CN108975834A - A kind of external-wall heat-insulation material and preparation method thereof - Google Patents

A kind of external-wall heat-insulation material and preparation method thereof Download PDF

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Publication number
CN108975834A
CN108975834A CN201810905004.2A CN201810905004A CN108975834A CN 108975834 A CN108975834 A CN 108975834A CN 201810905004 A CN201810905004 A CN 201810905004A CN 108975834 A CN108975834 A CN 108975834A
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CN
China
Prior art keywords
parts
external
wall heat
insulation material
powder
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Pending
Application number
CN201810905004.2A
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Chinese (zh)
Inventor
吕环胜
吴金权
郑红兵
吕宗平
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HEFEI SHENZHOU CONSTRUCTION CO Ltd
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HEFEI SHENZHOU CONSTRUCTION CO Ltd
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Priority to CN201810905004.2A priority Critical patent/CN108975834A/en
Publication of CN108975834A publication Critical patent/CN108975834A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • C04B28/082Steelmaking slags; Converter slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses a kind of external-wall heat-insulation materials, including below according to the raw material of parts by weight: 7 parts -10 parts of granite break flour, 85 parts -100 parts of polymer mortar, 5 parts -10 parts of cullet, 3 parts -6 parts of mixed mud waterproofing agent, 2 parts -5 parts of steel slag, 8 parts -20 parts of flyash, 5 parts -10 parts of nano organic montmorillonite, 5 parts -15 parts of fire retardant, 20 parts -28 parts of smoke suppressant, 2 parts -5 parts of mixed mud exciting agent, 3 parts -5 parts of U-Ramin MC;3 parts -10 parts of Si-Mo powder, 5 parts -15 parts of Al2O3 powder;The present invention is added to Si-Mo powder and Al2O3 powder, can make the external-wall heat-insulation material being prepared, and fire protecting performance is good, and heat insulation property is strong, and wear-resisting property is good, and stability is strong, has preferable physical and mechanical property.

Description

A kind of external-wall heat-insulation material and preparation method thereof
Technical field
The present invention relates to a kind of construction material and preparation method thereof, specifically a kind of external-wall heat-insulation material and its preparation side Method.
Background technique
Currently, the main product of China's external wall outer insulation material is that polystyrene foam plate and polystyrene extruded sheet etc. have The advantages of machine thermal insulation material, these organic insulation materials is that excellent thermal insulation performance, price are low, but there is also critical defects, are exactly They belong to combustible material, have the risk for causing fire.
Organic heat-insulating plate be also in the current wall heat insulation material market of China be widely used, but protective performance compared with Difference generates poison gas when especially burning.The fire incident frequency that China is caused by large area using organic insulation material in recent years Hair, causes huge economic loss and personal injury;In addition, current external-wall heat-insulation material is when using high-rise, Anti-wind pressure is lower;With the proposition of " energy conservation, low-carbon, environmental protection " theory, residence energy saving work is increasingly taken seriously in China, There are higher technical requirements in country in terms of building exterior wall heat preserving, and especially fire of high-rise building takes place frequently in recent years.
And existing external-wall heat-insulation material thermal insulation property, fire resistance, wear-resisting property are poor, can not meet existing society Needs, it is a kind of meet modern architecture requirement anti-flammability energy-saving and heat-insulating material development it is extremely urgent.
Summary of the invention
The purpose of the present invention is to provide a kind of external-wall heat-insulation materials and preparation method thereof, to solve in above-mentioned background technique The problem of proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of external-wall heat-insulation material, including below according to the raw material of parts by weight: 7 parts -10 parts of granite break flour, polymer sand 85 parts -100 parts of slurry, 3 parts -6 parts of mixed mud waterproofing agent, 2 parts -5 parts of steel slag, 8 parts -20 parts of flyash, is received 5 parts -10 parts of cullet Rice 5 parts -10 parts of organo montmorillonite, 5 parts -15 parts of fire retardant, 20 parts -28 parts of smoke suppressant, 2 parts -5 parts of mixed mud exciting agent, dichloro Change 3 parts -5 parts of calcium;3 parts -10 parts of Si-Mo powder, 5 parts -15 parts of Al2O3 powder.
As a further solution of the present invention: a kind of preparation method of external-wall heat-insulation material, steps are as follows:
S1 makes slurry, weighs each raw material according to above-mentioned parts by weight;By granite break flour, polymer mortar, cullet and Mixed mud waterproofing agent is mixed in the same container, and deionized water is added, and makes its solid content 9-12%, uniform stirring and in It is stirred at 40-50 DEG C, until being thoroughly mixed to form slurry;
S2 injects above-mentioned mixed slurry in ceramic ball grinder, then ratio of grinding media to material 1-2: 3-5, ball milling 5-8h is added Si-Mo powder and Al2O3 powder;
Steel slag, flyash, nano organic montmorillonite, fire retardant and smoke suppressant are added into 90 parts of water, persistently stir by S3 35-45min;It is placed in mixing and blending machine again, disperses 20min under the speed of 200r/min, obtain uniformly mixed slurry;
Mixed mud exciting agent, U-Ramin MC, Si-Mo powder and Al2O3 powder are mixed with above-mentioned raw materials, are further continued for by S4 18min is stirred under the speed of 200r/min;The mixture arrived;
Obtained mixture is injected foaming in mold by S5, expansion is formed;Then 6-8h is cured under the conditions of 75-80 DEG C, Obtain external-wall heat-insulation material.
Compared with prior art, the beneficial effects of the present invention are: preparation process of the present invention is simple, wherein being added to Si-Mo Powder and Al2O3 powder can make the external-wall heat-insulation material being prepared, and fire protecting performance is good, and heat insulation property is strong, wear-resisting property Good, stability is strong, has preferable physical and mechanical property, and at low cost, energy saving.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
A kind of external-wall heat-insulation material, including below according to the raw material of parts by weight: 7 parts of granite break flour, polymer mortar 85 Part, 5 parts of cullet, 3 parts of mixed mud waterproofing agent, 2 parts of parts of steel slag, 8 parts of flyash, 5 parts of nano organic montmorillonite, 5 parts of fire retardant, 20 parts of smoke suppressant, 2 parts of mixed mud exciting agent, 3 parts of U-Ramin MC;3 parts of Si-Mo powder, 5 parts of Al2O3 powder.
A kind of preparation method of external-wall heat-insulation material, steps are as follows:
S1 makes slurry, weighs each raw material according to above-mentioned parts by weight;By granite break flour, polymer mortar, cullet and Mixed mud waterproofing agent is mixed in the same container, and deionized water is added, and makes its solid content 9%, uniform stirring and in 40 It is stirred at DEG C, until being thoroughly mixed to form slurry;
S2, above-mentioned mixed slurry is injected in ceramic ball grinder, ratio of grinding media to material 1: 3, then Si-Mo powder is added in ball milling 5h With Al2O3 powder;
Steel slag, flyash, nano organic montmorillonite, fire retardant and smoke suppressant are added into 90 parts of water, persistently stir by S3 35min;It is placed in mixing and blending machine again, disperses 20min under the speed of 200r/min, obtain uniformly mixed slurry;
Mixed mud exciting agent, U-Ramin MC, Si-Mo powder and Al2O3 powder are mixed with above-mentioned raw materials, are further continued for by S4 18min is stirred under the speed of 200r/min;The mixture arrived;
Obtained mixture is injected foaming in mold by S5, expansion is formed;Then 6h is cured under the conditions of 75 DEG C, obtained External-wall heat-insulation material.
Embodiment 2
A kind of external-wall heat-insulation material, including below according to the raw material of parts by weight: 8 parts of granite break flour, polymer mortar 90 Part, 7 parts of cullet, 4 parts of mixed mud waterproofing agent, 3.5 parts of steel slag, 12 parts of flyash, 7 parts of nano organic montmorillonite, fire retardant 8 Part, 24 parts of smoke suppressant, 3 parts of mixed mud exciting agent, 3.5 parts of U-Ramin MC;6.5 parts of Si Mo powder, 8 parts of Al2O3 powder.
A kind of preparation method of external-wall heat-insulation material, steps are as follows:
S1 makes slurry, weighs each raw material according to above-mentioned parts by weight;By granite break flour, polymer mortar, cullet and Mixed mud waterproofing agent is mixed in the same container, and deionized water is added, and makes its solid content 10%, uniform stirring and in 43 At a temperature of be stirred, until be thoroughly mixed to form slurry;
S2, above-mentioned mixed slurry is injected in ceramic ball grinder, ratio of grinding media to material 1: 4, then Si-Mo powder is added in ball milling 6h With Al2O3 powder;
Steel slag, flyash, nano organic montmorillonite, fire retardant and smoke suppressant are added into 90 parts of water, persistently stir by S3 38min;It is placed in mixing and blending machine again, disperses 20min under the speed of 200r/min, obtain uniformly mixed slurry;
Mixed mud exciting agent, U-Ramin MC, Si-Mo powder and Al2O3 powder are mixed with above-mentioned raw materials, are further continued for by S4 18min is stirred under the speed of 200r/min;The mixture arrived;
Obtained mixture is injected foaming in mold by S5, expansion is formed;Then 7h is cured under the conditions of 78 DEG C, obtained External-wall heat-insulation material.
Embodiment 3
A kind of external-wall heat-insulation material, including below according to the raw material of parts by weight: 9 parts of granite break flour, polymer mortar 95 Part, 8.5 parts of cullet, 5.5 parts of mixed mud waterproofing agent, 4.5 parts of steel slag, 16 parts of flyash, 8.5 parts of nano organic montmorillonite, resistance Fire 12 parts of agent, 26 parts of smoke suppressant, 4 parts of mixed mud exciting agent, 4.5 parts of U-Ramin MC;8 parts of Si Mo powder, 12 parts of Al2O3 powder.
A kind of preparation method of external-wall heat-insulation material, steps are as follows:
S1 makes slurry, weighs each raw material according to above-mentioned parts by weight;By granite break flour, polymer mortar, cullet and Mixed mud waterproofing agent is mixed in the same container, and deionized water is added, and makes its solid content 11%, uniform stirring and in 48 It is stirred at DEG C, until being thoroughly mixed to form slurry;
S2, above-mentioned mixed slurry is injected in ceramic ball grinder, ratio of grinding media to material 2: 4, then Si-Mo powder is added in ball milling 7h With Al2O3 powder;
Steel slag, flyash, nano organic montmorillonite, fire retardant and smoke suppressant are added into 90 parts of water, persistently stir by S3 44min;It is placed in mixing and blending machine again, disperses 20min under the speed of 200r/min, obtain uniformly mixed slurry;
Mixed mud exciting agent, U-Ramin MC, Si-Mo powder and Al2O3 powder are mixed with above-mentioned raw materials, are further continued for by S4 18min is stirred under the speed of 200r/min;The mixture arrived;
Obtained mixture is injected foaming in mold by S5, expansion is formed;Then 7.58h is cured under the conditions of 78 DEG C, obtained To external-wall heat-insulation material.
Embodiment 4
A kind of external-wall heat-insulation material, including below according to the raw material of parts by weight: 10 parts of granite break flour, polymer mortar 100 parts, 10 parts of cullet, 6 parts of mixed mud waterproofing agent, 5 parts of steel slag, 20 parts of flyash, 10 parts of nano organic montmorillonite, fire retardant 15 parts, 28 parts of smoke suppressant, 5 parts of mixed mud exciting agent, 5 parts of U-Ramin MC;10 parts of Si Mo powder, 15 parts of Al2O3 powder.
A kind of preparation method of external-wall heat-insulation material, steps are as follows:
S1 makes slurry, weighs each raw material according to above-mentioned parts by weight;By granite break flour, polymer mortar, cullet and Mixed mud waterproofing agent is mixed in the same container, and deionized water is added, and makes its solid content 12%, uniform stirring and in 50 It is stirred at DEG C, until being thoroughly mixed to form slurry;
S2, above-mentioned mixed slurry is injected in ceramic ball grinder, then Si-Mo powder is added in ratio of grinding media to material 2:5, ball milling 8h With Al2O3 powder;Ah
Steel slag, flyash, nano organic montmorillonite, fire retardant and smoke suppressant are added into 90 parts of water, persistently stir by S3 45min;It is placed in mixing and blending machine again, disperses 20min under the speed of 200r/min, obtain uniformly mixed slurry;
Mixed mud exciting agent, U-Ramin MC, Si-Mo powder and Al2O3 powder are mixed with above-mentioned raw materials, are further continued for by S4 18min is stirred under the speed of 200r/min;The mixture arrived;
Obtained mixture is injected foaming in mold by S5, expansion is formed;Then 8h is cured under the conditions of 80 DEG C, obtained External-wall heat-insulation material.
Comparative example 1
The difference of comparative example 1 and embodiment 3 is not add Si-Mo powder, remaining step is constant.
Comparative example 2
Comparative example 2 and the difference of embodiment 3 are, do not add Al2O3 powder, remaining step is constant.
Comparative example 3
Comparative example 3 and the difference of embodiment 3 are, do not add Si-Mo powder and Al2O3 powder, remaining step is constant.
The resulting wall thermal insulation material finished product of embodiment 1-4 and comparative example 1-3 is carried out technical indicator to test;As a result such as Following table:
As seen from the above table, the present invention is added to Si-Mo powder and Al2O3 powder, can make the exterior-wall heat insulation material being prepared Material, fire protecting performance is good, and heat insulation property is strong, and wear-resisting property is good, and stability is strong, with preferable physical and mechanical property, and at This is low, energy saving.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (7)

1. a kind of external-wall heat-insulation material, which is characterized in that including below according to the raw material of parts by weight: 7 part -10 of granite break flour Part, 85 parts -100 parts of polymer mortar, 5 parts -10 parts of cullet, 3 parts -6 parts of mixed mud waterproofing agent, 2 parts -5 parts of steel slag, flyash 8 parts -20 parts, 5 parts -10 parts of nano organic montmorillonite, 5 parts -15 parts of fire retardant, 20 parts -28 parts of smoke suppressant, mixed mud exciting agent 2 - 5 parts, 3 parts -5 parts of U-Ramin MC of part;3 parts -10 parts of Si-Mo powder, 5 parts -15 parts of Al2O3 powder.
2. a kind of preparation method of external-wall heat-insulation material as described in claim 1, which is characterized in that steps are as follows:
S1 makes slurry, weighs each raw material according to above-mentioned parts by weight;By granite break flour, polymer mortar, cullet and
Soil waterproofing agent is mixed in the same container, and deionized water solidification is added;
Above-mentioned mixed slurry is injected in ceramic ball grinder, Si-Mo powder and Al2O3 powder is then added by S2;
Steel slag, flyash, nano organic montmorillonite, fire retardant and smoke suppressant are added into 90 parts of water S3, continue
Stir 35-45min;
Mixed mud exciting agent, U-Ramin MC, Si-Mo powder and Al2O3 powder are mixed with above-mentioned raw materials, are further continued in 200r/ by S4 18min is stirred under the speed of min;The mixture arrived;
Obtained mixture is injected foaming in mold by S5, expansion is formed;6-8h followed by aging, obtains external-wall heat-insulation material.
3. the preparation method of external-wall heat-insulation material according to claim 2, which is characterized in that in step S1, addition go from Sub- water makes solid content 9-12%, then uniform stirring and is stirred at 40-50 DEG C, until being thoroughly mixed to form slurry.
4. the preparation method of external-wall heat-insulation material according to claim 3, which is characterized in that in step S2, by mixing slurry After material injects in ceramic ball grinder, ratio of grinding media to material 1-2: 3-5, ball milling 5-8h.
5. the preparation method of external-wall heat-insulation material according to claim 4, which is characterized in that in step S3, stir 35- It after 45min, then is placed in mixing and blending machine, disperses 20min under the speed of 200r/min, obtain uniformly mixed slurry.
6. the preparation method of external-wall heat-insulation material according to claim 5, which is characterized in that in step S4, mixing time For 18min.
7. the preparation method of external-wall heat-insulation material according to claim 6, which is characterized in that in step S5, curing temperature For 75-80 DEG C of condition.
CN201810905004.2A 2018-08-09 2018-08-09 A kind of external-wall heat-insulation material and preparation method thereof Pending CN108975834A (en)

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