CN109016750A - A kind of polyethylene embossing packaging film and its production technology - Google Patents

A kind of polyethylene embossing packaging film and its production technology Download PDF

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Publication number
CN109016750A
CN109016750A CN201810831302.1A CN201810831302A CN109016750A CN 109016750 A CN109016750 A CN 109016750A CN 201810831302 A CN201810831302 A CN 201810831302A CN 109016750 A CN109016750 A CN 109016750A
Authority
CN
China
Prior art keywords
polyethylene
ldpe
low density
density polyethylene
packaging film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810831302.1A
Other languages
Chinese (zh)
Inventor
胡忠立
汪学文
查显宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huangshan Novel Co Ltd
Original Assignee
Huangshan Novel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huangshan Novel Co Ltd filed Critical Huangshan Novel Co Ltd
Priority to CN201810831302.1A priority Critical patent/CN109016750A/en
Publication of CN109016750A publication Critical patent/CN109016750A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C69/00Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore
    • B29C69/02Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore of moulding techniques only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/31Heat sealable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00Packaging equipment or accessories not otherwise provided for

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)

Abstract

The present invention relates to a kind of polyethylene embossing packaging film and its production technologies.The polyethylene embosses packaging film by carrying out embossed acquisition after the heated softening of polyvinyl blow molding, the polyvinyl blow molding includes corona layer, middle layer and hot sealing layer, the corona layer includes 48~52wt.% low density polyethylene (LDPE) (LDPE) and 48~52wt.% linear low density polyethylene (LLDPE), the middle layer includes linear low density polyethylene (LLDPE), and the hot sealing layer includes 32~36wt.% low density polyethylene (LDPE) (LDPE) and 64~68wt.% linear low density polyethylene (LLDPE).Polyethylene embossing packaging film of the present invention can show good stiffness effect, mist degree effect, heat seal strength, impact strength and other excellent physical mechanical properties with higher etc. compared to curtain coating graining film.

Description

A kind of polyethylene embossing packaging film and its production technology
Technical field
The invention belongs to technology field of membrane materials, it is specifically related to a kind of polyethylene embossing packaging film and its production technology.
Background technique
With the promotion of people's quality of life, consumer is not concerned only with product when buying the products such as daily necessities Brand effect, while to the packaging of product also growing interest.Country's composite soft packaging material makes rapid progress at present, and packaging is increasingly Thus fineness more attracts the attention of consumer.In order to effectively prevent product to be imitated, many manufacturing enterprises and packaging enterprise Industry takes great effort in anti-fake direction.Currently, the graining film with antifalse effect used that circulates in the market is all made of The tape casting production.Casting films are that a kind of tensionless winkler foundation of quenching production, the cast film of non-directional are cast by melt, are divided into simple Curtain coating and multi-layer co-extruded two kinds of curtain coating.Used graining film mostly uses online curtain coating embossing mode to obtain currently on the market, should Production method are as follows: by calibrator after film cooling, then carry out Corona Surface Treatment and embossing, then the mistake of trimming winding Journey.This mode does not have heating device in embossing, and film embosses after curtain coating is cooling, and this mode is highly vulnerable to breakage film Physical structure, and higher (general at least two space of a whole page) is lost in which.The major defect of curtain coating mode graining film is that material is soft It is soft, stiffness effect is poor, impact strength is poor, film clarity is higher, and film heat sealability is general (not high pressure resistant).
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of polyethylene embossing packaging film and its production technologies.
In order to achieve the object of the present invention, the invention adopts the following technical scheme:
A kind of polyethylene embossing packaging film, the polyethylene emboss packaging film by being pressed after the heated softening of polyvinyl blow molding Line processing obtains, and the polyvinyl blow molding includes corona layer, middle layer and hot sealing layer, and the corona layer includes 48~ 52wt.% low density polyethylene (LDPE) (LDPE) and 48~52wt.% linear low density polyethylene (LLDPE), the middle layer packet Include linear low density polyethylene (LLDPE), the hot sealing layer include 32~36wt.% low density polyethylene (LDPE) (LDPE) and 64~ 68wt.% linear low density polyethylene (LLDPE).
Preferred embodiment: the corona layer includes 50wt.% low density polyethylene (LDPE) (LDPE) and 50wt.% linea low density Polyethylene (LLDPE), the hot sealing layer include that 34wt.% low density polyethylene (LDPE) (LDPE) and 66wt.% linea low density are poly- Ethylene (LLDPE).
Further scheme: the low density polyethylene (LDPE) (LDPE) in the corona layer and hot sealing layer is SUMITOMO CHEMICAL production and grain The sub- trade mark is the product of L420, and the linear low density polyethylene (LLDPE) in the corona layer and hot sealing layer is raw for Dow Produce and the particle trade mark be the product of 2045G, the linear low density polyethylene (LLDPE) of the middle layer be Dow produce and The particle trade mark is the product of 5538G.
Further scheme: the corona layer of the polyvinyl blow molding with a thickness of 12 microns, intermediate layer thickness be 16 microns, heat-sealing Layer is with a thickness of 12 microns;The polyethylene embossing packaging film is with a thickness of 50 microns.
A kind of production technology of the polyethylene embossing packaging film, including following procedure of processing:
Step 1, the raw particles of the corona layer, middle layer and hot sealing layer are added separately to melt in extruder and are squeezed Out, by obtaining the polyvinyl blow molding after blown film, cooling and shaping;
Step 2, the polyvinyl blow molding unreels and passes through after heating roller reaches softening point and embossed again by dandy roll Processing carries out cooling treatment by chill roll later and obtains the polyethylene embossing packaging film.
The beneficial effects of the present invention are:
(1) polyethylene embossing packaging film of the present invention is by carrying out embossed acquisition after the heated softening of polyvinyl blow molding, originally Invention polyethylene, which embosses packaging film, can show good stiffness effect, mist degree effect compared to curtain coating graining film, have higher Heat seal strength, impact strength and other excellent physical mechanical properties etc..
(2) LDPE in corona layer of the present invention makes polyethylene embossing packaging film have good flattening effect, good Surface corona treatment effect, it is ensured that the planarization of film;The middle layer can both have been mentioned using the metallocene LLDPE of middle-high density The stiffness effect of polyethylene embossing packaging film entirety is risen, and the good heat seal strength of hot sealing layer can be supported;The hot sealing layer makes The heat seal strength of internal layer can be improved with metallocene LLDPE, to prevent appearance fried packet, bale broken etc. in film use process from asking Topic.
(3) present invention uses the thickness ratio of 1:1.25:1, and the higher key of intermediate layer thickness ratio is can be big The big stiffness for promoting polyethylene embossing packaging film supports effect, it can effective to improve polyethylene embossing packaging film single side curling Phenomenon, and it is easy to batch machining production.
(4) polyethylene embossing packaging film of the present invention embosses method using offline hot pressing, i.e., reaches soft by heating roller in film It is embossed again after changing point, the physical structure that can be very good protective film in this way (relative to cold pressing mode, can destroy film Physical structure), and do not change the physical mechanical property of film, to reach a kind of concave-convex effect.In embossing processes can by pair The surface treatment of dandy roll, forms the figure line effect of certain rule in film embossing, to play a kind of anti-fake function well Energy.
Detailed description of the invention
Fig. 1 is production process route figure of the present invention.
Fig. 2 is embossed cotton schematic device.
Attached meaning marked in the figure is as follows:
11- let off roll;12- heating roller;13- pressure roller;14- dandy roll;15- chill roll;16- wind-up roll.
Specific embodiment
More specific detail is made to technical solution of the present invention below with reference to embodiment.
Raw materials used source is as shown in table 1 below in following embodiment:
Table 1
The production technology of polyethylene embossing packaging film of the present invention, including following procedure of processing:
Step 1, the raw particles of the corona layer, middle layer and hot sealing layer are added separately to melt in extruder and are squeezed Out, by obtaining the polyvinyl blow molding, 40 microns of the polyvinyl blow molding thickness after blown film, cooling and shaping.
The preparation of the polyvinyl blow molding is respectively according to the Formulation Implementation in following table 2:
Table 2
Film layer Embodiment 1 Embodiment 2 Embodiment 3
Corona layer 50wt.%L420+50wt.%2045G 48wt.%L420+52wt.%2045G 52wt.%L420+48wt.%2045G
Middle layer 100wt.%5538G 100wt.%5538G 100wt.%5538G
Hot sealing layer 34wt.%L420+66wt.%2045G 32wt.%L420+68wt.%2045G 36wt.%L420+64wt.%2045G
Step 2, the polyvinyl blow molding unreels and passes through after heating roller reaches softening point and embossed again by dandy roll Processing carries out cooling treatment by chill roll later and obtains the polyethylene embossing packaging film.
The polyethylene obtained after the polyvinyl blow molding embossed is embossed 50 microns of packaging film finished product thickness, the present invention The particular technique index that polyethylene embosses packaging film finished product is as shown in table 3 below:
Table 3

Claims (5)

1. a kind of polyethylene embosses packaging film, it is characterised in that: it is heated soft by polyvinyl blow molding that the polyethylene embosses packaging film Embossed acquisition is carried out after change, the polyvinyl blow molding includes corona layer, middle layer and hot sealing layer, and the corona layer includes 48~52wt.% low density polyethylene (LDPE) (LDPE) and 48~52wt.% linear low density polyethylene (LLDPE), the centre Layer include linear low density polyethylene (LLDPE), the hot sealing layer include 32~36wt.% low density polyethylene (LDPE) (LDPE) and 64~68wt.% linear low density polyethylene (LLDPE).
2. polyethylene as described in claim 1 embosses packaging film, it is characterised in that: the corona layer includes 50wt.% low close It spends polyethylene (LDPE) and 50wt.% linear low density polyethylene (LLDPE), the hot sealing layer includes 34wt.% low-density Polyethylene (LDPE) and 66wt.% linear low density polyethylene (LLDPE).
3. polyethylene as described in claim 1 embosses packaging film, it is characterised in that: the corona layer is low close in hot sealing layer Degree polyethylene (LDPE) be SUMITOMO CHEMICAL produce and the particle trade mark be L420 product, the corona layer with it is linear in hot sealing layer Low density polyethylene (LDPE) (LLDPE) be Dow production and the particle trade mark be 2045G product, the middle layer it is linear low close The product that degree polyethylene (LLDPE) is Dow production and the particle trade mark is 5538G.
4. polyethylene as described in claim 1 embosses packaging film, it is characterised in that: the corona layer thickness of the polyvinyl blow molding For 12 microns, intermediate layer thickness be 16 microns, hot sealing layer is with a thickness of 12 microns;The polyethylene embossing packaging film is micro- with a thickness of 50 Rice.
5. a kind of production technology for embossing packaging films such as the described in any item polyethylene of Claims 1 to 4, it is characterised in that including Following procedure of processing:
Step 1, the raw particles of the corona layer, middle layer and hot sealing layer are added separately to melting extrusion in extruder, By obtaining the polyvinyl blow molding after blown film, cooling and shaping;
Step 2, the polyvinyl blow molding, which unreels and passes through after heating roller reaches softening point, carries out embossed by dandy roll again, Cooling treatment is carried out by chill roll later and obtains the polyethylene embossing packaging film.
CN201810831302.1A 2018-07-26 2018-07-26 A kind of polyethylene embossing packaging film and its production technology Pending CN109016750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810831302.1A CN109016750A (en) 2018-07-26 2018-07-26 A kind of polyethylene embossing packaging film and its production technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112080042A (en) * 2019-06-12 2020-12-15 中国石油化工股份有限公司 Auxiliary agent composition and preparation method thereof, linear low-density polyethylene composition and preparation method thereof, and polyethylene casting packaging film

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Publication number Priority date Publication date Assignee Title
CN112080042A (en) * 2019-06-12 2020-12-15 中国石油化工股份有限公司 Auxiliary agent composition and preparation method thereof, linear low-density polyethylene composition and preparation method thereof, and polyethylene casting packaging film
CN112080042B (en) * 2019-06-12 2022-02-18 中国石油化工股份有限公司 Auxiliary agent composition and preparation method thereof, linear low-density polyethylene composition and preparation method thereof, and polyethylene casting packaging film

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