CN109021362A - A kind of anti-oxidant insulating materials - Google Patents

A kind of anti-oxidant insulating materials Download PDF

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Publication number
CN109021362A
CN109021362A CN201810951466.8A CN201810951466A CN109021362A CN 109021362 A CN109021362 A CN 109021362A CN 201810951466 A CN201810951466 A CN 201810951466A CN 109021362 A CN109021362 A CN 109021362A
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CN
China
Prior art keywords
polyurethane
accounts
gross mass
insulating materials
mass percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810951466.8A
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Chinese (zh)
Inventor
张倩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Research And Development Corp Mstar Technology Ltd
Original Assignee
Suzhou Research And Development Corp Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Research And Development Corp Mstar Technology Ltd filed Critical Suzhou Research And Development Corp Mstar Technology Ltd
Priority to CN201810951466.8A priority Critical patent/CN109021362A/en
Publication of CN109021362A publication Critical patent/CN109021362A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of anti-oxidant insulating materials, including base polyethylene, it is mixed with phenolic resin, styrene, polyurethane, curing agent, adhesive and hindered phenol antioxidant in the polyvinyl body, the mass percent of gross mass is 80%-99%, to account for the mass percent of gross mass be 0.5%-19% to the phenolic resin wherein the polyethylene accounts for.Anti-oxidant insulating materials of the invention can be used for the external insulation of cable, has good antioxygenic property, is able to extend the service life of cable.

Description

A kind of anti-oxidant insulating materials
Technical field
The present invention relates to a kind of anti-oxidant insulating materials.
Background technique
Cable is a kind of common industrial products, is widely used in conductive and signal communication, and cable is usually by intermediate The insulating layer composition of wire and external package.External insulating layer exposing in air, under the irradiation of temperature and sunlight, is held Easily slowly oxidation and aging, and then influence the service life of cable.Therefore the antioxygenic property of cable insulation layer makes concerning to cable Use the service life.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of anti-oxidant insulating materials, the anti-oxidant insulating materials is available In the external insulation of cable, there is good antioxygenic property, be able to extend the service life of cable.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of anti-oxidant insulating materials is provided, It includes base polyethylene, be mixed in the polyvinyl body phenolic resin, styrene, polyurethane, curing agent, adhesive and Hindered phenol antioxidant, wherein the polyethylene accounts for, the mass percent of gross mass is 80%-99%, the phenolic resin accounts for total matter The mass percent of amount is 0.5%-19%.
In a preferred embodiment of the present invention, the polyurethane is acroleic acid polyurethane, alcohol acid and polyurethane, the poly- ammonia of polyester One of ester, polyether-polyurethane, epoxy polyurethane.
In a preferred embodiment of the present invention, the hindered phenol antioxidant is sulphur union II phenol.
In a preferred embodiment of the present invention, it is 85% that the polyethylene, which accounts for the mass percent of gross mass, the phenolic aldehyde The mass percent that resin accounts for gross mass is 12%, and the mass percent that the styrene accounts for gross mass is 1%, and the polyurethane accounts for The mass percent of gross mass is 1%, and the mass percent that the curing agent accounts for gross mass is 0.2%, and the adhesive accounts for total matter The mass percent of amount is 0.2%, and the mass percent that the hindered phenol antioxidant accounts for gross mass is 0.6%.
The beneficial effects of the present invention are: anti-oxidant insulating materials of the invention can be used for the external insulation of cable, have Good antioxygenic property is able to extend the service life of cable.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The embodiment of the present invention:
Anti-oxidant insulating materials of the invention includes base polyethylene, and phenolic resin, benzene second are mixed in the polyvinyl body Alkene, polyurethane, curing agent, adhesive and hindered phenol antioxidant, wherein the mass percent that the polyethylene accounts for gross mass is The mass percent that 80%-99%, the phenolic resin account for gross mass is 0.5%-19%.
Preferably, the polyurethane is acroleic acid polyurethane, alcohol acid and polyurethane, polyester-polyurethane, polyether-polyurethane, epoxy One of polyurethane.
Preferably, the hindered phenol antioxidant is sulphur union II phenol.Sulphur union II phenol makes material have good inoxidizability Can, so that material is not allowed oxidizable and aging in air, is able to extend the service life of cable.
Preferably, it is 85% that the polyethylene, which accounts for the mass percent of gross mass, and the phenolic resin accounts for the quality of gross mass Percentage is 12%, and the mass percent that the styrene accounts for gross mass is 1%, and the polyurethane accounts for the mass percent of gross mass It is 1%, the mass percent that the curing agent accounts for gross mass is 0.2%, and the mass percent that the adhesive accounts for gross mass is 0.2%, the mass percent that the hindered phenol antioxidant accounts for gross mass is 0.6%.It is this match make material insulation performance and Antioxygenic property and mechanical performance reach good balance.
Polyethylene and phenolic resin have good insulation performance, can be used for the external insulation layer of cable.Polyurethane can The mechanical performance of material is improved, there is good hardness.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (4)

1. a kind of anti-oxidant insulating materials, which is characterized in that including base polyethylene, be mixed with phenolic aldehyde in the polyvinyl body Resin, styrene, polyurethane, curing agent, adhesive and hindered phenol antioxidant, wherein the polyethylene accounts for the quality of gross mass Percentage is 80%-99%, to account for the mass percent of gross mass be 0.5%-19% to the phenolic resin.
2. anti-oxidant insulating materials according to claim 1, which is characterized in that the polyurethane be acroleic acid polyurethane, One of alcohol acid and polyurethane, polyester-polyurethane, polyether-polyurethane, epoxy polyurethane.
3. anti-oxidant insulating materials according to claim 1 or 2, which is characterized in that the hindered phenol antioxidant is sulphur Union II phenol.
4. anti-oxidant insulating materials according to claim 3, which is characterized in that the polyethylene accounts for the quality hundred of gross mass Divide than being 85%, the mass percent that the phenolic resin accounts for gross mass is 12%, and the styrene accounts for the quality percentage of gross mass Than being 1%, the mass percent that the polyurethane accounts for gross mass is 1%, and the mass percent that the curing agent accounts for gross mass is 0.2%, the mass percent that the adhesive accounts for gross mass is 0.2%, and the hindered phenol antioxidant accounts for the quality hundred of gross mass Divide than being 0.6%.
CN201810951466.8A 2018-08-21 2018-08-21 A kind of anti-oxidant insulating materials Withdrawn CN109021362A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810951466.8A CN109021362A (en) 2018-08-21 2018-08-21 A kind of anti-oxidant insulating materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810951466.8A CN109021362A (en) 2018-08-21 2018-08-21 A kind of anti-oxidant insulating materials

Publications (1)

Publication Number Publication Date
CN109021362A true CN109021362A (en) 2018-12-18

Family

ID=64626435

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810951466.8A Withdrawn CN109021362A (en) 2018-08-21 2018-08-21 A kind of anti-oxidant insulating materials

Country Status (1)

Country Link
CN (1) CN109021362A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030158314A1 (en) * 2002-01-23 2003-08-21 Abu-Isa Ismat A. Intumescent fire retardant composition and method of manufacture thereof
CN101367973A (en) * 2008-10-09 2009-02-18 上海交通大学 Preparation method for high-strength heat-proof polythene composite material
CN102746609A (en) * 2012-06-04 2012-10-24 安徽扬天塑业科技有限公司 Environment-friendly cable material and its preparation method
CN105602075A (en) * 2016-03-22 2016-05-25 安徽渡江电缆集团有限公司 High-flame-retardant modified phenolic resin cable material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030158314A1 (en) * 2002-01-23 2003-08-21 Abu-Isa Ismat A. Intumescent fire retardant composition and method of manufacture thereof
CN101367973A (en) * 2008-10-09 2009-02-18 上海交通大学 Preparation method for high-strength heat-proof polythene composite material
CN102746609A (en) * 2012-06-04 2012-10-24 安徽扬天塑业科技有限公司 Environment-friendly cable material and its preparation method
CN105602075A (en) * 2016-03-22 2016-05-25 安徽渡江电缆集团有限公司 High-flame-retardant modified phenolic resin cable material

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Application publication date: 20181218