CN109061063B - Tower column structure for evaluating performance of natural gas mercury removing agent - Google Patents

Tower column structure for evaluating performance of natural gas mercury removing agent Download PDF

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Publication number
CN109061063B
CN109061063B CN201810906789.5A CN201810906789A CN109061063B CN 109061063 B CN109061063 B CN 109061063B CN 201810906789 A CN201810906789 A CN 201810906789A CN 109061063 B CN109061063 B CN 109061063B
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adsorption
cylindrical
natural gas
flange
tube
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CN109061063A (en
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韩中喜
严启团
李剑
葛守国
田闻年
张庆男
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Petrochina Co Ltd
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    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
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Abstract

The invention relates to a tower column structure for evaluating the performance of a natural gas demercuration agent, which comprises a plurality of adsorption tubes connected in series, wherein each adsorption tube is a cylindrical tube body with flanges at two ends, the tube body is filled with the demercuration agent to be evaluated, and tube openings at two ends of the tube body are provided with a screen and an annular gasket; the head end of the first adsorption pipe is provided with a first spiral sleeve body which is fixedly connected with an air inlet joint; the tail end of the last adsorption tube is provided with a second spiral sleeve body which is fixedly connected with an air outlet joint; two adjacent adsorption tubes are connected by a coupling component; the coupling component comprises a third spiral sleeve body and a cylindrical coupling body, wherein the third spiral sleeve body is sleeved on the opposite flanges respectively, and the cylindrical coupling body is connected between the opposite flanges in an abutting mode; a through hole for conducting the adjacent adsorption tubes is axially arranged in the coupling body; the side wall of the coupling body is provided with a communicating hole communicated with the through hole, and the outer end of the communicating hole is connected with a sampling valve. The invention has the advantages of adjustable tower column length, capability of detecting the mass transfer zone length and more convenient detection of the demercuration depth and the demercuration agent mercury capacity.

Description

Tower column structure for evaluating performance of natural gas mercury removing agent
Technical Field
The invention relates to the field of natural gas mercury removal agent research and development and oil gas ground engineering, in particular to a tower column structure for evaluating the performance of a natural gas mercury removal agent.
Background
Mercury is a common trace heavy metal element in natural gas, has toxicity and corrosivity, and brings potential safety threat to gas field production. In order to eliminate the potential safety hazard of mercury, mercury removal treatment is required to be carried out on the mercury-containing natural gas.
At present, the adsorption tube for evaluating the demercuration agent researched at home and abroad is mainly used for evaluating the demercuration agent of flue gas, and the long mass transfer zone cannot be detected when the adsorption tube is used, so that the demercuration depth and the mercury capacity of the demercuration agent are difficult to detect. Present adsorption tube usually needs the later stage artificially to punch at the lateral wall just can gather middle appearance gas detection, and this kind of sample mode not only can cause the interior air current disturbance of adsorption tube, also can cause the adsorbent to block the sample connection. The adsorption tube researched at home and abroad is usually of a single-section structure, is not easy to disassemble and is also not easy to match and use among different experiments.
Therefore, the inventor provides a tower column structure for evaluating the performance of the natural gas mercury removing agent by virtue of experience and practice of related industries for many years, so as to overcome the defects in the prior art.
Disclosure of Invention
The invention aims to provide a tower column structure for evaluating the performance of a natural gas demercuration agent, which can simultaneously realize the evaluation of the mercury capacity, the mass transfer zone length and the demercuration depth of the demercuration agent so as to meet the requirement of evaluating the performance of the natural gas demercuration agent.
Another object of the present invention is to provide a column structure for evaluating the performance of a natural gas mercury removing agent, wherein the installation direction of the sampling valve arranged below each adsorption tube can be adjusted to be the same direction of the column structure, so as to facilitate the connection of corresponding detection equipment on the column structure.
The tower column structure comprises a plurality of adsorption tubes which are connected in series, wherein each adsorption tube is a cylindrical tube body with flanges at two ends, the cylindrical tube body is filled with a mercury removing agent to be evaluated, pipe orifices at two ends of the cylindrical tube body are covered with a screen, an annular gasket is arranged on the periphery of the screen, and the screen and the annular gasket are both arranged on the end face of the flange; the head end of the first adsorption pipe is provided with a first spiral sleeve body sleeved on the head end flange, and the end flange is provided with an air inlet joint and is fixedly connected with the first spiral sleeve body; the tail end of the last adsorption tube is provided with a second spiral sleeve body sleeved on the tail end flange, and the end flange is provided with an air outlet joint and is fixedly connected with the second spiral sleeve body; two adjacent adsorption tubes are connected through a coupling component; each coupling component comprises a third spiral sleeve body and a cylindrical coupling body, wherein the third spiral sleeve body is sleeved on the opposite flanges respectively, the cylindrical coupling body is connected between the opposite flanges in an abutting mode, and the cylindrical coupling body is fixed between the opposite flanges through the third spiral sleeve body; internal threads are respectively arranged in the first, second and third screw sleeves, and external threads which are correspondingly connected with the internal threads are respectively arranged on the outer sides of the two ends of the cylindrical coupling body and the outer sides of the air inlet joint and the air outlet joint; a through hole for conducting the adjacent adsorption tubes is axially arranged in the cylindrical coupling body; the side wall of the cylindrical joint hoop body is provided with a communicating hole communicated with the through hole, and the outer end of the communicating hole is connected with a sampling valve.
In a preferred embodiment of the present invention, the first, second and third spiral sleeves are cylinders with one open end, the inner diameter of the cylinder is the same as the diameter of the flange, the bottom of the cylinder is provided with a through hole, and the diameter of the through hole is larger than the diameter of the cylindrical tube of the adsorption tube; the through hole is sleeved outside the adsorption pipe, and the opening of the cylinder faces to the flange at the end part of the adsorption pipe and is sleeved on the flange; the inner wall of the cylinder body is provided with the internal thread; the diameters of the cylindrical coupling body, the air inlet joint and the air outlet joint are the same as the diameter of the flange; the cylindrical coupling body, the air inlet joint, the air outlet joint and the corresponding flange end faces are provided with the screen and the annular gasket in a clamping mode.
In a preferred embodiment of the present invention, the adsorption tube, the cylindrical coupling body, the gas inlet joint, the gas outlet joint, the screen mesh, and the first, second, and third spiral sleeves are made of stainless steel; the annular gasket is made of polytetrafluoroethylene.
In a preferred embodiment of the invention, the mercury remover to be evaluated is in the form of granules.
In a preferred embodiment of the present invention, the length of the tube body of each of the adsorption tubes is 10 cm.
In a preferred embodiment of the present invention, a positioning pin is disposed between the cylindrical collar body and the corresponding flange.
According to the tower column structure for evaluating the performance of the natural gas mercury removal agent, the sampling is carried out at the through hole of the coupling body, so that the disturbance of air flow in the adsorption tube can be reduced, the sampling is representative, and the evaluation result is more reliable; the multi-section adsorption tube series connection structure has length adjustability, can detect the length of a mass transfer zone, can conveniently detect the demercuration depth and the mercury capacity of the demercuration agent, meets the requirements of natural gas demercuration agent evaluation, and can also meet the requirements of different experiments.
Drawings
The drawings are only for purposes of illustrating and explaining the present invention and are not to be construed as limiting the scope of the present invention. Wherein:
FIG. 1: is a schematic diagram I of the tower column structure for evaluating the performance of the natural gas mercury removing agent.
FIG. 2 is a second schematic diagram (with locating pins) of the tower column structure for evaluating the performance of the natural gas mercury removing agent.
FIG. 3 is a schematic structural view of a third spiral sleeve body according to the present invention.
FIG. 4 is a schematic structural view of the cylindrical contact-hoop body of the present invention.
FIG. 5 is a schematic view of the inlet fitting of the present invention.
FIG. 6 is a schematic view of the outlet joint according to the present invention.
FIG. 7 is a schematic view of the structure of the screen of the present invention.
FIG. 8 is a schematic view of the structure of the annular gasket of the present invention.
Reference numerals:
100. a tower column structure for evaluating the performance of the natural gas demercuration agent;
1. an adsorption tube;
11. a flange;
2. screening a screen;
3. an annular gasket;
41. a first spiral sleeve body;
42. an inlet fitting;
51. a second spiral sleeve body;
52. an outlet fitting;
6. a collar member;
61. a third spiral sleeve body;
62. a cylindrical collar body;
621. a through hole;
622. a communicating hole;
7. a sampling valve;
8. mercury removing agent;
9. and a positioning pin.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Unless otherwise indicated, all references to up and down directions herein are to the same extent as the references to up and down directions in FIG. 1 shown in the present application and described herein.
As shown in fig. 1 to 8, the tower column structure 100 for evaluating the performance of the natural gas mercury removing agent provided by the present invention comprises a plurality of adsorption tubes 1 connected in series in the vertical direction, each adsorption tube 1 is a cylindrical tube body with flanges 11 at two ends, and the cylindrical tube body is filled with the mercury removing agent 8 to be evaluated; as shown in fig. 7 and 8, the pipe orifices at two ends of the cylindrical pipe body are covered with the screen 2, the periphery of the screen 2 is provided with an annular gasket 3, and the screen 2 and the annular gasket 3 are both arranged on the end face of the flange 11; the head end of the first adsorption tube 1 (the uppermost adsorption tube) is provided with a first spiral sleeve body 41 sleeved on the head end flange 11, the end flange 11 is provided with an air inlet joint 42 (as shown in fig. 5), and the air inlet joint 42 is fixedly connected to the end flange 11 by the first spiral sleeve body 41; the end of the last adsorption tube 1 (the lowest adsorption tube) is provided with a second spiral sleeve body 51 sleeved on the end flange 11, the end flange 11 is provided with an air outlet joint 52 (as shown in fig. 6), and the air outlet joint 52 is fixedly connected to the end flange 11 by the second spiral sleeve body 51; two adjacent adsorption tubes 1 are connected through a coupling component 6; each coupling component 6 comprises a third spiral sleeve body 61 respectively sleeved on the opposite flanges 11 and a cylindrical coupling body 62 (shown in fig. 3 and 4) connected between the opposite flanges in an abutting mode, and the cylindrical coupling body 62 is fixed on the opposite flanges 11 through the two third spiral sleeve bodies 61 respectively; the first spiral sleeve body 41, the second spiral sleeve body 51 and the third spiral sleeve body 61 are respectively provided with internal threads, and the outer sides of the two ends of the cylindrical coupling body 62 and the outer sides of the air inlet joint 42 and the air outlet joint 52 are respectively provided with external threads correspondingly connected with the internal threads; a through hole 621 for conducting the adjacent adsorption tube 1 is axially arranged in the cylindrical coupling body 62; the lateral wall of the cylindrical coupling body 62 is provided with a communicating hole 622 for communicating the through hole 621, the outer end of the communicating hole 622 is connected with a sampling valve 7 so as to take out gas conveniently, and the sampling valve 7 adopts a needle valve structure.
As shown in fig. 3, the first spiral sleeve 41, the second spiral sleeve 51 and the third spiral sleeve 61 are cylinders (i.e. the longitudinal section is n-shaped) with one open end, the inner diameter of the cylinder is the same as the diameter of the flange 11, the bottom of the cylinder is provided with a through hole 611, the diameter of the through hole 611 is larger than the diameter of the cylindrical tube of the adsorption tube 1; the through hole 611 is sleeved outside the adsorption tube 1, and the open end 612 of the cylinder faces to the flange 11 at the end of the adsorption tube and is sleeved on the flange 11; the inner wall of the cylinder body is provided with the internal thread; the diameters of the cylindrical coupling body 62, the air inlet connector 42 and the air outlet connector 52 are the same as the diameter of the flange 11; the screen 2 and the annular gasket 3 are arranged between the cylindrical coupling body 62, the air inlet joint 42 and the air outlet joint 52 and the corresponding end faces of the flange 11.
In the present embodiment, the adsorption tube 1, the cylindrical coupling body 62, the gas inlet joint 42, the gas outlet joint 52, the screen 2, the first spiral sleeve body 41, the second spiral sleeve body 51 and the third spiral sleeve body 61 are made of stainless steel materials, and can resist mercury corrosion and oil-water corrosion for a long time; the annular gasket 3 is made of polytetrafluoroethylene. The mercury removing agent 8 to be evaluated is in solid granular form. The length of the pipe body of each adsorption pipe 1 is 10 cm.
When the tower column structure for evaluating the performance of the natural gas mercury removing agent is used, the mercury removing agent 6 is filled in the adsorption tubes 1 which are connected in series, the mercury-containing natural gas is injected from the gas inlet 421 of the gas inlet joint 42 (the mercury content of the injected mercury-containing natural gas can be detected by an instrument), and when the natural gas passes through the adsorption tube, mercury in the natural gas is adsorbed by active substances (such as copper sulfide) in the mercury removing agent, after the natural gas passes through each section of adsorption tube 1, the mercury content of the mercury removing agent can be continuously reduced, the performance of the mercury removing agent can be researched by detecting the change of the mercury content of the natural gas at the outlet of the sampling valve 7 of each section of the adsorption pipe (the mercury content of the natural gas before the section of each section of the adsorption pipe and the mercury content of the natural gas after the section can be detected by an instrument, and the mercury removed by the mercury removing agent can be converted under the condition of known air inflow), so that the performance evaluation of the mercury removing agent is obtained.
According to the tower column structure for evaluating the performance of the natural gas mercury removal agent, the sampling is carried out at the through hole of the coupling body, so that the disturbance of air flow in the adsorption tube can be reduced, the sampling is representative, and the evaluation result is more reliable; the multi-section adsorption tube series connection structure has length adjustability, can detect the length of a mass transfer zone, can conveniently detect the demercuration depth and the mercury capacity of the demercuration agent, meets the requirements of natural gas demercuration agent evaluation, and can also meet the requirements of different experiments.
The mass transfer zone is a term of art for studying adsorbent or catalyst, and is called mass transfer zone, when the mercury-containing natural gas passes through the adsorption tube structure, not every section of adsorption tube can play a demercuration role, for example, the first section can completely adsorb mercury in the natural gas, so that the latter section of adsorption tube can not play a demercuration role any more, and the mass transfer zone or mass transfer zone refers to a section of adsorption tube which plays a demercuration role, and if the mercury-containing natural gas cannot be detected after the first section of adsorption tube, the mass transfer zone of the demercuration agent is short and should be shorter than the length of the first section of adsorption tube.
The demercuration depth refers to a detection value of the mercury content of the natural gas containing mercury after the natural gas passes through the demercuration agent with a certain thickness, if the detection value is higher, the demercuration capability of the demercuration agent is strong, and the demercuration depth is deep, otherwise, if the detection value of the mercury content of the natural gas after demercuration is higher, the demercuration capability of the demercuration agent is weak, and the demercuration depth is shallow.
The demercuration agent is free of mercury at the beginning of use, but during the use process, when natural gas containing mercury flows through the demercuration agent, the mercury in the natural gas is captured by active substances in the demercuration agent, the captured mercury remains on the demercuration agent, and after the demercuration agent is invalid, namely after the demercuration agent no longer has the demercuration capacity, the mercury content of the invalid demercuration agent is detected, and the value is the mercury capacity of the demercuration agent.
In the tower column structure for evaluating the performance of the natural gas mercury removing agent, two adjacent adsorption tubes 1 are connected through the coupling component 6, wherein the cylindrical coupling body 62 can axially rotate relative to the upper adsorption tube and the lower adsorption tube, so that the installation direction of the sampling valve on each cylindrical coupling body 62 can be adjusted to be towards the same direction of the tower column structure by adjusting the position of the cylindrical coupling body 62, and thus, the tower column structure can be conveniently connected with corresponding detection instruments or equipment, and an operator can conveniently observe a plurality of detection instruments.
Further, as shown in fig. 2, in the present embodiment, in order to more accurately position the mounting direction of the sampling valves, the sampling valves are oriented in the same direction of the column structure, and positioning pins 9 are provided between the cylindrical collar body 62 and the corresponding flange 11. One or two positioning pins 9 can be arranged between each flange 11 and the cylindrical coupling body 62; when the tower column structure is assembled, the cylindrical hoop connecting body 62 is positioned firstly, and then the cylindrical hoop connecting body 62 is fixed by the third spiral sleeve bodies 61 on the upper side and the lower side of the cylindrical hoop connecting body 62, so that the sampling valves connected to each cylindrical hoop connecting body 62 can be ensured to face the same direction of the tower column structure.
Compared with the evaluation tower column of the prior flue gas demercuration agent, the tower column structure for evaluating the performance of the natural gas demercuration agent has the following advantages.
(1) The tower column structure is formed by connecting a plurality of sections of adsorption tubes in series, and can simultaneously realize the evaluation of mercury capacity, mass transfer zone length and mercury removal depth of the mercury removal agent;
(2) the adjacent adsorption tubes are connected through a coupling component, and sampling at the cavity of the coupling component can reduce airflow disturbance inside the adsorption tubes, so that the sampling is representative, and the evaluation result is more reliable;
(3) the polytetrafluoroethylene annular gaskets are adopted for sealing and connecting, so that the air tightness of the connecting part can be ensured.
(4) The screen mesh in the tower column structure is used for fixing the mercury removing agent and is made of a stainless steel mesh, so that the resistance caused by the screen mesh can be reduced to the maximum extent.
(5) The unique coupling part design of this column structure can freely dismantle equipment single section adsorption tube, makes this column structure overall length freely adjustable, has satisfied the demand of different experiments.
(6) The installation direction of the sampling valve arranged below each adsorption tube can be adjusted to the same direction facing the tower column structure, and the tower column structure can be conveniently connected with corresponding detection equipment.
The above description is only an exemplary embodiment of the present invention, and is not intended to limit the scope of the present invention. Any equivalent changes and modifications that can be made by one skilled in the art without departing from the spirit and principles of the invention should fall within the protection scope of the invention.

Claims (6)

1. A tower column structure for evaluating performance of a natural gas demercuration agent is characterized by comprising a plurality of adsorption tubes which are connected in series in the vertical direction, wherein each adsorption tube is a cylindrical tube body with flanges at two ends, the cylindrical tube body is filled with the demercuration agent to be evaluated, pipe orifices at two ends of the cylindrical tube body are covered with a screen, the periphery of the screen is provided with an annular gasket, and the screen and the annular gasket are both arranged on the end face of the flange; the head end of the first adsorption pipe is provided with a first spiral sleeve body sleeved on a head end flange, and the end flange is provided with an air inlet joint and is fixedly connected with the first spiral sleeve body; the tail end of the last adsorption tube is provided with a second spiral sleeve body sleeved on a tail end flange, and the end flange is provided with an air outlet joint and is fixedly connected with the second spiral sleeve body; two adjacent adsorption tubes are connected through a coupling component; each coupling component comprises a third spiral sleeve body sleeved on the opposite flanges respectively and a cylindrical coupling body abutted between the opposite flanges, the cylindrical coupling body is fixed between the opposite flanges by the third spiral sleeve body, and the cylindrical coupling body and the upper and lower adsorption pipes connected with the cylindrical coupling body can be connected in a circumferential rotating manner; internal threads are respectively arranged in the first, second and third screw sleeves, and external threads which are correspondingly connected with the internal threads are respectively arranged on the outer sides of the two ends of the cylindrical coupling body and the outer sides of the air inlet joint and the air outlet joint; a through hole for conducting the adjacent adsorption tubes is axially arranged in the cylindrical coupling body; the side wall of the cylindrical joint hoop body is provided with a communicating hole communicated with the through hole, and the outer end of the communicating hole is connected with a sampling valve.
2. The tower structure for evaluating the performance of the natural gas mercury removing agent as claimed in claim 1, wherein the first, second and third spiral sleeves are cylinders with one open end, the inner diameter of the cylinder is the same as the diameter of the flange, the bottom surface of the cylinder is provided with a through hole, and the diameter of the through hole is larger than that of the cylindrical tube body of the adsorption tube; the through hole is sleeved outside the adsorption pipe, and the opening of the cylinder faces to the flange at the end part of the adsorption pipe and is sleeved on the flange; the inner wall of the cylinder body is provided with the internal thread; the diameters of the cylindrical coupling body, the air inlet joint and the air outlet joint are the same as the diameter of the flange; the cylindrical coupling body, the air inlet joint, the air outlet joint and the corresponding flange end faces are provided with the screen and the annular gasket in a clamping mode.
3. The tower structure for evaluating the performance of the natural gas mercury removing agent as claimed in claim 1, wherein the adsorption pipe, the cylindrical collar body, the gas inlet joint, the gas outlet joint, the screen mesh, the first, second and third spiral casings are made of stainless steel material; the annular gasket is made of polytetrafluoroethylene.
4. The column structure for natural gas demercuration agent performance evaluation according to claim 1, wherein the demercuration agent to be evaluated is in a granular form.
5. The column structure for evaluating the performance of the natural gas mercury removing agent as claimed in claim 1, wherein the length of the tube body of each adsorption tube is 10 cm.
6. The tower structure for evaluating the performance of the natural gas mercury removing agent as claimed in claim 1, wherein a positioning pin is arranged between the cylindrical collar body and the corresponding flange.
CN201810906789.5A 2018-08-10 2018-08-10 Tower column structure for evaluating performance of natural gas mercury removing agent Active CN109061063B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2814386Y (en) * 2005-08-17 2006-09-06 中国石油天然气股份有限公司 Flue gas sampling device
CN201384908Y (en) * 2008-12-30 2010-01-20 浙江工业大学 Smoke-gas mercury adsorption device
CN201940146U (en) * 2010-12-28 2011-08-24 中电投远达环保工程有限公司 Horizontal flue gas mercury removing device
CN102221540A (en) * 2010-04-15 2011-10-19 中国科学院城市环境研究所 Method and device for analyzing trace gaseous elemental mercury
CN202315635U (en) * 2011-09-23 2012-07-11 浙江勤策空分设备有限公司 Gas taking device in middle of adsorption tower of pressure swing adsorption gas device
CN204241433U (en) * 2014-12-19 2015-04-01 上海神开气体技术有限公司 A kind of device removing carbon dioxide in gas mixture
CN204625245U (en) * 2015-05-07 2015-09-09 中国科学院新疆理化技术研究所 A kind of device utilizing absorption method to remove Mercury in Wastewater
CN204973485U (en) * 2015-07-28 2016-01-20 上海立足生物科技有限公司 Carbon dioxide absorption tower device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2814386Y (en) * 2005-08-17 2006-09-06 中国石油天然气股份有限公司 Flue gas sampling device
CN201384908Y (en) * 2008-12-30 2010-01-20 浙江工业大学 Smoke-gas mercury adsorption device
CN102221540A (en) * 2010-04-15 2011-10-19 中国科学院城市环境研究所 Method and device for analyzing trace gaseous elemental mercury
CN201940146U (en) * 2010-12-28 2011-08-24 中电投远达环保工程有限公司 Horizontal flue gas mercury removing device
CN202315635U (en) * 2011-09-23 2012-07-11 浙江勤策空分设备有限公司 Gas taking device in middle of adsorption tower of pressure swing adsorption gas device
CN204241433U (en) * 2014-12-19 2015-04-01 上海神开气体技术有限公司 A kind of device removing carbon dioxide in gas mixture
CN204625245U (en) * 2015-05-07 2015-09-09 中国科学院新疆理化技术研究所 A kind of device utilizing absorption method to remove Mercury in Wastewater
CN204973485U (en) * 2015-07-28 2016-01-20 上海立足生物科技有限公司 Carbon dioxide absorption tower device

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