CN108976974A - A kind of nano montmorillonite modified silicon Acrylote/boron is without copper from polishing type antifouling paint and preparation method thereof - Google Patents
A kind of nano montmorillonite modified silicon Acrylote/boron is without copper from polishing type antifouling paint and preparation method thereof Download PDFInfo
- Publication number
- CN108976974A CN108976974A CN201810795100.6A CN201810795100A CN108976974A CN 108976974 A CN108976974 A CN 108976974A CN 201810795100 A CN201810795100 A CN 201810795100A CN 108976974 A CN108976974 A CN 108976974A
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- China
- Prior art keywords
- boron
- parts
- nano montmorillonite
- copper
- antifouling paint
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- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 229910052796 boron Inorganic materials 0.000 title claims abstract description 53
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 51
- 229910052901 montmorillonite Inorganic materials 0.000 title claims abstract description 37
- 238000005498 polishing Methods 0.000 title claims abstract description 35
- 239000003973 paint Substances 0.000 title claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 27
- 239000010949 copper Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 montmorillonite modified silicon Chemical class 0.000 claims abstract description 49
- 239000011347 resin Substances 0.000 claims abstract description 31
- 229920005989 resin Polymers 0.000 claims abstract description 31
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 30
- 239000010703 silicon Substances 0.000 claims abstract description 30
- 238000000576 coating method Methods 0.000 claims abstract description 14
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000002519 antifouling agent Substances 0.000 claims abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 7
- 239000012188 paraffin wax Substances 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 23
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 7
- 235000019441 ethanol Nutrition 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000012046 mixed solvent Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000138 intercalating agent Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- XNFIRYXKTXAHAC-UHFFFAOYSA-N tralopyril Chemical compound BrC1=C(C(F)(F)F)NC(C=2C=CC(Cl)=CC=2)=C1C#N XNFIRYXKTXAHAC-UHFFFAOYSA-N 0.000 claims description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 229940006460 bromide ion Drugs 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- MVDVWCSJXBTFLX-UHFFFAOYSA-M dodecyl-dimethyl-phenylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C1=CC=CC=C1 MVDVWCSJXBTFLX-UHFFFAOYSA-M 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- ZGYICYBLPGRURT-UHFFFAOYSA-N tri(propan-2-yl)silicon Chemical compound CC(C)[Si](C(C)C)C(C)C ZGYICYBLPGRURT-UHFFFAOYSA-N 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 3
- QAQSNXHKHKONNS-UHFFFAOYSA-N 1-ethyl-2-hydroxy-4-methyl-6-oxopyridine-3-carboxamide Chemical compound CCN1C(O)=C(C(N)=O)C(C)=CC1=O QAQSNXHKHKONNS-UHFFFAOYSA-N 0.000 claims description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- MTLWTRLYHAQCAM-UHFFFAOYSA-N 2-[(1-cyano-2-methylpropyl)diazenyl]-3-methylbutanenitrile Chemical compound CC(C)C(C#N)N=NC(C#N)C(C)C MTLWTRLYHAQCAM-UHFFFAOYSA-N 0.000 claims description 2
- KWGACYZYFZTYRN-UHFFFAOYSA-N OC(C)(C)C(C)(C)O.B(O)(O)O.BrCC1=CC=CC=C1 Chemical compound OC(C)(C)C(C)(C)O.B(O)(O)O.BrCC1=CC=CC=C1 KWGACYZYFZTYRN-UHFFFAOYSA-N 0.000 claims description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- KBPWECBBZZNAIE-UHFFFAOYSA-N aniline;hydron;bromide Chemical compound Br.NC1=CC=CC=C1 KBPWECBBZZNAIE-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001555 benzenes Chemical class 0.000 claims description 2
- 239000001055 blue pigment Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001054 red pigment Substances 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000001038 titanium pigment Substances 0.000 claims description 2
- PQSIXYSSKXAOFE-UHFFFAOYSA-N tri(propan-2-yl)silyl prop-2-enoate Chemical compound CC(C)[Si](C(C)C)(C(C)C)OC(=O)C=C PQSIXYSSKXAOFE-UHFFFAOYSA-N 0.000 claims description 2
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 claims description 2
- 229940094989 trimethylsilane Drugs 0.000 claims description 2
- MXSVLWZRHLXFKH-UHFFFAOYSA-N triphenylborane Chemical compound C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 MXSVLWZRHLXFKH-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims 2
- 150000002191 fatty alcohols Chemical class 0.000 claims 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- OPQYYINFGFKYSM-UHFFFAOYSA-N N=NC=NN.N=NC=NN.C(C(C)C)(=O)O Chemical compound N=NC=NN.N=NC=NN.C(C(C)C)(=O)O OPQYYINFGFKYSM-UHFFFAOYSA-N 0.000 claims 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 238000009830 intercalation Methods 0.000 claims 1
- 230000002687 intercalation Effects 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 231100000331 toxic Toxicity 0.000 abstract description 9
- 230000002588 toxic effect Effects 0.000 abstract description 9
- 230000002045 lasting effect Effects 0.000 abstract description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 2
- 102100040409 Ameloblastin Human genes 0.000 description 2
- WYLIRYQDDKDHLT-UHFFFAOYSA-N CC1=CC=CC=C1C.CC1=CC=CC=C1C Chemical compound CC1=CC=CC=C1C.CC1=CC=CC=C1C WYLIRYQDDKDHLT-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 101000891247 Homo sapiens Ameloblastin Proteins 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- 230000003834 intracellular effect Effects 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 125000005395 methacrylic acid group Chemical class 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 0 C***(C)N(OC)O*(C)=C Chemical compound C***(C)N(OC)O*(C)=C 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- AUBSNUSTVUZGCC-UHFFFAOYSA-N [NH4+].[Br-].C(C)[PH3+].[Br-] Chemical group [NH4+].[Br-].C(C)[PH3+].[Br-] AUBSNUSTVUZGCC-UHFFFAOYSA-N 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- KEVMYFLMMDUPJE-UHFFFAOYSA-N diisoamyl Natural products CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
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- 150000002829 nitrogen Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
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- 239000013535 sea water Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
A kind of nano montmorillonite modified silicon Acrylote/boron, from polishing type antifouling paint and preparation method thereof, weighs following components without copper in parts by weight: silicon Acrylote/boron is from polishing resin 30-60 parts, 0.5-3.5 parts of modified nano montmorillonite, 0.5-3.5 parts of chlorinated paraffin, 1-4 parts of antisettling agent, anti-fouling agent 1-10 parts organic, 18-50 parts of pigments and fillers, 14-26 parts of solvent；Glass microballoon is added into above-mentioned raw materials, glass microballoon and raw material are uniformly mixed with glass bar；Above-mentioned uniformly mixed raw material with high speed disperser is stirred and is ground to get.Coating low toxic and environment-friendly of the invention also has and hydrolyzes relatively stable excellent performance lasting, antifouling efficiency is stable.
Description
Technical field
The invention belongs to marine anti-pollution technical field, especially a kind of nano montmorillonite modified silicon Acrylote/boron without copper from
Polishing type antifouling paint and preparation method thereof.
Background technique
With the development of blue economic strategy, marine cause goes from strength to strength, and marine biofouling is to ship, underwater facility etc.
Brought harm is increasingly valued by people.On the one hand marine biofouling will increase ship resistance, cause to navigate
Speed reduces, fuel consumption increases；On the other hand it can accelerate metal erosion, shorten the service life of ship and marine facility.And
In the method for solving marine biofouling, be using antifouling paint is also most effective measure the most extensively.
There are many kinds of marine antifouling coatings, by whether containing poisonous anti-fouling agent and antifouling mechanism division, can be divided into two major classes:
Traditional marine antifouling coating and environmentally friendly marine antifouling coating.The antifouling mechanism of traditional marine antifouling coating is with one
Constant speed degree releases anti-fouling agent and forms toxic environment to prevent the attachment of marine organisms.But with the continuous release of anti-fouling agent, prevent
Dirty effect will gradually weaken.Most typically organic tin marine antifouling coating.Organic tin antifouling paint system is very big
Inhibiting effect played to biological attachment growth in degree, but because of its high toxicity, this kind of tributyl tin antifouling paint 2008 by
Disabling.Although organotin is disabled because of toxic hazard marine ecology, organic tin antifouling paint is obtained from polishing principles
It inherits and develops.The mechanism of Tin-free Spc Anti-fouling Paint with have tin self polishing copolymer antifouling paint essentially identical, be to pass through acrylic acid
Polymer hydrolysis in the seawater or ion exchange guarantee the steady exudation of anti-fouling agent, to reach anti-fouling effect, but at present
There is no a Tin-free Spc Anti-fouling Paints of good performance in the market.
Summary of the invention
The object of the present invention is to provide a kind of nano montmorillonite modified silicon Acrylote/boron without copper from polishing type antifouling paint,
Its not only not stanniferous, copper heavy metal, low toxic and environment-friendly also have and hydrolyze relatively stable excellent performance lasting, antifouling efficiency is stable.
It is a further object of the present invention to provide above-mentioned nano montmorillonite modified silicon Acrylote/boron without copper from the antifouling painting of polishing type
The preparation method of material, simple process is clear, and prepared antifouling paint good antifouling effect, low toxic and environment-friendly, mechanical strength are high.
To achieve the above object, the present invention takes following technical scheme:
A kind of nano montmorillonite modified silicon Acrylote/boron, from polishing type antifouling paint, includes following without copper in parts by weight
Component: silicon Acrylote/boron from polishing resin 30-60 parts, 0.5-3.5 parts of modified nano montmorillonite, 0.5-3.5 parts of chlorinated paraffin,
1-4 parts of antisettling agent, anti-fouling agent 1-10 parts organic, 18-50 parts of pigments and fillers, 14-26 parts of solvent.
Further, the silicon Acrylote/boron has following structure unit from polishing resin:
Wherein, n is more than or equal to 1, three R1Group is selected from the set being made of H, methyl and ethyl,
Two R2Group is selected from the set being made of carbomethoxy, ethoxycarbonyl and butyl ester base, R3Group is silane side group, two
A R4Group is selected from the set being made of alkyl and aryl, R5Group is former for nitrogen-containing group or containing substituted or unsubstituted nitrogen
The heterocyclic compound of son, wherein R5Middle carbon atom number is 1-15.Boron-containing compound and acrylic silicone are hung on side chain, main
Chain is acrylic acid soft segment and hard section alternating structure.
Further, the antisettling agent is selected from by Disparlon, polyoxyethylene fatty amine (alcohol), Polyoxyethylene fatty
The set of alcohol sulfate (Uniperol W), polyglycol ether composition；Organic anti-fouling agent be selected from by ZnPT, Econea, CuPT,
The set of Sea-Nine 211, DCOIT composition；The pigments and fillers be selected from by barium sulfate, Blue pigment, Red pigment,
The set of Carbon black, talcum powder, zinc oxide, titanium dioxide composition.
Further, steps are as follows from the preparation method of polishing resin for the silicon Acrylote/boron:
(1) monomer component and mass fraction used in are as follows:
15-45 parts of acrylic monomer
30-60 parts of acrylic silicone
1-12 parts of initiator
20-70 parts of boron-containing compound
100-200 parts of solvent
(2) the preparation method step:
Alcohols and benzene class two-component mixed solvent are added in four-hole bottle, is warming up to 95~100 DEG C；By acrylic compounds list
Body, acrylic silicone and one or more of azo-initiators are configured to mixed solution, then that the mixed solution is slow
It is added drop-wise in reaction system, when dropwise addition is 3 hours a length of, and later, the reaction was continued 2 hours；To guarantee conversion ratio, then add a small amount of
Benzoyl peroxide: benzoyl peroxide is dissolved in xylene solution, is added drop-wise in reaction system, and control time for adding is
0.5 hour, the reaction was continued later 1.5 hours；Finally obtain acrylic silicon resin；
Other two kinds of mixed solvents are added in four-hole bottle, are gradually added boron-containing compound while stirring, it is warming up to 95~
100℃；Then the acrylic silicon resin being prepared is added, wherein carboxyl-functional in boron-containing compound and acrylic silicon resin
Group's molar ratio is 1:1, and reaction continues 10 hours；Partial solvent is steamed, makes resin solid content 20%-70%, obtains third
Olefin(e) acid silicon/boron polishes resin certainly.Preferably, the olefin(e) acid silicon/boron is 40% from resin solid content is polished.
Further, the acrylic monomer is selected from by methacrylic acid (MAA), methyl methacrylate (MMA), third
The set of olefin(e) acid butyl ester (BA), butyl methacrylate (BMA), glycidyl methacrylate (GMA) composition；
The acrylic silicone is selected from by tri isopropyl silane acrylate, two silicon of methacryloxypropyl pentamethyl
Oxygen alkane, methacryloxypropyl amido trimethyl silane, acryloxy tri isopropyl silane, methacryloxy pentamethyl two
The set of siloxanes composition；
The boron-containing compound includes selected from by triphenylboron pyridine alkane, triphenyl borine octadecylamine, sodium tetraborate, nitrogen
Change the set of boron, 4- bromomethyl benzene boric acid pinacol ester composition；
The initiator is selected from by azo-bis-isobutyl cyanide (AIBN), azobisisovaleronitrile (AMBN), azobisisoheptonitrile
(ABVN), the set of azo-bis-iso-dimethyl (AIBME), azo isobutyl cyano formamide (V30) composition；
The solvent is selected from by dimethylbenzene, ethyl alcohol, tetrahydrofuran, n-butanol, isopropanol, propylene glycol monomethyl ether, acetone, nothing
The set of water methanol, deionized water composition.
Further, the modified nano montmorillonite the preparation method is as follows:
It weighs sodium-based montmorillonite and is dispersed in water under high velocity agitation, be warming up to 80~100 DEG C, be added under strong agitation
Intercalator stirs at low speed after strong stirring a period of time, after reacting a period of time；It filters, the white depositions that will be obtained, uses
Deionized water, which is washed to no bromide ion, to be existed, and obtained white depositions are put into baking oven and are dried at 60~80 DEG C, are ground
Mill, sieves for subsequent use.The modified nano montmorillonite has certain anti-seaweed performance.
Further, the intercalator is selected from by dodecyl dimethyl phenyl ammonium bromide, dodecyldimethylamine base phenyl
Ammonium bromide, cetyl trimethylammonium bromide, cetyl pyridinium bromide, double bromination dodecyldimethylamine base ethyl phosphonium bromide ammonium groups
At set.
A kind of nano montmorillonite modified silicon Acrylote/boron without copper from the preparation method of polishing type antifouling paint, it
Include the following steps:
Silicon Acrylote/boron is weighed from polishing resin, modified nano montmorillonite, chlorinated paraffin, anti-first, in accordance with parts by weight
It is micro- that glass is added into above-mentioned raw materials for sedimentation agent, organic anti-fouling agent, talcum powder, zinc oxide, titanium dioxide, pigments and fillers, solvent
Pearl is uniformly mixed glass microballoon and raw material with glass bar；
Above-mentioned uniformly mixed raw material is stirred and is ground with high speed disperser, stirring to fineness is less than 50um, most
Nano montmorillonite modified silicon Acrylote/boron is obtained eventually without copper from polishing type antifouling paint.
Further, the revolving speed of the high speed disperser is 30~50rpm, and mixing time is 30~50min.
The beneficial effects of the present invention are: coating of the invention is not stanniferous, copper heavy metal, have low toxic and environment-friendly, hydrolysis opposite
Stablize the stable advantage of lasting, antifouling efficiency；Modified nano montmorillonite can change the permeability of frustule wall, cause intracellular
Enzyme inactivation and protein denaturation, to show certain except algae activity, modified montmorillonite is good with resin compatible, coating
Excellent in mechanical performance；Good antifouling effect, low toxic and environment-friendly, intensity are high.
Specific embodiment
Embodiment 1
The two-component solvent of 80 parts of dimethylbenzene (Xylene) and 20 parts of dehydrated alcohols is added in 500mL four round flask,
95~100 DEG C are heated to, and is condensed back.Strength mechanical stirring.Each 1.5 parts of azodiisobutyronitriles (AIBN) and azo two is different
Heptonitrile (ABVN) and 30 parts of tri isopropyl silane acrylate, 15 parts of methacrylic acids (MAA), 10 parts of methyl methacrylates
(MMA), 15 parts of butyl acrylates (BA) are configured to mixed solution, are then gradually added drop-wise in reaction system under nitrogen protection,
3h is about when dropwise addition, rear the reaction was continued 2h, then add the xylene solution of 1 part of benzoyl peroxide (BPO).Last sustained response
1.5h obtains acrylic silicon resin (being abbreviated as AASP, similarly hereinafter).
112 parts of dimethylbenzene and 78 parts of acetone mixed solvents are added in four-hole bottle, and 20 parts of triphenylboron pyridine alkane are added, and are mixed
145 parts are added after closing uniformly and above walks the acrylic silicon resin (AASP) being prepared, and are reacted 10h under the same terms, are cooled to room
Temperature obtains silicon Acrylote/boron resin (being abbreviated as ABSP, similarly hereinafter).
Embodiment 2
500mL four round flask is added in the two-component solvent of 80 parts of dimethylbenzene (Xylene) and 20 parts of n-butanols (BuOH)
In, 95~100 DEG C are heated to, and be condensed back.Strength mechanical stirring.By 1.8 parts of azodiisobutyronitriles (AIBN) and 4.2 parts of idols
Nitrogen diisoamyl nitrile (AMBN) and 30 parts of methacryloxypropyl amido trimethyl silanes, 10 parts of methacrylic acids (MAA), 15 parts of first
Base methyl acrylate (MMA), 25 parts of butyl acrylates (BA) are configured to mixed solution, are then gradually added drop-wise under nitrogen protection
In reaction system, when dropwise addition, is about 3h, rear the reaction was continued 2h, then add 1.5 parts of benzoyl peroxides (BPO) dimethylbenzene it is molten
Liquid.Last sustained response 1.5h obtains acrylic silicon resin (AASP).
100 parts of dimethylbenzene and 80 parts of tetrahydrofuran mixed solvents are added in four-hole bottle, and 30 parts of triphenyl borines 18 are added
Alkylamine is added 150 parts after mixing and above walks the acrylic silicon resin being prepared, reacts 10h under same reaction conditions, cold
But silicon Acrylote/boron resin (ABSP) is obtained to room temperature.
Embodiment 3
It weighs a certain amount of sodium-based montmorillonite and is dispersed in water under high velocity agitation, 80~100 DEG C are warming up to, in strong mixing
Lower addition intercalator dodecyl dimethyl phenyl ammonium bromide stirs at low speed after strong stirring a period of time, reaction a period of time
Afterwards；It filters, the white depositions that will be obtained are washed with deionized to no bromide ion and exist, by obtained white depositions
It is put into baking oven and is dried at 60~80 DEG C, grind, sieve for subsequent use, obtain the modified nano montmorillonite with anti-seaweed property.
Embodiment 4
30 parts of silicon Acrylote/boron, which are weighed, according to formula polishes resin, 0.5 part of modified montmorillonoid, 0.5 part of chlorinated paraffin, 1 certainly
Part polyglycol ether, 3 parts of Econea, 3 parts of talcum powder, 12 parts of zinc oxide, 3 parts of titanium dioxide, 2 parts of barium sulfate, 14 parts of dimethylbenzene and
120 parts of glass microballoon is finally added in n-butanol into above-mentioned raw materials.By above-mentioned uniformly mixed raw material high speed disperser into
Row stirring and grinding, its fineness is tested after stirring, after fineness is less than 50um, is terminated stirring, is otherwise continued to stir
Until reaching requirement.Nano montmorillonite modified silicon Acrylote/boron is finally obtained without copper from polishing type antifouling paint.
Embodiment 5
30 parts of silicon Acrylote/boron, which are weighed, according to formula polishes resin, 1 part of modified montmorillonoid, 1.5 parts of chlorinated paraffins, 1.5 certainly
Part Disparlon, 3 parts of ZnPT, 4 parts of Econea, 3 parts of talcum powder, 15 parts of zinc oxide, 3 parts of titanium dioxide, 4 parts of barium sulfate, 21 parts
200 parts of glass microballoon is finally added in dimethylbenzene and tetrahydrofuran into above-mentioned raw materials.Above-mentioned uniformly mixed raw material is high
Fast dispersion machine is stirred and grinds, its fineness is tested after stirring, after fineness is less than 50um, terminates stirring, no
Then continue stirring until reaching requirement.It is antifouling without copper from polishing type to finally obtain nano montmorillonite modified silicon Acrylote/boron
Coating.
Referring to national standard " extra large soak test method before anti-fouling paint template " (GB/T5370-2007), embodiment is examined to exist
The anti-fouling effect of Qingdao sea area, for embodiment without obvious biological attachment after real extra large hanging plate three months, any surface finish shows the material
With good anti-fouling effect.
In conclusion the present invention has the advantages that nano montmorillonite modified silicon Acrylote/boron is without copper from the antifouling painting of polishing type
Material is compared with existing from polishing class coating, and by not stanniferous, copper heavy metal silicon Acrylote/boron, polishing resin is matrix tree certainly
Rouge, have the advantages that low toxic and environment-friendly, hydrolysis relatively it is stable it is lasting, antifouling efficiency is stable；The addition of modified montmorillonoid can be with simultaneously
So that coating is changed the permeability of fouling organism cell wall, leads to intracellular enzyme inactivation and protein denaturation, greatly improve coating
Antifouling capacity, while there is the mechanical property of stronger coating；Final prepared nano montmorillonite modified silicon Acrylote/boron
It is high from polishing type antifouling paint good antifouling effect, low toxic and environment-friendly, mechanical strength without copper.
Examples detailed above is technical conception and technical characteristics to illustrate the invention, can not be limited with this of the invention
Protection scope.The equivalent transformation or modification that all essence according to the present invention is done, should all cover in protection scope of the present invention
Within.
Claims (10)
1. a kind of nano montmorillonite modified silicon Acrylote/boron is without copper from polishing type antifouling paint, which is characterized in that in parts by weight
Including following components: silicon Acrylote/boron polishes resin 30-60 parts, 0.5-3.5 parts of modified nano montmorillonite, chlorinated paraffin certainly
0.5-3.5 parts, 1-4 parts of antisettling agent, anti-fouling agent 1-10 parts organic, 18-50 parts of pigments and fillers, 14-26 parts of solvent.
2. without copper from polishing type antifouling paint, feature exists nano montmorillonite modified silicon Acrylote/boron according to claim 1
In the silicon Acrylote/boron has following structure unit from polishing resin:
Wherein, n is more than or equal to 1, three R1Group is selected from the set being made of H, methyl and ethyl, two R2Group is selected from
The set being made of carbomethoxy, ethoxycarbonyl and butyl ester base, R3Group is silane side group, two R4Group is selected from by alkyl and aryl
The set of composition, R5Group is nitrogen-containing group or the heterocyclic compound containing substituted or unsubstituted nitrogen-atoms, wherein R5Middle carbon
Atomicity is 1-15.
3. nano montmorillonite modified silicon Acrylote/boron according to claim 1 is without copper from polishing type antifouling paint, feature
It is, the antisettling agent is selected from by Disparlon, polyoxyethylene fatty amine, polyoxyethylene fatty alcohol, polyoxyethylene fatty alcohol
The set of sulfate, polyglycol ether composition；Organic anti-fouling agent be selected from by ZnPT, Econea, CuPT, Sea-Nine 211,
The set of DCOIT composition；The pigments and fillers be selected from by barium sulfate, Blue pigment, Red pigment, Carbon black,
The set of talcum powder, zinc oxide, titanium dioxide composition.
4. nano montmorillonite modified silicon Acrylote/boron according to claim 1 or 2 without copper from polishing type antifouling paint,
It is characterized in that, steps are as follows from the preparation method of polishing resin for the silicon Acrylote/boron:
(1) monomer component and mass fraction used in are as follows:
15-45 parts of acrylic monomer
30-60 parts of acrylic silicone
1-12 parts of initiator
20-70 parts of boron-containing compound
100-200 parts of solvent
(2) the preparation method step:
Alcohols and benzene class two-component mixed solvent are added in four-hole bottle, is warming up to 95~100 DEG C；By acrylic monomer, third
Olefin(e) acid siloxanes and one or more of azo-initiators are configured to mixed solution, are then slowly dropped to the mixed solution
In reaction system, when dropwise addition, is 3 hours a length of, and later, the reaction was continued 2 hours；Then add a small amount of benzoyl peroxide: by peroxide
Change benzoyl to be dissolved in xylene solution, be added drop-wise in reaction system, control time for adding is 0.5 hour, is continued later anti-
It answers 1.5 hours；Finally obtain acrylic silicon resin；
Other two kinds of mixed solvents are added in four-hole bottle, is gradually added boron-containing compound while stirring, is warming up to 95~100
℃；Then the acrylic silicon resin being prepared is added, wherein carboxyl functional group in boron-containing compound and acrylic silicon resin
Molar ratio is 1:1, and reaction continues 10 hours；Partial solvent is steamed, makes resin solid content 20%-70%, obtains propylene
Sour silicon/boron polishes resin certainly.
5. nano montmorillonite modified silicon Acrylote/boron according to claim 4 is without copper from polishing type antifouling paint, feature
It is, the olefin(e) acid silicon/boron is 40% from resin solid content is polished.
6. nano montmorillonite modified silicon Acrylote/boron according to claim 4 is without copper from polishing type antifouling paint, feature
It is, the acrylic monomer is selected from by methacrylic acid, methyl methacrylate, butyl acrylate, methacrylic acid fourth
The set of ester, glycidyl methacrylate composition；
The acrylic silicone is selected from by tri isopropyl silane acrylate, two silicon oxygen of methacryloxypropyl pentamethyl
Alkane, methacryloxypropyl amido trimethyl silane, acryloxy tri isopropyl silane, two silicon of methacryloxy pentamethyl
The set of oxygen alkane composition；
The boron-containing compound includes selected from by triphenylboron pyridine alkane, triphenyl borine octadecylamine, sodium tetraborate, nitridation
The set of boron, 4- bromomethyl benzene boric acid pinacol ester composition；
The initiator is selected from by azo-bis-isobutyl cyanide, azobisisovaleronitrile, azobisisoheptonitrile, two isobutyric acid diformazan of azo
The set of ester, azo isobutyl cyano formamide composition；
The solvent is selected from the set being made of dimethylbenzene, ethyl alcohol, tetrahydrofuran, n-butanol, isopropanol, propylene glycol monomethyl ether.
7. nano montmorillonite modified silicon Acrylote/boron according to claim 1 or 2 without copper from polishing type antifouling paint,
Be characterized in that, the modified nano montmorillonite the preparation method is as follows:
It weighs sodium-based montmorillonite and is dispersed in water under high velocity agitation, be warming up to 80~100 DEG C, intercalation is added under strong agitation
Agent stirs at low speed after strong stirring a period of time, after reacting a period of time；Filter, the white depositions that will be obtained, spend from
Sub- water washing to no bromide ion exists, and obtained white depositions are put into baking oven and are dried at 60~80 DEG C, grinding, mistake
Sieve, it is spare.
8. nano montmorillonite modified silicon Acrylote/boron according to claim 7 is without copper from polishing type antifouling paint, feature
It is, the intercalator is selected from by dodecyl dimethyl phenyl ammonium bromide, dodecyldimethylamine base phenyl ammonium bromide, hexadecane
The set of base trimethylammonium bromide, cetyl pyridinium bromide, double bromination dodecyldimethylamine base ethyl phosphonium bromide ammoniums composition.
9. a kind of nano montmorillonite modified silicon Acrylote/boron described in any item of the claim 1 to 8 is antifouling from polishing type without copper
The preparation method of coating, which is characterized in that it includes the following steps:
Silicon Acrylote/boron, which is weighed, first, in accordance with parts by weight polishes resin, modified nano montmorillonite, chlorinated paraffin, anti-settling certainly
Agent, organic anti-fouling agent, talcum powder, zinc oxide, titanium dioxide, pigments and fillers, solvent, glass microballoon is added into above-mentioned raw materials, uses
Glass bar is uniformly mixed glass microballoon and raw material；
Above-mentioned uniformly mixed raw material is stirred and is ground with high speed disperser, stirring to fineness is less than 50um, final to obtain
To nano montmorillonite modified silicon Acrylote/boron without copper from polishing type antifouling paint.
10. nano montmorillonite modified silicon Acrylote/boron according to claim 9 is without copper from the preparation of polishing type antifouling paint
Method, it is characterised in that: the revolving speed of the high speed disperser is 30~50rpm, and mixing time is 30~50min.
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| CN110655843A (en) * | 2019-09-05 | 2020-01-07 | 哈尔滨工程大学 | C3N4Preparation method of photocatalytic self-polishing resin-based composite coating material |
| CN114213732A (en) * | 2021-11-25 | 2022-03-22 | 安徽永高塑业发展有限公司 | Modified master batch for enhancing weather resistance of polyethylene winding pipe and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655843A (en) * | 2019-09-05 | 2020-01-07 | 哈尔滨工程大学 | C3N4Preparation method of photocatalytic self-polishing resin-based composite coating material |
| CN114213732A (en) * | 2021-11-25 | 2022-03-22 | 安徽永高塑业发展有限公司 | Modified master batch for enhancing weather resistance of polyethylene winding pipe and preparation method thereof |
| CN117801181A (en) * | 2024-02-27 | 2024-04-02 | 烟台舜康生物科技有限公司 | Method for preparing organic-inorganic nanocomposite material by UV photopolymerization |
| CN117801181B (en) * | 2024-02-27 | 2024-05-14 | 烟台舜康生物科技有限公司 | Method for preparing organic-inorganic nanocomposite material by UV photopolymerization |
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Application publication date: 20181211 |