CN109023980A - A kind of manufacturing method of antiskid Polywoven Bag - Google Patents
A kind of manufacturing method of antiskid Polywoven Bag Download PDFInfo
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- CN109023980A CN109023980A CN201810830602.8A CN201810830602A CN109023980A CN 109023980 A CN109023980 A CN 109023980A CN 201810830602 A CN201810830602 A CN 201810830602A CN 109023980 A CN109023980 A CN 109023980A
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- Prior art keywords
- antiskid
- woven bag
- manufacturing
- bag
- boehmite
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
- D01D5/426—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by cutting films
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0038—Polyolefin fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/106—Roughness, anti-slip, abrasiveness
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1685—Wear resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/20—Packaging
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nonwoven Fabrics (AREA)
Abstract
The present invention provides a kind of manufacturing method of antiskid Polywoven Bag, comprising the following steps: S1: drying is blended in raw material;S2: drawing process;S3: knitting process;S4: non-skid coating is prepared;S5: coating processes;S6: bag making.The purpose of the present invention is to provide a kind of good antiskid effects, the manufacturing method of the high Anti sliding braided bag that again can be fire-retardant of wear-resisting property.
Description
Technical field
The present invention relates to Polywoven Bag processing technique field, in particular to a kind of manufacturer of antiskid Polywoven Bag
Method.
Background technique
Polyolefin plastics woven bag is and cheap due to its light, thin, secured, waterproof, do not go rotten, fast from after coming out
Speed is used widely.With the continuous development of technology, the prior art woven bag is carried with manipulator, feeding, still
The woven bag surface being prepared by polypropylene is smooth, inadequate to the frictional adhesion of manipulator, therefore in carrying, feeding process
In be easy to appear slippage, cause danger with personnel or cause damages to material, and the prior art is for being loaded with material
Woven bag carries out accumulation deposit by way of stacked on top, and contact area is small between woven bag does not have non-skid property, stacks
Woven bag be easy to happen inclination and collapse, cause safety accident.Therefore need to research and develop a kind of Anti sliding braided bag.
Summary of the invention
The purpose of the present invention is to provide a kind of good antiskid effects, the system of the high Anti sliding braided bag that again can be fire-retardant of wear-resisting property
Make method.
The present invention provides a kind of manufacturing method of antiskid Polywoven Bag, comprising the following steps:
S1: drying is blended in raw material: PP GRANULES, calcium carbonate, auxiliary agent being put into dry blender and stir drying;
S2: drawing process: the material after the blending of S1 step is dry enters extruder, the heating and spiral shell by barrel
The shearing of bar and machine barrel is extruded as film by die head molding, after 30-40 DEG C of water is cooling, is cut into embryo silk with blade,
And be stretched to form flat filament by drying-plate, it is coiled that flat filament receives silk by receive silk machine after thermal finalization;
S3: knitting process: by coiled flat filament by circular weaving machine at cylinder-shaped woven bag, by examining, it is qualified to examine
Afterwards, then by winder it winds;
S4: non-skid coating is prepared: by chlorinated polypropylene, boehmite, silane coupling agent, Si3N4Long fibre, modified rosin tree
Rouge, plasticizer, antioxidant and solvent are stirred to react 6h at 65 DEG C, obtain glutinous shape liquid, glutinous shape liquid and boehmite are existed
Non-skid coating is made through filtering in mixed grinding in grinding machine;
S5: coating processes: the round woven bag of S3 is sent into the inverse roll printing machine equipped with non-skid coating, by anti-skidding painting
Material is coated on woven bag surface, through 105 DEG C of dry solidifications of heat source;
S6: the round woven bag being cured in step S4 bag making: is become into finished product braiding by printing, cutting and sewing
Bag.
As a further improvement of the present invention, in step S4 component weight proportion are as follows:
As a further improvement of the present invention, in step S4 component weight proportion are as follows:
As a further improvement of the present invention, Si3N4Long stapled length is 5-10mm.
As a further improvement of the present invention, silane coupling agent KH550, KH560 or KH570 is one such or more
Kind.
As a further improvement of the present invention, the diameter of boehmite is 40-60 mesh.
As a further improvement of the present invention, antioxidant 2,6- di-tert-butyl-4-methy phenol or thio dipropyl
Sour double lauryls.
Compared with prior art, the invention has the following advantages:
1. woven bag of the invention is provided with anti-skidding outer layer, there is Si in anti-skidding outer layer3N4Long fibre and boehmite, Si3N4It is long
Fiber and boehmite are distributed in anti-skidding outer layer forms network structure, and line style and point-type surface bulge are formed in anti-skidding outer layer,
The surface roughness and surface area for increasing woven bag prevent from removing to increase the non-skid property and wear-resisting property of woven bag
Occur the perils such as slip, topple over when fortune, stacking woven bag.
2. anti-skidding grain of the invention is boehmite and Si3N4Long fibre, boehmite surface come with reaction active groups Al-
OH, therefore boehmite has excellent dispersion performance, and Si3N4Long stapled dispersibility is poor, and it is heavy to occur in non-skid coating
Drop, by adding boehmite, the active group Al-OH and Si of boehmite3N4The group Si-OH on long fibre surface interacts, and mentions
High Si3N4Dispersibility of the long fibre in anti-skidding binding liquid, to improve Si3N4The uniformity that long fibre disperses in anti-slip layer,
Collaboration improves the coefficient of friction of anti-slip layer, increases the anti-skidding uniform performance of woven bag.
3. of the invention overcomes Si3N4" the candle wick effect " that long fibre is easy to appear causes the inflammable disadvantage of woven bag, when
Si3N4When long fibre burns, boehmite is decomposed into aluminium oxide and water, thermal decomposition process heat absorption, the vapor of releasing at high temperature
Imflammable gas can be diluted and harmful vapors is inhibited to generate, the alumina solid of generation blocks air, promotes burning Si3N4It is long
The extinguishing of fiber, so boehmite, which can cooperate with, effectively prevents Si while improving non-skid property3N4Long fibre burns away, and improves
The flame retardant property of woven bag.
4. boehmite of the invention can improve the mechanical property, flame retardant property and thermally conductive function of woven bag, boehmite is tool
There is the material of layer structure, composite material thermal resistance can be effectively reduced, improves internal heat transfer efficiency, boehmite and Si3N4Long fibre phase
Interaction forms the thermally conductive network chain of staggeredly combination, effectively augmentation of heat transfer, improve woven bag it is heated when inside heat transference efficiency,
The heat dissipation performance and heat resistance for improving woven bag also improve heat-sinking capability when woven bag burning, promote oneself of woven bag
Put out flame retardant property.
5. outer layer of the invention, which is used, is bonded in outer layer of polypropylene by the non-skid coating of matrix of chlorinated polypropylene, chlorination is poly-
When propylene and polypropylene woven bag contact, with gravitational attraction polypropylene between the crystallization of identical chemical structure crystallization, thus to polypropylene
There is very strong cohesive force, using silane coupling agent, makes boehmite and Si3N4Long fibre and chlorinated polypropylene are crosslinked, and improve chlorination
Polyacrylic crosslinking degree, so that the fusing point of chlorinated polypropylene, increases the temperature capacity and stabilization of the anti-skidding outer layer of woven bag
Property.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with specific embodiment.Obviously, described
Embodiment be only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiment of the present invention, ability
Domain those of ordinary skill every other embodiment obtained without creative efforts, belongs to guarantor of the present invention
The range of shield.
The present invention discloses a kind of manufacturing method of antiskid Polywoven Bag, specific embodiment is as follows.
Embodiment 1
The present invention provides a kind of manufacturing method of antiskid Polywoven Bag, comprising the following steps:
S1: drying is blended in raw material: PP GRANULES, calcium carbonate, auxiliary agent being put into dry blender and stir drying;
S2: drawing process: the material after the blending of S1 step is dry enters extruder, the heating and spiral shell by barrel
The shearing of bar and machine barrel is extruded as film by die head molding, after 30-40 DEG C of water is cooling, is cut into embryo silk with blade,
And be stretched to form flat filament by drying-plate, it is coiled that flat filament receives silk by receive silk machine after thermal finalization;
S3: knitting process: by coiled flat filament by circular weaving machine at cylinder-shaped woven bag, by examining, it is qualified to examine
Afterwards, then by winder it winds;
S4: non-skid coating is prepared: by weight ratio by 100 parts of chlorinated polypropylenes, 35 parts of boehmites, 1 part of silane coupling agent
The Si that KH550,5 parts of length are 5mm3N4Long fibre, 10 parts of modified rosin resins, 10 parts of plasticizer, 0.005 part of antioxidant 2,
6- di-tert-butyl-4-methy phenol or the double lauryls of thio-2 acid and 100 parts of solvents are stirred to react 6h at 65 DEG C, obtain
Non-skid coating is made through filtering in glutinous shape liquid, the mixed grinding in grinding machine by glutinous shape liquid and boehmite;
S5: coating processes: the round woven bag of S3 is sent into the inverse roll printing machine equipped with non-skid coating, by anti-skidding painting
Material is coated on woven bag surface, through 105 DEG C of dry solidifications of heat source;
S6: the round woven bag being cured in step S4 bag making: is become into finished product braiding by printing, cutting and sewing
Bag.
Embodiment 2
The present invention provides a kind of manufacturing method of antiskid Polywoven Bag, comprising the following steps:
S1: drying is blended in raw material: PP GRANULES, calcium carbonate, auxiliary agent being put into dry blender and stir drying;
S2: drawing process: the material after the blending of S1 step is dry enters extruder, the heating and spiral shell by barrel
The shearing of bar and machine barrel is extruded as film by die head molding, after 30-40 DEG C of water is cooling, is cut into embryo silk with blade,
And be stretched to form flat filament by drying-plate, it is coiled that flat filament receives silk by receive silk machine after thermal finalization;
S3: knitting process: by coiled flat filament by circular weaving machine at cylinder-shaped woven bag, by examining, it is qualified to examine
Afterwards, then by winder it winds;
S4: non-skid coating is prepared: by weight ratio by 100 parts of chlorinated polypropylenes, 60 parts of boehmites, 2 parts of silane coupling agents
The Si that KH560,20 parts of length are 10mm3N4Long fibre, 20 parts of modified rosin resins, 15 parts of plasticizer, 0.2 part of antioxidant 2,
6- di-tert-butyl-4-methy phenol or the double lauryls of thio-2 acid and 100 parts of solvents are stirred to react 6h at 65 DEG C, obtain
Non-skid coating is made through filtering in glutinous shape liquid, the mixed grinding in grinding machine by glutinous shape liquid and boehmite;
S5: coating processes: the round woven bag of S3 is sent into the inverse roll printing machine equipped with non-skid coating, by anti-skidding painting
Material is coated on woven bag surface, through 105 DEG C of dry solidifications of heat source;
S6: the round woven bag being cured in step S4 bag making: is become into finished product braiding by printing, cutting and sewing
Bag.
Embodiment 3
The present invention provides a kind of manufacturing method of antiskid Polywoven Bag, comprising the following steps:
S1: drying is blended in raw material: PP GRANULES, calcium carbonate, auxiliary agent being put into dry blender and stir drying;
S2: drawing process: the material after the blending of S1 step is dry enters extruder, the heating and spiral shell by barrel
The shearing of bar and machine barrel is extruded as film by die head molding, after 30-40 DEG C of water is cooling, is cut into embryo silk with blade,
And be stretched to form flat filament by drying-plate, it is coiled that flat filament receives silk by receive silk machine after thermal finalization;
S3: knitting process: by coiled flat filament by circular weaving machine at cylinder-shaped woven bag, by examining, it is qualified to examine
Afterwards, then by winder it winds;
S4: prepare non-skid coating: by weight ratio by 100 parts of chlorinated polypropylenes, 45 parts of boehmites, 1.5 parts it is silane coupled
The Si that agent KH570,15 parts of length are 8mm3N4Long fibre, 15 parts of modified rosin resins, 12 parts of plasticizer, 0.015 part of antioxidant
2,6- di-tert-butyl-4-methy phenols or the double lauryls of thio-2 acid and 100 parts of solvents are stirred to react 6h at 65 DEG C, obtain
To glutinous shape liquid, non-skid coating is made through filtering in the mixed grinding in grinding machine by glutinous shape liquid and boehmite;
S5: coating processes: the round woven bag of S3 is sent into the inverse roll printing machine equipped with non-skid coating, by anti-skidding painting
Material is coated on woven bag surface, through 105 DEG C of dry solidifications of heat source;
S6: the round woven bag being cured in step S4 bag making: is become into finished product braiding by printing, cutting and sewing
Bag.
Blank control example
The present invention provides a kind of manufacturing method of antiskid Polywoven Bag, comprising the following steps:
S1: drying is blended in raw material: PP GRANULES, calcium carbonate, auxiliary agent being put into dry blender and stir drying;
S2: drawing process: the material after the blending of S1 step is dry enters extruder, the heating and spiral shell by barrel
The shearing of bar and machine barrel is extruded as film by die head molding, after 30-40 DEG C of water is cooling, is cut into embryo silk with blade,
And be stretched to form flat filament by drying-plate, it is coiled that flat filament receives silk by receive silk machine after thermal finalization;
S3: knitting process: by coiled flat filament by circular weaving machine at cylinder-shaped woven bag, by examining, it is qualified to examine
Afterwards, then by winder it winds;
S4: the round woven bag being cured in step S4 bag making: is become into finished product braiding by printing, cutting and sewing
Bag.
Standard GB10006- is respectively referred to woven bag preparation test bars in embodiment 1- embodiment 3, blank comparative example
88 " measuring methods of plastic film and thin slice coefficient of friction " measure the coefficient of friction of woven bag, test by friction coefficient instrument
Method are as follows: take the woven bag sample of 3 8cm × 20cm, the requirement sample that woven bag tries happy and auspicious testing surface answer it is smooth, no wrinkle and
The scar of frictional property may be changed, sample edge is answered round and smooth, and the testing surface of woven bag sample answers free from dust, fingerprint and any
The foreign substance of surface nature may be changed;The status adjustment of sample and the standard environment of test are at 23 ± 2 DEG C of temperature, relatively
It carries out sample status adjustment at least 16 hours under the standard environment of humidity 45%~55%, is then tried under same environment
It tests;The testing surface of one woven bag sample is upward, it is entirely fixed on horizontal bed, woven bag sample and testing stand
Length direction should be parallel;The testing surface of another woven bag sample is downward, sliding block is encased, with adhesive tape in sliding block forward position and upper
Woven bag sample is fixed on surface;The sliding block for being fixed with woven bag sample is placed on first sample center without impact, and makes two
The test direction of sample is parallel with glide direction and dynamometric system does not stress just;15s is kept after two sample contacts, starts instrument
Relatively move two samples.The measurement of coefficient of friction is carried out, as a result such as the following table 1.
The frictional behaviour of table 1 embodiment 1-3 and blank control example
It can be concluded that, embodiment 1-3 at least improves 182.21% compared to the frictional force of blank control example, implementation by table 1
Test result in example 1- embodiment 3 shows with boehmite, silane coupling agent, Si3N4Long stapled content increases, woven bag
Frictional force be constantly to become larger, this is because having Si in anti-skidding outer layer3N4Long fibre and boehmite, Si3N4Long fibre and Bo Mu
Stone is distributed in anti-skidding outer layer forms network structure, and line style and point-type surface bulge are formed in anti-skidding outer layer, increases woven bag
Surface roughness and surface area, to increase the non-skid property and wear-resisting property of woven bag, and boehmite and Si3N4It is long
Fiber, boehmite surface come with reaction active groups Al-OH, therefore boehmite has an excellent dispersion performance, and Si3N4 long
The dispersibility of fiber is poor, can settle in non-skid coating, by adding boehmite, the active group Al-OH of boehmite
With Si3N4The group Si-OH on long fibre surface interacts, and improves dispersibility of the Si3N4 long fibre in anti-skidding binding liquid, from
And improve Si3N4The uniformity that long fibre disperses in anti-slip layer, collaboration improve the coefficient of friction of anti-slip layer, increase woven bag
Anti-skidding uniform performance, collaboration improve the frictional behaviour of woven bag.
Using the thermal conductivity of measuring thermal conductivity instrument test woven bag, tested according to ASTM E1461, disk diameter is
10mm, with a thickness of 3mm, plate heat flow method;Woven bag heat resistance is measured using heat distortion temperature tester, according to GB/T
1634-2004 is tested, and woven bag sample is 10mm × 4mm, load 0.45MPa, is horizontally arranged;It is fired by horizontal vertical
Saggar tests the flame retardant property of woven bag sample, test result such as table 2:
Thermal conductivity, heat resistance, the anti-flammability of table 2 embodiment 1-3 and blank control example
Embodiment 1, embodiment 2 and embodiment 3 are to change boehmite, silane coupling agent, Si3N4Long stapled content is in
The test result of existing Polywoven Bag heating conduction, heat resistance and flame retardant property, wherein with boehmite, silane coupled
Agent, the increase of the long stapled dosage of Si3N4, heating conduction and heat resistance also increase accordingly, this is because boehmite is that have
Composite material thermal resistance can be effectively reduced in the material of layer structure, improve internal heat transfer efficiency, boehmite and Si3N4Long fibre is mutual
Effect forms the thermally conductive network chain of staggeredly combination, effectively augmentation of heat transfer, improve woven bag it is heated when inside heat transference efficiency, mention
The heat dissipation performance and heat resistance of high woven bag also improve heat-sinking capability when woven bag burning, promote the self-extinguishment of woven bag
Flame retardant property, and outer layer of polypropylene, chlorinated polypropylene and polypropylene are bonded in by the non-skid coating of matrix of chlorinated polypropylene
When woven bag contacts, with gravitational attraction polypropylene between the crystallization of identical chemical structure crystallization, to have very strong bonding to polypropylene
Power makes boehmite and Si using silane coupling agent3N4Long fibre and chlorinated polypropylene are crosslinked, and improve the crosslinking of chlorinated polypropylene
Degree, so that the fusing point of chlorinated polypropylene, increases the temperature capacity and stability of the anti-skidding outer layer of woven bag.
In terms of flame retardant property, boehmite content increases, and raising trend is also presented in flame retardant property, wherein in embodiment 2,
Si3N4Long fiber length is longer, and " candle wick effect " easy to form causes woven bag burning, but when the burning of Si3N4 long fibre,
Boehmite is decomposed into aluminium oxide and water, thermal decomposition process heat absorption at high temperature, and the vapor of releasing can dilute flammable gas
Body simultaneously inhibits harmful vapors to generate, and the alumina solid of generation blocks air, promotes burning Si3N4Long stapled extinguishing, shows
Woven bag sample self-gravitation, so boehmite, which can cooperate with, effectively prevents Si while improving non-skid property3N4Long fibre is after afterflame
It burns, improves the flame retardant property of woven bag.
From the aspect of performance and cost, optimal embodiment is embodiment 3.
A kind of manufacturing method of antiskid Polywoven Bag provided by the present invention is described in detail above.Herein
In apply specific embodiment principle and implementation of the present invention are described, the explanation of above example is only intended to
It facilitates the understanding of the method and its core concept of the invention.It should be pointed out that for those skilled in the art,
Without departing from the principles of the invention, can be with several improvements and modifications are made to the present invention, these improvement and modification are also fallen
Enter in the protection scope of the claims in the present invention.
Claims (7)
1. a kind of manufacturing method of antiskid Polywoven Bag, it is characterised in that: the following steps are included:
S1: drying is blended in raw material: PP GRANULES, calcium carbonate, auxiliary agent being put into dry blender and stir drying;
S2: drawing process: the material after the blending of S1 step is dry enters extruder, by the heating of barrel and screw rod with
The shearing of machine barrel is extruded as film by die head molding, after 30-40 DEG C of water is cooling, is cut into embryo silk with blade, and pass through
It crosses drying-plate to be stretched to form flat filament, it is coiled that flat filament receives silk by receive silk machine after thermal finalization;
S3: knitting process: by coiled flat filament by circular weaving machine at cylinder-shaped woven bag, by examining, after the assay was approved, then
It is wound by winder;
S4: non-skid coating is prepared: by chlorinated polypropylene, boehmite, silane coupling agent, Si3N4Long fibre, modified rosin resin, increasing
Modeling agent, antioxidant and solvent are stirred to react 6h at 65 DEG C, glutinous shape liquid are obtained, by glutinous shape liquid and boehmite in grinding machine
Non-skid coating is made through filtering in middle mixed grinding;
S5: coating processes: the round woven bag of S3 is sent into the inverse roll printing machine equipped with non-skid coating, non-skid coating is applied
It is overlying on woven bag surface, through 105 DEG C of dry solidifications of heat source;
S6: the round woven bag being cured in step S4 bag making: is become into finished product woven bag by printing, cutting and sewing.
2. a kind of manufacturing method of antiskid Polywoven Bag according to claim 1, it is characterised in that: the step S4
The weight proportion of middle component are as follows:
3. a kind of manufacturing method of antiskid Polywoven Bag according to claim 1, it is characterised in that: the step S4
The weight proportion of middle component are as follows:
4. a kind of manufacturing method of antiskid Polywoven Bag according to claim 1, it is characterised in that: the Si3N4It is long
The length of fiber is 5-10mm.
5. a kind of manufacturing method of antiskid Polywoven Bag according to claim 1, it is characterised in that: the silane is even
Joining agent is that KH550, KH560 or KH570 are one such or a variety of.
6. a kind of manufacturing method of antiskid Polywoven Bag according to claim 1, it is characterised in that: the boehmite
Diameter be 40-60 mesh.
7. a kind of manufacturing method of antiskid Polywoven Bag according to claim 1, it is characterised in that: described anti-oxidant
Agent is 2,6- di-tert-butyl-4-methy phenol or the double lauryls of thio-2 acid.
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CN201810830602.8A Withdrawn CN109023980A (en) | 2018-07-26 | 2018-07-26 | A kind of manufacturing method of antiskid Polywoven Bag |
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2018
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