CN109023971A - A method of waterproof roll is prepared using waste and old porous ceramics and tire - Google Patents

A method of waterproof roll is prepared using waste and old porous ceramics and tire Download PDF

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Publication number
CN109023971A
CN109023971A CN201810931804.1A CN201810931804A CN109023971A CN 109023971 A CN109023971 A CN 109023971A CN 201810931804 A CN201810931804 A CN 201810931804A CN 109023971 A CN109023971 A CN 109023971A
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China
Prior art keywords
waste
porous ceramics
waterproof roll
old
tire
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CN201810931804.1A
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Chinese (zh)
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赵庆亮
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Maanshan Yonggu Waterproof Technology Co Ltd
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Maanshan Yonggu Waterproof Technology Co Ltd
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Priority to CN201810931804.1A priority Critical patent/CN109023971A/en
Publication of CN109023971A publication Critical patent/CN109023971A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/08—Bituminous material, e.g. asphalt, tar, bitumen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • D—TEXTILES; PAPER
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    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
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    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1692—Weather resistance

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Inorganic Fibers (AREA)

Abstract

The invention discloses a kind of methods for preparing waterproof roll using waste and old porous ceramics and tire, method is simple, it is easy to operate, not only there is wider temperature use scope using the waterproof material for material preparation of coating obtained by the present invention simultaneously, its is ageing-resistant simultaneously, anti-fatigue performance is excellent, and waterproof performance also complies with GB-18242-2008 standard, takes full advantage of waste and old porous ceramics and waste tire, production cost is saved, the utilization of resources is optimized.Porous ceramics is generally used for filtering and field of purification, so waste and old porous ceramics duct has included a large amount of impurity, acid is successively carried out to it to boil, soda boiling, ultrasound, microwave, acetone soak, roast a series of processing, the impurity in ceramic channel walls can sufficiently be removed, open duct, increasing specific surface area, be conducive to treated basalt fiber and form interspersed three-dimensional space network structure into its duct, this spacial framework can effectively transmit stress or dissipation stress, enhance anti-aging, the anti-fatigue performance of target material.

Description

A method of waterproof roll is prepared using waste and old porous ceramics and tire
Technical field
The invention belongs to waterproof material technical fields, especially a kind of to prepare waterproof roll using waste and old porous ceramics and tire The method of material.
Background technique
Building class modified asphalt waterproof coiled material is using polyester fiber non-woven fabric as tire base at present, with SBS (styrene-fourth two Alkene-styrene) modified rubber asphalt sizing material is that tire base invades stain coating, it is invade stain coating anti-with plastic film Viscous separation layer, modified asphalt waterproof coiled material is through selection, ingredient, congruent melting, the processes processing and fabricating such as invade stain, composite molding and curling It forms, has good weatherability, pull resistance, elongation percentage is high, wear-resisting property is good and workability is excellent.But its ingredient is multiple Miscellaneous, higher cost is unfavorable for the sustainable development of resource, wastes more physical resources and financial resources.
Summary of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of side for preparing waterproof roll using waste and old porous ceramics and tire Method.
The invention is realized by the following technical scheme:
A method of waterproof roll is prepared using waste and old porous ceramics and tire, which is characterized in that the waterproof roll packet Include polyester blank, prepreg, material of coating, wherein the material of coating is made of raw material from the following weight: waste and old porous ceramics 3-5, Waste tire 8-10, treated basalt fiber 5-10, ptfe emulsion 5-10, styrene-butadiene-styrene are embedding Section copolymer 3-8, matrix pitch 30-60, rubber 20-30, anti-aging agent 3-6.
Further, the material of coating preparation method the following steps are included:
(1) it after clear water washes clean being utilized after waste and old porous ceramics coarse crushing, is added in hydrochloric acid solution, under boiling conditions, It using ultrasonic treatment 10-20min, is subsequently transferred in sodium hydroxide solution, boils ultrasonic treatment 10-20min, be put into after taking-up In microwave device, then microwave treatment 10-20s places 5-10h at -5~-10 DEG C, 2-3MPa, is washed after taking-up with clear water It to neutrality, is then placed in acetone, impregnates 10-12h, filter and dry at 140-145 DEG C, then be transferred in tube furnace and roasted Burning processing；
(2) waste tire is crushed to partial size after freeze-drying is 10-100 μm, is then added to ptfe emulsion In, 40-50min is stirred at 500-800rpm, and step (1) gains, treated basalt fiber are then added, are warming up to 70- 75 DEG C, continue to stir 2-3h, after then placing 4-5h at 40-45 DEG C, -0.08~-0.1MPa, filtering, and at 80-85 DEG C It is dry；
(3) 10-20min is mixed at 165-170 DEG C, 100-120rpm in matrix pitch and aromatic naphtha, then, step is added Suddenly (2) gains, anti-aging agent continue to stir 30-50min.
Further, step (1) concentration of hydrochloric acid solution is 0.5-1.5mol/L.
Further, step (1) the ultrasonic treatment condition is 400-500W.
Further, step (1) microwave treatment conditions are 1000-1500W.
Further, step (1) the calcination process concrete operations are as follows: in a nitrogen atmosphere, with the rate of 3-4 DEG C/min It is warming up to 230-240 DEG C, 40-50min is roasted, then be warming up to 420-450 DEG C with same rate, roasts 30-40min, then equally It is warming up to 500-510 DEG C, 30-35min is roasted, is then turned off tube furnace power supply, being crushed to partial size after cooled to room temperature is 5-100μm。
Further, step (2) the ptfe emulsion solid content is 15-20%.
Further, step (2) described treated basalt fiber the preparation method comprises the following steps: will be by basalt fibre, titanium dioxide Titanium, zinc oxide are placed in a vacuum drying oven, and at 140-145 DEG C after dry 5-10h, are added it in ethanol solution, After stirring 10-15min under 1000-1100rpm, silane coupling agent is added, continues to stir 30-40min, then utilizes the dilute of 4-6% Salt acid for adjusting pH is stirred to react 3-5h at 85-90 DEG C to 5-6 with the revolving speed of 300-400rpm, filtering, after washing and drying, Be added in polypropylene chip, be heated to polypropylene fusion after mixing, then spinning, collect gained spinning fibre to get Treated basalt fiber.
Beneficial effects of the present invention: the method provided by the invention for preparing waterproof roll using waste and old porous ceramics and tire Simply, easy to operate, while using the waterproof material for material preparation of coating obtained by the present invention not only there is wider temperature to use model It encloses, while its is ageing-resistant, anti-fatigue performance is excellent, waterproof performance also complies with GB-18242-2008 standard, takes full advantage of waste and old Porous ceramics and waste tire save production cost, optimize the utilization of resources.Porous ceramics is generally used for filtering and purifying neck Domain, so waste and old porous ceramics duct has included a large amount of impurity, successively it is carried out acid boil, soda boiling, ultrasound, microwave, acetone It impregnates, roast a series of processing, can sufficiently remove the impurity in ceramic channel walls, open duct, increasing specific surface area is conducive to change Property basalt fibre enter its duct form interspersed three-dimensional space network structure, this spacial framework can be passed effectively Pass stress or dissipation stress, enhance anti-aging, the anti-fatigue performance of target material, at the same also promote treated basalt fiber with The combination of substrate further increases its anti-aging property；Basalt fibre is modified using titanium dioxide and zinc oxide, is changed It is apt to its agglomeration, enhances anti-fatigue performance, and act synergistically, improve the heat resistance and low-temperature tenderness of target material, widen Its temperature use scope.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A method of waterproof roll is prepared using waste and old porous ceramics and tire, which is characterized in that the waterproof roll packet Include polyester blank, prepreg, material of coating, wherein the material of coating is made of raw material from the following weight: waste and old porous ceramics 3 gives up Old tire 8, treated basalt fiber 5, ptfe emulsion 5, styrene-butadiene-styrene block copolymer 3, Matrix pitch 30, rubber 20, anti-aging agent 3.
Further, the material of coating preparation method the following steps are included:
(1) it after clear water washes clean being utilized after waste and old porous ceramics coarse crushing, is added in hydrochloric acid solution, under boiling conditions, It using ultrasonic treatment 10min, is subsequently transferred in sodium hydroxide solution, boils ultrasonic treatment 10min, microwave dress is put into after taking-up In setting, then microwave treatment 10s places 5h at -5 DEG C, 2MPa, is washed with clear water to neutrality after taking-up, is then placed in acetone In, 10h is impregnated, is filtered and dry at 140 DEG C, then be transferred in tube furnace and carry out calcination process；
(2) waste tire is crushed to partial size after freeze-drying is 10 μm, is then added in ptfe emulsion, 40min is stirred under 500rpm, step (1) gains, treated basalt fiber are then added, are warming up to 70 DEG C, continues to stir 2h, Then after placing 4h at 40 DEG C, -0.08MPa, filtering, and it is dry at 80 DEG C；
(3) 10min is mixed at 165 DEG C, 100rpm in matrix pitch and aromatic naphtha, then, be added obtained by step (2) Object, anti-aging agent continue to stir 30min.
Further, step (1) concentration of hydrochloric acid solution is 0.5mol/L.
Further, step (1) the ultrasonic treatment condition is 400W.
Further, step (1) microwave treatment conditions are 1000W.
Further, step (1) the calcination process concrete operations are as follows: in a nitrogen atmosphere, with the rate liter of 3 DEG C/min Temperature roasts 40min to 230 DEG C, then is warming up to 420 DEG C with same rate, roasts 30min, then be equally warming up to 500 DEG C, roasts 30min is then turned off tube furnace power supply, and it is 5 μm that partial size is crushed to after cooled to room temperature.
Further, step (2) the ptfe emulsion solid content is 15%.
Further, step (2) described treated basalt fiber the preparation method comprises the following steps: will be by basalt fibre, titanium dioxide Titanium, zinc oxide are placed in a vacuum drying oven, and at 140 DEG C after dry 5h, are added it in ethanol solution, at 1000rpm After stirring 10min, silane coupling agent is added, continues to stir 30min, then pH to 5 is adjusted using 4% dilute hydrochloric acid, at 85 DEG C Under, 3h is stirred to react with the revolving speed of 300rpm, filter, after washing and drying, be added in polypropylene chip, after mixing plus Heat to polypropylene fusion, then spinning collects gained spinning fibre to get treated basalt fiber.
Embodiment 2
A method of waterproof roll is prepared using waste and old porous ceramics and tire, which is characterized in that the waterproof roll packet Include polyester blank, prepreg, material of coating, wherein the material of coating is made of raw material from the following weight: waste and old porous ceramics 4 gives up Old tire 9, treated basalt fiber 7, ptfe emulsion 8, styrene-butadiene-styrene block copolymer 5, Matrix pitch 50, rubber 25, anti-aging agent 4.
Further, the material of coating preparation method the following steps are included:
(1) it after clear water washes clean being utilized after waste and old porous ceramics coarse crushing, is added in hydrochloric acid solution, under boiling conditions, It using ultrasonic treatment 15min, is subsequently transferred in sodium hydroxide solution, boils ultrasonic treatment 15min, microwave dress is put into after taking-up In setting, then microwave treatment 15s places 7h at -8 DEG C, 2.5MPa, is washed with clear water to neutrality after taking-up, is then placed in third In ketone, 11h is impregnated, is filtered and dry at 143 DEG C, then be transferred in tube furnace and carry out calcination process；
(2) waste tire is crushed to partial size after freeze-drying is 50 μm, is then added in ptfe emulsion, 45min is stirred under 700rpm, step (1) gains, treated basalt fiber are then added, are warming up to 72 DEG C, continues to stir 3h, Then after placing 5h at 43 DEG C, -0.085MPa, filtering, and it is dry at 82 DEG C；
(3) 14min is mixed at 167 DEG C, 110rpm in matrix pitch and aromatic naphtha, then, be added obtained by step (2) Object, anti-aging agent continue to stir 40min.
Further, step (1) concentration of hydrochloric acid solution is 1mol/L.
Further, step (1) the ultrasonic treatment condition is 450W.
Further, step (1) microwave treatment conditions are 1200W.
Further, step (1) the calcination process concrete operations are as follows: in a nitrogen atmosphere, with the rate liter of 4 DEG C/min Temperature roasts 42min to 235 DEG C, then is warming up to 430 DEG C with same rate, roasts 35min, then be equally warming up to 505 DEG C, roasts 32min is then turned off tube furnace power supply, and it is 50 μm that partial size is crushed to after cooled to room temperature.
Further, step (2) the ptfe emulsion solid content is 17%.
Further, step (2) described treated basalt fiber the preparation method comprises the following steps: will be by basalt fibre, titanium dioxide Titanium, zinc oxide are placed in a vacuum drying oven, and at 142 DEG C after dry 8h, are added it in ethanol solution, at 1050rpm After stirring 12min, silane coupling agent is added, continues to stir 35min, then pH to 6 is adjusted using 5% dilute hydrochloric acid, at 88 DEG C Under, 4h is stirred to react with the revolving speed of 350rpm, filter, after washing and drying, be added in polypropylene chip, after mixing plus Heat to polypropylene fusion, then spinning collects gained spinning fibre to get treated basalt fiber.
Embodiment 3
A method of waterproof roll is prepared using waste and old porous ceramics and tire, which is characterized in that the waterproof roll packet Include polyester blank, prepreg, material of coating, wherein the material of coating is made of raw material from the following weight: waste and old porous ceramics 5 gives up Old tire 10, treated basalt fiber 10, ptfe emulsion 10, styrene-butadiene-styrene block copolymer 8, matrix pitch 60, rubber 30, anti-aging agent 6.
Further, the material of coating preparation method the following steps are included:
(1) it after clear water washes clean being utilized after waste and old porous ceramics coarse crushing, is added in hydrochloric acid solution, under boiling conditions, It using ultrasonic treatment 20min, is subsequently transferred in sodium hydroxide solution, boils ultrasonic treatment 20min, microwave dress is put into after taking-up In setting, then microwave treatment 20s places 10h at -10 DEG C, 3MPa, is washed with clear water to neutrality after taking-up, is then placed in third In ketone, 12h is impregnated, is filtered and dry at 145 DEG C, then be transferred in tube furnace and carry out calcination process；
(2) waste tire is crushed to partial size after freeze-drying is 100 μm, is then added in ptfe emulsion, 50min is stirred at 800 rpm, and step (1) gains, treated basalt fiber are then added, is warming up to 75 DEG C, continues to stir 3h, after then placing 5h at 45 DEG C, -0.1MPa, filtering, and it is dry at 85 DEG C；
(3) 20min is mixed at 170 DEG C, 120rpm in matrix pitch and aromatic naphtha, then, be added obtained by step (2) Object, anti-aging agent continue to stir 50min.
Further, step (1) concentration of hydrochloric acid solution is 1.5mol/L.
Further, step (1) the ultrasonic treatment condition is 500W.
Further, step (1) microwave treatment conditions are 1500W.
Further, step (1) the calcination process concrete operations are as follows: in a nitrogen atmosphere, with the rate liter of 4 DEG C/min Temperature roasts 50min to 240 DEG C, then is warming up to 450 DEG C with same rate, roasts 40min, then be equally warming up to 510 DEG C, roasts 35min is then turned off tube furnace power supply, and it is 100 μm that partial size is crushed to after cooled to room temperature.
Further, step (2) the ptfe emulsion solid content is 20%.
Further, step (2) described treated basalt fiber the preparation method comprises the following steps: will be by basalt fibre, titanium dioxide Titanium, zinc oxide are placed in a vacuum drying oven, and at 145 DEG C after dry 10h, are added it in ethanol solution, at 1100rpm After stirring 15min, silane coupling agent is added, continues to stir 40min, then pH to 6 is adjusted using 6% dilute hydrochloric acid, at 90 DEG C Under, 5h is stirred to react with the revolving speed of 400rpm, filter, after washing and drying, be added in polypropylene chip, after mixing plus Heat to polypropylene fusion, then spinning collects gained spinning fibre to get treated basalt fiber.
Comparative example 1
This comparative example is omitted step (1) to the operation processing step of waste and old porous ceramics, removes this compared to embodiment 2 Except method and step it is all the same.
Comparative example 2
This comparative example replaces treated basalt fiber compared to embodiment 2, with basalt fibre, method step in addition to this It is rapid all the same.
Comparative example 3
The addition of titanium dioxide is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is all the same.
Comparative example 4
The addition of zinc oxide is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is all the same.
Performance test:
To coat obtained by each embodiment and comparative example material and polyester blank, prepreg, polyethylene film it is dry by polyester blank, Prepreg extracts, coats material of coating, cover isolated material and cooling and waterproof material is made in curling, and measures gained waterproof material Performance, test result are as shown in table 1:
Table 1
As can be seen from Table 1, not only there is wider temperature using the waterproof material of the material preparation of coating prepared obtained by the present invention Use scope, while its is ageing-resistant, anti-fatigue performance is excellent, waterproof performance also complies with GB-18242-2008 standard, makes full use of Waste and old porous ceramics and waste tire save production cost, optimize the utilization of resources.

Claims (8)

1. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire, which is characterized in that the waterproof roll Including polyester blank, prepreg, material of coating, wherein the material of coating is made of raw material from the following weight: waste and old porous ceramics 3- 5, waste tire 8-10, treated basalt fiber 5-10, ptfe emulsion 5-10, styrene-butadiene-styrene Block copolymer 3-8, matrix pitch 30-60, rubber 20-30, anti-aging agent 3-6.
2. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 1, feature Be, the preparation method of the material of coating the following steps are included:
(1) it after clear water washes clean being utilized after waste and old porous ceramics coarse crushing, is added in hydrochloric acid solution, under boiling conditions, It using ultrasonic treatment 10-20min, is subsequently transferred in sodium hydroxide solution, boils ultrasonic treatment 10-20min, be put into after taking-up In microwave device, then microwave treatment 10-20s places 5-10h at -5~-10 DEG C, 2-3MPa, is washed after taking-up with clear water It to neutrality, is then placed in acetone, impregnates 10-12h, filter and dry at 140-145 DEG C, then be transferred in tube furnace and roasted Burning processing；
(2) waste tire is crushed to partial size after freeze-drying is 10-100 μm, is then added to ptfe emulsion In, 40-50min is stirred at 500-800rpm, and step (1) gains, treated basalt fiber are then added, are warming up to 70- 75 DEG C, continue to stir 2-3h, after then placing 4-5h at 40-45 DEG C, -0.08~-0.1MPa, filtering, and at 80-85 DEG C It is dry；
(3) 10-20min is mixed at 165-170 DEG C, 100-120rpm in matrix pitch and aromatic naphtha, then, step is added Suddenly (2) gains, anti-aging agent continue to stir 30-50min.
3. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 2, feature It is, step (1) concentration of hydrochloric acid solution is 0.5-1.5mol/L.
4. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 2, feature It is, step (1) the ultrasonic treatment condition is 400-500W.
5. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 2, feature It is, step (1) microwave treatment conditions are 1000-1500W.
6. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 2, feature It is, step (1) the calcination process concrete operations are as follows: in a nitrogen atmosphere, 230- is warming up to the rate of 3-4 DEG C/min 240 DEG C, 40-50min is roasted, then be warming up to 420-450 DEG C with same rate, roast 30-40min, then be equally warming up to 500- 510 DEG C, 30-35min is roasted, tube furnace power supply is then turned off, it is 5-100 μm that partial size is crushed to after cooled to room temperature.
7. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 2, feature It is, step (2) the ptfe emulsion solid content is 15-20%.
8. a kind of method for preparing waterproof roll using waste and old porous ceramics and tire according to claim 2, feature Be, step (2) described treated basalt fiber the preparation method comprises the following steps: basalt fibre, titanium dioxide, zinc oxide will be placed in In vacuum oven, at 140-145 DEG C after dry 5-10h, adds it in ethanol solution, stirred at 1000-1100rpm After mixing 10-15min, silane coupling agent is added, continues to stir 30-40min, then adjusts pH to 5-6 using the dilute hydrochloric acid of 4-6%, At 85-90 DEG C, 3-5h is stirred to react with the revolving speed of 300-400rpm, filters, after washing and drying, is added to polypropylene chip In, it is heated to polypropylene fusion after mixing, then spinning, collects gained spinning fibre to get treated basalt fiber.
CN201810931804.1A 2018-08-16 2018-08-16 A method of waterproof roll is prepared using waste and old porous ceramics and tire Pending CN109023971A (en)

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CN114436674A (en) * 2022-02-11 2022-05-06 洛阳理工学院 Preparation method of network-like silicon carbide fiber

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CN107022128A (en) * 2017-04-13 2017-08-08 安徽世界村新材料有限公司 A kind of preparation method of waste old modified composite material
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