CN109021399A - A kind of fiber-reinforced plastic and preparation method thereof - Google Patents
A kind of fiber-reinforced plastic and preparation method thereof Download PDFInfo
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- CN109021399A CN109021399A CN201810967053.9A CN201810967053A CN109021399A CN 109021399 A CN109021399 A CN 109021399A CN 201810967053 A CN201810967053 A CN 201810967053A CN 109021399 A CN109021399 A CN 109021399A
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- antibacterial agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/325—Calcium, strontium or barium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to a kind of fiber-reinforced plastic, the raw material including following parts by weight: 90-110 parts of polypropylene, 4-6 parts of metallocene PE, 3-5 parts of epoxidized soybean oil, 4-7 parts of three polyglycerol, 2-4 parts of vinyltriethoxysilane, 2-4 parts of calcium phosphate, 3-6 parts of basalt fibre, 3-6 parts of glass fibre, 2-5 parts of silicon nitride, 3-6 parts of tourmaline, 10-16 parts of antibacterial agent, 1-3 parts of fire retardant, 1-3 parts of antioxidant.Plastics of the present invention increase the intensity of plastics by the way that basalt fibre, glass fibre etc. is added；By the way that zinc borate is added as fire retardant, plastics inflammable disadvantage in use is prevented, the safety of plastics is improved；By the way that the antibacterial agent of nano cupric oxide, nano zeolite, nano-titanium dioxide composition is added, play the role of inhibition or kills bacterium, avoids bacterium and bred on plastics.
Description
Technical field
The present invention relates to plastics and preparation method thereof, and in particular to a kind of fiber-reinforced plastic and preparation method thereof.
Background technique
Plastics are seen everywhere in daily life, for example the holding vessel major part of some solids, liquid is all plastics system
Product.It is very big convenient that plastics are brought to people's lives, and with the extensive use of plastics, some disadvantages of plastics are also just sudden and violent therewith
Dew.Such as the requirement used is far not achieved in the intensity of most plastic products, which limits further using for plastics.Separately
Outside, plastic applications also have certain requirement when food service industry to its antibiotic property.
Summary of the invention
It is an object of the invention to: a kind of fiber-reinforced plastic and preparation method thereof is provided.
To achieve the goals above, the invention provides the following technical scheme:
A kind of fiber-reinforced plastic, the raw material including following parts by weight:
90-110 parts of polypropylene, 4-6 parts of metallocene PE, 3-5 parts of epoxidized soybean oil, 4-7 parts of three polyglycerol, ethylene
2-4 parts of ethyl triethoxy silicane alkane, 2-4 parts of calcium phosphate, 3-6 parts of basalt fibre, 3-6 parts of glass fibre, 2-5 parts of silicon nitride, electricity
3-6 parts of gas stone, 10-16 parts of antibacterial agent, 1-3 parts of fire retardant, 1-3 parts of antioxidant.
Preferably, a kind of fiber-reinforced plastic, the raw material including following parts by weight:
102 parts of polypropylene, 5 parts of metallocene PE, 4 parts of epoxidized soybean oil, 5 parts of three polyglycerol, three ethoxy of vinyl
3 parts of base silane, 3 parts of calcium phosphate, 4 parts of basalt fibre, 5 parts of glass fibre, 3 parts of silicon nitride, 5 parts of tourmaline, 12 parts of antibacterial agent,
2 parts of fire retardant, 2 parts of antioxidant.
Preferably, the antibacterial agent is the mixture of nano cupric oxide, nano zeolite, nano-titanium dioxide.
Preferably, nano cupric oxide in the antibacterial agent, nano zeolite, nano-titanium dioxide mass ratio be 1:(3-
5):(2-4)。
Preferably, nano cupric oxide in the antibacterial agent, nano zeolite, nano-titanium dioxide mass ratio be 1:4:3.
Preferably, the fire retardant is zinc borate.
Preferably, the antioxidant is Hinered phenols antioxidant.
A kind of preparation method of fiber-reinforced plastic weighs each raw material according to the ratio, mixing, melting mixing, extruding pelletization
?.
The beneficial effects of the present invention are:
Plastics of the present invention increase the intensity of plastics by the way that basalt fibre, glass fibre etc. is added；By the way that boric acid is added
Zinc prevents plastics inflammable disadvantage in use, improves the safety of plastics as fire retardant；By the way that nano oxygen is added
The antibacterial agent for changing copper, nano zeolite, nano-titanium dioxide composition plays the role of inhibition or kills bacterium, avoids bacterium and exist
It is bred on plastics.
Specific embodiment
Embodiment 1
A kind of fiber-reinforced plastic, the raw material including following parts by weight:
90 parts of polypropylene, 4 parts of metallocene PE, 3 parts of epoxidized soybean oil, 4 parts of three polyglycerol, vinyl triethoxyl
2 parts of silane, 2 parts of calcium phosphate, 3 parts of basalt fibre, 3 parts of glass fibre, 2 parts of silicon nitride, 3 parts of tourmaline, 10 parts of antibacterial agent, boron
1 part of sour zinc, 1 part of Hinered phenols antioxidant.
Antibacterial agent is made of nano cupric oxide, nano zeolite, the nano-titanium dioxide that mass ratio is 1:3:4.
The preparation method of above-mentioned fiber-reinforced plastic is to weigh each raw material according to the ratio, is mixed, melting mixing, extruding pelletization
?.
Embodiment 2
A kind of fiber-reinforced plastic, the raw material including following parts by weight:
102 parts of polypropylene, 5 parts of metallocene PE, 4 parts of epoxidized soybean oil, 5 parts of three polyglycerol, three ethoxy of vinyl
3 parts of base silane, 3 parts of calcium phosphate, 4 parts of basalt fibre, 5 parts of glass fibre, 3 parts of silicon nitride, 5 parts of tourmaline, 12 parts of antibacterial agent,
2 parts of zinc borate, 2 parts of Hinered phenols antioxidant.
Antibacterial agent is made of nano cupric oxide, nano zeolite, the nano-titanium dioxide that mass ratio is 1:4:3.
The preparation method of above-mentioned fiber-reinforced plastic is to weigh each raw material according to the ratio, is mixed, melting mixing, extruding pelletization
?.
Embodiment 3
A kind of fiber-reinforced plastic, the raw material including following parts by weight:
110 parts of polypropylene, 6 parts of metallocene PE, 5 parts of epoxidized soybean oil, 7 parts of three polyglycerol, three ethoxy of vinyl
4 parts of base silane, 4 parts of calcium phosphate, 6 parts of basalt fibre, 6 parts of glass fibre, 5 parts of silicon nitride, 6 parts of tourmaline, 16 parts of antibacterial agent,
3 parts of zinc borate, 3 parts of Hinered phenols antioxidant.
Antibacterial agent is made of nano cupric oxide, nano zeolite, the nano-titanium dioxide that mass ratio is 1:5:2.
The preparation method of above-mentioned fiber-reinforced plastic is to weigh each raw material according to the ratio, is mixed, melting mixing, extruding pelletization
?.
Comparative example 1
Nano cupric oxide, nano zeolite, the nano-titanium dioxide for being 1:4:3 by mass ratio by the antibacterial agent in embodiment 2
It is nano cupric oxide that composition, which replaces with antibacterial agent, other formulas and preparation method are all constant.
Comparative example 2
Nano cupric oxide, nano zeolite, the nano-titanium dioxide for being 1:4:3 by mass ratio by the antibacterial agent in embodiment 2
It is nano-titanium dioxide that composition, which replaces with antibacterial agent, other formulas and preparation method are all constant.
Comparative example 3
Nano cupric oxide, nano zeolite, the nano-titanium dioxide for being 1:4:3 by mass ratio by the antibacterial agent in embodiment 2
Composition replaces with antibacterial agent and is made of nano cupric oxide, the nano zeolite that mass ratio is 1:4, other formulas and preparation method are not
Become.
Comparative example 4
Nano cupric oxide, nano zeolite, the nano-titanium dioxide for being 1:4:3 by mass ratio by the antibacterial agent in embodiment 2
Composition replaces with antibacterial agent and is made of nano cupric oxide, the nano-titanium dioxide that mass ratio is 1:3, other formulas and preparation method
It is all constant.
Comparative example 5
Nano cupric oxide, nano zeolite, the nano-titanium dioxide for being 1:4:3 by mass ratio by the antibacterial agent in embodiment 2
Composition replaces with antibacterial agent and is made of nano zeolite, the nano-titanium dioxide that mass ratio is 4:3, other formulas and preparation method are all
It is constant.
Antibacterial test is carried out to plastics obtained by embodiment 1-3 and comparative example 1-5, anti-microbial property presses " QB/T 2591-
2003 antibiotic plastic test method of antibacterial performance and antibacterial effect " test method as defined in standard tested, bacteriologic test bacterium
Kind be staphylococcus aureus, Escherichia coli, as a result as shown in the table:
| Staphylococcus aureus | Escherichia coli | |
| Embodiment 1 | 99.4% | 99.2% |
| Embodiment 2 | 99.5% | 99.6% |
| Embodiment 3 | 99.3% | 99.2% |
| Comparative example 1 | 70.5% | 66.5% |
| Comparative example 2 | 65.3% | 66.7% |
| Comparative example 3 | 72.5% | 71.8% |
| Comparative example 4 | 76.9% | 77.7% |
| Comparative example 5 | 70.9% | 72.4% |
As can be seen from the table: the anti-microbial property of the plastics of the embodiment of the present invention is apparently higher than comparative example, has good
Good anti-microbial property, meets the requirement of long acting antibiotic.
Claims (8)
1. a kind of fiber-reinforced plastic, it is characterised in that: the raw material including following parts by weight:
90-110 parts of polypropylene, 4-6 parts of metallocene PE, 3-5 parts of epoxidized soybean oil, 4-7 parts of three polyglycerol, vinyl three
2-4 parts of Ethoxysilane, 2-4 parts of calcium phosphate, 3-6 parts of basalt fibre, 3-6 parts of glass fibre, 2-5 parts of silicon nitride, tourmaline
3-6 parts, 10-16 parts of antibacterial agent, 1-3 parts of fire retardant, 1-3 parts of antioxidant.
2. a kind of fiber-reinforced plastic according to claim 1, it is characterised in that: the raw material including following parts by weight:
102 parts of polypropylene, 5 parts of metallocene PE, 4 parts of epoxidized soybean oil, 5 parts of three polyglycerol, vinyl triethoxyl silicon
It is 3 parts of alkane, 3 parts of calcium phosphate, 4 parts of basalt fibre, 5 parts of glass fibre, 3 parts of silicon nitride, 5 parts of tourmaline, 12 parts of antibacterial agent, fire-retardant
2 parts of agent, 2 parts of antioxidant.
3. a kind of fiber-reinforced plastic according to claim 1, it is characterised in that: the antibacterial agent is nano oxidized
Copper, nano zeolite, nano-titanium dioxide mixture.
4. a kind of fiber-reinforced plastic according to claim 3, it is characterised in that: nano oxidized in the antibacterial agent
Copper, nano zeolite, nano-titanium dioxide mass ratio be 1:(3-5): (2-4).
5. a kind of fiber-reinforced plastic according to claim 4, it is characterised in that: nano oxidized in the antibacterial agent
Copper, nano zeolite, nano-titanium dioxide mass ratio be 1:4:3.
6. a kind of fiber-reinforced plastic according to claim 1, it is characterised in that: the fire retardant is zinc borate.
7. a kind of fiber-reinforced plastic according to claim 1, it is characterised in that: the antioxidant is anti-for Hinered phenols
Oxygen agent.
8. a kind of preparation method of fiber-reinforced plastic described in -7 any one according to claim 1, it is characterised in that: press
Proportion weighs each raw material, mixes, melting mixing, extruding pelletization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810967053.9A CN109021399A (en) | 2018-08-23 | 2018-08-23 | A kind of fiber-reinforced plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810967053.9A CN109021399A (en) | 2018-08-23 | 2018-08-23 | A kind of fiber-reinforced plastic and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109021399A true CN109021399A (en) | 2018-12-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810967053.9A Pending CN109021399A (en) | 2018-08-23 | 2018-08-23 | A kind of fiber-reinforced plastic and preparation method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114375968A (en) * | 2022-01-24 | 2022-04-22 | 河南科技大学 | Self-curing non-toxic antibacterial material and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0427858A1 (en) * | 1989-02-28 | 1991-05-22 | Kanebo Ltd. | Antibacterial or conductive composition and applications thereof |
| CN1539874A (en) * | 2003-04-22 | 2004-10-27 | 陈建强 | Antibacterial, keeping foodstuff fresh, uvioresistant plastic fabricated from Nano material |
| CN101592271A (en) * | 2009-06-11 | 2009-12-02 | 周锦彪 | Environment-friendly water-supply hose with antibacterial functions |
| CN103289201A (en) * | 2013-06-21 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Indoor sport floor surface material |
| CN106957168A (en) * | 2017-02-28 | 2017-07-18 | 韦尧天 | One kind can antibiotic ceramic tile and preparation method thereof |
-
2018
- 2018-08-23 CN CN201810967053.9A patent/CN109021399A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0427858A1 (en) * | 1989-02-28 | 1991-05-22 | Kanebo Ltd. | Antibacterial or conductive composition and applications thereof |
| CN1539874A (en) * | 2003-04-22 | 2004-10-27 | 陈建强 | Antibacterial, keeping foodstuff fresh, uvioresistant plastic fabricated from Nano material |
| CN101592271A (en) * | 2009-06-11 | 2009-12-02 | 周锦彪 | Environment-friendly water-supply hose with antibacterial functions |
| CN103289201A (en) * | 2013-06-21 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Indoor sport floor surface material |
| CN106957168A (en) * | 2017-02-28 | 2017-07-18 | 韦尧天 | One kind can antibiotic ceramic tile and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114375968A (en) * | 2022-01-24 | 2022-04-22 | 河南科技大学 | Self-curing non-toxic antibacterial material and preparation method and application thereof |
| CN114375968B (en) * | 2022-01-24 | 2023-09-26 | 河南科技大学 | Self-curing nontoxic antibacterial material and preparation method and application thereof |
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Application publication date: 20181218 |
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