CN109052751A - A kind of electrochemical process for treating of sanitary sewage - Google Patents

A kind of electrochemical process for treating of sanitary sewage Download PDF

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Publication number
CN109052751A
CN109052751A CN201810962193.7A CN201810962193A CN109052751A CN 109052751 A CN109052751 A CN 109052751A CN 201810962193 A CN201810962193 A CN 201810962193A CN 109052751 A CN109052751 A CN 109052751A
Authority
CN
China
Prior art keywords
sanitary sewage
organic matter
electrolytic cell
sodium hypochlorite
sterilizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810962193.7A
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Chinese (zh)
Inventor
陈琳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Futeni Water Engineering Co Ltd
Original Assignee
Suzhou Futeni Water Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Futeni Water Engineering Co Ltd filed Critical Suzhou Futeni Water Engineering Co Ltd
Priority to CN201810962193.7A priority Critical patent/CN109052751A/en
Publication of CN109052751A publication Critical patent/CN109052751A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/70Treatment of water, waste water, or sewage by reduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • C02F1/766Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/008Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a kind of electrochemical process for treating of sanitary sewage, it is electrochemically reacted its main feature is that sanitary sewage and seawater are mixed into electrolytic cell by 1:20 volume ratio by this method, it is electrolysed the chlorine generated and sodium hydroxide generates sodium hypochlorite, oxidation reaction occurs for organic matter in sodium hypochlorite and sanitary sewage, so that organic matter is carried out sterilizing to sanitary sewage while obtaining degradation, is discharged into sea after up to standard.The present invention has structure simple compared with prior art; densification degree is high; sewage treatment capacity is big; degradation of organic substances and sterilizing carry out simultaneously in same equipment; simple process, it is easy to operate, it is stable, expense is low; and occupancy ship and the intracorporal space of ocean structure are small, reliably, effectively protect marine environment.

Description

A kind of electrochemical process for treating of sanitary sewage
Technical field
The present invention and technical field of sewage, specifically a kind of electrochemistry for ship or sewage Processing method.
Background technique
Currently, the sanitary sewage that generates in navigation of ship is generally used after biochemical treatment reaches discharge standard both at home and abroad It is discharged into sea, biochemical processing process utilizes microbial degradation organic matter, continuous constant water inlet is needed, so the equipment of sewage treatment Volume is big, however ship rides the sea, and equipment load is smaller more advantageous, while operator is limited on ship, operates simpler Equipment operate normally a possibility that it is bigger, treatment effect is also just more obvious.Problem of the existing technology is: equipment load Weight, occupies ship and the intracorporal space of ocean structure is big, and the processing time is long, fluctuation of service, is easy to cause dirt to marine environment Dye, and processing capacity is low, and operating cost is high.
Summary of the invention
The purpose of the present invention is in view of the deficiencies of the prior art and provide a kind of sanitary sewage electrochemical process for treating, Using the electrolytic cell of claustra structure, cell reaction is carried out using seawater as electrolyte, chlorine and the sodium hydroxide for being electrolysed generation are raw Make sanitary sewage qualified discharge, work by sodium hypochlorite by organic matter degradation and sterilizing in sanitary sewage at sodium hypochlorite Skill is simple, and device structure is compact, and degradation of organic substances and sterilizing carry out simultaneously in same equipment, easy to operate, and operation is steady Calmly, expense is low, and occupancy ship and the intracorporal space of ocean structure are small, reliably, effectively protects marine environment.
Realizing the technical solution of the object of the invention is: a kind of electrochemical process for treating of sanitary sewage, its main feature is that the party Sanitary sewage is entered electrolytic cell with sea water mixing and is electrochemically reacted by method, and the chlorine and sodium hydroxide for being electrolysed generation generate secondary Oxidation reaction occurs for the organic matter in sodium chlorate, sodium hypochlorite and sanitary sewage, makes organic matter while obtaining degradation to life Sewage carries out sterilizing, and specific processing step is as follows:
A, the electrochemical reaction of sanitary sewage
Sanitary sewage and seawater are pumped into electrolytic cell by macerator pump and sea water pump respectively by the volume ratio of 1:15~25 simultaneously and carry out electricity Chemical reaction;The electrolytic cell is the cabinet of titanium alloy production, interior to be equipped with positive electrode plate and the interlaced setting of negative electrode plate Claustra structure, when sanitary sewage and seawater flow through claustra structure, will electrolysis generate chlorine in closed claustra structure with Sodium hydroxide generates sodium hypochlorite, and sodium hypochlorite flows out electrolytic cell in company with sanitary sewage;
B, the oxidation reaction of organic matter
Above-mentioned sodium hypochlorite is sent into the oxidation reaction that letdown tank carries out organic matter in company with the water outlet of sanitary sewage outflow electrolytic cell; The baffling area and buffer area constituted in the letdown tank equipped with folded plate, baffling area side are equipped with water inlet pipe mouth, and buffer area side is set There is effluent pipe mouth, electrolytic cell is discharged under the hydraulic disturbance in baffling area, and javelwater is solved the active oxygen of release and is lived dirty Organic matter in water is sufficiently mixed, and further carries out organic matter degradation and sterilizing to sanitary sewage, slow after fully reacting It rushes in area and carries out reduction reaction to balance still unreacted chlorine residue, through organic matter degradation and sterilizing with the sodium sulfite being added Sanitary sewage it is up to standard after by emptying pump from effluent pipe mouth be discharged.
The present invention has structure simple compared with prior art, and densification degree is high, and sewage treatment capacity is big, degrades organic Object and sterilizing carry out simultaneously in same equipment, and simple process is easy to operate, stable, expense is low, and occupy ship Oceangoing ship and the intracorporal space of ocean structure are small, reliably, effectively protect marine environment.
Detailed description of the invention
Fig. 1 is figure of the embodiment of the present invention
Fig. 2 is the A-A sectional view of Fig. 1.
Specific embodiment
Refering to attached drawing 1, the present invention is by sewage receiving slit 2, sea water pump 3, letdown tank 6, dosing tank 7, macerator pump 8, electrolytic cell 9 The electrochemical treatments of sanitary sewage are carried out with the device that emptying pump 10 forms;8 import of macerator pump and sewage receiving slit 2 export Connection;9 import of electrolytic cell is connect with the outlet of macerator pump 8 and sea water pump 3, and the outlet of electrolytic cell 9 connects with 6 import of letdown tank It connects, the outlet of letdown tank 6 is connect with 10 import of emptying pump;Buffer area 11 is equipped in the letdown tank 6 and several piece folded plate is interlaced The baffling area 1 of setting, 1 side of baffling area are equipped with water inlet pipe mouth, and 11 side of buffer area is equipped with effluent pipe mouth;The dosing tank 7 goes out Mouth is connect with letdown tank 6.
Refering to attached drawing 2, the electrolytic cell 9 is the cabinet of titanium alloy production, interior to be equipped with positive electrode plate 4 and negative electrode plate 5 The claustra structure of interlaced setting.
Below by way of specific embodiment, the present invention is described in further detail.
Embodiment 1
A, the electrochemical reaction of sanitary sewage
Sanitary sewage and seawater are pumped into electrolytic cell 9 by macerator pump 8 and sea water pump 3 respectively by 1:20 volume ratio simultaneously and carry out electrification Learn reaction;The electrolytic cell 9 is the cabinet of titanium alloy production, interior to be equipped with positive electrode plate 4 and the interlaced setting of negative electrode plate 5 Claustra structure, when sanitary sewage and seawater flow through claustra structure, will electrolysis generate chlorine in closed claustra structure with Sodium hydroxide generates sodium hypochlorite, and sodium hypochlorite flows out electrolytic cell 9 in company with sanitary sewage;
B, the oxidation reaction of organic matter
The oxidation that above-mentioned sodium hypochlorite is sent into the progress organic matter of letdown tank 6 in company with the water outlet of sanitary sewage outflow electrolytic cell 9 is anti- It answers;Equipped with buffer area 11 and the baffling area 1 being made of several piece folded plate in the letdown tank 6,1 side of baffling area is equipped with water inlet pipe Mouthful, 11 side of buffer area is equipped with effluent pipe mouth, and electrolytic cell 9 is discharged under the hydraulic disturbance in baffling area 1, javelwater is explained The organic matter in active oxygen and sanitary sewage put is sufficiently mixed, and further carries out organic matter degradation to sanitary sewage and sterilization disappears Poison, it is still unreacted to balance with the sodium sulfite progress reduction reaction from dosing tank 7 in buffer area 11 after fully reacting Chlorine residue, the sanitary sewage of ship fully achieves the discharge standard of national regulation after above-mentioned electrochemical treatments, then by arranging It puts pump 10 and is pumped into sea from effluent pipe mouth, reliably, effectively protect marine environment.
Above only the present invention is further illustrated, and not to limit this patent, all is equivalence enforcement of the present invention, It is intended to be limited solely by within the scope of the claims of this patent.

Claims (1)

1. a kind of electrochemical process for treating of sanitary sewage, it is characterised in that sanitary sewage and sea water mixing are entered electricity by this method Solution slot is electrochemically reacted, and the chlorine and sodium hydroxide for being electrolysed generation generate sodium hypochlorite, in sodium hypochlorite and sanitary sewage Organic matter oxidation reaction occurs, so that organic matter is carried out sterilizing, specific processing step to sanitary sewage while obtaining degradation It is rapid as follows:
A, the electrochemical reaction of sanitary sewage
Sanitary sewage and seawater are pumped into electrolytic cell by macerator pump and sea water pump respectively by the volume ratio of 1:15~25 simultaneously and carry out electricity Chemical reaction;The electrolytic cell is the cabinet of titanium alloy production, interior to be equipped with positive electrode plate and the interlaced setting of negative electrode plate Claustra structure, when sanitary sewage and seawater flow through claustra structure, will electrolysis generate chlorine in closed claustra structure with Sodium hydroxide generates sodium hypochlorite, and sodium hypochlorite flows out electrolytic cell in company with sanitary sewage;
B, the oxidation reaction of organic matter
Above-mentioned sodium hypochlorite is sent into the oxidation reaction that letdown tank carries out organic matter in company with the water outlet of sanitary sewage outflow electrolytic cell; The baffling area and buffer area constituted in the letdown tank equipped with folded plate, baffling area side are equipped with water inlet pipe mouth, and buffer area side is set There is effluent pipe mouth, electrolytic cell is discharged under the hydraulic disturbance in baffling area, and javelwater is solved the active oxygen of release and is lived dirty Organic matter in water is sufficiently mixed, and further carries out organic matter degradation and sterilizing to sanitary sewage, slow after fully reacting It rushes in area and carries out reduction reaction to balance still unreacted chlorine residue, through organic matter degradation and sterilizing with the sodium sulfite being added Sanitary sewage it is up to standard after by emptying pump from effluent pipe mouth be discharged.
CN201810962193.7A 2018-08-22 2018-08-22 A kind of electrochemical process for treating of sanitary sewage Withdrawn CN109052751A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810962193.7A CN109052751A (en) 2018-08-22 2018-08-22 A kind of electrochemical process for treating of sanitary sewage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810962193.7A CN109052751A (en) 2018-08-22 2018-08-22 A kind of electrochemical process for treating of sanitary sewage

Publications (1)

Publication Number Publication Date
CN109052751A true CN109052751A (en) 2018-12-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921795A (en) * 2019-12-11 2020-03-27 同济大学 Method for sterilizing hospital wastewater and synchronously removing PPCPs (pentatricopeptide repeats) by electrochemically activated water

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159352A (en) * 2013-04-12 2013-06-19 中船第九设计研究院工程有限公司 Electrochemical treatment method for domestic sewage
CN203173871U (en) * 2013-04-12 2013-09-04 中船第九设计研究院工程有限公司 Sewage electrochemical treatment device
CN106277481A (en) * 2016-09-10 2017-01-04 安徽蓝鼎环保能源科技有限公司 The electrochemical process for treating of one way of life sewage

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159352A (en) * 2013-04-12 2013-06-19 中船第九设计研究院工程有限公司 Electrochemical treatment method for domestic sewage
CN203173871U (en) * 2013-04-12 2013-09-04 中船第九设计研究院工程有限公司 Sewage electrochemical treatment device
CN106277481A (en) * 2016-09-10 2017-01-04 安徽蓝鼎环保能源科技有限公司 The electrochemical process for treating of one way of life sewage

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921795A (en) * 2019-12-11 2020-03-27 同济大学 Method for sterilizing hospital wastewater and synchronously removing PPCPs (pentatricopeptide repeats) by electrochemically activated water

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Application publication date: 20181221

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