CN109053089A - A kind of Antique Imitation Tiles and preparation method thereof using cinder preparation - Google Patents
A kind of Antique Imitation Tiles and preparation method thereof using cinder preparation Download PDFInfo
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- CN109053089A CN109053089A CN201811174322.2A CN201811174322A CN109053089A CN 109053089 A CN109053089 A CN 109053089A CN 201811174322 A CN201811174322 A CN 201811174322A CN 109053089 A CN109053089 A CN 109053089A
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- Prior art keywords
- cinder
- antique imitation
- imitation tiles
- granularity
- preparation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention discloses a kind of Antique Imitation Tiles and preparation method thereof using cinder preparation, belong to ancient building recovery technology field, it is to be composed of the following weight percentages of raw materials: cinder 45%~53%, Extra-fine sand 1~5%, bunt gypsum 5%~10%, white cement 10%~15%, water 25%~32%, iron oxide black 1~2%, oxalic acid 1.0~1.5%, tertiary sodium phosphate 0.5%~1.0%, methyl sodium nitrate 0.4%~0.6%；There is good compression strength and frost resistance using Antique Imitation Tiles prepared by the present invention, and brick body color is cinerous, color is more life-like.
Description
Technical field
The present invention relates to ancient building recovery technology field, in particular to a kind of Antique Imitation Tiles and its preparation using cinder preparation
Method.
Background technique
Cinder, one kind of industrial solid wastes, thermal power plant, industry and civil boiler and the discharge of other equipment fire coal
Waste residue, also known as clinker.Main component is silica, aluminium oxide, iron oxide, calcium oxide, magnesia etc..Not according to ingredient
Together, can be used for manufacturing cement, brick and refractory material etc..Some can be used for producing aluminium oxide or refine the rare metals such as gallium, germanium.18
It begins in century manufacture tabia using cinder, as construction material.Since 20th century, countries in the world are all carrying out the comprehensive of cinder
It closes and utilizes, the states such as Japan, Denmark cinder is all utilized, and cinder is mainly used for production construction material.
Currently, the construction of the characteristic small town town He Gu old countries is being carried out in domestic many places, need a large amount of caesious imitative
Ancient city wall brick, country forbid to fire clay brick again, this provides good Policy Background and huge for the resource utilization of cinder
Social demand.
Summary of the invention
The present invention provides a kind of Antique Imitation Tiles and preparation method thereof using cinder preparation, and preparation method is simple for this,
It is at low cost, energy conservation and environmental protection, use easy to spread.
The technical solution of the present invention is as follows:
A kind of Antique Imitation Tiles prepared using cinder, are to be composed of the following weight percentages of raw materials: cinder 45%~53%,
Extra-fine sand 1%~5%, bunt gypsum 5%~10%, white cement 10%~15%, water 25%~32%, iron oxide black 1%~2%, grass
Acid 1.0%~1.5%, tertiary sodium phosphate 0.5%~1.0%, methyl sodium nitrate 0.4%~0.6%；The cinder is coal enterprise burning
Cinder after coal is sieved into the coal slag granules that granularity is 0.1~0.5cm, 0.5~1.0cm after crushing.
Wherein it is preferred to which the fineness of the bunt gypsum is 200 mesh.
Wherein it is preferred to which the fineness of the white cement is 200 mesh.
Wherein it is preferred to which the Extra-fine sand is the river drift of Lower Reaches of The Yellow River.
A method of Antique Imitation Tiles being prepared using cinder, are included the following steps:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, it is molten to obtain mixture
Liquid；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, high-speed stirred 1~
2min obtains muddy mixture；
(5) hydraulic brick making machine molding is fed the mixture into, briquetting pressure is 5~30MPa, and setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
Wherein it is preferred to the weight for the cinder that the cinder of the 0.5~1.0cm of granularity and the granularity are 0.1~0.5cm
Amount is than being 1:1.5~2.
Beneficial effects of the present invention:
1. present invention adds oxalic acid, tertiary sodium phosphate and methyl sodium nitrate, methyl sodium nitrate is broken down into methyl in water
Silicic acid generates the methyl silicon with waterproof performance not soluble in water, same with oxalic acid, tertiary sodium phosphate synergistic effect, promotes cement
Grain mutually dispersion, flocculent structure are destroyed, and are released by wrapping portion water, flowing are participated in, to effectively increase concrete mixing
The mobility of object.And is conducive to the excitation to cinder, cement, improves the early strength of Antique Imitation Tiles, reduce certain ions to imitative
Ancient brick intensity bring influences.
2. there is good compression strength and frost resistance using the Antique Imitation Tiles of the method for the present invention preparation, and brick body color is blueness
Grey, color are more life-like.
3 city-wall brick compression mouldings of the invention avoid complex production process in sintering process, energy consumption height, easily produce largely
The problem of carbon dioxide isothermal chamber gas.
Specific embodiment
Below in conjunction with the specific embodiment of the invention, technical solution of the present invention is clearly and completely described, is shown
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
In following embodiments, for the fineness of the bunt gypsum used for 200 mesh, the fineness of white cement is 200 mesh.The powder of use is thin
Sand is the river drift of Lower Reaches of The Yellow River.
Embodiment 1
The present embodiment provides a kind of Antique Imitation Tiles prepared using cinder, are to be composed of the following weight percentages of raw materials: coal
Slag 57.5%, Extra-fine sand 3%, bunt gypsum 7%, white cement 12%, water 26.5%, iron oxide black 1.5%, oxalic acid 1.2%, tertiary sodium phosphate
0.8%, methyl sodium nitrate 0.5%；The cinder be coal enterprise burn coal after cinder, be sieved into after crushing granularity be 0.1~
The coal slag granules of 0.5cm, 0.5~1.0cm, the weight ratio of the two are 1:1.8.
The method that the present embodiment prepares Antique Imitation Tiles using cinder, includes the following steps:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, it is molten to obtain mixture
Liquid；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, high-speed stirred 1~
2min obtains muddy mixture；
(5) hydraulic brick making machine molding, briquetting pressure 20MPa are fed the mixture into, setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
Embodiment 2
The present embodiment provides a kind of Antique Imitation Tiles prepared using cinder, are to be composed of the following weight percentages of raw materials: coal
Slag 45%, Extra-fine sand 5%, bunt gypsum 5%, white cement 115%, water 26.4%, iron oxide black 1%, oxalic acid 1.5%, tertiary sodium phosphate
0.5%, methyl sodium nitrate 0.6%；The cinder be coal enterprise burn coal after cinder, be sieved into after crushing granularity be 0.1~
The coal slag granules of 0.5cm, 0.5~1.0cm, the weight ratio of the two are 1:1.5.
The method that the present embodiment prepares Antique Imitation Tiles using cinder, includes the following steps:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, it is molten to obtain mixture
Liquid；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, high-speed stirred 1~
2min obtains muddy mixture；
(5) hydraulic brick making machine molding, briquetting pressure 5MPa are fed the mixture into, setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
Embodiment 3
The present embodiment provides a kind of Antique Imitation Tiles prepared using cinder, are to be composed of the following weight percentages of raw materials: coal
Slag 53%, Extra-fine sand 1%, bunt gypsum 7.1%, white cement 10%, water 25%, iron oxide black 1.5%, oxalic acid 1.0%, tertiary sodium phosphate
1.0%, methyl sodium nitrate 0.4%；The cinder be coal enterprise burn coal after cinder, be sieved into after crushing granularity be 0.1~
The coal slag granules of 0.5cm, 0.5~1.0cm, the weight ratio of the two are 1:2.
The method that the present embodiment prepares Antique Imitation Tiles using cinder, includes the following steps:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, it is molten to obtain mixture
Liquid；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, high-speed stirred 1~
2min obtains muddy mixture；
(5) hydraulic brick making machine molding, briquetting pressure 10MPa are fed the mixture into, setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
Embodiment 4
The present embodiment provides a kind of Antique Imitation Tiles prepared using cinder, are to be composed of the following weight percentages of raw materials: coal
Slag 46%, Extra-fine sand 2%, bunt gypsum 10%, white cement 11%, water 27.5%, iron oxide black 1.2%, oxalic acid 1.2%, tertiary sodium phosphate
0.6%, methyl sodium nitrate 0.5%；The cinder be coal enterprise burn coal after cinder, be sieved into after crushing granularity be 0.1~
The coal slag granules of 0.5cm, 0.5~1.0cm, the weight ratio of the two are 1:1.6.
The method that the present embodiment prepares Antique Imitation Tiles using cinder, includes the following steps:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, it is molten to obtain mixture
Liquid；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, high-speed stirred 1~
2min obtains muddy mixture；
(5) hydraulic brick making machine molding, briquetting pressure 25MPa are fed the mixture into, setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
Embodiment 5
The present embodiment provides a kind of Antique Imitation Tiles prepared using cinder, are to be composed of the following weight percentages of raw materials: coal
Slag 45.8%, Extra-fine sand 2%, bunt gypsum 6%, white cement 10.9%, water 32%, iron oxide black 1.1%, oxalic acid 1.2%, tertiary sodium phosphate
0.5%, methyl sodium nitrate 0.5%；The cinder be coal enterprise burn coal after cinder, be sieved into after crushing granularity be 0.1~
The coal slag granules of 0.5cm, 0.5~1.0cm, the weight ratio of the two are 1:1.9.
The method that the present embodiment prepares Antique Imitation Tiles using cinder, includes the following steps:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, it is molten to obtain mixture
Liquid；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, high-speed stirred 1~
2min obtains muddy mixture；
(5) hydraulic brick making machine molding, briquetting pressure 30MPa are fed the mixture into, setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
Antique Imitation Tiles system made from embodiment 1 to 5 is examined according to " small-sized ordinary concrete building block " GB/T8239-2014
It surveys, the specification of brick is 480mm × 240mm × 100mm when test, and test result is as follows shown in table 1:
As upper table content it is found that using Antique Imitation Tiles made from preparation method of the present invention with good compression strength and freeze proof
Property, meet GB/T8239-2014 standard requirements.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of Antique Imitation Tiles prepared using cinder, it is characterised in that be to be composed of the following weight percentages of raw materials: cinder
45%~53%, Extra-fine sand 1%~5%, bunt gypsum 5%~10%, white cement 10%~15%, water 25%~32%, iron oxide black
1%~2%, oxalic acid 1.0%~1.5%, tertiary sodium phosphate 0.5%~1.0%, methyl sodium nitrate 0.4%~0.6%；The coal
Slag is that the cinder after coal burns in coal enterprise, and the coal slag granules that granularity is 0.1~0.5cm, 0.5~1.0cm are sieved into after crushing.
2. a kind of Antique Imitation Tiles prepared using cinder according to claim 1, it is characterised in that: the fineness of the bunt gypsum
For 200 mesh.
3. a kind of Antique Imitation Tiles prepared using cinder according to claim 1, it is characterised in that: the fineness of the white cement
For 200 mesh.
4. a kind of Antique Imitation Tiles prepared using cinder according to claim 1, it is characterised in that: the Extra-fine sand is the Yellow River
The river drift in downstream.
5. a kind of described in any item methods for preparing Antique Imitation Tiles using cinder of Claims 1 to 4, it is characterised in that including following
Step:
(1) taking granularity is that the cinder of 0.5~1.0cm is uniformly mixed with white cement；
(2) cinder, Extra-fine sand and bunt gypsum for taking granularity to be 0.1~0.5cm are uniformly mixed；
(3) it takes oxalic acid, tertiary sodium phosphate, methyl sodium nitrate and iron oxide black to be added to the water, is uniformly mixed, obtains mixture solution；
(4) mixture solution is added in step (1) and step (2) resulting mixed material, 1~2min of high-speed stirred is obtained
Muddy mixture；
(5) hydraulic brick making machine molding is fed the mixture into, briquetting pressure is 5~30MPa, and setting time is for 24 hours；
(6) it conserves: molding Antique Imitation Tiles sprinkling maintenance 7 days.
6. a kind of method for preparing Antique Imitation Tiles using cinder according to claim 5, it is characterised in that: the granularity 0.5
The weight ratio for the cinder that the cinder of~1.0cm and the granularity are 0.1~0.5cm is 1:1.5~2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811174322.2A CN109053089A (en) | 2018-10-09 | 2018-10-09 | A kind of Antique Imitation Tiles and preparation method thereof using cinder preparation |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811174322.2A CN109053089A (en) | 2018-10-09 | 2018-10-09 | A kind of Antique Imitation Tiles and preparation method thereof using cinder preparation |
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| CN109053089A true CN109053089A (en) | 2018-12-21 |
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| CN201811174322.2A Pending CN109053089A (en) | 2018-10-09 | 2018-10-09 | A kind of Antique Imitation Tiles and preparation method thereof using cinder preparation |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112851301A (en) * | 2021-01-18 | 2021-05-28 | 湖南省醴陵市兆荣瓷业有限公司 | Manufacturing method and formula of archaized tile |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3437680A1 (en) * | 1984-10-15 | 1986-04-17 | Tubag Trass-, Zement- Und Steinwerke Gmbh, 5473 Kruft | Binder for restoration mortar |
| CN101713234A (en) * | 2009-10-30 | 2010-05-26 | 武汉理工大学 | Non-autoclaved and unburned brick and preparation method thereof |
| CN103936340A (en) * | 2013-01-22 | 2014-07-23 | 金正义 | Archaized blue brick and its preparation method |
| CN108249840A (en) * | 2018-01-25 | 2018-07-06 | 广西亿品投资有限公司 | Pavior brick modelled after an antique and preparation method thereof |
-
2018
- 2018-10-09 CN CN201811174322.2A patent/CN109053089A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3437680A1 (en) * | 1984-10-15 | 1986-04-17 | Tubag Trass-, Zement- Und Steinwerke Gmbh, 5473 Kruft | Binder for restoration mortar |
| CN101713234A (en) * | 2009-10-30 | 2010-05-26 | 武汉理工大学 | Non-autoclaved and unburned brick and preparation method thereof |
| CN103936340A (en) * | 2013-01-22 | 2014-07-23 | 金正义 | Archaized blue brick and its preparation method |
| CN108249840A (en) * | 2018-01-25 | 2018-07-06 | 广西亿品投资有限公司 | Pavior brick modelled after an antique and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 雍本编著: "《特种混凝土施工手册》", 30 June 2005, 中国建材工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112851301A (en) * | 2021-01-18 | 2021-05-28 | 湖南省醴陵市兆荣瓷业有限公司 | Manufacturing method and formula of archaized tile |
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