CN109081439A - A method of sewage is handled using corncob as the denitrification filter pool reactor of biomass carrier and using it - Google Patents

A method of sewage is handled using corncob as the denitrification filter pool reactor of biomass carrier and using it Download PDF

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Publication number
CN109081439A
CN109081439A CN201811259036.6A CN201811259036A CN109081439A CN 109081439 A CN109081439 A CN 109081439A CN 201811259036 A CN201811259036 A CN 201811259036A CN 109081439 A CN109081439 A CN 109081439A
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CN
China
Prior art keywords
corncob
water inlet
reactor
water
sewage
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CN201811259036.6A
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Chinese (zh)
Inventor
李昂
马放
郭海娟
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JIANGSU HIT YIXING ACADEMY OF ENVIRONMENTAL PROTECTION CO Ltd
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JIANGSU HIT YIXING ACADEMY OF ENVIRONMENTAL PROTECTION CO Ltd
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Priority to CN201811259036.6A priority Critical patent/CN109081439A/en
Publication of CN109081439A publication Critical patent/CN109081439A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2806Anaerobic processes using solid supports for microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2826Anaerobic digestion processes using anaerobic filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia

Abstract

A method of sewage being handled using corncob as the denitrification filter pool reactor of biomass carrier and using it, it is related to a kind of denitrification filter pool reactor and the method using its processing sewage.The invention aims to solve to be unable to reach country-level A standard using the treatment process processing sewage of existing sewage, water outlet TN, and need additional a large amount of expensive carbon sources, the high problem of processing cost.It is a kind of using corncob as the denitrification filter pool reactor of biomass carrier include reactor body, water tank inlet, water inlet pipe, multiple outlet pipes and backwash water inlet pipe.The method for handling sewage: sewage enters in reactor body, and the hydraulic detention time in reactor body is 60min~70min, then is discharged from multiple outlet pipes, the sewage that obtains that treated.The present invention is suitable for processing sewage.

Description

It is a kind of as the denitrification filter pool reactor of biomass carrier and to be utilized at it using corncob The method for managing sewage
Technical field
The present invention relates to a kind of denitrification filter pool reactor and the methods for handling sewage using it.
Background technique
" China Environmental State Bulletin " is pointed out within 2016, and Chinese surface water pollution is heavier, and seven big water systems are generally slight dirty The problems such as dye, lake eutrophication, is prominent.Nitrate nitrogen, the ammonia nitrogen of town domestic sewage for concentrating discharge that a large amount of chemical fertilizer generate etc. Various forms of nitrogens are accumulated, and are exacerbated the degree of water body in lake eutrophication, are influenced and constrain the development of social economy. China executes " municipal sewage plant's integrated wastewater discharge standard " level-one A standard in newly-built and existing sewage treatment plant TN < 15mg/L, and conventional sewage treatment process due in denitrification process organic matter it is usually insufficient, make to be discharged TN and be unable to reach Country-level A standard, it is therefore desirable to additional carbon.But additional carbon dosage is big, and expensive.Therefore, seek a kind of honest and clean The plus slow release carbon source of valence becomes one of the hot spot studied at present.
Corncob as the typical agricultural wastes in China one of, inside is with higher there are a large amount of organic matter Utility value can not only provide carbon source material required for denitrifying microorganism denitrification using corncob as slow release carbon source, moreover it is possible to Attachment site is provided as carrier for microorganism.But lignin existing for corn wicking surface is more difficult to be utilized by the microorganism, and is restricted The further utilization of organic matter in corncob.
Summary of the invention
The invention aims to solve to be unable to reach country using the treatment process processing sewage of existing sewage, water outlet TN Level-one A standard, and additional a large amount of expensive carbon sources, the high problem of processing cost are needed, and provide one kind with corncob and be The denitrification filter pool reactor of biomass carrier and the method for handling sewage using it.
It is a kind of using corncob as the denitrification filter pool reactor of biomass carrier include reactor body, water tank inlet, into Water pipe, multiple outlet pipes and backwash water inlet pipe;
The reactor body includes biomass carrier and supporting plate, and biomass carrier and supporting plate are set from top to bottom It sets in the inside of reactor body;
Water inlet and backwash water inlet have been opened on the lower section of supporting plate, the side wall of reactor body;Supporting plate it is upper Multiple water outlets have been opened from top to bottom on square, reactor body side wall;Outlet pipe passes through water outlet and reactor body phase Connection;
The water tank inlet is connected by water inlet pipe and water inlet with reactor body;The backwash water inlet pipe It is connected by backwash water inlet with reactor body, and backwashes water inlet pipe and be equipped with valve and backwash intake pump;
The biomass carrier is the corncob for hanging with denitrifying bacterium and whiterot fungi.
Using it is a kind of by the method for the denitrification filter pool reactor for treatment sewage of biomass carrier of corncob be by following What step was completed:
Sewage is added in water tank inlet, opens water inlet peristaltic pump, inlet valve and multiple outlet pipes, sewage by into Water peristaltic pump, inlet valve and water inlet pipe enter in reactor body, and the hydraulic detention time in reactor body is 60min~70min, then be discharged from multiple outlet pipes, the sewage that obtains that treated;At interval of 20 days~30 days, valve is opened With backwash intake pump, clear water is entered in reactor body and is carried out by backwash water inlet pipe, valve and backwash intake pump Backwash removes the old loose biomembrane adhered on biomass carrier;
The flow of inlet water of the reactor body are as follows: 0.6L/h~0.7L/h.
The principle of the present invention and advantage:
One, biomass carrier is arranged in the present invention in reactor body, and biomass carrier is to hang with denitrifying bacterium and white rot The corncob of bacterium, corncob can not only releasing organics matter serve as carbon source material, moreover it is possible to as carrier provide microorganism adhere to position Point;On the other hand, the whiterot fungi biofilm added can effectively decompose lignin in corn wicking surface, in order to corncob inside The abundant release of organic matter;Denitrification filter pool reactor entire in this way, which not only reduces, adds carbon source required cost, improves simultaneously The utilization rate of corncob organic matter, increases the removal rate of TN, by regularly replacing the corncob of proper proportion, can guarantee The operation steady in a long-term of reactor plays the operation of entire reactor key;
Two, a kind of using corncob as the denitrification filter pool reactor for treatment sewage of biomass carrier using the present invention, water outlet Middle TN < 15mg/L, stable effluent quality is up to standard, reaches " municipal sewage plant's integrated wastewater discharge standard " level-one A standard;
Three, supporting plate is set in reactor body of the present invention, and supporting plate plays the role of fixed biomass carrier, and rises equal The effect of even water distribution;
Four, the present invention in it is a kind of using corncob as biomass carrier denitrification filter pool reactor run 111 days after, replacement The biomass carrier of a quarter ratio can make a kind of denitrification filter pool reaction with corncob biomass carrier in invention Device continues stable operation 31 days, by regularly replacing the biomass carrier of proper proportion, can guarantee that one kind is in the present invention with jade Meter Xin is the denitrification filter pool reactor of biomass carrier
Operation steady in a long-term.
The present invention is suitable for processing sewage.
Detailed description of the invention
Fig. 1 is a kind of using corncob as the denitrification filter pool reactor of biomass carrier described in specific embodiment one Structural schematic diagram.
Specific embodiment
Specific embodiment 1: embodiment is described with reference to Fig. 1, present embodiment one kind is carried by biomass of corncob The denitrification filter pool reactor of body includes reactor body, water tank inlet 1, water inlet pipe 4, multiple outlet pipes 5 and backwash water inlet Pipe 8;
The reactor body includes biomass carrier 6 and supporting plate 7, and biomass carrier 6 and supporting plate 7 from up to The lower inside that reactor body is set;
Water inlet and backwash water inlet have been opened on the lower section of supporting plate 7, the side wall of reactor body;Supporting plate 7 Top, reactor body side wall on opened multiple water outlets from top to bottom;Outlet pipe 5 passes through water outlet and reactor body It is connected;
The water tank inlet 1 is connected by water inlet pipe 4 and water inlet with reactor body;The backwash water inlet Pipe 8 is connected by backwash water inlet with reactor body, and is backwashed water inlet pipe 8 and be equipped with valve 9 and backwash water inlet Pump 10;
The biomass carrier 6 is the corncob for hanging with denitrifying bacterium and whiterot fungi.
The principle and advantage of present embodiment:
One, biomass carrier 6 is arranged in present embodiment in reactor body, and biomass carrier 6 is to hang with denitrifying bacterium With the corncob of whiterot fungi, corncob can not only releasing organics matter serve as carbon source material, moreover it is possible to as carrier provide microorganism Attachment site;On the other hand, the whiterot fungi biofilm added can decompose lignin, effectively in corn wicking surface in order to corn The abundant release of core inner organic matter;Denitrification filter pool reactor entire in this way, which not only reduces, adds carbon source required cost, together When improve the utilization rate of corncob organic matter, increase the removal rate of TN, pass through the corncob of periodic replacement proper proportion, energy The operation steady in a long-term for enough guaranteeing reactor, plays the operation of entire reactor key;
It is two, a kind of using corncob as the denitrification filter pool reactor for treatment sewage of biomass carrier using present embodiment, TN < 15mg/L in water outlet, stable effluent quality is up to standard, reaches " municipal sewage plant's integrated wastewater discharge standard " level-one A mark It is quasi-;
Three, supporting plate 7 is set in present embodiment reactor body, and supporting plate 7 plays the work of fixed biomass carrier 6 With, and play water distribution uniformity;
Four, in present embodiment it is a kind of using corncob as biomass carrier denitrification filter pool reactor run 111 days after, The biomass carrier 6 for replacing a quarter ratio can make a kind of denitrification filter with corncob biomass carrier in invention Pond reactor continues stable operation 31 days, by regularly replacing the biomass carrier 6 of proper proportion, can guarantee one in the present invention Kind is using corncob as the denitrification filter pool reactor of biomass carrier
Operation steady in a long-term.
Present embodiment is suitable for processing sewage.
Specific embodiment 2: the differences between this implementation mode and the specific implementation mode are that: the reactor body is It is closed.Other steps are same as the specific embodiment one.
Specific embodiment 3: one of present embodiment and specific embodiment one or two difference are: the support The hole that multiple diameters are 0.6mm~0.8mm is uniformly provided on plate 7, the punching rate of supporting plate 7 is 10%~15%.Other steps It is the same as one or two specific embodiments.
Specific embodiment 4: one of present embodiment and specific embodiment one to three difference are: the water inlet Pipe 4 is equipped with water inlet peristaltic pump 2 and inlet valve 3.Other steps are identical as specific embodiment one to three.
Specific embodiment 5: one of present embodiment and specific embodiment one to four difference are: the biology Matter carrier 6 is prepared as follows:
One, it prepares corn core carrier: corncob being cut into radius and is the cylindrical body of 0.8cm~1.1cm, then is naturally dried to Its quality is no longer changed, and obtains dry corncob cylindrical body;By putting for the corncob cylindrical body rule of multiple dryings To supporting plate 7, corn core carrier is obtained;
The height of the corn core carrier of 7 top of supporting plate is 48cm~50cm in step 1;
Two, sludge biofilm:
Activated sludge is mixed with artificial distribution, obtains activated sludge and the mixture of artificial distribution;By activated sludge with The mixture of artificial distribution is added in water tank inlet 1, opens water inlet peristaltic pump 2 and inlet valve 3, activated sludge with manually match The mixture of water is entered in reactor body by water inlet peristaltic pump 2, inlet valve 3 and water inlet pipe 4, in reactor body It stops 1.5 days~2 days, makes activated sludge biofilm in corn core carrier surface, then by the mixture of activated sludge and artificial distribution It is discharged from outlet pipe 5, closes water inlet peristaltic pump 2 and inlet valve 3;
In activated sludge described in step 2 and the mixture of artificial distribution the mass fraction of activated sludge be 20%~ 25%;
Three, whiterot fungi culture and biofilm:
1., whiterot fungi Phanerochaetc chrysosporium is incubated in white rot bacterium culture medium:
Step 3 1. described in white rot bacterium culture medium are as follows: 20% potato prepare liquid 1L, glucose 20g, KH2PO4 3g、 MgSO4·7H2O 1.5g, thiamine micro 8mg and agar 20g;
Step 3 1. described in 20% potato prepare liquor manufacture method are as follows: peeled potatoes 200g is cut into small pieces, adds Water 1L boils 20min, filters off potato ball, filtrate is supplied 1L;
Step 3 1. described in white rot bacterium culture medium needs sterilize at 112 DEG C 20min;
Step 3 1. described in whiterot fungi need to aseptically access in white rot bacterium culture medium, at 30 DEG C, 160r/ In the shaking table of min then whiterot fungi seed liquor is mixed with artificial distribution to logarithmic growth phase, obtains whiterot fungi seed liquor by culture With the mixed liquor of artificial distribution;
Step 3 1. described in whiterot fungi seed liquor and artificial distribution volume ratio be 1:1;
2., the mixed liquor of whiterot fungi seed liquor and artificial distribution is added in water tank inlet 1, open water inlet peristaltic pump 2 With inlet valve 3, the mixed liquor of whiterot fungi seed liquor and artificial distribution pass through water inlet peristaltic pump 2, inlet valve 3 and water inlet pipe 4 It enters in reactor body, is stopped 6 days~7 days in reactor body, make whiterot fungi biofilm in corn core carrier surface, obtain To the corncob for hanging with denitrifying bacterium and whiterot fungi, as biomass carrier 6.Other steps and one to four phase of specific embodiment Together.
Activated sludge described in present embodiment step 2 derives from Harbin peace sewage treatment plant;
Present embodiment step 3 1. described in whiterot fungi Phanerochaetc chrysosporium buy in China Microorganism fungus kind net.
Specific embodiment 6: one of present embodiment and specific embodiment one to five difference are: institute in step 2 The artificial distribution's composition stated are as follows: MgSO4·7H2O, 0.08g/L;KNO3, 0.15g/L;KH2PO4, 0.015g/L;CaCl2, 0.04g/L and microelement, 1mL/L;The artificial distribution prepares by the following method: by 0.08g MgSO4·7H2O、 0.15g KNO3、0.015g KH2PO4、0.04g CaCl2It is dissolved into 1L distilled water with 1mL microelement, obtains the artificial of 1L Water distribution.Other steps are identical as specific embodiment one to five.
Specific embodiment 7: one of present embodiment and specific embodiment one to six difference are: institute in step 2 The trace element suite stated becomes: EDTA, 50mg/L;CoCl2·6H2O, 0.05mg/L;H3BO3, 0.05mg/L;(NH4)6Mo7O24·4H2O, 0.05mg/L;KI, 0.1mg/L;CuSO4·5H2O, 1.6mg/L;ZnSO4, 2.2mg/L;FeSO4·7H2O, 5mg/L.Other steps are identical as specific embodiment one to six.
Specific embodiment 8: one of present embodiment and specific embodiment one to seven difference are: step 3 2. in Artificial distribution's composition are as follows: MgSO4·7H2O, 0.08g/L;KNO3, 0.15g/L;KH2PO4, 0.015g/L;CaCl2, 0.04g/L and microelement, 1ml/L;The artificial distribution prepares by the following method: by 0.08g MgSO4·7H2O、 0.15g KNO3、0.015g KH2PO4、0.04g CaCl2It is dissolved into 1L distilled water with 1mL microelement, obtains the artificial of 1L Water distribution.Other steps are identical as specific embodiment one to seven.
Specific embodiment 9: present embodiment is using a kind of anti-using corncob as the denitrification filter pool of biomass carrier The method for answering device processing sewage is completed by the following steps:
Sewage is added in water tank inlet 1, water inlet peristaltic pump 2, inlet valve 3 and multiple outlet pipes 5 are opened, sewage is logical It crosses water inlet peristaltic pump 2, inlet valve 3 and water inlet pipe 4 to enter in reactor body, when hydraulic retention in reactor body Between be 60min~70min, then be discharged from multiple outlet pipes 5, the sewage that obtains that treated;At interval of 20 days~30 days, open Valve 9 and backwash intake pump 10, clear water enter reactor by backwash water inlet pipe 8, valve 9 and backwash intake pump 10 It is backwashed in main body, removes the old loose biomembrane adhered on biomass carrier 6;
The flow of inlet water of the reactor body are as follows: 0.6L/h~0.7L/h.
Specific embodiment 10: the difference of present embodiment and specific embodiment nine is: the sewage index is COD, 53.8mg/L~56.2mg/L;NO3 -- N 18.7mg/L~19.3mg/L;NO2 --N<0.9mg/L;TN, 18.2mg/L~ 19.8mg/L.Other steps are identical as specific embodiment nine.
Beneficial effects of the present invention are verified using following embodiment:
Embodiment one: it utilizes a kind of using corncob as the side of the denitrification filter pool reactor for treatment sewage of biomass carrier Method is completed by the following steps:
Sewage is added in water tank inlet 1, water inlet peristaltic pump 2, inlet valve 3 and multiple outlet pipes 5 are opened, sewage is logical It crosses water inlet peristaltic pump 2, inlet valve 3 and water inlet pipe 4 to enter in reactor body, when hydraulic retention in reactor body Between be 65min, then be discharged from multiple outlet pipes 5, the sewage that obtains that treated;At interval of 25 days, valve 9 and backwash are opened Intake pump 10, clear water are entered in reactor body and are carried out instead by backwash water inlet pipe 8, valve 9 and backwash intake pump 10 It rinses, removes the old loose biomembrane adhered on biomass carrier 6;
The flow of inlet water of the reactor body are as follows: 0.65L/h;
The sewage index is COD, 53.8mg/L~56.2mg/L;NO3 -- N, 18.7mg/L~19.3mg/L;TN, 18.2mg/L~19.8mg/L;
It is described it is a kind of by the denitrification filter pool reactor of biomass carrier of corncob include reactor body, water inlet water Case 1, water inlet pipe 4, multiple outlet pipes 5 and backwash water inlet pipe 8;
The reactor body includes biomass carrier 6 and supporting plate 7, and biomass carrier 6 and supporting plate 7 from up to The lower inside that reactor body is set;
Water inlet and backwash water inlet have been opened on the lower section of supporting plate 7, the side wall of reactor body;Supporting plate 7 Top, reactor body side wall on opened multiple water outlets from top to bottom;Outlet pipe 5 passes through water outlet and reactor body It is connected;
The water tank inlet 1 is connected by water inlet pipe 4 and water inlet with reactor body;The backwash water inlet Pipe 8 is connected by backwash water inlet with reactor body, and is backwashed water inlet pipe 8 and be equipped with valve 9 and backwash water inlet Pump 10;
The biomass carrier 6 is the corncob for hanging with denitrifying bacterium and whiterot fungi;
The reactor body is closed;
The hole that multiple diameters are 0.6mm~0.8mm is uniformly provided on the supporting plate 7, the punching rate of supporting plate 7 is 15%;
The water inlet pipe 4 is equipped with water inlet peristaltic pump 2 and inlet valve 3;
The biomass carrier 6 is prepared as follows:
One, it prepares corn core carrier: corncob being cut into radius and is the cylindrical body of 1cm, then naturally dries to its quality not It changes again, obtains dry corncob cylindrical body;The corncob cylindrical body rule of multiple dryings is placed into supporting plate 7 On, obtain corn core carrier;
The height of the corn core carrier of 7 top of supporting plate is 50cm in step 1;
Two, sludge biofilm:
Activated sludge is mixed with artificial distribution, obtains activated sludge and the mixture of artificial distribution;By activated sludge with The mixture of artificial distribution is added in water tank inlet 1, opens water inlet peristaltic pump 2 and inlet valve 3, activated sludge with manually match The mixture of water is entered in reactor body by water inlet peristaltic pump 2, inlet valve 3 and water inlet pipe 4, in reactor body It stops 1.5 days~2 days, makes activated sludge biofilm in corn core carrier surface, then by the mixture of activated sludge and artificial distribution It is discharged from outlet pipe 5, closes water inlet peristaltic pump 2 and inlet valve 3;
The mass fraction of activated sludge is 20% in activated sludge described in step 2 and the mixture of artificial distribution;
The composition of artificial distribution described in step 2 are as follows: MgSO4·7H2O, 0.08g/L;KNO3, 0.15g/L;KH2PO4, 0.015g/L;CaCl2, 0.04g/L and microelement, 1mL/L;The artificial distribution prepares by the following method: will 0.08g MgSO4·7H2O、0.15g KNO3、0.015g KH2PO4、0.04g CaCl21L distillation is dissolved into 1mL microelement In water, the artificial distribution of 1L is obtained;
Trace element suite described in step 2 becomes: EDTA, 50mg/L;CoCl2·6H2O, 0.05mg/L;H3BO3, 0.05mg/L;(NH4)6Mo7O24·4H2O, 0.05mg/L;KI, 0.1mg/L;CuSO4·5H2O, 1.6mg/L;ZnSO4, 2.2mg/ L;FeSO4·7H2O, 5mg/L;
Three, whiterot fungi culture and biofilm:
1., whiterot fungi Phanerochaetc chrysosporium is incubated in white rot bacterium culture medium:
Step 3 1. described in white rot bacterium culture medium are as follows: 20% potato prepare liquid 1L, glucose 20g, KH2PO4 3g、 MgSO4·7H2O 1.5g, thiamine micro 8mg and agar 20g;
Step 3 1. described in 20% potato prepare liquor manufacture method are as follows: peeled potatoes 200g is cut into small pieces, adds Water 1L boils 20min, filters off potato ball, filtrate is supplied 1L;
Step 3 1. described in white rot bacterium culture medium needs sterilize at 112 DEG C 20min;
Step 3 1. described in whiterot fungi need to aseptically access in white rot bacterium culture medium, at 30 DEG C, 160r/ In the shaking table of min then whiterot fungi seed liquor is mixed with artificial distribution to logarithmic growth phase, obtains whiterot fungi seed liquor by culture With the mixed liquor of artificial distribution;
Step 3 1. described in whiterot fungi seed liquor and artificial distribution volume ratio be 1:1;
2., the mixed liquor of whiterot fungi seed liquor and artificial distribution is added in water tank inlet 1, open water inlet peristaltic pump 2 With inlet valve 3, the mixed liquor of whiterot fungi seed liquor and artificial distribution pass through water inlet peristaltic pump 2, inlet valve 3 and water inlet pipe 4 It enters in reactor body, is stopped 6 days~7 days in reactor body, make whiterot fungi biofilm in corn core carrier surface, obtain To the corncob for hanging with denitrifying bacterium and whiterot fungi, as biomass carrier 6;
Step 3 2. described in artificial distribution composition are as follows: MgSO4·7H2O, 0.08g/L;KNO3, 0.15g/L;KH2PO4, 0.015g/L;CaCl2, 0.04g/L and microelement, 1ml/L;The artificial distribution prepares by the following method: will 0.08g MgSO4·7H2O、0.15g KNO3、0.015g KH2PO4、0.04g CaCl21L distillation is dissolved into 1mL microelement In water, the artificial distribution of 1L is obtained.
Activated sludge described in one step 2 of embodiment derives from Harbin peace sewage treatment plant;
One step 3 of embodiment 1. described in whiterot fungi Phanerochaetc chrysosporium purchase in China it is micro- Biological inoculum net.
Method treated sewage index using embodiment one is COD, 24.5~29.5mg/L;NO3 -- N, 5.8~ 6.2mg/L;NO2 -- N, 0.7~0.9mg/L;TN, 7.9~8.1mg/L.
The whiterot fungi added in embodiment one shows through high-flux sequence in a large amount of reproductions of corn wicking surface, improves and is System increases the steady of system compared to the denitrification filter pool reactor for not adding whiterot fungi to the utilization rate of lignin in corncob It is qualitative, the system stable operation period is extended, makes reactor can be with the continuous operation of efficient stable.
In summary, the present invention is to NO in sewage3 -- N and COD has apparent removal effect, and without nitrite nitrogen product It is tired, reach good denitrification effect.
Above-described embodiment only technical concept feature to illustrate the invention, its object is to allow person skilled in the art The present invention can be understood and implemented accordingly, it is not intended to limit the scope of the present invention.All Spirit Essences according to the present invention Made equivalent change or modification, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of using corncob as the denitrification filter pool reactor of biomass carrier, it is characterised in that one kind is biology with corncob The denitrification filter pool reactor of matter carrier include reactor body, water tank inlet (1), water inlet pipe (4), multiple outlet pipes (5) and It backwashes water inlet pipe (8);
The reactor body includes biomass carrier (6) and supporting plate (7), and biomass carrier (6) and supporting plate (7) are certainly Up to the lower inside that reactor body is arranged in;
Water inlet and backwash water inlet have been opened on the lower section of supporting plate (7), the side wall of reactor body;Supporting plate (7) Top, reactor body side wall on opened multiple water outlets from top to bottom;Outlet pipe (5) passes through water outlet and reactor master Body is connected;
The water tank inlet (1) is connected by water inlet pipe (4) and water inlet with reactor body;The backwash water inlet Pipe (8) is connected by backwash water inlet with reactor body, and is backwashed water inlet pipe (8) and be equipped with valve (9) and recoil Wash intake pump (10);
The biomass carrier (6) is the corncob for hanging with denitrifying bacterium and whiterot fungi.
2. according to claim 1 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists It is closed in the reactor body.
3. according to claim 1 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists In being uniformly provided with the hole that multiple diameters are 0.6mm~0.8mm on the supporting plate (7), the punching rate of supporting plate (7) is 10% ~15%.
4. according to claim 1 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists Water inlet peristaltic pump (2) and inlet valve (3) are equipped in the water inlet pipe (4).
5. according to claim 4 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists It is prepared as follows in the biomass carrier (6):
One, it prepares corn core carrier: corncob being cut into radius and is the cylindrical body of 0.8cm~1.1cm, then naturally dries to its matter Amount is no longer changed, and obtains dry corncob cylindrical body;Being placed into for corncob cylindrical body rule of multiple dryings is held On supporting plate (7), corn core carrier is obtained;
The height of corn core carrier in step 1 above supporting plate (7) is 48cm~50cm;
Two, sludge biofilm:
Activated sludge is mixed with artificial distribution, obtains activated sludge and the mixture of artificial distribution;By activated sludge and manually The mixture of water distribution is added in water tank inlet (1), opens water inlet peristaltic pump (2) and inlet valve (3), activated sludge with manually The mixture of water distribution is entered in reactor body by water inlet peristaltic pump (2), inlet valve (3) and water inlet pipe (4), is being reacted It is stopped 1.5 days~2 days in device main body, makes activated sludge biofilm in corn core carrier surface, then by activated sludge and artificial distribution Mixture discharge from the outlet pipe (5), close water inlet peristaltic pump (2) and inlet valve (3);
The mass fraction of activated sludge is 20%~25% in activated sludge described in step 2 and the mixture of artificial distribution;
Three, whiterot fungi culture and biofilm:
1., whiterot fungi (Phanerochaetc chrysosporium) is incubated in white rot bacterium culture medium:
Step 3 1. described in white rot bacterium culture medium are as follows: 20% potato prepare liquid 1L, glucose 20g, KH2PO4 3g、 MgSO4·7H2O 1.5g, thiamine micro 8mg and agar 20g;
Step 3 1. described in 20% potato prepare liquor manufacture method are as follows: peeled potatoes 200g is cut into small pieces, adds water 1L boils 20min, filters off potato ball, filtrate is supplied 1L;
Step 3 1. described in white rot bacterium culture medium needs sterilize at 112 DEG C 20min;
Step 3 1. described in whiterot fungi need to aseptically access in white rot bacterium culture medium, at 30 DEG C, 160r/min Shaking table in culture to logarithmic growth phase, then whiterot fungi seed liquor is mixed with artificial distribution, obtain whiterot fungi seed liquor with The mixed liquor of artificial distribution;
Step 3 1. described in whiterot fungi seed liquor and artificial distribution volume ratio be 1:1;
2., the mixed liquor of whiterot fungi seed liquor and artificial distribution is added in water tank inlet (1), open water inlet peristaltic pump (2) With inlet valve (3), the mixed liquor of whiterot fungi seed liquor and artificial distribution by water inlet peristaltic pump (2), inlet valve (3) and into Water pipe (4) enters in reactor body, stops 6 days~7 days in reactor body, makes whiterot fungi biofilm in corn core carrier Surface obtains the corncob for hanging with denitrifying bacterium and whiterot fungi, as biomass carrier (6).
6. according to claim 1 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists Artificial distribution's composition described in step 2 are as follows: MgSO4·7H2O, 0.08g/L;KNO3, 0.15g/L;KH2PO4, 0.015g/ L;CaCl2, 0.04g/L and microelement, 1mL/L;The artificial distribution prepares by the following method: by 0.08g MgSO4·7H2O、0.15g KNO3、0.015g KH2PO4、0.04g CaCl2It is dissolved into 1L distilled water with 1mL microelement, Obtain the artificial distribution of 1L.
7. according to claim 1 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists Trace element suite described in step 2 becomes: EDTA, 50mg/L;CoCl2·6H2O, 0.05mg/L;H3BO3, 0.05mg/ L;(NH4)6Mo7O24·4H2O, 0.05mg/L;KI, 0.1mg/L;CuSO4·5H2O, 1.6mg/L;ZnSO4, 2.2mg/L; FeSO4·7H2O, 5mg/L.
8. according to claim 1 a kind of using corncob as the denitrification filter pool reactor of biomass carrier, feature exists In step 3 2. described in artificial distribution composition are as follows: MgSO4·7H2O, 0.08g/L;KNO3, 0.15g/L;KH2PO4, 0.015g/L;CaCl2, 0.04g/L and microelement, 1ml/L;The artificial distribution prepares by the following method: will 0.08g MgSO4·7H2O、0.15g KNO3、0.015g KH2PO4、0.04g CaCl21L distillation is dissolved into 1mL microelement In water, the artificial distribution of 1L is obtained.
9. using as claimed in claim 4 a kind of using corncob as the denitrification filter pool reactor for treatment sewage of biomass carrier Method, it is characterised in that using a kind of using corncob as the method for the denitrification filter pool reactor for treatment sewage of biomass carrier It is completed by the following steps:
Sewage is added in water tank inlet (1), water inlet peristaltic pump (2), inlet valve (3) and multiple outlet pipes (5) are opened, it is dirty Water is entered in reactor body by water inlet peristaltic pump (2), inlet valve (3) and water inlet pipe (4), in reactor body Hydraulic detention time is 60min~70min, then the discharge from multiple outlet pipes (5), the sewage that obtains that treated;At interval of 20 It~30 days, valve (9) and backwash intake pump (10) are opened, clear water passes through backwash water inlet pipe (8), valve (9) and recoil It washes intake pump (10) and enters in reactor body and backwashed, that adheres in removal biomass carrier (6) is old loose Biomembrane;
The flow of inlet water of the reactor body are as follows: 0.6L/h~0.7L/h.
10. it is according to claim 9 using a kind of using corncob as the denitrification filter pool reactor for treatment of biomass carrier The method of sewage, it is characterised in that the sewage index is COD, 53.8mg/L~56.2mg/L;NO3 -- N 18.7mg/L~ 19.3mg/L;NO2 --N<0.9mg/L;TN, 18.2mg/L~19.8mg/L.
CN201811259036.6A 2018-10-26 2018-10-26 A method of sewage is handled using corncob as the denitrification filter pool reactor of biomass carrier and using it Pending CN109081439A (en)

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CN113830897A (en) * 2021-10-13 2021-12-24 重庆市江津排水有限公司 Based on A2Low-carbon-source sewage treatment device and method for O process

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Application publication date: 20181225