CN108993140A - A kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method - Google Patents
A kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method Download PDFInfo
- Publication number
- CN108993140A CN108993140A CN201811125420.7A CN201811125420A CN108993140A CN 108993140 A CN108993140 A CN 108993140A CN 201811125420 A CN201811125420 A CN 201811125420A CN 108993140 A CN108993140 A CN 108993140A
- Authority
- CN
- China
- Prior art keywords
- temperature
- meeting
- evaporator
- adsorption
- fuel oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 69
- 239000000295 fuel oil Substances 0.000 title claims abstract description 35
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000012545 processing Methods 0.000 title claims abstract description 20
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 12
- 239000012855 volatile organic compound Substances 0.000 claims abstract description 72
- 230000003647 oxidation Effects 0.000 claims abstract description 55
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 55
- 238000009833 condensation Methods 0.000 claims abstract description 51
- 230000005494 condensation Effects 0.000 claims abstract description 35
- 238000001816 cooling Methods 0.000 claims abstract description 19
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 13
- 238000004458 analytical method Methods 0.000 claims abstract description 12
- 239000007789 gas Substances 0.000 claims description 81
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 239000003507 refrigerant Substances 0.000 claims description 21
- 238000011084 recovery Methods 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000003463 adsorbent Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 9
- 238000004880 explosion Methods 0.000 claims description 8
- 230000008859 change Effects 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000003795 desorption Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000010815 organic waste Substances 0.000 claims description 5
- 238000005057 refrigeration Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000008025 crystallization Effects 0.000 claims description 2
- 230000008676 import Effects 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims 2
- 235000019628 coolness Nutrition 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 21
- 229910052799 carbon Inorganic materials 0.000 abstract description 19
- 238000010521 absorption reaction Methods 0.000 abstract description 15
- 230000000903 blocking effect Effects 0.000 abstract 1
- 230000007423 decrease Effects 0.000 abstract 1
- 239000010779 crude oil Substances 0.000 description 18
- 239000003921 oil Substances 0.000 description 14
- 238000001514 detection method Methods 0.000 description 12
- 239000003502 gasoline Substances 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000002912 waste gas Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- -1 methane hydrocarbon Chemical class 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8687—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The invention discloses a kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method, device include: VOCsTransportation system, condenser system, adsorption system and catalytic oxidation system；Method includes the following steps: that high concentration fuel oil VOCs containing steam by condenser system, is passed through the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting and third temperature awkward silence at a meeting gradient cooling by (1)；(2) gas at normal temperature after condensing enters adsorption system, and adsorption system adsorbs vacuum analysis mode using double tanks, further decreases organic exhaust gas concentration；(3) gas concentration is fluctuated into lesser gas by catalytic oxidation system, is CO by the light component catalysis oxidation in low-concentration organic exhaust gas2And H2O completes the qualified discharge of fuel oil VOCs containing steam.The present invention can couple the technological merit of condensation technology, absorption and catalysis oxidation, solve the problems, such as in condensation process vapor blocking heat exchanger, problem of temperature rise and contain light component such as two qualified discharge of carbon in adsorption process.
Description
Technical field
The present invention relates to environmental technology field, especially a kind of processing fuel oil VOC containing steamsCondensation adsorption be catalyzed oxygen
Change device and method.
Background technique
Crude oil, gasoline and naphtha are fuel oil common in petrochemical industry, in transport, storage, produce and use
Easy evaporating loss in journey, it is mainly carbon four, light dydrocarbon and carbon six in organic exhaust gas i.e. VOCs that the oil gas evaporated, which is also known as, and there are also few
Carbon one, carbon two, carbon three and the carbon seven of amount.According to statistics, for gasoline from the oil gas that oil tank evaporates, organic solvent volume score is high
Up to 30% or so.Naphtha is similar with gasoline physico-chemical property, especially light naphthar, and boiling range is 70 DEG C~145 DEG C, some refinings
The light naphthar of factory is also eager to excel than gasoline volatility.Crude oil and crude oil place of production oil tank, such as the South Pars crude oil in the Middle East, light component
Content is high, and volatility and gasoline are very nearly the same.
It is Chinese every year because the petroleum resources of storage, the misuse of transport facilities are up to tons up to a million, this not only waste of resource, Er Qiezao
At environmental disruption；The oil gas overflowed simultaneously easily reaches explosion limit after mixing with air, to cause the safety accidents such as fire.Cause
This needs administers the petroleum resources of volatilization, and one kind is recovery technology, and another kind of is destruction technology.Recovery technology is mainly wrapped
Include the technologies such as condensation, absorption and sorption and UF membrane.The volatile organic matter of recycling can be directly or through returning after simple purification
Technical process recycles, to reduce the consumption of raw material.Destruction technology mainly includes high temperature incineration, catalysis burning, biological oxidation, low
Isothermal plasma destroys and the technologies such as photochemical catalytic oxidation.
Condensation method petroleum vapor recovery is to utilize the vapor partial pressure power of hydrocarbons at different temperatures poor, using mechanical refrigeration skill
Art mostly uses polynary working medium overlapping to reduce oil gas temperature step by step, and hydrocarbons vapor partial pressure is made to reach saturation state, and gradually cold
Congeal into a kind of oil-gas recovery method of liquid.Foreign countries begin to the research work of Investigation of Petroleum Vapor Recovery Technology early in the middle of last century, until
More than 400 condensation method oil-gas recovery devices, Chinese Zhenghai refining in 1989 are installed in the whole world by Margaret Edwards company of the U.S. in 1997
Oily factory introduces the condensation method oil-gas recovery device of a set of the said firm's manufacture, is safely operated so far, remarkable in economical benefits；TaiWan, China
Existing 24 large and medium-sized oil depots all apply condensation method oil-gas recovery device.Condensation method Investigation of Petroleum Vapor Recovery Technology is usually according to oil
Gas composition, the rate of recovery and exhaust emission standard determine the minimum temperature setting of condensing unit, and the efficient process that condenses is using multistage
Cooling, end-o f-pipe -control concentration be -110 DEG C can meet GB20950-2007 " storage tank farm atmosphere pollutants emission standards " and
(non-methane hydrocarbon emission limit value 25g/m3, goes the national standards such as GB20952-2007 " gas station's atmosphere pollutants emission standards "
Except efficiency >=95).With the raising of national emission standard and the requirement of oil vapor treatment equipment energy consumption, single processing technique is
It is not able to satisfy the demand in market, the development and application for meeting technique is in the ascendant.Oil gas adsorption recovery technology is always domestic and international
One research topic of concern, the performance of oil gas adsorbent influence the cost of investment, operating cost and peace of entire recovery technology
Full performance.The adsorbent for being presently available for petroleum vapor recovery is mainly active carbon class, silica type and zeolite molecular sieve class, various absorption
All there are some problems in agent, such as the deterioration problem of adsorbent, active carbon thermal coefficient is low, have combustibility, activated carbon fibre valence
Lattice are high, packing volume is big, and silica gel water imbibition is strong etc., need to screen or develop the Special adsorbent for being suitable for petroleum vapor recovery thus.
Catalytic oxidation technologies are applied in the fine chemistry industry of petrochemical industry middle and lower reaches than wide, since crude oil gasoline naphtha etc. is waved
The oil-gas component issued contains a small amount of carbon one, carbon two and carbon three, the especially presence of carbon two, the characteristics of being not easily recycled,
So that qualified discharge (120mg/m3) huge to recovery technology pressure.Catalytic oxidation technologies are made in pernicious gas using catalyst
Combustible component oxygenolysis at a lower temperature purification method.CnHm and organic molten Ji steam oxidation are decomposed and generated
CO2And H2O simultaneously releases heat.Its reaction equation are as follows:
As VOCs discharge standard is lower and lower, it is ensured that final exhaust emissions concentration meets " petroleum refining industry pollutant
Discharge standard " GB 31570-2015 and " petro chemical industry pollutant emission standard " GB 31571-2015 requirement (non-first
Alkane total hydrocarbon emissions limit value 25g/m3, removal efficiency >=95), the high-concentration organic waste gas such as crude oil gasoline naphtha are used alone
Condensation technology, absorption techniques adsorption technology are difficult to accomplish qualified discharge, destroy technology and require strictly volatile organic matter concentration,
And heating power oxidation technology temperature is excessively high, and has open fire.Catalytic oxidation technologies are lower with respect to initiation temperature, and the flames of anger generates, relatively
Heating power oxidation technology is more safer.It in the VOCs containing steam such as crude oil gasoline naphtha, is easily crystallized containing steam, and containing not
The light component easily recycled such as carbon two, the general single organic media pressure of qualified discharge pressure ratio are big.It is suitable for using condensation adsorption
The processing of catalysis oxidation coupling technique, wherein condensation process controls two-way awkward silence at a meeting using single compressor, recycles organic solvent in VOCs
90% or more, VOCs concentration is further decreased by adsorption technology, reduces the load of catalysis oxidation, last catalytic oxidation technologies
The light component being not easily recycled such as carbon two is decomposed into CO2And H2O realizes qualified discharge.
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of processing fuel oil VOC containing steamsCondensation adsorption urge
Change oxidation unit and method, the technological merit of condensation technology, absorption and catalysis oxidation can be coupled, solves water in condensation process and steam
Gas blocks heat exchanger, problem of temperature rise and contains light component such as two qualified discharge problem of carbon in adsorption process.
In order to solve the above technical problems, the present invention provides a kind of processing fuel oil VOC containing steamsCondensation adsorption be catalyzed oxygen
Makeup is set, comprising: VOCsTransportation system, condenser system, adsorption system and catalytic oxidation system；Fuel oil VOC containing steamsInto
VOCsTransportation system successively becomes gas up to standard by condenser system, adsorption system and catalytic oxidation system and carries out high altitude discharge.
The Physical Property Analysis of organic media, the calculating of condensation technology energy consumption temperature analysis are determined in the VOCs containing steam such as based on crude gasoline naphtha
Determine the distribution of awkward silence at a meeting cooling capacity, by two heat exchangers in parallel of a refrigerant compression mechanism cold, solves moisture condensation crystal ice in VOCs
Stifled problem, being pre-processed by condensation reduces absorption inlet gas concentration, solves adsorption system problem of temperature rise, is urged by adsorption system solution
Change the oxidation excessively high problem of inlet gas concentration, the light hydrocarbons such as carbon in oil and gas oilstone cerebrol VOCs containing steam is decomposed using catalysis oxidation
Two, it is ensured that the continuous qualified discharge of long period.
Preferably, VOCsTransportation system includes air-introduced machine 6 and emptying cylinder 22；The air inlet of air-introduced machine 6 is as fuel oil VOCs
Entrance, gas up to standard by emptying 22 high altitude discharge of cylinder；Air-introduced machine 6 is flame-proof converter roots blower, with the source VOCs general pipeline
The pressure sensor of line interlocks, and the start and stop pressure of frequency conversion roots blower is 500pa and 0pa, goal pressure 100pa.
Preferably, condenser system includes R404A air-cooled condenser 1, R404A compressor 2, R23 air-cooled condenser 3, R23 pressure
Contracting machine 4, refrigerant heat exchanger 5, the first evaporator 8, the second evaporator A9, the second evaporator B10, third evaporator A11, third
Evaporator B12 and liquid trap 13；R404A circulation is the first evaporator 8, the second evaporator A9, the second evaporator B10 and refrigerant
Heat exchanger 5 provides cooling capacity, and R404A refrigerant passes sequentially through R404A compressor 2, R404A air-cooled condenser 1, expansion valve and first
Evaporator 8, the second evaporator A9, the second evaporator B10 and refrigerant heat exchanger 5 finally enter the formation of R404A compressor 2 and close
Formula circulation；R23 circulation provides cooling capacity for third evaporator A11, third evaporator B12, and R23 refrigerant passes sequentially through R23 compression
Machine 4, R23 air-cooled condenser 3, expansion valve and third evaporator A11, third evaporator B12 finally enter the formation of R23 compressor 4
Closed cycle；First evaporator is 5 ± 5 DEG C of evaporators, and the second evaporator is -25 ± 5 DEG C of evaporators, and third evaporator is -75
± 5 DEG C of evaporators.
Preferably, condenser system is three-level condensation process, i.e. the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting and third temperature is cold
, wherein second temperature awkward silence at a meeting and third temperature awkward silence at a meeting are that single compressor controls two-way awkward silence at a meeting, and second temperature awkward silence at a meeting i.e. second is steamed
Send out device A9 and the second evaporator B10, third awkward silence at a meeting, that is, third evaporator A11 and third evaporator B12；When the road A because of vapor
When Crystallization Plugging heat exchanger, with the road B system, the road A is carried out holding frost with warm refrigerant at this time, and the switching of the road A/B uses；Second temperature is cold
Field and third temperature awkward silence at a meeting are double-condenser parallel connection；Wherein, the treatment temperature of the first temperature awkward silence at a meeting is 5 ± 5 DEG C, second temperature
The treatment temperature of awkward silence at a meeting is -25 ± 5 DEG C, and the treatment temperature of third temperature awkward silence at a meeting is -75 ± 5 DEG C.
Preferably, the refrigerant of condenser system is R404A and R23, wherein the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting use
R404A, third temperature awkward silence at a meeting are bipolar cascade refrigeration system, i.e. R404A condenses R23, realized by refrigerant heat exchanger 5；System
The condensate form of cooling system is air-cooled condenser, i.e. R404A air-cooled condenser 1 and R23 air-cooled condenser 3.
Preferably, adsorption system includes vacuum pump 7, nitrogen hot gas heat exchanger 14, adsorption tanks A15 and adsorption tanks B16；Absorption
Tank A15 and adsorption tanks B16 is in parallel, and a tank adsorbs tank parsing, and parsing is carried out by vacuum pump 7, the high concentrations of gas of parsing into
Enter condenser system import, nitrogen hot gas heat exchanger 14 comes into operation in the deep analysis of adsorbent.
Preferably, adsorption system is used vacuum desorption, is used hot nitrogen qi exhaustion at quarterly intervals using double adsorption tanks, normal desorption
Attached, wherein the heat source of hot nitrogen desorption provides for catalytic oxidation system, is realized by nitrogen hot gas heat exchanger 14, three kinds of adsorbents
For petroleum vapor recovery Special adsorbent, be used in combination, by activated alumina, silica gel and molecular sieve 1:6:12 mass ratio from it is lower toward
Upper filling.
Preferably, catalytic oxidation system includes air chest 17, air blower 18, gas heat exchanger 19, anti-explosion electric heater
20 and catalyst oxidation reactor 21；Tail gas passes sequentially through air chest 17, gas heat exchanger 19, anti-explosion electric heater 20, catalysis oxygen
Change reactor 21, finally again passes by the heat exchange cooling qualified discharge of gas heat exchanger 19；Air blower 18 is frequency conversion centrifugal blower,
Frequency conversion is interlocked with the electric thermo-couple temperature in catalyst oxidation reactor 21, target value is 400 DEG C.
Correspondingly, a kind of processing fuel oil VOC containing steamsCondensation adsorption catalysed oxidation processes, include the following steps:
(1) high concentration fuel oil VOCs containing steam is passed through into the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting by condenser system
And third temperature awkward silence at a meeting gradient cooling；By the easy condensed components condensing recovery in high-concentration organic waste gas, handling has for low concentration
Machine exhaust gas；
(2) gas at normal temperature after condensing enters adsorption system, and adsorption system adsorbs vacuum analysis mode using double tanks, into
One step reduces organic exhaust gas concentration；
(3) gas concentration is fluctuated into lesser gas by catalytic oxidation system, by light group in low-concentration organic exhaust gas
Dividing catalysis oxidation is CO2And H2O completes the qualified discharge of fuel oil VOCs containing steam.
Preferably, in step (1), second temperature awkward silence at a meeting and third temperature awkward silence at a meeting are double-condenser parallel connection, using single pressure
Contracting machine controls double path system, realizes the energy conservation of condenser system.
The invention has the benefit that the present invention has coupled the technological merit of condensation technology, adsorption technology and catalysis oxidation,
It is calculated according to the Physical Property Analysis of organic media, condensation technology energy consumption temperature analysis in fuel oil VOCs containing steam and determines awkward silence at a meeting cooling capacity
Distribution solves the problems, such as that moisture condensation crystal ice is stifled in VOCs, passes through by two heat exchangers in parallel of a refrigerant compression mechanism cold
Condensation pretreatment reduces absorption inlet gas concentration, solves adsorption system problem of temperature rise, solves catalysis oxidation air inlet by adsorption system
Excessive concentration problem decomposes the light hydrocarbons such as carbon two in oil and gas oilstone cerebrol VOCs containing steam using catalysis oxidation, it is ensured that long
Period continuous qualified discharge；By the overall skid-mounted of equipment, realize that occupied area is small, in-site installation is convenient and efficient.
Detailed description of the invention
Fig. 1 is the device of the invention structural schematic diagram.
Wherein, 1, R404A air-cooled condenser；2, R404A compressor；3, R23 air-cooled condenser 3；4, R23 compressor；5,
Refrigerant heat exchanger；6, air-introduced machine；7, vacuum pump；8, the first evaporator；9, the second evaporator A；10, the second evaporator B；11,
Third evaporator A；12, third evaporator B；13, liquid trap；14, nitrogen hot gas heat exchanger；15, adsorption tanks A；16, adsorption tanks B；
17, air chest；18, air blower；19, gas heat exchanger；20, anti-explosion electric heater；21, catalyst oxidation reactor；22, it empties
Cylinder.
Specific embodiment
As shown in Figure 1, a kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment, comprising: VOCs is defeated
Send system, condenser system, adsorption system and catalytic oxidation system；VOCs transportation system is mainly 6 air-introduced machines and empties cylinder 22, cold
Solidifying system includes R404A air-cooled condenser 1, R404A compressor 2, the first evaporator 8, the second evaporator A9, the second evaporator
B10, R23 air-cooled condenser 3, R23 compressor 4, refrigerant heat exchanger 5, third evaporator A11, third evaporator B12 and liquid collecting
Device 13, adsorption system include adsorption tanks A15, adsorption tanks B16, vacuum pump 7 and nitrogen hot gas heat exchanger 14, catalytic oxidation system packet
Include air chest 17, air blower 18, gas heat exchanger 19, anti-explosion electric heater 20 and catalyst oxidation reactor 21；Air-introduced machine 6
Entrance of the air inlet as fuel oil VOCs containing steam, the gas outlet of air-introduced machine 6 connect the air inlet of the first evaporator 8, then
VOCs gas successively passes through the second evaporator A9, the second evaporator B10, third evaporator A11, third evaporator B12, adsorption tanks
A15, adsorption tanks B16, air chest 17, gas heat exchanger 19, anti-explosion electric heater 20 and catalyst oxidation reactor 21, it is last up to standard
Gas passes through emptying 22 high altitude discharge of cylinder.
Wherein condensing unit is minimum cold using compression refrigeration cycle, including compressor, condenser, expansion valve, evaporator etc.
Preferably -75 DEG C of solidifying temperature.Catalyst oxidation reactor includes regular formula noble metal (Pb/Pt) catalyst or rare earth catalyst.Condensation
Evaporator in system is three-dimensional heat exchanger, can through the organic exhaust gas temperature after condenser system to be 10~30 DEG C；It will
Cooling capacity all recycles in cold air, and energy-saving effect is obvious.
A kind of condensation adsorption catalysed oxidation processes handling fuel oil VOCs containing steam, include the following steps:
(1) by high concentration fuel oil VOCs containing steam by condenser system, by the first temperature field, second temperature awkward silence at a meeting and
Third temperature awkward silence at a meeting gradient cooling, wherein second temperature awkward silence at a meeting and third temperature awkward silence at a meeting are double-condenser parallel connection, solve condensation
Steam crystal ice blocks up problem in the process；By the easy condensed components condensing recovery in high-concentration organic waste gas, handling has for low concentration
Machine exhaust gas solves the problems, such as that adsorption system temperature rise is big；
(2) gas at normal temperature after condensing enters adsorption system, and adsorption system adsorbs vacuum analysis mode using double tanks, into
One step reduces organic exhaust gas concentration；
(3) gas concentration is fluctuated into lesser gas by catalytic oxidation system, by light group in low-concentration organic exhaust gas
Divide such as carbon two, catalysis oxidation CO2And H2O completes the qualified discharge of fuel oil VOCs containing steam.
Fuel oil in the present invention is specially crude oil, gasoline or naphtha etc..
Embodiment 1
The equipment is used to handle the South Pars crude oil shipment tolerance of VOCs containing steam 3500Nm3/h。
Start condenser system first, by the crude oil shipment waste gas condensation of VOCs containing steam to -75 DEG C, is matched using gas chromatography
Standby fid detector detection condensation inlet and outlet and absorption outlet VOCs, continuous detection 3 days, every 3 hours sample detections 1 time, wherein cold
The solidifying imported crude oil shipment exhaust gas concentration of VOCs containing steam is 60g/m3~600g/m3, it is useless that absorption outlet crude oil loads VOCs containing steam onto ship
Gas concentration is 4.1g/m3~12g/m3, wherein outlet exhaust concentration to be adsorbed, which is stablized, is lower than 20g/m3When, open electric heater
After 30min, starting air blower, motor heat is automatically closed at this time, catalyst oxidation reactor temperature and frequency conversion fan automatic linkage,
Temperature control is at 250 DEG C~450 DEG C, and optimum temperature is 350 DEG C, system stable operation, and air cooling detection is sampled at exhaust tube,
It as a result is 10mg/m3, qualified discharge.
Embodiment 2
The equipment is used to handle gasoline entrucking and the abhiseca tolerance of VOCs containing steam 2000Nm3/h。
Start condenser system first, by the crude oil shipment waste gas condensation of VOCs containing steam to -75 DEG C, is matched using gas chromatography
Standby fid detector detection condensation inlet and outlet and absorption outlet VOCs, continuous detection 3 days, every 3 hours sample detections 1 time, wherein cold
The solidifying imported crude oil shipment exhaust gas concentration of VOCs containing steam is 50g/m3~400g/m3, it is useless that absorption outlet crude oil loads VOCs containing steam onto ship
Gas concentration is 3g/m3~16g/m3, wherein outlet exhaust concentration to be adsorbed, which is stablized, is lower than 20g/m3When, open electric heater
After 30min, starting air blower, motor heat is automatically closed at this time, catalyst oxidation reactor temperature and frequency conversion fan automatic linkage,
Temperature control is at 250 DEG C~450 DEG C, and optimum temperature is 350 DEG C, system stable operation, and air cooling detection is sampled at exhaust tube,
It as a result is 9mg/m3, qualified discharge.
Embodiment 3
The equipment is used to handle the naphtha entrucking tolerance of VOCs containing steam 2000Nm3/h。
Start condenser system first, by the crude oil shipment waste gas condensation of VOCs containing steam to -75 DEG C, is matched using gas chromatography
Standby fid detector detection condensation inlet and outlet and absorption outlet VOCs, continuous detection 3 days, every 3 hours sample detections 1 time, wherein cold
The solidifying imported crude oil shipment exhaust gas concentration of VOCs containing steam is 80g/m3~900g/m3, it is useless that absorption outlet crude oil loads VOCs containing steam onto ship
Gas concentration is 6g/m3~18g/m3, wherein outlet exhaust concentration to be adsorbed, which is stablized, is lower than 20g/m3When, open electric heater
After 30min, starting air blower, motor heat is automatically closed at this time, catalyst oxidation reactor temperature and frequency conversion fan automatic linkage,
Temperature control is at 250 DEG C~450 DEG C, and optimum temperature is 350 DEG C, system stable operation, and air cooling detection is sampled at exhaust tube,
It as a result is 7mg/m3, qualified discharge.
The present invention has coupled the technological merit of condensation technology, adsorption technology and catalysis oxidation, based on crude gasoline naphtha
The Physical Property Analysis of organic media, condensation technology energy consumption temperature analysis, which calculate, in VOCs containing steam determines the distribution of awkward silence at a meeting cooling capacity, passes through
One refrigerant compression mechanism cold, two heat exchangers in parallel solve the problems, such as that moisture condensation crystal ice is stifled in VOCs, by condensing pre- place
Reason reduces absorption inlet gas concentration, solves adsorption system problem of temperature rise, and it is excessively high to solve catalysis oxidation inlet gas concentration by adsorption system
Problem decomposes the light hydrocarbons such as carbon two in oil and gas oilstone cerebrol VOCs containing steam using catalysis oxidation, it is ensured that long period is continuous
Qualified discharge；By the overall skid-mounted of equipment, realize that occupied area is small, in-site installation is convenient and efficient.
Claims (10)
1. a kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment characterized by comprising VOCsConveying
System, condenser system, adsorption system and catalytic oxidation system；Fuel oil VOC containing steamsInto VOCsTransportation system is successively passed through
Condenser system, adsorption system and catalytic oxidation system become gas up to standard and carry out high altitude discharge.
2. processing fuel oil VOC containing steam as described in claim 1sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
VOCsTransportation system includes air-introduced machine (6) and emptying cylinder (22)；The air inlet of air-introduced machine (6) is as fuel oil VOCsEntrance, reach
Standard gas body passes through emptying cylinder (22) high altitude discharge；Air-introduced machine (6) is flame-proof converter roots blower, the pressure with the source VOCs main pipe line
Force snesor interlocking, the start and stop pressure of frequency conversion roots blower are 500pa and 0pa, goal pressure 100pa.
3. processing fuel oil VOC containing steam as described in claim 1sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
Condenser system include R404A air-cooled condenser (1), R404A compressor (2), R23 air-cooled condenser (3), R23 compressor (4),
Refrigerant heat exchanger (5), the first evaporator (8), the second evaporator A (9), the second evaporator B (10), third evaporator A (11),
Third evaporator B (12) and liquid trap (13)；It is the first evaporator (8) that R404A, which is recycled, the second evaporator A (9), the second evaporation
Device B (10) and refrigerant heat exchanger (5) provide cooling capacity, and it is air-cooled that R404A refrigerant passes sequentially through R404A compressor (2), R404A
Condenser (1), expansion valve and the first evaporator (8), the second evaporator A (9), the second evaporator B (10) and refrigerant heat exchanger
(5), R404A compressor (2) are finally entered and form closed cycle；R23 circulation is third evaporator A (11), third evaporator B
(12) cooling capacity is provided, R23 refrigerant passes sequentially through R23 compressor (4), R23 air-cooled condenser (3), expansion valve and third evaporation
Device A (11), third evaporator B (12) finally enter R23 compressor (4) and form closed cycle；First evaporator is 5 ± 5 DEG C of steamings
Device is sent out, the second evaporator is -25 ± 5 DEG C of evaporators, and third evaporator is -75 ± 5 DEG C of evaporators.
4. processing fuel oil VOC containing steam as claimed in claim 3sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
Condenser system is three-level condensation process, i.e. the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting and third temperature awkward silence at a meeting, wherein second temperature
Awkward silence at a meeting and third temperature awkward silence at a meeting are that single compressor controls two-way awkward silence at a meeting, and second temperature awkward silence at a meeting i.e. the second evaporator A (9) and second steams
It sends out device B (10), third awkward silence at a meeting, that is, third evaporator A (11) and third evaporator B (12)；When the road A because of vapor Crystallization Plugging
When heat exchanger, with the road B system, the road A is carried out holding frost with warm refrigerant at this time, and the switching of the road A/B uses；Second temperature awkward silence at a meeting and third
Temperature awkward silence at a meeting is double-condenser parallel connection；Wherein, the treatment temperature of the first temperature awkward silence at a meeting is 5 ± 5 DEG C, the place of second temperature awkward silence at a meeting
Managing temperature is -25 ± 5 DEG C, and the treatment temperature of third temperature awkward silence at a meeting is -75 ± 5 DEG C.
5. processing fuel oil VOC containing steam as claimed in claim 3sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
The refrigerant of condenser system is R404A and R23, wherein the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting use R404A, third temperature
Awkward silence at a meeting is bipolar cascade refrigeration system, i.e. R404A condenses R23, is realized by refrigerant heat exchanger (5)；The condensation of refrigeration system
Form is air-cooled condenser, i.e. R404A air-cooled condenser (1) and R23 air-cooled condenser (3).
6. processing fuel oil VOC containing steam as described in claim 1sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
Adsorption system includes vacuum pump (7), nitrogen hot gas heat exchanger (14), adsorption tanks A (15) and adsorption tanks B (16)；Adsorption tanks A (15)
With adsorption tanks B (16) parallel connection, a tank adsorbs tank parsing, and parsing is carried out by vacuum pump (7), and the high concentrations of gas of parsing enters
Condenser system import, nitrogen hot gas heat exchanger (14) come into operation in the deep analysis of adsorbent.
7. processing fuel oil VOC containing steam as claimed in claim 6sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
Adsorption system is used vacuum desorption, is desorbed at quarterly intervals with hot nitrogen, wherein hot nitrogen qi exhaustion using double adsorption tanks, normal desorption
Attached heat source provides for catalytic oxidation system, is realized by nitrogen hot gas heat exchanger (14), and three kinds of adsorbents are that petroleum vapor recovery is special
With adsorbent, it is used in combination, is loaded from lower to upper by the mass ratio of activated alumina, silica gel and molecular sieve 1:6:12.
8. processing fuel oil VOC containing steam as described in claim 1sCondensation adsorption catalytic oxidizing equipment, which is characterized in that
Catalytic oxidation system includes air chest (17), air blower (18), gas heat exchanger (19), anti-explosion electric heater (20) and catalysis
Oxidation reactor (21)；Tail gas passes sequentially through air chest (17), gas heat exchanger (19), anti-explosion electric heater (20) and catalysis oxygen
Change reactor (21), finally again passes by gas heat exchanger (19) heat exchange cooling qualified discharge；Air blower (18) be frequency conversion from
Electric thermo-couple temperature in heart blower and catalyst oxidation reactor (21) interlocks frequency conversion, and target value is 400 DEG C.
9. a kind of processing fuel oil VOC containing steamsCondensation adsorption catalysed oxidation processes, which comprises the steps of:
(1) by high concentration fuel oil VOCs containing steam by condenser system, pass through the first temperature awkward silence at a meeting, second temperature awkward silence at a meeting and the
Three temperature awkward silence at a meeting gradient coolings；The easy condensed components condensing recovery in high-concentration organic waste gas is handled for low concentration organic waste
Gas；
(2) gas at normal temperature after condensing enters adsorption system, and adsorption system adsorbs vacuum analysis mode using double tanks, further
Reduce organic exhaust gas concentration；
(3) gas concentration is fluctuated into lesser gas by catalytic oxidation system, the light component in low-concentration organic exhaust gas is urged
Change is oxidized to CO2And H2O completes the qualified discharge of fuel oil VOCs containing steam.
10. processing fuel oil VOC containing steam as claimed in claim 9sCondensation adsorption catalysed oxidation processes, which is characterized in that
In step (1), second temperature awkward silence at a meeting and third temperature awkward silence at a meeting are double-condenser parallel connection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811125420.7A CN108993140A (en) | 2018-09-26 | 2018-09-26 | A kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811125420.7A CN108993140A (en) | 2018-09-26 | 2018-09-26 | A kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108993140A true CN108993140A (en) | 2018-12-14 |
Family
ID=64590091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811125420.7A Pending CN108993140A (en) | 2018-09-26 | 2018-09-26 | A kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108993140A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111359429A (en) * | 2020-03-11 | 2020-07-03 | 北京安星达环保技术发展有限公司 | VOCs processing intelligent coupling device and method |
| CN112023689A (en) * | 2020-08-25 | 2020-12-04 | 中国石油天然气集团有限公司 | Purification method and purification system for acrylonitrile gas |
| CN112742181A (en) * | 2020-12-14 | 2021-05-04 | 浙江赛鹭鑫仪器有限公司 | VOCs waste gas treatment system and method |
| CN113996616A (en) * | 2021-11-12 | 2022-02-01 | 安庆军峰危险货物运输有限公司 | Hazardous chemical substance-related tank car green cleaning device and method based on VOCs separation and recovery technology |
| CN114887441A (en) * | 2022-05-05 | 2022-08-12 | 紫科装备股份有限公司 | Treatment process for VOCs in crude oil |
| CN116549996A (en) * | 2023-06-05 | 2023-08-08 | 青岛金海晟环保设备有限公司 | Energy-saving VOCs oil gas recovery treatment system and recovery method |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335197A (en) * | 2000-07-20 | 2002-02-13 | 中国石油化工集团公司 | Method of treating organic waste gas containing vapor |
| US20040011121A1 (en) * | 2000-06-22 | 2004-01-22 | Ashe Michael Joseph | System and method for abating a gas flow containing volatile organic compounds |
| KR20090079433A (en) * | 2008-01-17 | 2009-07-22 | 제이지 인바이론멘탈 테크놀로지 컴퍼니., 리미티드. | Method of Treating and Purifying Organic Waste Gas Through Condensing-Absorbing Process and Advanced Catalytic Oxidation Process and Apparatus Therefor |
| CN201578875U (en) * | 2009-10-27 | 2010-09-15 | 中国石油化工股份有限公司 | Low-temperature condensation and adsorption recovery device containing high-concentration low-level aromatic hydrocarbon exhaust gas |
| CN101874936A (en) * | 2009-11-20 | 2010-11-03 | 南京都乐制冷设备有限公司 | Condensed explosion-proof oil gas reclaiming device |
| CN103394267A (en) * | 2013-08-06 | 2013-11-20 | 广东申菱空调设备有限公司 | Oil gas recovery device combining condensation and adsorption |
| CN105080278A (en) * | 2015-08-13 | 2015-11-25 | 中国石油化工股份有限公司 | Oil and gas recovery method |
| CN106166399A (en) * | 2016-07-29 | 2016-11-30 | 泉州市天龙环境工程有限公司 | A kind of device for recovering oil and gas and method |
| CN106178807A (en) * | 2016-07-29 | 2016-12-07 | 常州大学 | A kind of gas recovery system for oil of " double condensation adsorption " integrated technology |
| CN107754546A (en) * | 2017-11-21 | 2018-03-06 | 南京都乐制冷设备有限公司 | A kind of condensation catalytic unit and processing method for handling high-concentration organic waste gas |
| CN207822795U (en) * | 2017-09-15 | 2018-09-07 | 南通亚泰工程技术有限公司 | Composite type ship harbour oil gas minimum discharge retracting device |
-
2018
- 2018-09-26 CN CN201811125420.7A patent/CN108993140A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040011121A1 (en) * | 2000-06-22 | 2004-01-22 | Ashe Michael Joseph | System and method for abating a gas flow containing volatile organic compounds |
| CN1335197A (en) * | 2000-07-20 | 2002-02-13 | 中国石油化工集团公司 | Method of treating organic waste gas containing vapor |
| KR20090079433A (en) * | 2008-01-17 | 2009-07-22 | 제이지 인바이론멘탈 테크놀로지 컴퍼니., 리미티드. | Method of Treating and Purifying Organic Waste Gas Through Condensing-Absorbing Process and Advanced Catalytic Oxidation Process and Apparatus Therefor |
| CN201578875U (en) * | 2009-10-27 | 2010-09-15 | 中国石油化工股份有限公司 | Low-temperature condensation and adsorption recovery device containing high-concentration low-level aromatic hydrocarbon exhaust gas |
| CN101874936A (en) * | 2009-11-20 | 2010-11-03 | 南京都乐制冷设备有限公司 | Condensed explosion-proof oil gas reclaiming device |
| CN103394267A (en) * | 2013-08-06 | 2013-11-20 | 广东申菱空调设备有限公司 | Oil gas recovery device combining condensation and adsorption |
| CN105080278A (en) * | 2015-08-13 | 2015-11-25 | 中国石油化工股份有限公司 | Oil and gas recovery method |
| CN106166399A (en) * | 2016-07-29 | 2016-11-30 | 泉州市天龙环境工程有限公司 | A kind of device for recovering oil and gas and method |
| CN106178807A (en) * | 2016-07-29 | 2016-12-07 | 常州大学 | A kind of gas recovery system for oil of " double condensation adsorption " integrated technology |
| CN207822795U (en) * | 2017-09-15 | 2018-09-07 | 南通亚泰工程技术有限公司 | Composite type ship harbour oil gas minimum discharge retracting device |
| CN107754546A (en) * | 2017-11-21 | 2018-03-06 | 南京都乐制冷设备有限公司 | A kind of condensation catalytic unit and processing method for handling high-concentration organic waste gas |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111359429A (en) * | 2020-03-11 | 2020-07-03 | 北京安星达环保技术发展有限公司 | VOCs processing intelligent coupling device and method |
| CN111359429B (en) * | 2020-03-11 | 2020-12-01 | 北京安星达环保技术发展有限公司 | VOCs processing intelligent coupling device and method |
| CN112023689A (en) * | 2020-08-25 | 2020-12-04 | 中国石油天然气集团有限公司 | Purification method and purification system for acrylonitrile gas |
| CN112742181A (en) * | 2020-12-14 | 2021-05-04 | 浙江赛鹭鑫仪器有限公司 | VOCs waste gas treatment system and method |
| CN113996616A (en) * | 2021-11-12 | 2022-02-01 | 安庆军峰危险货物运输有限公司 | Hazardous chemical substance-related tank car green cleaning device and method based on VOCs separation and recovery technology |
| CN114887441A (en) * | 2022-05-05 | 2022-08-12 | 紫科装备股份有限公司 | Treatment process for VOCs in crude oil |
| CN114887441B (en) * | 2022-05-05 | 2022-12-02 | 紫科装备股份有限公司 | Treatment process for VOCs in crude oil |
| CN116549996A (en) * | 2023-06-05 | 2023-08-08 | 青岛金海晟环保设备有限公司 | Energy-saving VOCs oil gas recovery treatment system and recovery method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108993140A (en) | A kind of processing fuel oil VOC containing steamsCondensation adsorption catalytic oxidizing equipment and method | |
| CN205730434U (en) | A kind of novel collection olefiant gas degree of depth reclaims and emission control system | |
| CN105080278B (en) | Oil-gas recovery method | |
| CN101579596A (en) | Device and method for recovering oil gas by condensation-adsorption combined technology | |
| CN107754546A (en) | A kind of condensation catalytic unit and processing method for handling high-concentration organic waste gas | |
| CN1935319B (en) | Oil gas adsorption recovering method and apparatus utilizing heating desorption | |
| CN107413173A (en) | A kind of efficiently organic exhaust gas recovery and treatment method and complexes | |
| CN104857735A (en) | Condensation adsorption recovery device of VOCs gas | |
| CN108722107A (en) | A kind of organic waste gas treatment equipment | |
| CN109939534A (en) | A kind of device of Adsorption Concentration and catalysis burning coupling processing VOCs exhaust gas | |
| CN202226647U (en) | Oil gas recovering system for gas station | |
| CN203549850U (en) | Organic waste gas comprehensive disposal system | |
| CN106310698A (en) | Oil and gas recycling method | |
| CN204865443U (en) | Exhaust gas treating device | |
| CN113209820B (en) | Process for treating low-air-volume VOCs waste gas by cryogenic serial catalytic oxidation | |
| CN213556279U (en) | Carbon dioxide ammonia method capturing and low-temperature liquefying system of coal-fired power plant | |
| CN209438375U (en) | A kind of condensation adsorption catalytic oxidizing equipment handling fuel oil VOCs containing steam | |
| CN102911704B (en) | Method for comprehensive oil gas recovery | |
| CN101165029A (en) | Method for extracting benzene-like compounds from flammable explosive gas of benzene-containing compounds | |
| CN202246576U (en) | Low-temperature condensation absorption recycling device for oil gas | |
| CN207546127U (en) | A kind of condensation catalytic unit for handling high-concentration organic waste gas | |
| CN107297085B (en) | A kind of steam blowing tail gas treatment process and complexes | |
| CN105833657A (en) | Alcohol mixture tail gas treatment device and method | |
| CN106310697A (en) | Novel integrated oil and gas deep recovery and emission control device | |
| CN215539820U (en) | Epoxypropane exhaust treatment device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181214 |