CN109065736A - A kind of preparation facilities of perovskite light absorption film - Google Patents

A kind of preparation facilities of perovskite light absorption film Download PDF

Info

Publication number
CN109065736A
CN109065736A CN201810719295.6A CN201810719295A CN109065736A CN 109065736 A CN109065736 A CN 109065736A CN 201810719295 A CN201810719295 A CN 201810719295A CN 109065736 A CN109065736 A CN 109065736A
Authority
CN
China
Prior art keywords
spin coating
conduit
hole
substrate
extends
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810719295.6A
Other languages
Chinese (zh)
Inventor
姜辛
王立鹏
邱建航
王高翔
邰凯平
刘鲁生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Metal Research of CAS
Original Assignee
Institute of Metal Research of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Metal Research of CAS filed Critical Institute of Metal Research of CAS
Priority to CN201810719295.6A priority Critical patent/CN109065736A/en
Publication of CN109065736A publication Critical patent/CN109065736A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/12Deposition of organic active material using liquid deposition, e.g. spin coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention relates to solar cell preparation technology, especially a kind of preparation facilities of perovskite light absorption film.One vacuum device used one end conduit of continous way spin coating liquid of the device extends to be connected in perovskite precursor solution tank, with perovskite precursor solution, and it is interior, corresponding with the sample stage of spin coater which extends to spin coater;Another vacuum device used one end conduit of continous way spin coating liquid is extended in reversed polarity NaOH solution tank NaOH, is connected to reversed polarity solution, which extends to that spin coater is interior, corresponding with the sample stage of spin coater, and spin coating substrate is placed on sample stage;Slidingtype spin coating cover plate is set at the top of spin coater, and the conduit location hole that the vacuum device used conduit of the continous way spin coating liquid is each passed through on slidingtype spin coating cover plate extends in spin coater.It is the configuration of the present invention is simple, low in cost, it is easy to produce and use, it is particularly suitable for preparing perovskite thin film in glove box the continuous preparation, it can be achieved that perovskite thin film.

Description

A kind of preparation facilities of perovskite light absorption film
Technical field
The present invention relates to solar cell preparation technology, the preparation of especially a kind of perovskite light absorption film is filled It sets.
Background technique
With the aggravation of consumption and the environmental pollution of traditional energy, demand of the people to renewable and clean energy resource is increasingly compeled It cuts.Solar energy has the advantages such as total amount is big, is easily obtained as a kind of clean energy resource.It, will for various solar utilization techniques The photovoltaic power generation technology that solar energy is converted into electric energy is always emphasis concerned by people.However, traditional silicon-based photovoltaic cells preparation The cost is relatively high, and silicon materials production process is seriously polluted, limits its application.Film photovoltaic cell especially perovskite solar energy Battery is gradually attracted people's attention with cheap cost and easy preparation process.
Perovskite solar cell module mainly includes transparent conductive electrode, electron transfer layer, perovskite light absorbing layer, sky Cave transport layer and to electrode etc., in perovskite solar battery preparation process, since perovskite light absorbing material is to water and oxygen Air-sensitive sense, it usually needs operated in inert-atmosphere glove box, process flow is complex, prepared perovskite light absorption film Yields be in lower range.
Summary of the invention
For the deficiency in existing perovskite thin film technology of preparing, the purpose of the present invention is to provide a kind of easy to operate Perovskite light absorption film preparation facilities improves working efficiency to simplify the preparation flow of film.
The technical scheme is that
A kind of preparation facilities of perovskite light absorption film, including continous way spin coating liquid is vacuum device used, slidingtype spin coater Cover board and spin coater, specific structure are as follows:
One vacuum device used one end conduit of continous way spin coating liquid extends in perovskite precursor solution tank and perovskite forerunner The connection of object solution, it is interior, corresponding with the sample stage of spin coater which extends to spin coater;The rotation of another continous way The vacuum device used one end conduit of masking liquid extends to be connected in reversed polarity NaOH solution tank NaOH, with reversed polarity solution, which extends to Spin coater is interior, corresponding with the sample stage of spin coater, and spin coating substrate is placed on sample stage;
Slidingtype spin coating cover plate is set at the top of spin coater, and the vacuum device used conduit of the continous way spin coating liquid is worn respectively The conduit location hole crossed on slidingtype spin coating cover plate extends in spin coater.
The preparation facilities of the perovskite light absorption film, the suction of continous way spin coating liquid put dress and replace with continous way syringe Or continous way syringe pump.
The preparation facilities of the perovskite light absorption film, slidingtype spin coating cover plate include cover plate main body, sampling hole, Sliding block, conduit location hole are provided with sampling hole on cover plate main body, and cover plate main body is equipped with sliding block, is provided with conduit location hole on sliding block, Conduit passes through conduit location hole and extends in spin coater, and conduit location hole is respectively as follows: perovskite precursor solution hole and reversed polarity is molten Fluid apertures, spin coating substrate are placed on sample stage by sampling hole.
The preparation facilities of the perovskite light absorption film, it includes three-way valve that continous way spin coating liquid is vacuum device used, is led Pipe, syringe, three-way valve are connected to syringe, and conduit is installed at the both ends of three-way valve respectively, in which: a three-way valve one End conduit extends to be connected in perovskite precursor solution tank, with perovskite precursor solution, which stretches In to spin coater, it is corresponding with spin coater sample stage;Another three-way valve one end conduit extends in reversed polarity NaOH solution tank NaOH and anti- Polar solvent connection, it is interior, corresponding with spin coater sample stage which extends to spin coater.
The preparation facilities of the perovskite light absorption film further includes protective glue band positioning device, the positioning of protective glue band Device is equipped with positioning pin and porus positioning plate, opens up dowel hole and substrate location hole, two dowel holes on porus positioning plate It is opened in the both ends of porus positioning plate respectively, substrate location hole is opened between two dowel holes, and positioning pin is plugged in positioning In pin hole, substrate is placed in substrate positioning hole.
The preparation facilities of the perovskite light absorption film, the dowel hole in the size and porus positioning plate of positioning pin Size is identical, and the size of porus positioning plate upper substrate location hole is identical as the size of spin coating substrate;In use, positioning pin is inserted into In dowel hole, and substrate is put into the substrate positioning hole of porus positioning plate, the edge of protective glue band is directed at positioning pin side Edge, that realizes protective glue band is accurately pasted on spin coating substrate.
It advantage for present invention and has the beneficial effect that:
The present invention includes that protective glue band positioning device, continous way spin coating liquid is vacuum device used and slidingtype spin coating cover plate, Its is simple and reasonable for structure, and device is easy to produce and use, low in cost, is particularly suitable for preparing perovskite in glove box thin Film, it can be achieved that perovskite light absorption film continuous preparation, and work efficiency is high.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the band positioning device structure schematic diagram of protective glue shown in Fig. 1.
Fig. 3 is the vacuum device used structural schematic diagram of continous way spin coating liquid shown in Fig. 1.
Fig. 4 is slidingtype spin coater covering plate structure schematic diagram shown in Fig. 1.
Fig. 5 is X-ray diffractogram (a), the UV-vis DRS of MAPbI3 type perovskite thin film prepared by embodiment 1 Scheme (b), 50000 times of scanning electron microscope diagrams (c);25000 times of scanning electron microscope diagrams (d);(a) in figure, abscissa 2Theta (degree) is represented the angle of diffraction (degree), and ordinate Intensity (a.u.) represents intensity;(b) in figure, abscissa Wavelength (nm) is represented wavelength (nanometer), and ordinate Intensity (a.u.) represents intensity.
Drawing reference numeral explanation:
1- protective glue band positioning device, 2- continous way spin coating liquid is vacuum device used, 3- slidingtype spin coating cover plate, 4- spin coating Machine, 5- perovskite precursor solution tank, 6- reversed polarity NaOH solution tank NaOH, 7- positioning pin, 8- porus positioning plate, 9- three-way valve, 10- are led Pipe, 11- syringe, 12- cover plate main body, 13- sampling hole, 14- sliding block, 15- conduit location hole, 16- dowel hole, 17- substrate Location hole, 18- sample stage.
Specific embodiment
The present invention will be further described combined with specific embodiments below, but the present invention is not limited to following embodiments.
As shown in Figure 1, perovskite light absorption film preparation facilities of the invention, specifically includes that protective glue band positioning device 1, continous way spin coating liquid is vacuum device used 2, slidingtype spin coating cover plate 3 and spin coater 4, and specific structure is as follows:
As shown in Fig. 2, protective glue band positioning device 1 includes positioning pin 7 and porus positioning plate 8, opened up on porus positioning plate 8 Dowel hole 16 and substrate location hole 17, two dowel holes 16 are opened in the both ends of porus positioning plate 8, substrate positioning respectively Hole 17 is opened between two dowel holes 16, and positioning pin 7 is plugged in dowel hole 16, and substrate is placed in substrate location hole 17 It is interior.
The size of positioning pin 7 is identical as 16 size of dowel hole on porus positioning plate 8, and 8 upper substrate of porus positioning plate is fixed The size in position hole 17 is identical as the size of spin coating substrate.In use, positioning pin 7 is inserted into dowel hole 16, and substrate is put Enter in the substrate location hole 17 of porus positioning plate 8, the edge of protective glue band is directed at 7 edge of positioning pin, guarantor can be accurately positioned Retaining tape, so that the accurate stickup of protective glue band is realized, consequently facilitating electrode evaporation.
As shown in figure 3, continous way spin coating liquid vacuum device used 2 includes three-way valve 9, conduit 10, syringe 11, three-way valve 9 both ends are installed by conduit 10 respectively, in which: the conduit 10 of 9 one end of three-way valve extends to perovskite precursor solution tank 5 It is interior, be connected to perovskite precursor solution, the conduit 10 of 9 other end of three-way valve extends in spin coater 4, with spin coater 4 Sample stage 18 is corresponding;The conduit 10 of another 9 one end of three-way valve extends in reversed polarity NaOH solution tank NaOH 6, connects with reversed polarity solution Logical, it is interior, corresponding with the sample stage 18 of spin coater 4 that the conduit 10 of 9 other end of three-way valve extends to spin coater 4.Three-way valve 9 It is connected to syringe 11, syringe is for absorption and release solution.
In addition, continous way spin coating liquid vacuum device used 2 could alternatively be continous way syringe or continous way syringe pump.
As shown in figure 4, slidingtype spin coating cover plate 3 includes cover plate main body 12, sampling hole 13, sliding block 14, conduit location hole 15, sampling hole 13 is provided on cover plate main body 12, cover plate main body 12 is equipped with sliding block 14, is provided with conduit location hole 15 on sliding block 14, Conduit 10 passes through conduit location hole 15 and extends in spin coater 4, and conduit location hole 15 is respectively as follows: perovskite precursor solution hole and anti- Polar solvent hole, spin coating substrate are placed on sample stage 18 by sampling hole 13.
In use, substrate is removed, sliding is passed through after substrate pastes protective glue band by protective glue band positioning device 1 The sampling hole 13 of formula spin coating cover plate 3 is placed on the sample stage 18 of spin coater 4, by the threeway of continous way spin coating liquid vacuum device used 2 Valve 9 is placed in imbibition gear, perovskite precursor solution and reversed polarity solution is drawn respectively with syringe 11, then by triple valve Door 9 is adjusted to gear is added dropwise, and the sliding block 14 of slidingtype spin coating cover plate 3 is slid into perovskite precursor solution hole location, with note Emitter 11 discharges perovskite precursor solution and starts spin coater 4, slides the sliding block 14 of slidingtype spin coating cover plate 3 after starting To reversed polarity solution hole location, and reversed polarity solution is discharged with syringe 11 in the suitable time and rinses substrate, lead to after spin coating The sampling hole 13 on slidingtype spin coating cover plate 3 is crossed, substrate is taken out and is heat-treated, the perovskite that can be obtained high quality is thin Film.
Embodiment 1
In the present embodiment, conducting glass substrate is put into the substrate positioning hole of porus positioning plate, it is fixed that positioning pin is inserted into Then position pin hole takes one section of protective glue band, and is pasted on substrate after its edge is directed at positioning pin edge.
Substrate is removed and separated from porus positioning plate, is then transferred in glove box, is fixed on spin coater On sample stage.It is molten that the MAPbI3 that 100 μ L concentration are 1.6mol/L is drawn respectively using the vacuum device used conduit of continous way spin coating liquid Liquid (perovskite precursor solution) and 1.5mL anhydrous ether (reversed polarity solution), mobile sliding block lead perovskite precursor solution Pipe is directed at substrate center, sets 5000 revs/min for the running parameter of spin coater, time 45s.Release MAPbI3 solution simultaneously starts Spin coater, then moving sliding block makes reversed polarity solution conduit be directed at substrate center, discharges anhydrous ether after spin coater starting 15s, Substrate is taken out from sampling hole after spin coating, is placed on 100 DEG C of hot plate after being heat-treated 150s, perovskite thin film can be obtained.
As shown in figure 5, unrestrained using the XRD diffracting spectrum of the MAPbI3 type perovskite thin film of device preparation, UV, visible light Reflect map and sem analysis result.XRD the result shows that, the device preparation MAPbI3 film be practically free of impurity phase, it is ultraviolet It can be seen that diffusing reflection spectrum shows that film has very high absorption efficiency in visible region, sem analysis shows the crystal grain of this film For size in 300nm or so, it is high that film is practically free of hole, crystalline quality.
Above description is explanation of the invention, is not intended to limit the invention, and limited range of the present invention is referring to right It is required that within protection scope of the present invention, any type of modification can be made.

Claims (6)

1. a kind of preparation facilities of perovskite light absorption film, which is characterized in that, sliding vacuum device used including continous way spin coating liquid Formula spin coating cover plate and spin coater, specific structure are as follows:
It is interior, molten with perovskite predecessor that one vacuum device used one end conduit of continous way spin coating liquid extends to perovskite precursor solution tank Liquid connection, it is interior, corresponding with the sample stage of spin coater which extends to spin coater;Another continous way spin coating liquid Vacuum device used one end conduit extends to be connected in reversed polarity NaOH solution tank NaOH, with reversed polarity solution, which extends to spin coating Machine is interior, corresponding with the sample stage of spin coater, and spin coating substrate is placed on sample stage;
Slidingtype spin coating cover plate is set at the top of spin coater, and the vacuum device used conduit of the continous way spin coating liquid is each passed through cunning Conduit location hole on dynamic formula spin coating cover plate extends in spin coater.
2. the preparation facilities of perovskite light absorption film as described in claim 1, which is characterized in that the suction of continous way spin coating liquid is put Dress replaces with continous way syringe or continous way syringe pump.
3. the preparation facilities of perovskite light absorption film as described in claim 1, which is characterized in that slidingtype spin coating cover plate Including cover plate main body, sampling hole, sliding block, conduit location hole, sampling hole is provided on cover plate main body, cover plate main body is equipped with sliding block, Conduit location hole is provided on sliding block, conduit passes through conduit location hole and extends in spin coater, before conduit location hole is respectively as follows: perovskite It drives object solution hole and reversed polarity solution hole, spin coating substrate is placed on sample stage by sampling hole.
4. the preparation facilities of perovskite light absorption film as described in claim 1, which is characterized in that the suction of continous way spin coating liquid is put Device includes three-way valve, conduit, syringe, and three-way valve is connected to syringe, and conduit is installed at the both ends of three-way valve respectively, Wherein: three-way valve one end conduit extends to be connected in perovskite precursor solution tank, with perovskite precursor solution, this three It is interior, corresponding with spin coater sample stage that port valve door other end conduit extends to spin coater;Another three-way valve one end conduit extends to It is connected in reversed polarity NaOH solution tank NaOH, with reversed polarity solution, which extends in spin coater and spin coater sample Platform is corresponding.
5. the preparation facilities of perovskite light absorption film as described in claim 1, which is characterized in that further include that protective glue band is fixed Position device, protective glue band positioning device are equipped with positioning pin and porus positioning plate, open up dowel hole and substrate on porus positioning plate Location hole, two dowel holes are opened in the both ends of porus positioning plate respectively, substrate location hole be opened in two dowel holes it Between, positioning pin is plugged in dowel hole, and substrate is placed in substrate positioning hole.
6. the preparation facilities of perovskite light absorption film as claimed in claim 5, which is characterized in that the size of positioning pin and more Dowel hole size on the positioning plate of hole is identical, the size and the size phase of spin coating substrate of porus positioning plate upper substrate location hole Together;In use, positioning pin is inserted into dowel hole, and substrate is put into the substrate positioning hole of porus positioning plate, will protected The edge of adhesive tape is directed at positioning pin edge, and that realizes protective glue band is accurately pasted on spin coating substrate.
CN201810719295.6A 2018-07-03 2018-07-03 A kind of preparation facilities of perovskite light absorption film Pending CN109065736A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810719295.6A CN109065736A (en) 2018-07-03 2018-07-03 A kind of preparation facilities of perovskite light absorption film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810719295.6A CN109065736A (en) 2018-07-03 2018-07-03 A kind of preparation facilities of perovskite light absorption film

Publications (1)

Publication Number Publication Date
CN109065736A true CN109065736A (en) 2018-12-21

Family

ID=64818532

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810719295.6A Pending CN109065736A (en) 2018-07-03 2018-07-03 A kind of preparation facilities of perovskite light absorption film

Country Status (1)

Country Link
CN (1) CN109065736A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211076A (en) * 2010-04-08 2011-10-12 东京毅力科创株式会社 Coating treatment method, program, computer storage medium and coating treatment apparatus
CN105882120A (en) * 2016-05-11 2016-08-24 武汉理工大学 Printer for perovskite solar cell
CN107779840A (en) * 2016-08-25 2018-03-09 杭州纤纳光电科技有限公司 The evaporation equipment and its application method of a kind of perovskite thin film and application
CN207103057U (en) * 2017-06-02 2018-03-16 杭州纤纳光电科技有限公司 A kind of perovskite thin film coating apparatus
CN107812673A (en) * 2017-10-19 2018-03-20 苏州协鑫纳米科技有限公司 The apparatus for coating of perovskite thin film
CN207340307U (en) * 2017-11-06 2018-05-08 广东兴达鸿业电子有限公司 For the gauge taped
CN208460805U (en) * 2018-07-03 2019-02-01 中国科学院金属研究所 A kind of preparation facilities of perovskite light absorption film

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211076A (en) * 2010-04-08 2011-10-12 东京毅力科创株式会社 Coating treatment method, program, computer storage medium and coating treatment apparatus
CN105882120A (en) * 2016-05-11 2016-08-24 武汉理工大学 Printer for perovskite solar cell
CN107779840A (en) * 2016-08-25 2018-03-09 杭州纤纳光电科技有限公司 The evaporation equipment and its application method of a kind of perovskite thin film and application
CN207103057U (en) * 2017-06-02 2018-03-16 杭州纤纳光电科技有限公司 A kind of perovskite thin film coating apparatus
CN107812673A (en) * 2017-10-19 2018-03-20 苏州协鑫纳米科技有限公司 The apparatus for coating of perovskite thin film
CN207340307U (en) * 2017-11-06 2018-05-08 广东兴达鸿业电子有限公司 For the gauge taped
CN208460805U (en) * 2018-07-03 2019-02-01 中国科学院金属研究所 A kind of preparation facilities of perovskite light absorption film

Similar Documents

Publication Publication Date Title
EP3920241A1 (en) Power generation building material and manufacturing method therefor
CN101494248B (en) Flat-plate concentration solar battery and method for manufacturing the same
CN103700725B (en) A kind of preparation method based on nano particle copper indium sulfur-selenium thin film for solar cell
Chen et al. Design of efficient dye-sensitized solar cells with patterned ZnO–ZnS core–shell nanowire array photoanodes
CN103346193B (en) A kind of CdTe nanometer crystalline heterojunction solar cell and preparation method thereof
CN105609640A (en) Mechanically laminated perovskite solar cell and preparation method thereof
CN106128772B (en) A kind of preparation method of vulcanized lead quantum dot photovoltaic battery
CN102664215B (en) Method for preparing zinc selenide photoelectric film
CN108540082A (en) A kind of laminated type solar energy fluorescence condenser and preparation method thereof
CN208460805U (en) A kind of preparation facilities of perovskite light absorption film
CN105576127B (en) A kind of Multiple heterostructures interface perovskite solar cell and preparation method thereof
CN109065736A (en) A kind of preparation facilities of perovskite light absorption film
CN106449844A (en) Photovoltaic power generation system and manufacture method
CN103073048A (en) Method for preparing patterned ZnO film by liquid phase self-assembly technology
CN102515559B (en) Method for preparing copper sulfide film with microwave hydrothermal assisted sol-gel method
CN201749787U (en) Solar cell
CN101866968B (en) Spherical thin-film solar cell, preparation method thereof and spatial arrangement assembly based on cell
CN202395006U (en) Solar cell with synergistic conversion layer
CN105489778A (en) Method of preparing CH3NH3PbI3 perovskite thin film based on lead xanthate complex
CN102477549B (en) Method for depositing semiconductor film on flexible substrate
CN103295794A (en) Deposition instrument for quantum dot sensitized thin-film solar cells
CN209447819U (en) A kind of solar power generation glass block
CN203325843U (en) Fabric-surface manufacturing device for solar battery
CN107089926B (en) A kind of preparation method of flakes carbonamidine lead iodine nano wire
CN101887804A (en) Preparation method of large-area dye-sensitized solar battery photo-anode

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination