CN108975840A - A kind of technique of ardealite aerated-block - Google Patents

A kind of technique of ardealite aerated-block Download PDF

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Publication number
CN108975840A
CN108975840A CN201710395552.0A CN201710395552A CN108975840A CN 108975840 A CN108975840 A CN 108975840A CN 201710395552 A CN201710395552 A CN 201710395552A CN 108975840 A CN108975840 A CN 108975840A
Authority
CN
China
Prior art keywords
parts
aerated
ardealite
block
dosage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710395552.0A
Other languages
Chinese (zh)
Inventor
张儒全
班乃聪
张海琪
张兴龙
李西军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HONGRI CHEMICAL CO Ltd SHANDONG PROV
Original Assignee
HONGRI CHEMICAL CO Ltd SHANDONG PROV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HONGRI CHEMICAL CO Ltd SHANDONG PROV filed Critical HONGRI CHEMICAL CO Ltd SHANDONG PROV
Priority to CN201710395552.0A priority Critical patent/CN108975840A/en
Publication of CN108975840A publication Critical patent/CN108975840A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/143Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being phosphogypsum
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to energy saving building engineering material field, especially a kind of aerated-block production technology.Specifically using phosphogypsum powder as primary raw material, add land plaster, pulverized limestone, cement, foaming agent, foam stabilizer, water etc., and pass through following steps: stock, ingredient, stirring, casting, hot cell initial set, green body are cut, hot cell it is quiet stop, the aerated-block of the high standard performance that obtained dry density is low, compression strength is high such as microwave steam press maintenance;Wherein, it calculates according to the mass fraction, ardealite fine powder dosage is 350~500 parts, pulverized limestone dosage is 80~150 parts, slag powders dosage is 20~30 parts, cement consumption is 30~40 parts, foaming agent consumption is 0.3~0.5 part, foam stabilizer dosage is 0.04~0.06 part, water consumption is 200~300 parts.The present invention realizes waste utilization, reduces the cost of aerated-block, saves material and consumption, has biggish economic benefit and social benefit.

Description

A kind of technique of ardealite aerated-block
Technical field
The present invention relates to a kind of production methods of ardealite production aerated-block, belong to energy saving building engineering material field.
Background technique
The solid slag that ardealite generates when referring in phosphoric acid production with sulfuric acid treating phosphorite, main component are sulfuric acid Calcium, content generally can reach 70~90% or so, and submember contained therein is different and different with the rock phosphate in powder place of production, generally All phosphate and silicate containing rock composition Ca, Mg.China discharges about 20,000,000 tons of ardealite every year at present, adds up discharge capacity Nearly hundred million tons, be maximum one kind of discharge capacity in gypsum offscum, and the phosphogypsum slag of discharge occupies a large amount of soils, forms slag mountain, serious dirty Soil and water resources are contaminated, while restricting enterprise development, become a big environmentally friendly obstacle of enterprise development, the present invention mentions in order to solve the above problem New thinking has been supplied, has there is good economic benefit and social benefit.
Summary of the invention
For the raw material sources of existing aerated-block, the present invention provides a kind of producer of ardealite production aerated-block Method.
Technical solution of the present invention, a kind of production method of ardealite production aerated-block, the method steps are as follows:
(1) by water content be 0 ~ 25% ardealite and pulverized limestone, slag powders, cement in mass ratio: 500:150:30:40 carry out It is sufficiently mixed, is homogenized 1-3 hours;
(2) raw material for taking step (1) to be homogenized carries out stirring with slurry, and foaming agent stirring is added, foam stabilizer is added, reaction temperature is 30 ~ 60 DEG C, casting precuring is carried out, the precuring time is 2 ~ 3h;
(3) step (2) are subjected to steam press maintenance, vacuumizing the 0-- 6Mpa time controlled at 0.5-1 hours;
(4) it is carried out on the basis of step (3) raw pressure (heating), vacuum degree control is controlled in-0.6-1.0 Mpa, time in 1-2 Hour;
(5) on the basis of keeping 1.0 Mpa of vacuum degree, steam press maintenance 6-8 hours;
(6) decompression processing is carried out after the completion of step (5), pressure reduction is controlled at 1-2 hours, is slowly depressured;
(7) product is transported into storage storage.
The present invention is to be produced using enterprise's residue, belongs to environmentally friendly approval using phosphogypsum powder as primary raw material, production cost compared with It is low, product quality is good, and the environmental protection pressure of enterprise can be mitigated;Have compared with prior art following the utility model has the advantages that with ardealite For primary raw material, compares with flyash or sand feedstock production process with tradition and significantly reduce production cost.
The present invention plays positive work to the comprehensive utilization of ardealite to handle building gypsum plaster that ardealite is produced as raw material With meeting the requirement of national standard.
Present invention process process is clearly easily controllable, and application is good, the product of non-hazardous environment, and production environment is friendly.

Claims (1)

1. a kind of production method of ardealite production aerated-block, which is characterized in that the method steps are as follows:
(1) by water content be 0 ~ 25% ardealite and pulverized limestone, slag powders, cement in mass ratio: 500:150:30:40 carry out It is sufficiently mixed, is homogenized 1-3 hours;
(2) raw material for taking step (1) to be homogenized carries out stirring with slurry, and foaming agent stirring is added, foam stabilizer is added, reaction temperature is 30 ~ 60 DEG C, casting precuring is carried out, the precuring time is 2 ~ 3h;
(3) step (2) are subjected to steam press maintenance, vacuumizing the 0-- 6Mpa time controlled at 0.5-1 hours;
(4) it is carried out on the basis of step (3) raw pressure (heating), vacuum degree control is controlled in-0.6-1.0 Mpa, time in 1-2 Hour;
(5) on the basis of keeping 1.0 Mpa of vacuum degree, steam press maintenance 6-8 hours;
(6) decompression processing is carried out after the completion of step (5), pressure reduction is controlled at 1-2 hours, is slowly depressured;
(7) product is transported into storage storage.
CN201710395552.0A 2017-05-31 2017-05-31 A kind of technique of ardealite aerated-block Pending CN108975840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710395552.0A CN108975840A (en) 2017-05-31 2017-05-31 A kind of technique of ardealite aerated-block

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710395552.0A CN108975840A (en) 2017-05-31 2017-05-31 A kind of technique of ardealite aerated-block

Publications (1)

Publication Number Publication Date
CN108975840A true CN108975840A (en) 2018-12-11

Family

ID=64500974

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710395552.0A Pending CN108975840A (en) 2017-05-31 2017-05-31 A kind of technique of ardealite aerated-block

Country Status (1)

Country Link
CN (1) CN108975840A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2892116A1 (en) * 2005-10-14 2007-04-20 Inst Nat Sciences Appliq Producing a water-resistant calcium sulfate composition useful as a hydraulic binder in building materials comprises combining calcium sulfate with a sulfoaluminous clinker
CN101648403A (en) * 2009-09-04 2010-02-17 昆明理工大学 Method for producing air entrapping building block by utilizing ardealite
RU2009103066A (en) * 2009-01-30 2010-08-10 Общество с ограниченной ответственностью "Керам" (RU) RAW MATERIAL MIXTURE FOR PRODUCING GYPSUM BINDER AND PRODUCTS BASED ON IT
CN102173712A (en) * 2011-03-07 2011-09-07 雷冬华 Ardealite concrete aerated block
CN102515681B (en) * 2011-12-12 2014-07-02 昆明理工大学 Method for producing aerated building block with phosphogypsum as main raw material
CN106518153A (en) * 2016-10-31 2017-03-22 同济大学 Foamed concrete building block mainly prepared from phosphogypsum hydraulic composite binding material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2892116A1 (en) * 2005-10-14 2007-04-20 Inst Nat Sciences Appliq Producing a water-resistant calcium sulfate composition useful as a hydraulic binder in building materials comprises combining calcium sulfate with a sulfoaluminous clinker
RU2009103066A (en) * 2009-01-30 2010-08-10 Общество с ограниченной ответственностью "Керам" (RU) RAW MATERIAL MIXTURE FOR PRODUCING GYPSUM BINDER AND PRODUCTS BASED ON IT
CN101648403A (en) * 2009-09-04 2010-02-17 昆明理工大学 Method for producing air entrapping building block by utilizing ardealite
CN102173712A (en) * 2011-03-07 2011-09-07 雷冬华 Ardealite concrete aerated block
CN102515681B (en) * 2011-12-12 2014-07-02 昆明理工大学 Method for producing aerated building block with phosphogypsum as main raw material
CN106518153A (en) * 2016-10-31 2017-03-22 同济大学 Foamed concrete building block mainly prepared from phosphogypsum hydraulic composite binding material and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
中华人民共和国工业和信息化部发布: "《JC/T 2275-2014蒸汽加气混凝土生产设计规范》", 31 May 2015 *
国家环境保护局: "《化学工业固体废物治理》", 30 September 1991 *

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