterial is an aluminoxy compound polymer, a titanyl compound polymer, and/or a siloxy compound polymer; or the nano material is one or more of inorganic particles, organic particles and particles of an organic-inorganic composite with the dispersion size of below 150 nm.
7. The light absorbing material composition of claim 6, wherein the nano material is one or more of silica particles, alumina particles, acryl particles, polyurethane particles, silicone particles, and organic aluminum particles.
8. The light absorbing material composition according to claim 1, wherein the first light absorber and the second light absorber are each independently selected from any one or more of an inorganic light absorber, an organic light absorber, and an organic-inorganic composite light absorber.
9. A light-absorbing material composition according to claim 8, wherein the inorganic light-absorbing agent is a metal oxide or a metal salt, and wherein the metal in the metal oxide or the metal salt is copper, chromium, iron, or cadmium.
10. The light absorbing material composition according to claim 8, wherein the organic light absorber is phthalocyanine, porphyrin or azo, and the organic-inorganic composite light absorber is phthalocyanine metal chelate, porphyrin metal chelate or azo metal chelate.
11. The light absorbing material composition of claim 8, wherein the absorption spectra of the first light absorber and the second light absorber have an overlap.
12. The light absorbing material composition according to claim 8, wherein the first light absorber and the second light absorber are each independently selected from any one of the light absorbers of type ABS-642, ABS-626, FDR-004, and FDR-005.
13. The light absorbing material composition of claim 1, wherein the light absorbing material composition has a light absorption peak 50% absorption bandwidth greater than 30nm.
14. The light absorbing material composition of claim 13, wherein the light absorption peak has a 50% absorption bandwidth of 40 nm to 500nm.
15. An optical filter comprising a light absorbing film, wherein the light absorbing film is prepared by using the light absorbing material composition according to any one of claims 1 to 14.
16. The optical filter according to claim 15, further comprising a refractive material layer disposed on one surface or both opposite surfaces of the light absorbing film.
17. An optical product comprising an optical filter, wherein the optical filter is the optical filter according to claim 15 or 16.
18. The optical product of claim 17, wherein the optical product is a consumer electronic product, a sensor, or an optical imaging system.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1043515A (en) * | 1988-12-15 | 1990-07-04 | 科尔-麦克基化学公司 | Chemically inert pigmentary zinc oxides |
| CN1468289A (en) * | 2000-10-09 | 2004-01-14 | Composite particles | |
| CN101089726A (en) * | 2006-06-16 | 2007-12-19 | 台达电子工业股份有限公司 | Reflecting screen |
| CN101752490A (en) * | 2009-12-25 | 2010-06-23 | 彩虹集团公司 | A kind of LED packaging slurry and preparation method thereof |
| CN101903182A (en) * | 2007-06-29 | 2010-12-01 | 默克专利股份有限公司 | The microsphere that comprises polymer core, shell and absorbent |
| WO2016098810A1 (en) * | 2014-12-19 | 2016-06-23 | 旭硝子株式会社 | Optical filter and device using same |
| CN105980889A (en) * | 2014-02-12 | 2016-09-28 | 罗羽柱 | Optical filter and imaging device comprising same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100466545B1 (en) * | 2002-02-19 | 2005-01-15 | 한국전자통신연구원 | Method for manufacturing polymer nano particle |
-
2017
- 2017-06-14 CN CN201710449088.9A patent/CN109081946B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1043515A (en) * | 1988-12-15 | 1990-07-04 | 科尔-麦克基化学公司 | Chemically inert pigmentary zinc oxides |
| CN1468289A (en) * | 2000-10-09 | 2004-01-14 | Composite particles | |
| CN101089726A (en) * | 2006-06-16 | 2007-12-19 | 台达电子工业股份有限公司 | Reflecting screen |
| CN101903182A (en) * | 2007-06-29 | 2010-12-01 | 默克专利股份有限公司 | The microsphere that comprises polymer core, shell and absorbent |
| CN101752490A (en) * | 2009-12-25 | 2010-06-23 | 彩虹集团公司 | A kind of LED packaging slurry and preparation method thereof |
| CN105980889A (en) * | 2014-02-12 | 2016-09-28 | 罗羽柱 | Optical filter and imaging device comprising same |
| WO2016098810A1 (en) * | 2014-12-19 | 2016-06-23 | 旭硝子株式会社 | Optical filter and device using same |
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