CN109054540A - A kind of preparation method of infrared absorbing material and the coating that can be used for infrared stealth - Google Patents
A kind of preparation method of infrared absorbing material and the coating that can be used for infrared stealth Download PDFInfo
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- CN109054540A CN109054540A CN201810845267.9A CN201810845267A CN109054540A CN 109054540 A CN109054540 A CN 109054540A CN 201810845267 A CN201810845267 A CN 201810845267A CN 109054540 A CN109054540 A CN 109054540A
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- infrared
- absorbing material
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- infrared absorbing
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- 239000011358 absorbing material Substances 0.000 title claims abstract description 64
- 239000011248 coating agent Substances 0.000 title claims abstract description 54
- 238000000576 coating method Methods 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 51
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000002270 dispersing agent Substances 0.000 claims abstract description 35
- 238000001354 calcination Methods 0.000 claims abstract description 30
- 239000007864 aqueous solution Substances 0.000 claims abstract description 24
- 239000004471 Glycine Substances 0.000 claims abstract description 22
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 21
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012153 distilled water Substances 0.000 claims abstract description 19
- NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000003837 high-temperature calcination Methods 0.000 claims abstract description 18
- 239000003973 paint Substances 0.000 claims abstract description 17
- 238000004321 preservation Methods 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 230000001376 precipitating effect Effects 0.000 claims abstract description 8
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 28
- 229920000178 Acrylic resin Polymers 0.000 claims description 28
- 239000000919 ceramic Substances 0.000 claims description 28
- 239000006185 dispersion Substances 0.000 claims description 28
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 28
- 239000011325 microbead Substances 0.000 claims description 28
- 229920005749 polyurethane resin Polymers 0.000 claims description 27
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 14
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 14
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 14
- 238000005507 spraying Methods 0.000 claims description 14
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- NUMGUHMPKNCRJA-UHFFFAOYSA-N nitric acid;samarium Chemical compound [Sm].O[N+]([O-])=O NUMGUHMPKNCRJA-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- -1 samarium ion Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of preparation method of infrared absorbing material and can be used for the coating of infrared stealth, it is related to infrared absorbing material field, specifically the preparation method comprises the following steps: by samaric nitrate, glycine is added in container, add distilled water and dispersing agent, after ultrasonic disperse 40-60min, add yttrium nitrate aqueous solution, continue ultrasonic disperse 40-60min, precipitating reagent is added dropwise in 60-70 DEG C of water-bath heat preservation dropwise, it is retransferred after reaction 4-8h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1000-1050 DEG C, it takes out and is ground after calcining, cross 800 meshes, it can be very good to absorb human body or the extraneous infrared ray emitted；And infrared absorbing material of the present invention is evenly distributed in infrared stealth coating, and paint adhesion is good, and infrared emittance is low, and every mechanical performance reaches requirement, has broad application prospects.
Description
Technical field
The present invention relates to infrared absorbing material fields, and in particular to the preparation method of a kind of infrared absorbing material and can
Coating for infrared stealth.
Background technique
The laws such as the refraction for following visible light, reflection, absorption and scattering are propagated in infrared radiation in an atmosphere, have light
General physical characteristic, its transmission capacity in an atmosphere is related with the content of water in atmosphere and carbon dioxide.
When object launches outward infra-red radiation, water and carbon dioxide in atmosphere will absorb the radiation of certain wave band, and make
The infrared radiation signal of this wave band is decayed.Non-absorbent wave band passes through atmosphere undampedly, and such wave band is referred to as atmosphere
Window.
Infrared atmospheric window mouth is divided into 4, be respectively near-infrared (0.76~3 μm), in infrared (3~5 μm), far infrared (8~
14 μm) and super far infrared (15~1000 μm), atmospheric window relative transparent in first three wave band, super far infrared band is substantially not
Transparent, the service band of infrared detector is mainly for first three atmospheric window, therefore the exploitation of infrared stealth coating is also answered
It is carried out for these three atmospheric windows.
Infrared stealth coating is mysterious a member of coating family.It is not " stealthy " in science fiction works, but military
Term middle finger controls the observability of target or controls the combination of the skill and technology of target signature signal.
Because the reason of according to statistics, aircraft loses 80-90% in air battle is since aircraft is observed.Reduce platform features letter
Number, the probability of detected identification, tracking is just reduced, thus survival ability can be improved, reduce platform features signal not only
It is to tackle radar detection, further includes reducing a possibility that being found by other detection devices.
About the development of infrared stealth coating, there are reports both at home and abroad.The sheet that diameter is 70 μm by American scholar
Aluminium is doped in inorganic phosphate adhesive, obtains a kind of stealthy paint of low-launch-rate heat, which emits in 10.6 μm of spectrum regions
Rate is only 0.18.
The hot invisible coating of Du Fei-Di Tanning company of Britain production almost adapts to any desired infrared reflectivity.
A kind of semiconductor has been invented by certain German company, can carry out effective multispectral camouflage, has low hair in infrared band
Rate is penetrated, there is high-absorbility in high frequency band.
The country developed with infrared stealth coating being developed can be divided by ingredient it is following several: powder resin type control
Warm coating, metal powder resin type infrared stealth coating, low transmitting multi-layer film type inorganic, metal oxide class infrared stealth coating,
Metal ultra-fine powder material and use metal oxide as coating type Infrared stealthy materials of resin additive etc..
The infrared stealth coating studied at present is mostly solvent type, but solvent based coating inconvenient, seriously polluted, water
Property coating necessarily following development trend.The country rarely has the report to aqueous infrared stealth coating material.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of preparation method of infrared absorbing material and can be used for red
Outer stealthy coating.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of preparation method of infrared absorbing material, the preparation method comprises the following steps: samaric nitrate, glycine are added in container,
Distilled water and dispersing agent are added, yttrium nitrate aqueous solution is added in ultrasonic disperse, and after continuing ultrasonic disperse for a period of time, water-bath is protected
Precipitating reagent is added dropwise in temperature, retransfers after reaction and carries out high-temperature calcination in Muffle furnace, is ground after taking-up, is sieved.
Further, samaric nitrate, glycine are added in container, add distilled water and dispersing agent, ultrasonic disperse 40-
After 60min, yttrium nitrate aqueous solution is added, continues ultrasonic disperse 40-60min, precipitating is added dropwise in 60-70 DEG C of water-bath heat preservation dropwise
Agent retransfers after reacting 4-8h and carries out high-temperature calcination in Muffle furnace, and calcination temperature is 1000-1050 DEG C, takes after calcining
It is ground out, crosses 800 meshes.
Further, the samaric nitrate, glycine molar ratio be 5:3.
Further, the mass ratio of samaric nitrate, the gross mass of glycine and distilled water is 1:15-30.
Further, the dispersing agent can be in SRE-4010-100, YF-02, P-105, AKM-0531, OP-83RAT
Any one.
Further, the mass concentration of the yttrium nitrate aqueous solution is 25-40%.
Further, the aqueous solution of urea that the precipitating reagent is concentrated ammonia liquor or mass concentration is 32.5%.
A kind of coating can be used for infrared stealth, including it is above-mentioned infrared absorbing material, water-based acrylic resin, aqueous poly-
Urethane resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose.
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 150-
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after 200r/min dispersion 15min, with 400-500r/min's
Revolving speed disperses 30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
(3) beneficial effect
The present invention provides a kind of preparation method of infrared absorbing material and can be used for the coating of infrared stealth, have with
It is lower the utility model has the advantages that
Existing research shows Sm before2O3As a kind of rare earth oxide, due to wherein Sm3+Special band structure, this
Body just has and has strong absorption characteristic in far infrared wave strong point, and yttrium nitrate reacts to obtain alkali formula nitric acid with precipitating reagent in the present invention
Yttrium, samaric nitrate is oxidant, glycine is reducing agent, and the two reaction product is decomposed under the conditions of high-temperature calcination, and Y can be obtained and mix
Miscellaneous Sm2O3, it may be possible to due to Y3+Radius (0.089nm) be less than Sm3+(0.0958nm), so Y3+Being doped into has cation
The Sm of defect2O3In structure, the conversion rates of samarium ion and oxonium ion can be suppressed, so that absorption infrared absorption frequency band is broadened, Xiang Jinhong
The migration of external wave strong point, the infrared stealth coating made by infrared absorbing material of the present invention are steadily inhaled in 800nm-2500nm
It receives, peak value can be very good the infrared ray for absorbing human body or extraneous transmitting in 1550nm；And infrared absorbing material of the present invention
It being evenly distributed in infrared stealth coating, paint adhesion is good, and infrared emittance is low, and every mechanical performance reaches requirement,
It has broad application prospects.
Detailed description of the invention
Fig. 1 is the SEM photograph of 1 coating of the embodiment of the present invention, and infrared absorbing material is infrared hidden as we can see from the figure
It is evenly distributed in body coating, the two compatibility is good.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of creative work.
Embodiment 1:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 400ml and SRE-4010-100 2g is added, after ultrasonic disperse 45min, adding mass concentration is
30% yttrium nitrate aqueous solution 20ml, continues ultrasonic disperse 50min, and concentrated ammonia liquor 10ml, reaction is added dropwise in 65 DEG C of water-bath heat preservations dropwise
It being retransferred after 6h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1000 DEG C, it takes out and is ground after calcining, mistake
800 meshes, can be obtained infrared absorbing material.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 200r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 450r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 2:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 600ml and YF-02 2g is added, after ultrasonic disperse 40min, add the nitric acid that mass concentration is 35%
Yttrium aqueous solution 20ml continues ultrasonic disperse 50min, and 32.5% aqueous solution of urea 15ml is added dropwise in 70 DEG C of water-bath heat preservations dropwise, instead
It answers to retransfer after 5h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1050 DEG C, it takes out and is ground after calcining, mistake
800 meshes, can be obtained infrared absorbing material.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 160r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 500r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 3:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 400ml and P-105 2g is added, after ultrasonic disperse 60min, add the nitric acid that mass concentration is 40%
Yttrium aqueous solution 20ml, continues ultrasonic disperse 60min, and concentrated ammonia liquor 15ml is added dropwise dropwise, retransfers after reacting 8h for 60 DEG C of water-bath heat preservations
Enter and carry out high-temperature calcination in Muffle furnace, calcination temperature is 1030 DEG C, takes out and is ground after calcining, crosses 800 meshes
Obtain infrared absorbing material.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 160r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 400r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 4:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 300ml and AKM-0531 2g is added, after ultrasonic disperse 40min, adding mass concentration is 25%
Yttrium nitrate aqueous solution 20ml continues ultrasonic disperse 40min, and 60 DEG C of water-baths keep the temperature and concentrated ammonia liquor 20ml is added dropwise dropwise, after reaction 4h again
It being transferred in Muffle furnace and carries out high-temperature calcination, calcination temperature is 1000 DEG C, takes out and is ground after calcining, 800 meshes are crossed,
Infrared absorbing material can be obtained.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose.
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 150r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 400r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 5:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 600ml and OP-83RAT 2g is added, after ultrasonic disperse 60min, adding mass concentration is 40%
Yttrium nitrate aqueous solution 20ml, continues ultrasonic disperse 60min, and 32.5% aqueous solution of urea is added dropwise in 70 DEG C of water-bath heat preservations dropwise
It is retransferred after 15ml, reaction 8h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1050 DEG C, takes out and carries out after calcining
800 meshes are crossed in grinding.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 200r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 500r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 6:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 350ml and SRE-4010-100 2g is added, after ultrasonic disperse 55min, adding mass concentration is
35% yttrium nitrate aqueous solution 20ml, continues ultrasonic disperse 60min, and concentrated ammonia liquor 20ml, reaction is added dropwise in 65 DEG C of water-bath heat preservations dropwise
It being retransferred after 8h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1000 DEG C, it takes out and is ground after calcining, mistake
800 meshes.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 180r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 500r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 7:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 500ml and OP-83RAT 2.5g is added, after ultrasonic disperse 55min, adding mass concentration is 40%
Yttrium nitrate aqueous solution, continue ultrasonic disperse 50min, concentrated ammonia liquor 20ml is added dropwise dropwise, turns again after reacting 8h for 65 DEG C of water-baths heat preservation
It moves into Muffle furnace and carries out high-temperature calcination, calcination temperature is 1000 DEG C, takes out and is ground after calcining, crosses 800 meshes.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 180r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 500r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 8:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 400ml and SRE-4010-100 2g is added, after ultrasonic disperse 60min, adding mass concentration is
33% yttrium nitrate aqueous solution 20ml continues ultrasonic disperse 60min, and it is 32.5% that mass concentration, which is added dropwise, in 65 DEG C of water-bath heat preservations dropwise
Aqueous solution of urea 20ml, retransfer after reacting 5h and carry out high-temperature calcination in Muffle furnace, calcination temperature is 1020 DEG C, calcining knot
It takes out and is ground after beam, cross 800 meshes.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 170r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 430r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 9:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 300ml and SRE-4010-100 2g is added, after ultrasonic disperse 60min, adding mass concentration is
38% yttrium nitrate aqueous solution 20ml, continues ultrasonic disperse 40min, and concentrated ammonia liquor 20ml, reaction is added dropwise in 70 DEG C of water-bath heat preservations dropwise
It being retransferred after 6.5h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1000 DEG C, it takes out and is ground after calcining, mistake
800 meshes.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 180r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 430r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 10:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 600ml and AKM-0531 2g is added, after ultrasonic disperse 60min, adding mass concentration is 30%
Yttrium nitrate aqueous solution 20ml, continues ultrasonic disperse 60min, and the urea that mass concentration is 32.5% is added dropwise in 68 DEG C of water-bath heat preservations dropwise
It is retransferred after aqueous solution 20ml, reaction 4.5h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1040 DEG C, after calcining
Taking-up is ground, and 800 meshes are crossed.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose.
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 200r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 500r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 11:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 400ml and SRE-4010-100 2g is added, after ultrasonic disperse 60min, adding mass concentration is
40% yttrium nitrate aqueous solution 20ml, continues ultrasonic disperse 40min, and concentrated ammonia liquor 20ml, reaction is added dropwise in 70 DEG C of water-bath heat preservations dropwise
It being retransferred after 4h and carries out high-temperature calcination in Muffle furnace, calcination temperature is 1050 DEG C, it takes out and is ground after calcining, mistake
800 meshes.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose；
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 200r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 440r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Embodiment 12:
A kind of preparation method of infrared absorbing material, specifically: samaric nitrate 16.82g, glycine 2.25g are added to
In container, distilled water 400ml and YF-02 2g is added, after ultrasonic disperse 50min, adding mass concentration is 25-40%'s
Yttrium nitrate aqueous solution, continues ultrasonic disperse 50min, and concentrated ammonia liquor 20ml is added dropwise dropwise, turns again after reacting 7.5h for 65 DEG C of water-bath heat preservations
It moves into Muffle furnace and carries out high-temperature calcination, calcination temperature is 1000 DEG C, takes out and is ground after calcining, crosses 800 meshes.
A kind of coating can be used for infrared stealth, including infrared absorbing material, water-based acrylic resin, aqueous polyurethane
Resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose.
Preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 200r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, is dispersed with the revolving speed of 450r/min
30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
The coating of made infrared stealth, in 800nm-2500nm smooth absorption, peak value is in 1550nm.
Performance evaluation:
The infrared energy total amount that usually an object releases is proportional to its temperature.One relatively small temperature
Variation usually can bring the variation of a relatively large infrared energy.
Infrared energy is generated by the vibration of atom and molecule, and when object temperature is lower, these vibrations are opposite
Relatively slow, the infrared of release can be also relatively small.When object temperature increases, infrared energy that the frequency of vibration increases and releases
Total amount is consequently increased, and the wavelength of the energy of the frequency and generation of vibration has relationship.Frequency is higher, and wavelength is shorter.Generally for
For most of materials, the frequency and wavelength for the wave that infrared energy issues be not fixed, curved distribution, in a model
Enclose interior fluctuation.On any specific wavelength, the infrared of sending can all increase as the temperature increases.
Infrared thermal imager is a kind of sensor that can detect pole small temperature difference, and the temperature difference is converted into real time video image
It shows.But can only see the hot outline of people and object, the true colors of object are not seen, as long as can control infrared emission
Rate just can be reduced the risk being exposed under infrared thermal imager, achieve the purpose that infrared stealth, and the following table 1 is the embodiment of the present invention
The coating of infrared stealth prepared by 1-5 brushes the infrared emittance contrast table on different substrate materials respectively.
Table 1:
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features；And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (10)
1. a kind of preparation method of infrared absorbing material, which is characterized in that the preparation method comprises the following steps: samaric nitrate, glycine are added
Into container, distilled water and dispersing agent are added, yttrium nitrate aqueous solution is added in ultrasonic disperse, continues ultrasonic disperse for a period of time
Afterwards, precipitating reagent is added dropwise in water-bath heat preservation, retransfers after reaction and carries out high-temperature calcination in Muffle furnace, is ground after taking-up, is sieved.
2. the preparation method of infrared absorbing material as described in claim 1, which is characterized in that the preparation method comprises the following steps: by nitric acid
Samarium, glycine are added in container, add distilled water and dispersing agent, after ultrasonic disperse 40-60min, add yttrium nitrate water
Solution, continues ultrasonic disperse 40-60min, and precipitating reagent is added dropwise dropwise, retransfers after reacting 4-8h into horse for 60-70 DEG C of water-bath heat preservation
High-temperature calcination is not carried out in furnace, calcination temperature is 1000-1050 DEG C, takes out and is ground after calcining, crosses 800 meshes.
3. the preparation method of infrared absorbing material as described in claim 1, which is characterized in that the samaric nitrate, glycine
Molar ratio be 5:3.
4. the preparation method of infrared absorbing material as described in claim 1, which is characterized in that samaric nitrate, glycine it is total
The mass ratio of quality and distilled water is 1:15-30.
5. the preparation method of infrared absorbing material as described in claim 1, which is characterized in that the dispersing agent can be
Any one in SRE-4010-100, YF-02, P-105, AKM-0531, OP-83RAT.
6. the preparation method of infrared absorbing material as described in claim 1, which is characterized in that the yttrium nitrate aqueous solution
Mass concentration is 25-40%.
7. the preparation method of infrared absorbing material as described in claim 1, which is characterized in that the precipitating reagent is concentrated ammonia liquor
Or the aqueous solution of urea that mass concentration is 32.5%.
8. a kind of coating that can be used for infrared stealth, which is characterized in that including such as of any of claims 1-7 red
Outside line absorbing material.
9. can be used for the coating of infrared stealth as claimed in claim 8, which is characterized in that further include water-based acrylic resin,
Waterborne polyurethane resin, nano-hollow ceramic microbead, dispersing agent 3218, NP-10, hydroxypropyl methyl cellulose.
10. can be used for the coating of infrared stealth as claimed in claim 9, which is characterized in that preparation method the following steps are included:
(1) water-based acrylic resin, waterborne polyurethane resin, infrared absorbing material are added in dispersion tank, 150-200r/
Nano-hollow ceramic microbead, dispersing agent 3218 and NP-10 are added after min dispersion 15min, with the revolving speed of 400-500r/min point
Dissipate 30min；
(2) hydroxypropyl methyl cellulose is added, paint viscosity is made to reach the requirement of spraying.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109911934A (en) * | 2019-04-08 | 2019-06-21 | 湖北展朋新材料股份有限公司 | A kind of rutile titanium dioxide of large specific surface area and preparation method thereof |
| CN109911926A (en) * | 2019-04-08 | 2019-06-21 | 湖北展朋新材料股份有限公司 | A kind of nanoscale strontium carbonate of uniform particle sizes and preparation method thereof |
| CN114623728A (en) * | 2022-03-22 | 2022-06-14 | 湖南中泰特种装备有限责任公司 | Preparation method of bulletproof plate with infrared stealth function and bulletproof plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925050A (en) * | 2012-11-15 | 2013-02-13 | 安徽理工大学 | Method for preparing water-based infrared-laser composite stealthy coating |
| JP2013087151A (en) * | 2011-10-14 | 2013-05-13 | Asahi Glass Co Ltd | Infrared absorption particle and manufacturing method therefor |
| CN103614058A (en) * | 2013-11-13 | 2014-03-05 | 东华大学 | Infrared camouflage paint as well as preparation method and application thereof |
-
2018
- 2018-07-27 CN CN201810845267.9A patent/CN109054540B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013087151A (en) * | 2011-10-14 | 2013-05-13 | Asahi Glass Co Ltd | Infrared absorption particle and manufacturing method therefor |
| CN102925050A (en) * | 2012-11-15 | 2013-02-13 | 安徽理工大学 | Method for preparing water-based infrared-laser composite stealthy coating |
| CN103614058A (en) * | 2013-11-13 | 2014-03-05 | 东华大学 | Infrared camouflage paint as well as preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| WENYAN ZHANG等: "Preparation and characterization of Sm2O3/Cu mosaic structure with infrared absorptive properties and low infrared emissivity", 《MATERIALS LETTERS》 * |
| 刘宗怀等: "硝酸稀土甘氨酸固体配合物的红外光谱研究", 《宝鸡文理学院学报（自然科学版）》 * |
| 朱文庆等: "均匀沉淀水热法微/纳米Sm2O3的合成与表征", 《人工晶体学报》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109911934A (en) * | 2019-04-08 | 2019-06-21 | 湖北展朋新材料股份有限公司 | A kind of rutile titanium dioxide of large specific surface area and preparation method thereof |
| CN109911926A (en) * | 2019-04-08 | 2019-06-21 | 湖北展朋新材料股份有限公司 | A kind of nanoscale strontium carbonate of uniform particle sizes and preparation method thereof |
| CN114623728A (en) * | 2022-03-22 | 2022-06-14 | 湖南中泰特种装备有限责任公司 | Preparation method of bulletproof plate with infrared stealth function and bulletproof plate |
| CN114623728B (en) * | 2022-03-22 | 2024-03-26 | 湖南中泰特种装备有限责任公司 | Preparation method of bulletproof plate with infrared stealth function and bulletproof plate |
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