CN108998859A - A kind of ceramic fibre material - Google Patents

A kind of ceramic fibre material Download PDF

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Publication number
CN108998859A
CN108998859A CN201810695718.5A CN201810695718A CN108998859A CN 108998859 A CN108998859 A CN 108998859A CN 201810695718 A CN201810695718 A CN 201810695718A CN 108998859 A CN108998859 A CN 108998859A
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China
Prior art keywords
parts
ceramic fibre
fibre material
material according
bonding agent
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Application number
CN201810695718.5A
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Chinese (zh)
Inventor
桂新辉
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Anhui Xin Rui Heavy Industry Co Ltd By Shares
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Anhui Xin Rui Heavy Industry Co Ltd By Shares
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Priority to CN201810695718.5A priority Critical patent/CN108998859A/en
Publication of CN108998859A publication Critical patent/CN108998859A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62227Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres
    • C04B35/62231Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres based on oxide ceramics
    • C04B35/62236Fibres based on aluminium oxide
    • C04B35/803
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241Chromium oxides, chromates, or oxide-forming salts thereof
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
    • C04B2235/5216Inorganic
    • C04B2235/524Non-oxidic, e.g. borides, carbides, silicides or nitrides
    • C04B2235/5244Silicon carbide

Abstract

The invention discloses a kind of ceramic fibre materials, belong to ceramic material field, the raw material including following parts by weight: 50-60 parts of aluminium oxide, 20-35 parts of Cab-O-sil, 3-6 parts of chromium oxide, 2-5 parts of zirconium oxide, 10-15 parts of nano-titanium dioxide, coloured clay 4-8 parts, 5-7 parts of muscovite, 0.5-0.8 parts of montmorillonite, 2-7 parts of silicon carbide fibre, 10-15 parts of bonding agent, 2-5 parts of coupling agent.Ceramic fibre material of the present invention has good heat-resisting quantity, and light weight, intensity is high, can be good at in various adverse circumstances.

Description

A kind of ceramic fibre material
Technical field
The present invention relates to ceramic material fields, and in particular to a kind of ceramic fibre material.
Background technique
Ceramic fibre is a kind of fibrous light refractory material, has that light-weight, high temperature resistant, thermal stability be good, thermal conductivity The advantages that low, specific heat is small and mechanical resistant shakes, thus in the industries such as machinery, metallurgy, chemical industry, petroleum, ceramics, glass, electronics All it is widely used.Material energy conservation more resistance to than the tradition such as insulating brick and castable reaches the ceramic fibre of 10-30% in Chinese state More wider array of applications are inside obtained, development prospect is very good.But existing ceramic fibre material can not meet and make With needs, therefore, it is necessary to the performances of ceramic fibre to further increase.
Summary of the invention
The purpose of the present invention is to provide a kind of ceramic fibre materials, with good heat-resisting quantity, light weight, intensity Height can be good at in various adverse circumstances.
To achieve the above object, the invention provides the following technical scheme:
A kind of ceramic fibre material, the raw material including following parts by weight: 50-60 parts of aluminium oxide, 20-35 parts of Cab-O-sil, oxygen Chromium 3-6 parts of change, 2-5 parts of zirconium oxide, 10-15 parts of nano-titanium dioxide, coloured clay 4-8 parts, 5-7 parts of muscovite, montmorillonite 0.5-0.8 parts, 2-7 parts of silicon carbide fibre, 10-15 parts of bonding agent, 2-5 parts of coupling agent.
Preferably, the ceramic fibre material, the raw material including following parts by weight: 55 parts of aluminium oxide, 27 parts of Cab-O-sil, 5 parts of chromium oxide, 4 parts of zirconium oxide, 12 parts of nano-titanium dioxide, 6 parts of coloured clay, 6 parts of muscovite, 0.7 part of montmorillonite, carbonization 5 parts of silica fibre, 12 parts of bonding agent, 3 parts of coupling agent.
Preferably, the bonding agent includes organic siliconresin, melamine resin.
Preferably, the organic siliconresin, melamine resin mass ratio be 3:1.
Preferably, the bonding agent is modified heat convertible resin.
It preferably, further include lubricant, the lubricant is 3-5 parts.
Preferably, the lubricant is made of graphite, boron nitride and molybdenum dioxide.
Preferably, the mass ratio of the graphite, boron nitride and molybdenum dioxide is 1:3:5.
Compared with prior art, the beneficial effects of the present invention are:
The present invention has good heat-resisting quantity, and light weight, intensity is high, can be good at in various adverse circumstances.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field Those of ordinary skill's every other embodiment obtained without making creative work, belongs to guarantor of the present invention The range of shield.
Embodiment 1
Ceramic fibre material described in the present embodiment, the combination including following parts by weight: 50 parts of aluminium oxide, Cab-O-sil 20 Part, 3 parts of chromium oxide, 2 parts of zirconium oxide, 10 parts of nano-titanium dioxide, 4 parts of coloured clay, 5 parts of muscovite, 0.5 part of montmorillonite, carbon 2 parts of SiClx fiber, 10 parts of bonding agent, 2 parts of coupling agent;The bonding agent includes organic siliconresin, melamine resin; The organic siliconresin, melamine resin mass ratio be 3:1;The bonding agent is modified heat convertible resin;Also wrap Lubricant is included, the lubricant is 3 parts;The lubricant is made of graphite, boron nitride and molybdenum dioxide;The graphite, nitridation The mass ratio of boron and molybdenum dioxide is 1:3:5.
Embodiment 2
Ceramic fibre material described in the present embodiment, the combination including following parts by weight: 55 parts of aluminium oxide, Cab-O-sil 27 Part, 5 parts of chromium oxide, 4 parts of zirconium oxide, 12 parts of nano-titanium dioxide, 6 parts of coloured clay, 6 parts of muscovite, 0.7 part of montmorillonite, carbon 5 parts of SiClx fiber, 12 parts of bonding agent, 3 parts of coupling agent;The bonding agent includes organic siliconresin, melamine resin; The organic siliconresin, melamine resin mass ratio be 3:1;The bonding agent is modified heat convertible resin;Also wrap Lubricant is included, the lubricant is 4 parts;The lubricant is made of graphite, boron nitride and molybdenum dioxide;The graphite, nitridation The mass ratio of boron and molybdenum dioxide is 1:3:5.
Embodiment 3
Ceramic fibre material described in the present embodiment, the combination including following parts by weight: 60 parts of aluminium oxide, Cab-O-sil 35 Part, 6 parts of chromium oxide, 5 parts of zirconium oxide, 15 parts of nano-titanium dioxide, 8 parts of coloured clay, 7 parts of muscovite, 0.8 part of montmorillonite, carbon 7 parts of SiClx fiber, 15 parts of bonding agent, 5 parts of coupling agent;The bonding agent includes organic siliconresin, melamine resin; The organic siliconresin, melamine resin mass ratio be 3:1;The bonding agent is modified heat convertible resin;Also wrap Lubricant is included, the lubricant is 5 parts;The lubricant is made of graphite, boron nitride and molybdenum dioxide;The graphite, nitridation The mass ratio of boron and molybdenum dioxide is 1:3:5.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple Described specific embodiment does various modifications or additions or is substituted in a similar manner, without departing from this hair Bright structure or beyond the scope defined by this claim, is within the scope of protection of the invention.

Claims (8)

1. a kind of ceramic fibre material, which is characterized in that the raw material including following parts by weight: 50-60 parts of aluminium oxide, Cab-O-sil 20-35 parts, 3-6 parts of chromium oxide, 2-5 parts of zirconium oxide, 10-15 parts of nano-titanium dioxide, coloured clay 4-8 parts, muscovite 5-7 Part, 0.5-0.8 parts of montmorillonite, 2-7 parts of silicon carbide fibre, 10-15 parts of bonding agent, 2-5 parts of coupling agent.
2. a kind of ceramic fibre material according to claim 1, which is characterized in that the raw material including following parts by weight: oxygen 55 parts of aluminium of change, 27 parts of Cab-O-sil, 5 parts of chromium oxide, 4 parts of zirconium oxide, 12 parts of nano-titanium dioxide, 6 parts of coloured clay, muscovite 6 Part, 0.7 part of montmorillonite, 5 parts of silicon carbide fibre, 12 parts of bonding agent, 3 parts of coupling agent.
3. a kind of ceramic fibre material according to claim 1, it is characterised in that: the bonding agent includes organosilicon tree Rouge, melamine resin.
4. a kind of ceramic fibre material according to claim 3, it is characterised in that: the organic siliconresin, melamine The mass ratio of formaldehyde resin is 3:1.
5. a kind of ceramic fibre material according to claim 1, it is characterised in that: the bonding agent is modified heat convertible tree Rouge.
6. a kind of ceramic fibre material according to claim 1, it is characterised in that: it further include lubricant, the lubricant It is 3-5 parts.
7. a kind of ceramic fibre material according to claim 6, it is characterised in that: the lubricant is by graphite, boron nitride It is formed with molybdenum dioxide.
8. a kind of ceramic fibre material according to claim 7, it is characterised in that: the graphite, boron nitride and titanium dioxide The mass ratio of molybdenum is 1:3:5.
CN201810695718.5A 2018-06-29 2018-06-29 A kind of ceramic fibre material Withdrawn CN108998859A (en)

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CN201810695718.5A CN108998859A (en) 2018-06-29 2018-06-29 A kind of ceramic fibre material

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CN201810695718.5A CN108998859A (en) 2018-06-29 2018-06-29 A kind of ceramic fibre material

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113912384A (en) * 2021-12-01 2022-01-11 泉州市龙亘耐火保温材料有限公司 Superfine ceramic fiber cotton and production method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113912384A (en) * 2021-12-01 2022-01-11 泉州市龙亘耐火保温材料有限公司 Superfine ceramic fiber cotton and production method thereof

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