CN109012113A - A kind of process flow of ion cleaning exhaust gas - Google Patents

A kind of process flow of ion cleaning exhaust gas Download PDF

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Publication number
CN109012113A
CN109012113A CN201810866204.1A CN201810866204A CN109012113A CN 109012113 A CN109012113 A CN 109012113A CN 201810866204 A CN201810866204 A CN 201810866204A CN 109012113 A CN109012113 A CN 109012113A
Authority
CN
China
Prior art keywords
exhaust gas
process flow
spray
ion cleaning
discharged
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810866204.1A
Other languages
Chinese (zh)
Inventor
郭磊
邹良栋
庞训宇
曹江
张亚斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhong Energy Saving And Cleaning Technology Development Co Ltd
China Energy Saving (lianyungang) Clean Technology Development Co Ltd
Original Assignee
Zhong Energy Saving And Cleaning Technology Development Co Ltd
China Energy Saving (lianyungang) Clean Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhong Energy Saving And Cleaning Technology Development Co Ltd, China Energy Saving (lianyungang) Clean Technology Development Co Ltd filed Critical Zhong Energy Saving And Cleaning Technology Development Co Ltd
Priority to CN201810866204.1A priority Critical patent/CN109012113A/en
Publication of CN109012113A publication Critical patent/CN109012113A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/44Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/104Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/50Inorganic acids
    • B01D2251/502Hydrochloric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides

Abstract

The present invention provides a kind of process flow of ion cleaning exhaust gas, it is related to waste gas purification field, the following steps are included: thering is the bottom of spray column to enter equipment exhaust gas, exhaust gas from bottom to top passes through spray tower packing, convection current is formed with top-down spray liquid, complete mass transport process, exhaust gas forms solution after spray liquid absorbs and falls into the sink of spray column bottom, exhaust gas after coagulation is discharged after the dehydration of device demisting, exhaust gas after coagulation is passed through to the gas gathering system of ionic decontamination devices, enter ion generator by air filter, the exhaust gas after two stage treatment is discharged by exhaust fan again, exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, exhaust gas after two stage treatment is discharged after through the fills unit in deep oxidation tower by exhaust tube, the present invention cross be added on the basis of ion cleaning method it is preposition with after Processing is set, the process flow of ion cleaning exhaust gas is improved, effectively increases the removal rate of harmful substance in exhaust gas.

Description

A kind of process flow of ion cleaning exhaust gas
Technical field
The present invention relates to waste gas purification fields, and in particular to a kind of process flow of ion cleaning exhaust gas.
Background technique
Ion cleaning is owned by France in advanced oxidation processes.Can effectively remove volatile organic matter (TVOC) in air, bacterium, The harmful substances such as pellet, sulphur compound.Its distinguishing feature is using hydroxyl radical free radical as primary oxidizers and organic matter It reacts, the organic free radical generated in reaction can continue to participate in the chain reaction of H, or by generating organic peroxy Further occurrence oxidative decomposition is directly degraded to final product CO2 and H2O after object free radical, to reach oxygenolysis The purpose of organic matter, specifically, the oxygen molecule in gas receives one surely when passing through ion Oxygen Generator at normal temperature The collision of the electronics of amount makes neutral molecule lose electronics and becomes the basic ion of anode, and the electronics discharged moment and it is another in Property molecule combine, form the basic ion of cathode, the oxonium ion with positive and negative charge respectively adsorbs 10-20 molecule formation cluster ion. Because of the catalytic action of hydrogen oxide, OOH, and generate O2、O2-、O2+、·OH、·HO2, the oxygen cluster aggregation such as O, O, have extremely strong Oxidability, oxidability is 1000 times of oxygen, the oxonium ion group of these high concentrations of generation rapidly with it is various it is inorganic, Organic pollutant gas (VOC) molecular collision activates contaminant gases molecule, and can open the chemical chain of contaminant gases molecule It is directly destroyed, furthermore the oxygen molecule in energetic ion oxygen activation gas generates secondary ion oxygen group, with contaminant gases point A series of redox reactions occur for son, and gas pollutant is resolved into carbon dioxide and water;To sulfide, benzene class, aromatic hydrocarbon Class equally has decomposition.
In the prior art, often focus on the improvement of ion purifier and ignore the preposition and postpositive disposal of ion cleaning method, Ion cleaning method, which can not be increased substantially, volatile organic matter (TVOC), bacterium, pellet, sulphur compound etc. The elimination efficiency of evil substance.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of process flows of ion cleaning exhaust gas, by ion Preposition and postpositive disposal is added on the basis of the method for purification, improves the process flow of ion cleaning exhaust gas, effectively increasing in exhaust gas has The removal rate of evil substance.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of process flow of ion cleaning exhaust gas, comprising the following steps:
S1, there is the bottom of spray column to enter equipment the exhaust gas, exhaust gas from bottom to top passes through spray tower packing, and from top to bottom Spray liquid form convection current, complete mass transport process, exhaust gas forms solution after spray liquid absorbs and falls into the sink of spray column bottom, Exhaust gas after coagulation is discharged after the dehydration of device demisting;
S2, the exhaust gas after coagulation is passed through to the gas gathering systems of ionic decontamination devices, by air filter into Enter ion generator, then the exhaust gas after two stage treatment is discharged by exhaust fan;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through depth It is discharged after fills unit in degree oxidizing tower by exhaust tube.
Preferably, S1Described in spray tower packing be polypropylene plastics polyhedron empty ball.
Preferably, S1Described in spray liquid be clear water spray liquid, in alkalinity soda lye, liquor natrii hypochloritis, salt Any one in acid solution.
Preferably, S2Described in air filter filtering Deng Ji≤F5, Ya power Sun Shi≤5mmH of filtering material2O。
Preferably, S2Described in ionic decontamination devices the temperature classification of insulating materials be F grades.
Preferably, S3Described in fills unit be modified filler.
(3) beneficial effect
The present invention provides a kind of process flows of ion cleaning exhaust gas, have the advantages that
Firstly, the preposition processing of spray column and deep oxidation tower postpositive disposal, solution are added on the basis of ion cleaning method Certainly in gas ions oxidation reactor, organic matter is broken down into debris particles coming, and part of oxygen is also under the bombardment of high energy electron Composition is formed, since the residence time is extremely short in plasma reactor for gas, the debris particles coming of generation causes to react insufficient etc. Problem,
Secondly, deodorization purification is carried out to exhaust gas using ion purifier, it is no any to easily cause or may cause secondary pollution Material or chemical agent, without waste water or other any secondary pollutions after processing, and within the scope of all specified deodorization spaces Deodorization reaches state specified standards.Gas discharge meets odorant pollutant factory circle standard value second level in national standard after deodorization.
Finally, deep oxidation tower uses modified filler for packed column, debris particles coming can be effectively adsorbed, and promotes to be adsorbed on to fill out Expect that oxidation reaction occurs for these compositions on tower.Since the packed tower is not intended to absorption organic matter, and always there are equal compositions In the presence of, therefore, even if packed tower has adsorbed a small amount of organic matter, as the presence of the oxidation reactions such as ozone, so that packed tower Always it is in unsaturated state, i.e., no replacement is required for the packed tower of this system use, can be used for a long time.
Detailed description of the invention
Fig. 1 is the process flow chart of ion cleaning exhaust gas of the present invention.
Fig. 2 is the structural schematic diagram of ion purifier of the present invention.
Fig. 3 is the structural schematic diagram of scrubbing tower.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of creative work.
Embodiment 1:
A kind of process flow of ion cleaning exhaust gas, comprising the following steps:
S1, exhaust gas there is the bottom of spray column enter equipment, exhaust gas from bottom to top passes through spray column polypropylene plastics multi-panel Hollow sphere filler forms convection current with top-down clear water spray liquid, completes mass transport process, and exhaust gas is formed after spray liquid absorbs Solution is fallen into the sink of spray column bottom, and the exhaust gas after coagulation is discharged after the dehydration of device demisting;
S2, the gas gathering system that the exhaust gas after coagulation is passed through to ionic decontamination devices, by air filter into Enter ion generator, then the exhaust gas after two stage treatment is discharged by exhaust fan;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through depth It is discharged after modified filler fills unit in degree oxidizing tower by exhaust tube.
Embodiment 2:
A kind of process flow of ion cleaning exhaust gas, comprising the following steps:
S1, exhaust gas there is the bottom of spray column enter equipment, exhaust gas from bottom to top passes through spray column polypropylene plastics multi-panel Hollow sphere filler forms convection current with the top-down soda lye in alkalinity, completes mass transport process, exhaust gas is inhaled through spray liquid It forms solution after receipts to fall into the sink of spray column bottom, the exhaust gas after coagulation is discharged after the dehydration of device demisting;
S2, the gas gathering system that the exhaust gas after coagulation is passed through to ionic decontamination devices, by air filter into Enter ion generator, then the exhaust gas after two stage treatment is discharged by exhaust fan;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through depth It is discharged after modified filler fills unit in degree oxidizing tower by exhaust tube.
Embodiment 3:
A kind of process flow of ion cleaning exhaust gas, comprising the following steps:
S1, exhaust gas there is the bottom of spray column enter equipment, exhaust gas from bottom to top passes through spray column polypropylene plastics multi-panel Hollow sphere filler forms convection current with top-down liquor natrii hypochloritis, completes mass transport process, exhaust gas shape after spray liquid absorbs It is fallen into the sink of spray column bottom at solution, the exhaust gas after coagulation is discharged after the dehydration of device demisting;
S2, the gas gathering system that the exhaust gas after coagulation is passed through to ionic decontamination devices, by air filter into Enter ion generator, then the exhaust gas after two stage treatment is discharged by exhaust fan;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through depth It is discharged after modified filler fills unit in degree oxidizing tower by exhaust tube.
Embodiment 4:
A kind of process flow of ion cleaning exhaust gas, comprising the following steps:
S1, exhaust gas there is the bottom of spray column enter equipment, exhaust gas from bottom to top passes through spray column polypropylene plastics multi-panel Hollow sphere filler forms convection current with top-down hydrochloric acid solution, completes mass transport process, exhaust gas forms molten after spray liquid absorbs Liquid is fallen into the sink of spray column bottom, and the exhaust gas after coagulation is discharged after the dehydration of device demisting;
S2, the gas gathering system that the exhaust gas after coagulation is passed through to ionic decontamination devices, by air filter into Enter ion generator, then the exhaust gas after two stage treatment is discharged by exhaust fan;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through depth It is discharged after modified filler fills unit in degree oxidizing tower by exhaust tube.
Embodiment 5:
A kind of process flow of ion cleaning exhaust gas, comprising the following steps:
S1, exhaust gas there is the bottom of spray column enter equipment, exhaust gas from bottom to top passes through spray column polypropylene plastics multi-panel Hollow sphere filler forms convection current with top-down hydrochloric acid solution, completes mass transport process, exhaust gas forms molten after spray liquid absorbs Liquid is fallen into the sink of spray column bottom, and the exhaust gas after coagulation is discharged after the dehydration of device demisting;
S2, the gas gathering system that the exhaust gas after coagulation is passed through to ionic decontamination devices, by air filter into Enter ion generator, the filtration grade of air filter is F5, and the pressure loss of filtering material is 5mmH2O, then will by exhaust fan Exhaust gas discharge after two stage treatment;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through depth It is discharged after modified filler fills unit in degree oxidizing tower by exhaust tube.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, including the element that sentence "including a ..." limits, it is not excluded that There is also other identical elements in the process, method, article or apparatus that includes the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations, although with reference to the foregoing embodiments Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features;And these modification or Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.

Claims (6)

1. a kind of process flow of ion cleaning exhaust gas, which comprises the following steps:
S1, there is the bottom of spray column to enter equipment the exhaust gas, exhaust gas from bottom to top passes through spray tower packing, with top-down spray It drenches liquid and forms convection current, complete mass transport process, exhaust gas forms solution after spray liquid absorbs and falls into the sink of spray column bottom, level-one Treated, and exhaust gas is discharged after the dehydration of foam catcher demisting;
S2, the exhaust gas after coagulation is passed through to the gas gathering systems of ionic decontamination devices, enter ion by air filter Generator, then the exhaust gas after two stage treatment is discharged by exhaust fan;
S3, the exhaust gas after two stage treatment is passed through deep oxidation tower by air-introduced machine, the exhaust gas after two stage treatment is passing through deep oxidation It is discharged after fills unit in tower by exhaust tube.
2. the process flow of ion cleaning exhaust gas as described in claim 1, which is characterized in that S1Described in spray tower packing be Polypropylene plastics polyhedron empty ball.
3. the process flow of ion cleaning exhaust gas as described in claim 1, which is characterized in that S1Described in spray liquid be clear water Spray liquid, in the soda lye of alkalinity, liquor natrii hypochloritis, any one in hydrochloric acid solution.
4. the process flow of ion cleaning exhaust gas as described in claim 1, which is characterized in that S2Described in air filter Filter Deng Ji≤F5, Ya power Sun Shi≤5mmH of filtering material2O。
5. the process flow of ion cleaning exhaust gas as described in claim 1, which is characterized in that S2Described in ionic decontamination devices The temperature classification of middle insulating materials is F grades.
6. the process flow of ion cleaning exhaust gas as described in claim 1, which is characterized in that S3Described in fills unit be change Property filler.
CN201810866204.1A 2018-09-19 2018-09-19 A kind of process flow of ion cleaning exhaust gas Pending CN109012113A (en)

Priority Applications (1)

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CN201810866204.1A CN109012113A (en) 2018-09-19 2018-09-19 A kind of process flow of ion cleaning exhaust gas

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Application Number Priority Date Filing Date Title
CN201810866204.1A CN109012113A (en) 2018-09-19 2018-09-19 A kind of process flow of ion cleaning exhaust gas

Publications (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106178873A (en) * 2016-08-03 2016-12-07 茂名市广地化工有限公司 Waste gas processing method in the production of a kind of sodium hydrosulfite and waste gas treatment equipment
CN108211686A (en) * 2017-12-05 2018-06-29 青岛科技大学 A kind of tail gas photooxidation cracking purification method
CN108404656A (en) * 2018-05-10 2018-08-17 山东派力迪环保工程有限公司 Feed fish meal processes air purifying device of automatic control transfusion and its technique

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106178873A (en) * 2016-08-03 2016-12-07 茂名市广地化工有限公司 Waste gas processing method in the production of a kind of sodium hydrosulfite and waste gas treatment equipment
CN108211686A (en) * 2017-12-05 2018-06-29 青岛科技大学 A kind of tail gas photooxidation cracking purification method
CN108404656A (en) * 2018-05-10 2018-08-17 山东派力迪环保工程有限公司 Feed fish meal processes air purifying device of automatic control transfusion and its technique

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Application publication date: 20181218