CN108976641A - A kind of environment friendly plastic rubber floor and its manufacturing method - Google Patents

A kind of environment friendly plastic rubber floor and its manufacturing method Download PDF

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Publication number
CN108976641A
CN108976641A CN201810489458.6A CN201810489458A CN108976641A CN 108976641 A CN108976641 A CN 108976641A CN 201810489458 A CN201810489458 A CN 201810489458A CN 108976641 A CN108976641 A CN 108976641A
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CN
China
Prior art keywords
parts
environment friendly
plastic rubber
rubber floor
friendly plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810489458.6A
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Chinese (zh)
Inventor
蔡淦明
喻敏
顾峰
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Anhui Ogi Plastic Co Ltd
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Anhui Ogi Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Ogi Plastic Co Ltd filed Critical Anhui Ogi Plastic Co Ltd
Priority to CN201810489458.6A priority Critical patent/CN108976641A/en
Publication of CN108976641A publication Critical patent/CN108976641A/en
Pending legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of environment friendly plastic rubber floor, the environment friendly plastic rubber floor is made from the following raw materials in parts by weight: 70-80 parts of calcium carbonate, PVC50-55 parts, 20-30 parts of polyaminoester emulsion, 30-35 parts of ethylene glycol ether ester, 15-20 parts of butyl acetate, 20-25 parts of maleic anhydride, 15-25 parts of biomass vegetable oil, 5-10 parts of nano silica, 5-10 parts of chitin, 5-10 parts of calcium carbonate, 3-5 parts of anti-aging agent, 3-5 parts of crosslinking agent.Environment-friendly type plastic adhesive floor of the present invention has preferable flexibility, light resistance, weatherability, nontoxic, degradable, and plastic floor raw material of the invention is cheap, simple process, is suitable for heavy industrialization and uses, practical.

Description

A kind of environment friendly plastic rubber floor and its manufacturing method
Technical field
The present invention relates to plastic material technical field, in particular to a kind of environment friendly plastic rubber floor and its manufacturing method.
Background technique
Plastic floor i.e. PVC floor, main component are pvc material.PVC floor since its pattern is abundant, Color is various and is widely used in the various aspects with business at home.Plastic floor is that popular one kind is novel in the world today Light body floor decorative material, also referred to as " light body material ", are a kind of products very popular in American-European and Asia Japan and Korea S, fashionable Foreign countries initially enter Chinese market from the beginning of the eighties, and big and medium-sized cities at home have obtained universal approval so far, and use is non- It is often extensive, such as the various fields such as indoor family, hospital, school, office building, factory, public place, supermarket, business, stadiums Institute.
In existing plastic floor, plasticizer generallys use dioctyl phthalate (DOP) or terephthalic acid (TPA) two Monooctyl ester (DOTP).Wherein, dioctyl phthalate is more toxic, and degradation capability is very low, is easy after plastic floor is discarded Cause environmental pollution;Dioctyl terephthalate toxicity is lower, relatively safety, but equally exists that degradation capability is lower to ask Topic, equally pollutes the environment for this purpose, it is proposed that a kind of environment friendly plastic rubber floor and its manufacturing method.
Summary of the invention
The main purpose of the present invention is to provide a kind of environment friendly plastic rubber floor and its manufacturing methods, can effectively solve background The problems in technology.
To achieve the above object, the technical scheme adopted by the invention is as follows:
A kind of environment friendly plastic rubber floor and its manufacturing method, the environment friendly plastic rubber floor are made from the following raw materials in parts by weight: carbonic acid 70-80 parts of calcium, PVC50-55 parts, 20-30 parts of polyaminoester emulsion, 30-35 parts of ethylene glycol ether ester, butyl acetate 15-20 Part, 20-25 parts of maleic anhydride, 15-25 parts of biomass vegetable oil, 5-10 parts of nano silica, 5-10 parts of chitin, carbon Sour calcium 5-10 parts, 3-5 parts of anti-aging agent, 3-5 parts of crosslinking agent.
A kind of manufacturing method on environment friendly plastic rubber floor, comprising the following steps:
(1), each raw material for standby is weighed according to parts by weight;
(2), step (1) is weighed into obtain each interior progress calendering process processing of raw material addition kneading machine, controlling kneading machine temperature is 150-180 DEG C, mixing time is 60-80 minutes;
(3), it will be cooled to 60-70 DEG C by the material being kneaded, is then rolled using tri-roll press machine, wherein upper roll temperature It is 155-165 DEG C, middle roll temperature is 170-180 DEG C, and lower roll temperatures are 150-160 DEG C;
(4), the product that calendering machining obtains is subjected to cooling, formed, both obtain finished product.
Compared with prior art, the invention has the following beneficial effects: environment-friendly type plastic adhesive floors of the present invention to have preferably Flexibility, light resistance, weatherability, nontoxic, degradable, plastic floor raw material of the invention is cheap, simple process, is suitable for extensive Industrialization is used, practical.
Specific embodiment
Embodiment 1
A kind of environment friendly plastic rubber floor, the environment friendly plastic rubber floor are made from the following raw materials in parts by weight: 70 parts of calcium carbonate, PVC50 Part, 20 parts of polyaminoester emulsion, 30 parts of ethylene glycol ether ester, 15 parts of butyl acetate, 20 parts of maleic anhydride, biomass are planted Object oil 15 parts, 5 parts of nano silica, 5 parts of chitin, 5 parts of calcium carbonate, 3 parts of anti-aging agent, 3 parts of crosslinking agent.
A kind of manufacturing method on environment friendly plastic rubber floor, comprising the following steps:
(1), each raw material for standby is weighed according to parts by weight;
(2), step (1) is weighed into obtain each interior progress calendering process processing of raw material addition kneading machine, control kneading machine temperature is 150 DEG C, mixing time is 60 minutes;
(3), 60 DEG C will be cooled to by the material being kneaded, be then rolled using tri-roll press machine, wherein upper roll temperature is 155 DEG C, middle roll temperature is 170 DEG C, and lower roll temperatures are 150 DEG C;
(4), the product that calendering machining obtains is subjected to cooling, formed, both obtain finished product.
Embodiment 2
A kind of environment friendly plastic rubber floor, the environment friendly plastic rubber floor are made from the following raw materials in parts by weight: 75 parts of calcium carbonate, PVC53 Part, 25 parts of polyaminoester emulsion, 33 parts of ethylene glycol ether ester, 18 parts of butyl acetate, 23 parts of maleic anhydride, biomass are planted Object oil 20 parts, 8 parts of nano silica, 8 parts of chitin, 8 parts of calcium carbonate, 4 parts of anti-aging agent, 4 parts of crosslinking agent.
A kind of manufacturing method on environment friendly plastic rubber floor, comprising the following steps:
(1), each raw material for standby is weighed according to parts by weight;
(2), step (1) is weighed into obtain each interior progress calendering process processing of raw material addition kneading machine, control kneading machine temperature is 160 DEG C, mixing time is 70 minutes;
(3), 65 DEG C will be cooled to by the material being kneaded, be then rolled using tri-roll press machine, wherein upper roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, and lower roll temperatures are 155 DEG C;
(4), the product that calendering machining obtains is subjected to cooling, formed, both obtain finished product.
Embodiment 3
A kind of environment friendly plastic rubber floor, the environment friendly plastic rubber floor are made from the following raw materials in parts by weight: 80 parts of calcium carbonate, PVC55 Part, 30 parts of polyaminoester emulsion, 35 parts of ethylene glycol ether ester, 20 parts of butyl acetate, 25 parts of maleic anhydride, biomass are planted Object oil 25 parts, 10 parts of nano silica, 10 parts of chitin, 10 parts of calcium carbonate, 5 parts of anti-aging agent, 5 parts of crosslinking agent.
A kind of manufacturing method on environment friendly plastic rubber floor, comprising the following steps:
(1), each raw material for standby is weighed according to parts by weight;
(2), step (1) is weighed into obtain each interior progress calendering process processing of raw material addition kneading machine, control kneading machine temperature is 180 DEG C, mixing time is 80 minutes;
(3), 70 DEG C will be cooled to by the material being kneaded, be then rolled using tri-roll press machine, wherein upper roll temperature is 165 DEG C, middle roll temperature is 180 DEG C, and lower roll temperatures are 160 DEG C;
(4), the product that calendering machining obtains is subjected to cooling, formed, both obtain finished product.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (2)

1. a kind of environment friendly plastic rubber floor, which is characterized in that the environment friendly plastic rubber floor is made from the following raw materials in parts by weight: carbonic acid 70-80 parts of calcium, PVC50-55 parts, 20-30 parts of polyaminoester emulsion, 30-35 parts of ethylene glycol ether ester, butyl acetate 15-20 Part, 20-25 parts of maleic anhydride, 15-25 parts of biomass vegetable oil, 5-10 parts of nano silica, 5-10 parts of chitin, carbon Sour calcium 5-10 parts, 3-5 parts of anti-aging agent, 3-5 parts of crosslinking agent.
2. a kind of manufacturing method on environment friendly plastic rubber floor, it is characterised in that the following steps are included:
(1) each raw material for standby is weighed according to parts by weight;
(2) step (1) is weighed into obtain each interior progress calendering process processing of raw material addition kneading machine, control kneading machine temperature is 150- 180 DEG C, mixing time is 60-80 minutes;
(3) it will be cooled to 60-70 DEG C by the material being kneaded, is then rolled using tri-roll press machine, wherein upper roll temperature It is 155-165 DEG C, middle roll temperature is 170-180 DEG C, and lower roll temperatures are 150-160 DEG C;
(4) product that calendering machining obtains is subjected to cooling, formed, both obtain finished product.
CN201810489458.6A 2018-05-21 2018-05-21 A kind of environment friendly plastic rubber floor and its manufacturing method Pending CN108976641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810489458.6A CN108976641A (en) 2018-05-21 2018-05-21 A kind of environment friendly plastic rubber floor and its manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810489458.6A CN108976641A (en) 2018-05-21 2018-05-21 A kind of environment friendly plastic rubber floor and its manufacturing method

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CN108976641A true CN108976641A (en) 2018-12-11

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110466222A (en) * 2019-07-12 2019-11-19 安徽绿谷新材料有限公司 A kind of radiation-resistant environment-friendly type mixing plastic floor tile pad and its processing method
CN111057293A (en) * 2019-12-31 2020-04-24 龙群科技(云南)有限公司 Degradable environment-friendly plastic and preparation method thereof
CN114808604A (en) * 2022-03-21 2022-07-29 宝力科技(宁国)有限公司 Nanometer degradation type plastic course

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105733210A (en) * 2016-05-13 2016-07-06 金宝丽科技(苏州)有限公司 Environment-friendly antistatic plastic floor and preparation method thereof
CN105838045A (en) * 2016-05-13 2016-08-10 金宝丽科技(苏州)有限公司 APET (Amorphous Polyethylene Terephthalate) plastic floor and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105733210A (en) * 2016-05-13 2016-07-06 金宝丽科技(苏州)有限公司 Environment-friendly antistatic plastic floor and preparation method thereof
CN105838045A (en) * 2016-05-13 2016-08-10 金宝丽科技(苏州)有限公司 APET (Amorphous Polyethylene Terephthalate) plastic floor and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110466222A (en) * 2019-07-12 2019-11-19 安徽绿谷新材料有限公司 A kind of radiation-resistant environment-friendly type mixing plastic floor tile pad and its processing method
CN111057293A (en) * 2019-12-31 2020-04-24 龙群科技(云南)有限公司 Degradable environment-friendly plastic and preparation method thereof
CN114808604A (en) * 2022-03-21 2022-07-29 宝力科技(宁国)有限公司 Nanometer degradation type plastic course

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Application publication date: 20181211

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