CN109052539A - A kind of preparation method of swimming pool material for water treatment - Google Patents
A kind of preparation method of swimming pool material for water treatment Download PDFInfo
- Publication number
- CN109052539A CN109052539A CN201811014859.2A CN201811014859A CN109052539A CN 109052539 A CN109052539 A CN 109052539A CN 201811014859 A CN201811014859 A CN 201811014859A CN 109052539 A CN109052539 A CN 109052539A
- Authority
- CN
- China
- Prior art keywords
- swimming pool
- water
- water treatment
- preparation
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical
Abstract
The present invention relates to a kind of preparation methods of swimming pool material for water treatment, belong to material for water treatment technical field.The present invention is using adsorbent material diatomite as main material, pass through compound tourmaline, and coat nanometer titanium dioxide layer, construct anion layer, nano-negative ion composite bactericidal layer is formed through surface amination processing back loading copper complex again, with destruction virocyte structure, the effect for the toxic compound that bacterium for degrading releases, oxygen and hydrone can be excited to form oxidability very strong hydroxyl and active oxygen, hydroxyl and active oxygen can be the synthesis organic matters in the presence of water body, their oxygenolysis are become harmless carbon dioxide and water, the cell membrane of virocyte can effectively be destroyed, sterilization is obvious；Swimming pool material for water treatment of the present invention can accelerate moisture movement, and light water is made to become active water, and generate water conservation film, enhance blood circulation, boost metabolism, and enhance Lymphatic Circulation, eliminate fatigue, and swimming pool is suitble to use.
Description
Technical field
The present invention relates to a kind of preparation methods of swimming pool material for water treatment, belong to material for water treatment technical field.
Background technique
Swimming is the favorite movement of people, and swimming can not only enjoy the enjoyment with water phase touching, moreover it is possible to reach and keep fit and healthy
Effect.It especially scorching summer, swims freely in swimming pool, strictly a kind of very satisfied enjoyment.As people live
Horizontal raising, indoor swimming provide the Swimming pool not constrained by season for vast swimming fan.But swimming is also wanted
Pay attention to various items, other than most basic safe knowledge, there are also negligible not at all, that is, the water in swimming pool, it can
The illnesss such as tinea pedis, the ringworm of the foot can be infected, it may contain various bacteria and helminth, can cause various diseases.Some places exist
Swimmer, which enters before swimming pool not taking, forces shower measure, fails tentatively to wash away mud, the sweat with swimmer, makes the urea of swimming pool
Increase with bacterial content.
With the enhancing of people's health consciousness, the people for going swimming pool to take exercise is more and more.Swimming-pool water Geological Problems are always complete
The great public health problem of social concerns.Especially summer, urea in swimming-pool water with the stream of people increase, often largely
It is exceeded.Urea is the nutriment of bacterium and algal grown, and the increase of content can accelerate bacterium and algal grown speed in water,
Accelerate water quality deterioration, cause sterilization algae removal difficult, to maintain sterilization algae removal effect, it is necessary to increase disinfectant consumption, bring new
Stimulation, causes vicious circle.Urea is badly in need of effective minimizing technology because its chemical property is more stable.Swimming-pool water at present
The main several ways of matter processing, supplement fresh water, active carbon filtering, are launched containing activity+chlorine or active oxygen quartz sand filtration
Medicament and ultraviolet ray sterilization bactericidal.Quartz sand filtration and ultraviolet device eliminate without any effect urea.Active carbon can
A part of urea is adsorbed, but activated carbon adsorption, without selective, other impurities such as calcium and magnesium ion can be also adsorbed in water, be dropped
Its low efficiency, while its saturated extent of adsorption is limited, it is necessary to timing, which updates, just can guarantee adsorptivity, therefore cost is relatively high using not
It is convenient.Fresh water is supplemented, is easy to cause water temperature variation greatly, water content consumption is big, and addition related agents waste, discharge water easily causes ring
Border pollution.
Currently, swimming-pool water sterilizes, useful chlorine, but excessive chlorine can cause to pierce to the skin of people, cornea etc.
Swash, many people think that, when the smell of chlorine in a swimming-pool water is very heavy, it is meant that it is very clean.But in fact, swimming-pool water
Smell comes from chloramines, this is the mixture of the substances such as chlorine and bacterium, urine and sweat.One true health and clean swimming pool
Any smell will not be had.
As the improvement of people's living standards, the consumption of swimming pool increasingly rises, the water process in swimming pool becomes key,
Existing swimming pool sewerage disposing is handled merely by bleaching powder, ineffective.
Summary of the invention
The technical problems to be solved by the invention: being handled for current swimming pool sewerage disposing merely by bleaching powder,
The problem of its is ineffective, and stimulation can be caused to the skin of people, cornea etc., provides a kind of system of swimming pool material for water treatment
Preparation Method.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
(1) mass fraction is added as ultrasonic disperse in 5% butyl titanate aqueous solution after taking diatomite, tourmaline ball milling, then is centrifuged
Simultaneously washing and drying is separated, compound material is obtained；
(2) it takes compound material to be added in deionized water to stir evenly, adds after 3- amino triethoxysilane is stirred to react and be centrifuged
Simultaneously washing and drying is separated, material must be modified；
(3) it takes modification material to be added to absolute ethanol to stir evenly, then it is 10~20% salicylide ethanol solutions that mass fraction, which is added dropwise,
It continues stirring until and copper acetate is added after being added dropwise, filter, wash after being stirred to react, vacuum drying, obtain swimming-pool water processing material
Material.
The mass ratio of step (1) diatomite and tourmaline is 1:1~3:1.
Step (1) the butyl titanate amount of aqueous solution used is 2~5 times of diatomite quality.
Step (2) the 3- amino triethoxysilane dosage is the 10~25% of compound material quality.
Step (3) the salicylide ethanol solution dosage is the 50~150% of modification material quality.
Step (3) the copper acetate dosage is the 5~15% of modification material quality.
Step (3) drop rate is 1~2g/min.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention by compound tourmaline, and coats nanometer titanium dioxide layer using adsorbent material diatomite as main material,
Anion layer is constructed, then forms nano-negative ion composite bactericidal layer through surface amination processing back loading copper complex, is had broken
Deteriorated case poison cell structure, the effect for the toxic compound that bacterium for degrading releases can excite oxygen and hydrone to form oxygen
Change ability very strong hydroxyl and active oxygen, hydroxyl and active oxygen can be the synthesis organic matters in the presence of water body, them
Oxygenolysis becomes harmless carbon dioxide and water, can effectively destroy the cell membrane of virocyte, solidify virus protein
Protein, and its corpse can be decomposed, sterilization is obvious；
(2) swimming pool material for water treatment of the present invention can accelerate moisture movement, and light water is made to become active water, to make the infiltration of water
Saturating power, extension, dissolving power, metabolism power enhancing, and water conservation film is generated, for the circulatory system, expansion capillary can be played,
Enhance blood circulation, boost metabolism, enhance the effect of Lymphatic Circulation, increase energy, easily remove human body dirt, eliminates tired
Labor is suitble to swimming pool to use.
Specific embodiment
Take 100~150g diatomite, 50~100g tourmaline, be fitted into ball mill with 150~250r/min ball milling 10~
300~500g mass fraction is added after 15h to disperse 2~3h with 300W ultrasonic echography in 5% butyl titanate aqueous solution, then
It is transferred in centrifuge with 3000~5000r/min centrifuge separation, collects and precipitate and 2~3 postpositions of precipitating are washed with deionized
In drying box, dry 6~8h, obtains compound material at 80~100 DEG C, takes 20~30g compound material, be added 200~300mL go from
In sub- water, 20~30min is stirred with 300~400r/min, 3~5g3- amino triethoxysilane is added, continues stirring 20
It is transferred to after~30h in centrifuge with 3000~5000r/min centrifuge separation, collects sediment and sediment is washed with deionized
It 2~3 times, putting the precipitate in drying box, dry 6~8h, must modify material at 80~100 DEG C, 20~30g modification material is taken,
It is added in 200~300g dehydrated alcohol, 20~30min is stirred with 300~400r/min, then 15~30g is added dropwise with 1~2g/min
Mass fraction is 10~20% salicylide ethanol solutions, continues stirring until addition 1.5~3.0g copper acetate after being added dropwise, continues
Filter residue is filtered to obtain after 20~30h of stirring, filter residue is washed with deionized sediment 2~3 times and is placed in drying box, 100
It is dried in vacuo 5~10h at~110 DEG C, obtains swimming pool material for water treatment.
100g diatomite is taken, 50g tourmaline is fitted into ball mill so that 300g mass point to be added after 150r/min ball milling 10h
Number is to disperse 2h in 5% butyl titanate aqueous solution with 300W ultrasonic echography, then be transferred in centrifuge and be centrifuged with 3000r/min
Separation, collection precipitate and are washed with deionized precipitating 2 times and be placed in drying box, and dry 6h, obtains compound material, take at 80 DEG C
20g compound material is added in 200mL deionized water, stirs 20min with 300r/min, adds 3g3- amino triethoxysilane,
Continue to be transferred in centrifuge and be centrifugated with 3000r/min after stirring 20h, collects sediment and sediment simultaneously is washed with deionized
It 2 times, puts the precipitate in drying box, dry 6h, must modify material at 80 DEG C, take 20g modification material, 200g dehydrated alcohol is added
In, 20min is stirred with 300r/min, then 15g mass fraction is added dropwise as 10% salicylide ethanol solution with 1g/min, persistently stirred
1.5g copper acetate is added to after being added dropwise, continues to filter to obtain filter residue after stirring 20h, sediment is washed with deionized in filter residue
It is placed in drying box for 2 times, is dried in vacuo 5h at 100 DEG C, obtains swimming pool material for water treatment.
125g diatomite is taken, 75g tourmaline is fitted into ball mill so that 400g mass point to be added after 200r/min ball milling 13h
Number be 5% butyl titanate aqueous solution in, with 300W ultrasonic echography disperse 2.5h, then be transferred in centrifuge with 4000r/min from
Heart separation, collection precipitate and are washed with deionized precipitating 2 times and be placed in drying box, and dry 7h, obtains compound material at 90 DEG C,
25g compound material is taken, is added in 250mL deionized water, 25min is stirred with 350r/min, adds 4g3- amino triethoxysilicane
Alkane continues to be transferred in centrifuge and be centrifugated with 4000r/min after stirring 25h, collect sediment and be washed with deionized it is heavy
It starch 2 times, puts the precipitate in drying box, dry 7h, must modify material at 90 DEG C, take 25g modification material, it is anhydrous that 250g is added
In ethyl alcohol, 25min is stirred with 350r/min, then 22g mass fraction is added dropwise as 15% salicylide ethanol solution with 1.5g/min, held
2.2g copper acetate is added to after being added dropwise for continuous stirring, continues to filter to obtain filter residue after stirring 25h, filter residue is washed with deionized
It is placed in drying box for sediment 3 times, is dried in vacuo 7h at 105 DEG C, obtains swimming pool material for water treatment.
150g diatomite is taken, 100g tourmaline is fitted into ball mill so that 500g mass point to be added after 250r/min ball milling 15h
Number is to disperse 3h in 5% butyl titanate aqueous solution with 300W ultrasonic echography, then be transferred in centrifuge and be centrifuged with 5000r/min
Separation, collection precipitate and are washed with deionized precipitating 3 times and be placed in drying box, and dry 8h, obtains compound material at 100 DEG C,
30g compound material is taken, is added in 300mL deionized water, 30min is stirred with 400r/min, adds 5g3- amino triethoxysilicane
Alkane continues to be transferred in centrifuge and be centrifugated with 5000r/min after stirring 30h, collect sediment and be washed with deionized it is heavy
Starch 3 times, put the precipitate in drying box, dry 8h, must modify material at 100 DEG C, take 30g modification to expect, addition 300g without
In water-ethanol, 30min is stirred with 400r/min, then 30g mass fraction is added dropwise as 20% salicylide ethanol solution with 2g/min, held
3.0g copper acetate is added to after being added dropwise for continuous stirring, continues to filter to obtain filter residue after stirring 30h, filter residue is washed with deionized
It is placed in drying box for sediment 3 times, is dried in vacuo 10h at 110 DEG C, obtains swimming pool material for water treatment.
The swimming pool material for water treatment that swimming pool material for water treatment prepared by the present invention and Guangzhou company produce is carried out
Detection, specific testing result such as following table table 1:
Detection method: the swimming-pool water processing material investment for being utilized respectively Examples 1 to 3 preparation has same pollution condition in 3
Swimming pool in, indices detection is carried out after 1h to it, concrete outcome such as following table table 1:
1 swimming-pool water of table handles material property characterization
Swimming pool material for water treatment prepared by the present invention as shown in Table 1 has high adsorption, highly selective, water quality after processing
It is good, human skin will not be damaged, be had broad application prospects.
Claims (7)
1. a kind of preparation method of swimming pool material for water treatment, which is characterized in that specific steps are as follows:
(1) mass fraction is added as ultrasonic disperse in 5% butyl titanate aqueous solution after taking diatomite, tourmaline ball milling, then is centrifuged
Simultaneously washing and drying is separated, compound material is obtained；
(2) it takes compound material to be added in deionized water to stir evenly, adds after 3- amino triethoxysilane is stirred to react and be centrifuged
Simultaneously washing and drying is separated, material must be modified；
(3) it takes modification material to be added to absolute ethanol to stir evenly, then it is 10~20% salicylide ethanol solutions that mass fraction, which is added dropwise,
It continues stirring until and copper acetate is added after being added dropwise, filter, wash after being stirred to react, vacuum drying, obtain swimming-pool water processing material
Material.
2. a kind of preparation method of swimming pool material for water treatment as described in claim 1, which is characterized in that step (1) is described
The mass ratio of diatomite and tourmaline is 1:1~3:1.
3. a kind of preparation method of swimming pool material for water treatment as described in claim 1, which is characterized in that step (1) is described
Butyl titanate amount of aqueous solution used is 2~5 times of diatomite quality.
4. a kind of preparation method of swimming pool material for water treatment as described in claim 1, which is characterized in that step (2) is described
3- amino triethoxysilane dosage is the 10~25% of compound material quality.
5. a kind of preparation method of swimming pool material for water treatment as described in claim 1, which is characterized in that step (3) is described
Salicylide ethanol solution dosage is the 50~150% of modification material quality.
6. a kind of preparation method of swimming pool material for water treatment as described in claim 1, which is characterized in that step (3) is described
Copper acetate dosage is the 5~15% of modification material quality.
7. a kind of preparation method of swimming pool material for water treatment as described in claim 1, which is characterized in that step (3) is described
Drop rate is 1~2g/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811014859.2A CN109052539A (en) | 2018-08-31 | 2018-08-31 | A kind of preparation method of swimming pool material for water treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811014859.2A CN109052539A (en) | 2018-08-31 | 2018-08-31 | A kind of preparation method of swimming pool material for water treatment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109052539A true CN109052539A (en) | 2018-12-21 |
Family
ID=64758998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811014859.2A Withdrawn CN109052539A (en) | 2018-08-31 | 2018-08-31 | A kind of preparation method of swimming pool material for water treatment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109052539A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382387A (en) * | 2005-09-23 | 2013-11-06 | 川汉油田服务有限公司 | Slurry compositions and methods for making same |
| CN104399434A (en) * | 2014-10-21 | 2015-03-11 | 繁昌县倍思生产力促进中心有限公司 | Cerium oxide-containing PM2.5 adsorbent and preparation method thereof |
| CN107555517A (en) * | 2017-07-29 | 2018-01-09 | 宿松县辉煌家庭农场 | A kind of lobster pond Special sterilizing odor removal composite material |
| CN107583464A (en) * | 2017-11-02 | 2018-01-16 | 广州怡居节能环保科技有限公司 | A kind of high-efficiency formaldehyde scavenging agent and preparation method thereof |
| CN107720976A (en) * | 2017-09-04 | 2018-02-23 | 安徽秀安生态农业有限公司 | A kind of composition to purify water |
| CN108064882A (en) * | 2017-12-11 | 2018-05-25 | 刘凡领 | A kind of preparation method of long-acting antibiotic agent |
-
2018
- 2018-08-31 CN CN201811014859.2A patent/CN109052539A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382387A (en) * | 2005-09-23 | 2013-11-06 | 川汉油田服务有限公司 | Slurry compositions and methods for making same |
| CN104399434A (en) * | 2014-10-21 | 2015-03-11 | 繁昌县倍思生产力促进中心有限公司 | Cerium oxide-containing PM2.5 adsorbent and preparation method thereof |
| CN107555517A (en) * | 2017-07-29 | 2018-01-09 | 宿松县辉煌家庭农场 | A kind of lobster pond Special sterilizing odor removal composite material |
| CN107720976A (en) * | 2017-09-04 | 2018-02-23 | 安徽秀安生态农业有限公司 | A kind of composition to purify water |
| CN107583464A (en) * | 2017-11-02 | 2018-01-16 | 广州怡居节能环保科技有限公司 | A kind of high-efficiency formaldehyde scavenging agent and preparation method thereof |
| CN108064882A (en) * | 2017-12-11 | 2018-05-25 | 刘凡领 | A kind of preparation method of long-acting antibiotic agent |
Non-Patent Citations (1)
| Title |
|---|
| 燃料化学工业出版社: "《化工辞典》", 31 August 1969 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107445342B (en) | Swimming pool water treatment system | |
| CN106892481A (en) | Magnetic coupling algicide and its application method | |
| CN101734775A (en) | Method for treating algal bloom by using modified attapulgite as flocculant | |
| CN107279031B (en) | Device and method for purifying water in fish tank | |
| CN1136154C (en) | Active oxygen eliminating agent concentrated liquid and its producing process and active oxygen eliminating agent powder | |
| CN107098537A (en) | Municipal wastewater handling process | |
| CN105776659A (en) | Method for treating sewage | |
| CN206289116U (en) | One kind production agricultural chemicals wastewater treatment equipment | |
| CN106178928A (en) | A kind of controlled natural biological taste removal is except formaldehyde products and its preparation method and application | |
| CN206570148U (en) | A kind of integrated combination purifier | |
| CN109052539A (en) | A kind of preparation method of swimming pool material for water treatment | |
| CN109570208A (en) | A kind of heavy-metal contaminated soil charcoal repair materials | |
| CN106268677B (en) | A kind of preparation method of modified watermelon peel adsorbent | |
| CN108083547A (en) | A kind of method of wastewater treatment | |
| CN106396236A (en) | Portable water jug capable of realizing purification, activation, benefit production and energy generation, and filter core thereof | |
| CN106492255A (en) | A kind of preparation method of composite type natural plant deodorizer | |
| CN104188338B (en) | A kind of purifier | |
| CN109467156A (en) | Landfill leachate multifunctional water treating agent and preparation method thereof | |
| CN107381704A (en) | A kind of new and effective water purification catridge | |
| CN106927537A (en) | A kind of river course concave convex rod purification of water quality bag and preparation method | |
| CN104905724B (en) | A kind of toilet lid that can adsorb stink substance | |
| CN107337250A (en) | A kind of processing method of waste water | |
| CN207451800U (en) | A kind of fish farm water-ozone purifier | |
| CN105230686B (en) | Air cleaning liquid compositionss and its using method, preparation method and preparation system | |
| CN203144223U (en) | Water purifying and sterilizing device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181221 |