CN109056384A - A kind of silk man textile fabric fine chemical wastewater discharge printing method - Google Patents

A kind of silk man textile fabric fine chemical wastewater discharge printing method Download PDF

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Publication number
CN109056384A
CN109056384A CN201810863689.9A CN201810863689A CN109056384A CN 109056384 A CN109056384 A CN 109056384A CN 201810863689 A CN201810863689 A CN 201810863689A CN 109056384 A CN109056384 A CN 109056384A
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CN
China
Prior art keywords
parts
textile fabric
paste
discharge
mill base
Prior art date
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Pending
Application number
CN201810863689.9A
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Chinese (zh)
Inventor
史天英
张晓光
王成军
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Large Dyehouse Zibo Silk Group Co ltd
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Large Dyehouse Zibo Silk Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Large Dyehouse Zibo Silk Group Co ltd filed Critical Large Dyehouse Zibo Silk Group Co ltd
Priority to CN201810863689.9A priority Critical patent/CN109056384A/en
Publication of CN109056384A publication Critical patent/CN109056384A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65112Compounds containing aldehyde or ketone groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15Locally discharging the dyes
    • D06P5/155Locally discharging the dyes with reductants

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

A kind of silk man textile fabric fine chemical wastewater discharge printing method, belongs to silk dye transfer technical field.Discharge printing is carried out to silk man textile fabric using discharge mill base, it is characterised in that: the preparation step of the discharge mill base are as follows: 1) press the ingredient of 6 ~ 8:92 of mass ratio ~ 94 of acrylate copolymer thickener and water, and be uniformly mixed and former paste is made;2) it forms by weight: 20 ~ 40 parts of pigment printing paste, 4 ~ 6 parts of water, 20 ~ 40 parts of original paste, 20 ~ 30 parts of adhesive, 8 ~ 10 parts of sodium formaldehyde sulfoxylate, 0.7 ~ 1.4 part of ingredient of ammonium hydroxide, and it is uniformly mixed obtained discharge mill base.The flower pattern ratio printed by this technique is substantially improved with conventional direct printing flower pattern lines fine degree.

Description

A kind of silk man textile fabric fine chemical wastewater discharge printing method
Technical field
A kind of silk man textile fabric fine chemical wastewater discharge printing method, belongs to silk dye transfer technical field.
Background technique
In silk printing with reactive dye, direct printing printing effect of the big ground colour with fine lines flower pattern people not to the utmost always Meaning, main cause have:
1, fine chemical wastewater contour sharpness is difficult to ensure, the i.e. secondary color part of having a common boundary between dichromatism is easy to produce imbibition phenomenon, is caused Make lines overstriking soft edge, seriously affects flower pattern effect.
2, the big ground colour of PLATE SCREAM PRINTING connects version and often occurs connecing version print, i.e., the place that cuts marks between two editions is especially deep, causes product Quality problems.
So contaminating background color discharge printing when encountering such flower pattern, being optimal selection.When doing reactive dye discharge printing, need It selects to do background color intolerant to the reactive dye of reducing agent completely, and the dyestuff of very resistance to reducing agent is selected to do pattern.But with regard to mesh For preceding reactive dye, there are no a dyestuff can completely resistance to reducing agent and reach the requirement done color and pull out slurry.
Summary of the invention
The technical problem to be solved by the present invention is overcoming the deficiencies of the prior art and provide, a kind of resistance to reducing agent ability is strong, spends The high silk man textile fabric fine chemical wastewater discharge printing method of type fine degree.
The technical solution adopted by the present invention to solve the technical problems is: the silk man textile fabric fine chemical wastewater discharge printing Method carries out discharge printing to silk man textile fabric using discharge mill base, it is characterised in that: the preparation of the discharge mill base walks Suddenly are as follows:
1) ingredient of 6 ~ 8:92 of mass ratio ~ 94 of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;
2) it forms by weight: 20 ~ 40 parts of pigment printing paste, 4 ~ 6 parts of water, 20 ~ 40 parts of original paste, 20 ~ 30 parts of adhesive, sodium formaldehyde sulfoxylate 8 ~ 10 parts, 0.7 ~ 1.4 part of ingredient of ammonium hydroxide, and it is uniformly mixed obtained discharge mill base.
The thickener selected in this technique is a key point, and the resistance to reducing agent ability showed in discharge mill base is more other Thickener is eager to excel, and technique requirement is met.A certain amount of sodium formaldehyde sulfoxylate and ammonium hydroxide cooperation are added in technique of the invention, individually addition is hung Stamp slurry, which still has, after white piece significantly degrades, and after placing eight hours, slurry degradation cannot reach print Flower requires.A certain amount of concentrated ammonia liquor is added in inventor's slurry, adjusts slurry pH while cooperation with sodium formaldehyde sulfoxylate, greatly improves The stability of slurry, after tested, slurry palliating degradation degree is unobvious within 24 hours, reached stamp requirement.This technique makes stamp Fabric obtains the flower pattern of fine homogeneous beauty, from the point of view of appended stamp sample effect, is used by the flower pattern ratio that this technique is printed Conventional direct printing flower pattern lines fine degree substantially improves.
Acrylate copolymer thickener is the dispersion liquid of lightly crosslinked acrylate copolymer, it can be surface-active Agent system provides brilliant stability and thickening properties, and has brilliant suspension in low viscosity formulations, no Emulsification and stabilization can also be helped by dissolving and being difficult to stable ingredient such as siloxanes.Preferably, the acrylate copolymer increases Viscosity of thick dose of the solid content at 29% ~ 31%, 1% aqueous solution is 4 ~ 9 mPas, 3200 ~ 3800mPas of viscosity.It is preferred that Acrylate copolymer thickener parameter it is most strong to adaptability of the invention, the energy of resistance to reducing agent showed in discharge mill base Power reaches best.Acrylate copolymer thickener preferentially selects graceful weaving dyeization (China) Co., Ltd of Hensel raw in the present invention Produce the thickener for being put into model PT-RV.
Preferably, the mass ratio of acrylate copolymer thickener described in step 1) and water is 7:92.8 ~ 93.4.It is excellent Acrylate copolymer thickener in the former paste of choosing can be uniformly mixed, suffered by more reductions faster in discharge mill base The influence of reducing agent.
Preferably, parts by weight described in step 2 form are as follows: and 27 ~ 33 parts of pigment printing paste, 5 parts of water, 27 ~ 33 parts of original paste, 23 ~ 27 parts of adhesive, 8.5 ~ 9.5 parts of sodium formaldehyde sulfoxylate, 0.9 ~ 1.1 part of ammonium hydroxide.The parts by weight composition of preferred discharge mill base, Neng Gouda The effect best to stamp flower pattern lines fine degree.
Preferably, the mass ratio of pigment printing paste described in step 2 and adhesive is 1:0.82 ~ 0.85.The use of adhesive Amount suitably increases and decreases with the dosage height of pigment printing paste, and the mass-energy density of preferred pigment printing paste and adhesive better ensures that technique The influence of soda acid ability suffered by middle adhesive;Pigment printing paste used is the production of Zibo hongda auxiliary agent Co., Ltd, and adhesive is black The adhesive of the model HD-203A of rich hongda auxiliary agent Co., Ltd production.
It is selected that reducing agent dawn background color is done with sodium formaldehyde sulfoxylate, using the pigment printing paste of resistance to sodium formaldehyde sulfoxylate as flower pattern color, to pull out Dye transfer flower.Preferably, the mass ratio of sodium formaldehyde sulfoxylate described in step 2 and ammonium hydroxide is 8.5 ~ 9:0.9 ~ 1.1.The dosage of sodium formaldehyde sulfoxylate Depending on the dawn complexity of fabric ground colour.The mass ratio of preferred sodium formaldehyde sulfoxylate and ammonium hydroxide reaches the stability of slurry most It is good.
Compared with prior art, have possessed by a kind of silk man textile fabric fine chemical wastewater discharge printing method of the invention Beneficial effect is: the resistance to more other thickeners of reducing agent ability that the thickener selected in this technique shows in discharge mill base are eager to excel, Meet technique requirement.A certain amount of sodium formaldehyde sulfoxylate and ammonium hydroxide cooperation are added in technique of the invention, individually adds print after sodium formaldehyde sulfoxylate Flower slurry, which still has, significantly degrades, and after placing eight hours, slurry degradation cannot reach stamp requirement.Invention A certain amount of concentrated ammonia liquor is added in people's slurry, adjusts slurry pH while cooperation with sodium formaldehyde sulfoxylate, substantially increases the steady of slurry Qualitative, after tested, slurry palliating degradation degree is unobvious within 24 hours, has reached stamp requirement.This technique makes PRINTED FABRIC obtain essence Carefully uniform beautiful flower pattern, from the point of view of appended stamp sample effect, the flower pattern ratio printed by this technique is conventional directly to be printed Flower flower pattern lines fine degree substantially improves.
Specific embodiment
The present invention will be further described combined with specific embodiments below, and wherein embodiment 1 is best implements.
Specific printing technology is as follows:
By weight, former paste: PT-RV NEW * 7, water 93;
Discharge mill base: the red lotus 3 of G-16, water 5, original paste 58, adhesive 25,8 ammonium hydroxide 1 of sodium formaldehyde sulfoxylate;
1, the preparation of former paste.Thickener PT-RV NEW* and soft water are stirred into paste according to the ratio of 7:93.
2, the preparation of mill base.It weighs 3 grams of the red lotus of pigment printing paste G-16 in the balance, 5 grams of water is added and are ground to pigment printing paste Grainless, it is another that 58 grams of former pastes prepared are added, it stirs evenly.Next 25 grams of adhesive are added, is stirred evenly.It weighs 8 grams of sodium formaldehyde sulfoxylates are added in slurry, are evenly stirred until that sodium formaldehyde sulfoxylate all dissolves.It is eventually adding 1 gram of ammonium hydroxide and adjusts pH value.
3, flower pattern is printed.Take 250 mesh screen printings.
4, washing is evaporated.The sample produced is dried, is evaporated having in the FCL of bottom, it is desirable that temperature is steamed at 110 DEG C Changing the time is 10 minutes.It evaporates and finishes, cleaned 10 minutes in 95 DEG C or so water, to remove part loose colour and slurry.
Embodiment 1
The preparation step of the discharge mill base of discharge printing is carried out to silk man textile fabric using discharge mill base are as follows:
1) the mass ratio 7:93 ingredient of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;Acrylate Viscosity of the solid content of thickening agent of copolymer at 30%, 1% aqueous solution is 6 mPas, viscosity 3400mPas;
2) form by weight: 30 parts of pigment printing paste, 5 parts of water, 30 parts of original paste, 25 parts of adhesive, 9 parts of sodium formaldehyde sulfoxylate, 1 part of ammonium hydroxide is matched Material, and it is uniformly mixed obtained discharge mill base.
Embodiment 2
The preparation step of the discharge mill base of discharge printing is carried out to silk man textile fabric using discharge mill base are as follows:
1) the mass ratio 7:92.8 ingredient of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;Acrylic acid Viscosity of the solid content of ester copolymer thickener at 30%, 1% aqueous solution is 7 mPas, viscosity 3550mPas;
2) it forms by weight: 27 parts of pigment printing paste, 5 parts of water, 33 parts of original paste, 23 parts of adhesive, 8.5 parts of sodium formaldehyde sulfoxylate, ammonium hydroxide 1.1 Part ingredient, and it is uniformly mixed obtained discharge mill base.
Embodiment 3
The preparation step of the discharge mill base of discharge printing is carried out to silk man textile fabric using discharge mill base are as follows:
1) the mass ratio 7:93.4 ingredient of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;Acrylic acid Viscosity of the solid content of ester copolymer thickener at 31%, 1% aqueous solution is 8 mPas, viscosity 3710mPas;
2) it forms by weight: 33 parts of pigment printing paste, 5 parts of water, 27 parts of original paste, 27 parts of adhesive, 9.5 parts of sodium formaldehyde sulfoxylate, ammonium hydroxide 0.9 Part ingredient, and it is uniformly mixed obtained discharge mill base.
Embodiment 4
The preparation step of the discharge mill base of discharge printing is carried out to silk man textile fabric using discharge mill base are as follows:
1) the mass ratio 7.5:92.5 ingredient of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;Propylene Viscosity of the solid content of acid ester copolymer thickener at 29%, 1% aqueous solution is 5mPas, viscosity 3360mPas;
2) it forms by weight: 22 parts of pigment printing paste, 4.5 parts of water, 27 parts, 23 parts of adhesive, 9 parts of sodium formaldehyde sulfoxylate, 1 part of ammonium hydroxide of original paste Ingredient, and it is uniformly mixed obtained discharge mill base.
Embodiment 5
The preparation step of the discharge mill base of discharge printing is carried out to silk man textile fabric using discharge mill base are as follows:
1) the mass ratio 6:94 ingredient of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;Acrylate Viscosity of the solid content of thickening agent of copolymer at 29%, 1% aqueous solution is 4mPas, viscosity 3200mPas;
2) it forms by weight: 20 parts of pigment printing paste, 6 parts of water, 20 parts, 30 parts of adhesive, 8 parts of sodium formaldehyde sulfoxylate, 1.4 parts of ammonium hydroxide of original paste Ingredient, and it is uniformly mixed obtained discharge mill base.
Embodiment 6
The preparation step of the discharge mill base of discharge printing is carried out to silk man textile fabric using discharge mill base are as follows:
1) the mass ratio 8:92 ingredient of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;Acrylate Viscosity of the solid content of thickening agent of copolymer at 31%, 1% aqueous solution is 9 mPas, viscosity 3800mPas;
2) it forms by weight: 40 parts of pigment printing paste, 4 parts of water, 40 parts of original paste, 20 parts of adhesive, 10 parts of sodium formaldehyde sulfoxylate, ammonium hydroxide 0.7 Part ingredient, and it is uniformly mixed obtained discharge mill base.
The lines fine degree of the embodiment of the present invention is obviously greatly improved.The above, be only it is of the invention compared with Good embodiment is not that the invention has other forms of limitations, any person skilled in the art possibly also with The technology contents make modifications or to change or modify the equivalent equivalent Example of the disclosure above.But it is all without departing from skill of the present invention Art plan content, any simple modification to the above embodiments, equivalent variations and remodeling according to the technical essence of the invention, Still fall within the protection scope of technical solution of the present invention.

Claims (6)

1. a kind of silk man textile fabric fine chemical wastewater discharge printing method carries out discharge to silk man textile fabric using discharge mill base Stamp, it is characterised in that: the preparation step of the discharge mill base are as follows:
1) ingredient of 6 ~ 8:92 of mass ratio ~ 94 of acrylate copolymer thickener and water is pressed, and is uniformly mixed and former paste is made;
2) it forms by weight: 20 ~ 40 parts of pigment printing paste, 4 ~ 6 parts of water, 20 ~ 40 parts of original paste, 20 ~ 30 parts of adhesive, sodium formaldehyde sulfoxylate 8 ~ 10 parts, 0.7 ~ 1.4 part of ingredient of ammonium hydroxide, and it is uniformly mixed obtained discharge mill base.
2. a kind of silk man textile fabric fine chemical wastewater discharge printing method according to claim 1, it is characterised in that: described Viscosity of the solid content at 29% ~ 31%, 1% aqueous solution of acrylate copolymer thickener be 4 ~ 9 mPas, viscosity 3200~3800mPa·s。
3. a kind of silk man textile fabric fine chemical wastewater discharge printing method according to claim 1, it is characterised in that: step 1) mass ratio of acrylate copolymer thickener and water described in is 7:92.8 ~ 93.4.
4. a kind of silk man textile fabric fine chemical wastewater discharge printing method according to claim 1, it is characterised in that: step 2) the parts by weight composition described in are as follows: 27 ~ 33 parts of pigment printing paste, 5 parts of water, 27 ~ 33 parts of original paste, 23 ~ 27 parts of adhesive, sodium formaldehyde sulfoxylate 8.5 ~ 9.5 parts, 0.9 ~ 1.1 part of ammonium hydroxide.
5. a kind of silk man textile fabric fine chemical wastewater discharge printing method according to claim 1, it is characterised in that: step 2) mass ratio of pigment printing paste and adhesive described in is 1:0.82 ~ 0.85.
6. a kind of silk man textile fabric fine chemical wastewater discharge printing method according to claim 1, it is characterised in that: step 2) mass ratio of sodium formaldehyde sulfoxylate and ammonium hydroxide described in is 8.5 ~ 9:0.9 ~ 1.1.
CN201810863689.9A 2018-08-01 2018-08-01 A kind of silk man textile fabric fine chemical wastewater discharge printing method Pending CN109056384A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201810863689.9A CN109056384A (en) 2018-08-01 2018-08-01 A kind of silk man textile fabric fine chemical wastewater discharge printing method

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Publication Number Publication Date
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103790042A (en) * 2014-02-13 2014-05-14 浙江理工大学 Comfort pigment printing method of textile
RU2014114257A (en) * 2014-04-10 2015-10-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет технологии и дизайна" (СПГУТД) METHOD FOR ERADING PRINTING ON SMOOTH-DYED FABRICS USING INTERFERENCE PIGMENTS
CN105586788A (en) * 2014-10-20 2016-05-18 无锡弘奋机械厂 Environmental-protective cotton cloth printing and dyeing technology
CN105862461A (en) * 2016-04-19 2016-08-17 浙江富润印染有限公司 Printing and dyeing technology for dual-mercerized cotton with colorful discharge printing effect

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103790042A (en) * 2014-02-13 2014-05-14 浙江理工大学 Comfort pigment printing method of textile
RU2014114257A (en) * 2014-04-10 2015-10-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет технологии и дизайна" (СПГУТД) METHOD FOR ERADING PRINTING ON SMOOTH-DYED FABRICS USING INTERFERENCE PIGMENTS
CN105586788A (en) * 2014-10-20 2016-05-18 无锡弘奋机械厂 Environmental-protective cotton cloth printing and dyeing technology
CN105862461A (en) * 2016-04-19 2016-08-17 浙江富润印染有限公司 Printing and dyeing technology for dual-mercerized cotton with colorful discharge printing effect

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郭文登等: ""真丝绸高色牢度染料和涂料复合印花工艺研究"", 《丝绸》 *
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