CN108975821A - A kind of environmental type tile binding material and preparation method thereof - Google Patents
A kind of environmental type tile binding material and preparation method thereof Download PDFInfo
- Publication number
- CN108975821A CN108975821A CN201810988863.2A CN201810988863A CN108975821A CN 108975821 A CN108975821 A CN 108975821A CN 201810988863 A CN201810988863 A CN 201810988863A CN 108975821 A CN108975821 A CN 108975821A
- Authority
- CN
- China
- Prior art keywords
- parts
- faujasite
- nano
- rice hull
- hull ash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
- C04B2111/00646—Masonry mortars
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of environmental type tile binding material, the raw material including following parts by weight: 22-28 parts of portland cement, gather materials 44-52 parts of compound object, polypropylene fibre are faujasite 12-16 parts composite modified, are modified rice hull ash 5-9 parts, 1.2-1.8 parts of pyrophyllite powder, 1-3 parts of nano-composition, 0.5-0.9 parts of nano-graphene powder, thixotropic agent 0.1-0.3 parts inorganic, 0.2-0.5 parts of water-reducing agent, 12-20 parts of deionized water.The present invention is using portland cement, the compound object that gathers materials as main base, then other inorganic material of arranging in pairs or groups, raw material are all made of inorganic raw material, it is environmentally protective, and adhesive strength is big, modified rice hull ash in the present invention, rice hull ash large specific surface area, lignin have dispersibility in concrete.
Description
Technical field
The present invention relates to building material technical fields, and in particular to a kind of environmental type tile binding material and its preparation side
Method.
Background technique
Tile binding material is a kind of high-quality environment protective type polyalcohol cement basis compoiste adhering material, belongs in tile materials
One kind, it is using good cement and good quartz sand and polymer adhesive as major ingredient, in addition proportion speed is various
Powdery binding material made of additive is mixed through mixing machine stirring, the product have certain flexibility, fundamentally solve
Cracking, hollowing in the presence of building decoration and fitment, the disadvantages such as fall off and leak.
Raw material in existing tile binding material is assembled using Organic Ingredients, and Organic Ingredients easily releases harmful substance,
Environment protection requirement is not met, Chinese patent literature (notification number: CN106010388B) discloses a kind of ceramic tile bond, it is wrapped
It has included following weight percentage components: deionized water 16-17%；Mother liquor 73-75%；Butadiene-styrene latex 7-9%；Fungicide
0.2%；Propylene glycol 1.5-2.0%；Wherein, the mother liquor includes following weight percentage components: deionized water 43-
48%；Soft monomer 46-51%；Hard monomer 0.55-0.75%；Functional monomer 1.4-2.0%；Initiator 0.20-0.30%；It protects
Protect colloid 1.1-1.3%；Emulsifier 0.7-1.0%；Organic amino pH adjusting agent 0.6-0.8%；Buffer 0.2-0.3%, this is viscous
Connecing the raw materials such as mother liquor in agent, butadiene-styrene latex is mostly organic material, and the feature of environmental protection is poor.
In addition, carrying out mixture using organic-inorganic raw material in existing bonding agent, or assembled entirely using inorganic raw material, the feature of environmental protection
On obtained very big improvement, but do not cause then whole ingredient viscous in view of interfacial adhesion strength, chemical adhesive power between raw material
Connect intensity decline.Chinese patent literature (publication number: CN107162523A) discloses a kind of tile binding material and preparation method thereof,
Wherein, the tile binding material by weight, 55~70 parts of quartz sand；18~23 parts of portland cement；7~9 parts of superfine cement；
4~6 parts of flyash；1.0~2.0 parts of SILICA FUME；1.0~2.0 parts of swelling agent；0.045~0.055 part of air entraining agent；Water-reducing agent 0.2
~0.3 part；0.08~1.0 part of polypropylene fibre；0.09~0.11 part of aluminum magnesium silicate thixotropic agent；The partial size of the SILICA FUME is
0.1~0.3um；The partial size of the superfine cement is 600~800 mesh, which is assembled using inorganic material entirely, though green ring
It protects, though the performances such as polypropylene fibre intensity added in raw material are good, but its surface hydrophilicity is poor, is not easy and other raw material groups
Match, reduces the integral strength of material instead；Based on this, the present invention after further research, prepares environmentally protective and performance
More perfect tile binding material.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental type tile binding materials and preparation method thereof, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of environmental type tile binding material, the raw material including following parts by weight:
22-28 parts of portland cement, gather materials the composite modified faujasite 12-16 of 44-52 parts of compound object, polypropylene fibre
Part, modified rice hull ash 5-9 parts, 1.2-1.8 parts of pyrophyllite powder, 1-3 parts of nano-composition, 0.5-0.9 parts of nano-graphene powder, nothing
0.1-0.3 parts of machine thixotropic agent, 0.2-0.5 parts of water-reducing agent, 12-20 parts of deionized water；
The composite modified faujasite of polypropylene fibre the preparation method comprises the following steps:
Step 1 prepares modcfied faujasite: faujasite being first acidified, Re-boostering test is subsequently added to deionization
It is stirred cleaning in water, until cleaning solution is neutrality, the faujasite after cleaning is ground, crosses 240-300 mesh, then
It is added in magnetic stirring apparatus, it is spare, then the lauryl sodium sulfate progress of faujasite gross mass 6-10% is added thereto
Stirring, speed of agitator rise to 65-75r/min, stir 15-25min, nanofiber powder is then added, carry out ultrasonic disperse 15-
25min is then filtered again, is dried, ground 30-70 mesh, spare；
Step 2, the preparation of the composite modified faujasite of polypropylene fibre: modification octahedral prepared by polypropylene, step 1
Zeolite is mixed according to weight ratio 85:15, then carries out blending extrusion, and extrusion temperature is 165-175 DEG C, subsequent re-dry,
It is re-fed into multi-functional melt spinning machine, forms birth fiber, wherein 220-230 DEG C of spinning temperature, winding speed 152-
154m/min；4 times of fiber post-tensioning of birth, 123-125 DEG C of draft temperature, setting temperature is 130 DEG C to get spare fiber, with
Spare fiber is subjected to sided corona treatment again afterwards, sided corona treatment power is 5Kw, and treatment temperature is 25 DEG C, and the processing time is 10min,
Up to the composite modified faujasite of polypropylene fibre.
Be as further scheme of the invention: the environmental type tile binding material includes the original of following parts by weight
Material:
24-27 parts of portland cement, gather materials the composite modified faujasite 13-15 of 45-51 parts of compound object, polypropylene fibre
Part, modified rice hull ash 6-9 parts, 1.4-1.8 parts of pyrophyllite powder, 2-3 parts of nano-composition, 0.6-0.8 parts of nano-graphene powder, nothing
0.2-0.3 parts of machine thixotropic agent, 0.3-0.5 parts of water-reducing agent, 14-18 parts of deionized water.
Be as further scheme of the invention: the environmental type tile binding material includes the original of following parts by weight
Material:
25 parts of portland cement, 14 parts of the composite modified faujasite of 48 parts of compound object, polypropylene fibre that gathers materials, modified rice husk
Grey 7 parts, 1.5 parts of pyrophyllite powder, 2 parts of nano-composition, 0.7 part of nano-graphene powder, 0.2 part of inorganic thixotropic agent, water-reducing agent
0.35 part, 16 parts of deionized water.
Be as further scheme of the invention: the compound object that gathers materials is coarse aggregate, fine aggregate according to weight ratio 1:9 group
At compound object, wherein coarse aggregate be granite stones, fine aggregate is quartz sand.
It is as further scheme of the invention: is received in the preparation method of the composite modified faujasite of polypropylene fibre
Rice fiber powder is nanofiber powder R51.
Be as further scheme of the invention: the rice hull ash preparation method is that rice husk is carried out high temperature sintering, calcination
Temperature is 750-850 DEG C of formation rice hull ash, is then add to deionized water rice hull ash, is added while stirring, is then added again
The lignin for entering rice hull ash total amount 12-18% continues to stir 6-12min, then filters, dries again, be re-fed into steam blasting machine
In material bin, it is passed through saturated vapor, pressure 1.1-1.5MPa, time 20-30s carry out pressure release then to get rice hull ash.
Be as further scheme of the invention: the nano-composition is nanometer calcium carbonate, nano-ceramic powder according to weight
Amount is formed than 4:1, and wherein the partial size of nanometer calcium carbonate is 40nm, and nano-ceramic powder partial size is 60nm.
Be as further scheme of the invention: the inorganic thixotropic agent is fumed silica, and water-reducing agent is polycarboxylic acids
Water-reducing agent.
The present invention also provides a kind of methods for preparing environmental type tile binding material, comprising the following steps:
Step 1, by portland cement, the composite modified faujasite of polypropylene fibre, modified rice hull ash, nano-composition,
Nano-graphene powder, progress is dry-mixed to be stirred at low speed, and obtains premix A；
Premix A, pyrophyllite powder, the compound object that gathers materials that step 1 obtains are carried out high-speed stirred, are premixed by step 2
Expect B；
Premix B in step 2, inorganic thixotropic agent, water-reducing agent, deionized water are carried out secondary low speed and stirred by step 3
It mixes to get tile binding material of the invention.
Be as further scheme of the invention: the step 1 is dry-mixed to stir at low speed middle speed of agitator as 55-65r/
Min, mixing time 25min；Speed of agitator is 105-115r/min, mixing time 10min in step 2 high-speed stirred；Step
The secondary speed of agitator stirred at low speed is 35-45r/min, mixing time 35min in rapid three.
Compared with prior art, the present invention have it is following the utility model has the advantages that
(1) present invention is using portland cement, the compound object that gathers materials as main base, then other inorganic material of arranging in pairs or groups, raw material
It is all made of inorganic raw material, it is environmentally protective, and adhesive strength is big, modified rice hull ash, rice hull ash large specific surface area are wooden in the present invention
Element has dispersibility in concrete, is passed through using rice hull ash with lignin and is mixed, then Steam explosion treatment, can enhance bonding agent
Tightness between raw material improves the chemical interactions between each raw material, while playing synergistic effect with nano-composition, can be into
One step enhances adhesive adhesive strength, and the pyrophyllite powder of addition is layer structure, reduces nanoparticle and reunites in concrete, together
It is dispersed in the base that Shi Zengqiang is modified rice hull ash, the composite modified faujasite of polypropylene fibre.
(2) present invention carries out blending extrusion, then wire drawing using modcfied faujasite and polypropylene, and modcfied faujasite is by eight
Face zeolite is first activated, and is then mixed with nanofiber powder, and nanofiber powder has the characteristics that surface area is big, and octahedral boils
Stone is made of oxygen-octahedron and aluminum-oxygen tetrahedron basic structural unit, modified through nanofiber, is applied in polypropylene
Improve the hydrophily of polypropylene fibre, and the interfacial adhesion of enhancing and concrete substrate.
Specific embodiment
Combined with specific embodiments below, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Raw material used in the embodiment of the present invention and manufacturer are as follows:
Raw material used in the embodiment of the present invention is as follows:
Portland cement, Mianzhu Bai Chuan special cement Co., Ltd；Granite stones, sunshine Wanshan Mountain Shi Ye Co., Ltd,
24-28mm, crush index 8.8%；Quartz sand, Lingshou County Hui Mao mineral products processing factory, fineness modulus 2.8；Faujasite, Xiamen
Hong Jing Environmental Protection Technology Co., Ltd；Lauryl sodium sulfate, Suzhou Rong Quan Chemical Co., Ltd.；Nanofiber powder, nine river science and technology
Co., Ltd；Polypropylene, the prosperous resource engineering chemistry Co., Ltd in Jinan, lignin, Shandong Xin Zhuo Chemical Co., Ltd.；Pyrophillite, spirit
Shou County Hui Mao mineral products processing factory, rice husk are sloughed the grain of rice for rice in the market and are formed；Nanometer calcium carbonate, nano-ceramic powder, gas phase
Silica, Jinan Xin Qijian Chemical Industry Science Co., Ltd；Polycarboxylate water-reducer, Shouguang Song Chuan commercial auxiliaries Co., Ltd.
Embodiment 1:
A kind of method preparing environmental type tile binding material of the present embodiment, comprising the following steps:
Step 1, by 22 parts of portland cements, the composite modified faujasite of 12 parts of polypropylene fibres, 5 parts of modified rice hull ash,
1 part of nano-composition, 0.5 part of nano-graphene powder, progress is dry-mixed to be stirred at low speed, speed of agitator 55r/min, and mixing time is
25min obtains premix A, and wherein nano-composition is nanometer calcium carbonate, nano-ceramic powder according to weight ratio 4:1 composition, nanometer
The partial size of calcium carbonate is 40nm, and nano-ceramic powder partial size is 60nm；
It should be noted that at present there are many workable portland cements, such as traditional portland, slag silicate salt water
The tile binding material of mud or Portland fly ash cement, preparation reaches preferable adhesive strength, and performance each other
Gap is little, therefore, will not specifically limit the type and model of portland cement herein, belongs to the protection model of the application
It encloses.
Premix A, 1.2 parts of pyrophyllite powders, 44 parts of compound objects that gather materials that step 1 obtains are carried out high-speed stirring by step 2
It mixes, speed of agitator 105r/min, mixing time 10min obtains premix B, wherein the compound object that gathers materials is coarse aggregate, thin bone
Expect the compound object formed according to weight ratio 1:9, coarse aggregate is granite stones, and fine aggregate is quartz sand；
Step 3, by step 2 premix B, 0.1 part of fumed silica, 0.2 part of polycarboxylate water-reducer, 12 parts go
Ionized water progress is secondary to be stirred at low speed, speed of agitator 35r/min, and mixing time is that 35min is bonded to get ceramic tile of the invention
Agent.
The composite modified faujasite of the polypropylene fibre of the present embodiment the preparation method comprises the following steps:
Step 1 prepares modcfied faujasite: faujasite being first acidified, Re-boostering test is subsequently added to deionization
It is stirred cleaning in water, until cleaning solution is neutrality, the faujasite after cleaning is ground, crosses 240 meshes, is then added
It is spare into magnetic stirring apparatus, then the lauryl sodium sulfate of addition faujasite gross mass 6% is stirred thereto, is stirred
It mixes revolving speed and rises to 65r/min, stir 15min, nanofiber powder R51 is then added, carry out ultrasonic disperse 15min, then take out again
Filter, drying, ground 30 mesh are spare；
Step 2, the preparation of the composite modified faujasite of polypropylene fibre: modification octahedral prepared by polypropylene, step 1
Zeolite is mixed according to weight ratio 85:15, then carries out blending extrusion, and extrusion temperature is 16 DEG C, subsequent re-dry, then is sent
Enter in multi-functional melt spinning machine, forms birth fiber, wherein 220 DEG C of spinning temperature, winding speed 152m/min；Birth
4 times of fiber post-tensioning, 123 DEG C of draft temperature, setting temperature is 130 DEG C to get spare fiber, then carries out spare fiber again
Sided corona treatment, sided corona treatment power are 5Kw, and treatment temperature is 25 DEG C, and the processing time is 10min to get polypropylene fibre compounding
Modcfied faujasite.
The rice hull ash preparation method of the present embodiment is that rice husk is carried out to high temperature sintering, and calcination temperature is 750 DEG C of formation rice husks
Rice hull ash is then add to deionized water by ash, is added while stirring, and the wooden of rice hull ash total amount 12% is then added
Element continues to stir 6min, then filters, dries again, be re-fed into steam blasting machine material bin, be passed through saturated vapor, pressure is
1.1MPa, time 20s carry out pressure release then to get rice hull ash.
Embodiment 2:
A kind of method preparing environmental type tile binding material of the present embodiment, comprising the following steps:
Step 1, by 28 parts of portland cements, the composite modified faujasite of 16 parts of polypropylene fibres, 5-9 parts of modified rice husks
Ash, 3 parts of nano-compositions, 0.9 part of nano-graphene powder, carry out it is dry-mixed stirs at low speed, speed of agitator 65r/min, when stirring
Between be 25min, obtain premix A, wherein nano-composition be nanometer calcium carbonate, nano-ceramic powder according to weight ratio 4:1 form,
The partial size of nanometer calcium carbonate is 40nm, and nano-ceramic powder partial size is 60nm；
Premix A, 1.8 parts of pyrophyllite powders, 52 parts of compound objects that gather materials that step 1 obtains are carried out high-speed stirring by step 2
It mixes, speed of agitator 115r/min, mixing time 10min obtains premix B, wherein the compound object that gathers materials is coarse aggregate, thin bone
Expect the compound object formed according to weight ratio 1:9, coarse aggregate is granite stones, and fine aggregate is quartz sand；
Step 3, by step 2 premix B, 0.3 part of fumed silica, 0.5 part of polycarboxylate water-reducer, 20 parts go
Ionized water progress is secondary to be stirred at low speed, speed of agitator 45r/min, and mixing time is that 35min is bonded to get ceramic tile of the invention
Agent.
The composite modified faujasite of the polypropylene fibre of the present embodiment the preparation method comprises the following steps:
Step 1 prepares modcfied faujasite: faujasite being first acidified, Re-boostering test is subsequently added to deionization
It is stirred cleaning in water, until cleaning solution is neutrality, the faujasite after cleaning is ground, crosses 300 meshes, is then added
It is spare into magnetic stirring apparatus, then the lauryl sodium sulfate of addition faujasite gross mass 10% is stirred thereto, is stirred
It mixes revolving speed and rises to 75r/min, stir 25min, nanofiber powder R51 is then added, carry out ultrasonic disperse 25min, then take out again
Filter, drying, ground 70 mesh are spare；
Step 2, the preparation of the composite modified faujasite of polypropylene fibre: modification octahedral prepared by polypropylene, step 1
Zeolite is mixed according to weight ratio 85:15, then carries out blending extrusion, and extrusion temperature is 175 DEG C, subsequent re-dry, then is sent
Enter in multi-functional melt spinning machine, forms birth fiber, wherein 230 DEG C of spinning temperature, winding speed 154m/min；Birth
4 times of fiber post-tensioning, 125 DEG C of draft temperature, setting temperature is 130 DEG C to get spare fiber, then carries out spare fiber again
Sided corona treatment, sided corona treatment power are 5Kw, and treatment temperature is 25 DEG C, and the processing time is 10min to get polypropylene fibre compounding
Modcfied faujasite.
The rice hull ash preparation method of the present embodiment is that rice husk is carried out to high temperature sintering, and calcination temperature is 850 DEG C of formation rice husks
Rice hull ash is then add to deionized water by ash, is added while stirring, and the wooden of rice hull ash total amount 18% is then added
Element continues to stir 12min, then filters, dries again, be re-fed into steam blasting machine material bin, be passed through saturated vapor, pressure is
1.5MPa, time 30s carry out pressure release then to get rice hull ash.
Embodiment 3:
A kind of method preparing environmental type tile binding material of the present embodiment, comprising the following steps:
Step 1, by 25 parts of portland cements, the composite modified faujasite of 14 parts of polypropylene fibres, 7 parts of modified rice hull ash,
2 parts of nano-compositions, 0.7 part of nano-graphene powder, progress is dry-mixed to be stirred at low speed, speed of agitator 60r/min, and mixing time is
25min obtains premix A, and wherein nano-composition is nanometer calcium carbonate, nano-ceramic powder according to weight ratio 4:1 composition, nanometer
The partial size of calcium carbonate is 40nm, and nano-ceramic powder partial size is 60nm；
Premix A, 1.5 parts of pyrophyllite powders, 48 parts of compound objects that gather materials that step 1 obtains are carried out high-speed stirring by step 2
It mixes, speed of agitator 110r/min, mixing time 10min obtains premix B, wherein the compound object that gathers materials is coarse aggregate, thin bone
Expect the compound object formed according to weight ratio 1:9, coarse aggregate is granite stones, and fine aggregate is quartz sand；
Step 3, by premix B, 0.2 part of fumed silica, the 0.35 part of polycarboxylate water-reducer, 16 parts in step 2
Deionized water progress is secondary to be stirred at low speed, speed of agitator 40r/min, and mixing time is 35min viscous to get ceramic tile of the invention
Connect agent.
The composite modified faujasite of the polypropylene fibre of the present embodiment the preparation method comprises the following steps:
Step 1 prepares modcfied faujasite: faujasite being first acidified, Re-boostering test is subsequently added to deionization
It is stirred cleaning in water, until cleaning solution is neutrality, the faujasite after cleaning is ground, crosses 270 meshes, is then added
It is spare into magnetic stirring apparatus, then the lauryl sodium sulfate of addition faujasite gross mass 8% is stirred thereto, is stirred
It mixes revolving speed and rises to 70r/min, stir 20min, nanofiber powder R51 is then added, carry out ultrasonic disperse 20min, then take out again
Filter, drying, ground 50 mesh are spare；
Step 2, the preparation of the composite modified faujasite of polypropylene fibre: modification octahedral prepared by polypropylene, step 1
Zeolite is mixed according to weight ratio 85:15, then carries out blending extrusion, and extrusion temperature is 170 DEG C, subsequent re-dry, then is sent
Enter in multi-functional melt spinning machine, forms birth fiber, wherein 225 DEG C of spinning temperature, winding speed 153m/min；Birth
4 times of fiber post-tensioning, 124 DEG C of draft temperature, setting temperature is 130 DEG C to get spare fiber, then carries out spare fiber again
Sided corona treatment, sided corona treatment power are 5Kw, and treatment temperature is 25 DEG C, and the processing time is 10min to get polypropylene fibre compounding
Modcfied faujasite.
The rice hull ash preparation method of the present embodiment is that rice husk is carried out to high temperature sintering, and calcination temperature is 800 DEG C of formation rice husks
Rice hull ash is then add to deionized water by ash, is added while stirring, and the wooden of rice hull ash total amount 15% is then added
Element continues to stir 9min, then filters, dries again, be re-fed into steam blasting machine material bin, be passed through saturated vapor, pressure is
1.3MPa, time 25s carry out pressure release then to get rice hull ash.
Comparative example 1:
A kind of tile binding material and preparation method thereof is disclosed using Chinese patent literature (publication number: CN107162523A)
In polypropylene fibre.
Comparative example 2:
With material and the basic phase of preparation method in the preparation method of the composite modified faujasite of 3 polypropylene fibre of embodiment
It together, is not both not compounded using modcfied faujasite.
Comparative example 3:
With material and the basic phase of preparation method in the preparation method of the composite modified faujasite of 3 polypropylene fibre of embodiment
Together, nanofiber powder R51 is not added in modcfied faujasite unlike.
Comparative example 4:
With material and the basic phase of preparation method in the preparation method of the composite modified faujasite of 3 polypropylene fibre of embodiment
Together, without sided corona treatment unlike.
The composite modified faujasite contact angle test of polypropylene fibre
It is tested using full-automatic Single Fiber contact angle measurement
Contact angle test result is as follows:
It is obtained from embodiment 3 and comparative example 1-4, being compounded using modcfied faujasite with polypropylene fibre effectively to be dropped
Low-fiber contact angle improves itself and the dispersibility in bonding agent, enhancing and basal body interface cementability, and then the present invention connects down
Further to test shear strength.
According to national regulation " measurement of adhesive tensile shear strength " (GB/T7124-2008) testing standard to polypropylene
Shear strength between the composite modified faujasite of fiber and matrix is tested for the property
Shear strength test result is as follows:
Obtained from shear strength performance test of the invention, the composite modified faujasite of polypropylene fibre of the invention with
Shear strength between matrix is 23MPa, and comparative example 1 is 7MPa, improves 16MPa, has and significantly improves, while of the invention eight
Nanofiber powder R51 is added in the zeolite of face and sided corona treatment effectively enhances shear strength.
Comparative example 5:
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with rice hull ash.
Comparative example 6:
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with pyrophyllite powder.
Comparative example 7:
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not using this in preparing adhesive
Invention design it is dry-mixed stir at low speed, high-speed stirred, it is secondary stir at low speed, and use conventional stirring condition.
Comparative example 8:
A kind of tile binding material and preparation method thereof is disclosed using Chinese patent literature (publication number: CN107162523A)
The raw material and method of middle embodiment 1.
It is tested according to JC/T547-2005 " ceramic wall low brick bonding agent " testing standard
It is as follows that embodiment 1-3 and comparative example 1-8 obtains tile binding material the performance test results
Obtained from comparative example 3 and comparative example 1-8, embodiment 3 relative to using Chinese patent literature (publication number:
CN107162523A the polypropylene fibre in a kind of tile binding material and preparation method thereof) is disclosed, gluing original intensity is stretched and mentions
High 0.6MPa, increase rate 30.7% are bonded former intensity and have and significantly improve, the composite modified octahedral of the polypropylene fibre of addition
Zeolite, rice hull ash, pyrophyllite powder have improvement to former intensity is bonded, while the stretching adhesive strength after heat ageing, freeze thawing
The stretching adhesive strength after stretching adhesive strength, immersion after circulation is higher than the intensity in comparative example 8, in addition, after immersion
Stretching adhesive strength in, rice hull ash, pyrophillite are very big to adhesive strength stability influence.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (10)
1. a kind of environmental type tile binding material, which is characterized in that the raw material including following parts by weight:
22-28 parts of portland cement gathers materials that 44-52 parts of compound object, polypropylene fibre are faujasite 12-16 parts composite modified, change
Property 5-9 parts of rice hull ash, 1.2-1.8 parts of pyrophyllite powder, 1-3 parts of nano-composition, 0.5-0.9 parts of nano-graphene powder, inorganic touching
Become agent 0.1-0.3 parts, 0.2-0.5 parts of water-reducing agent, 12-20 parts of deionized water；
The composite modified faujasite of polypropylene fibre the preparation method comprises the following steps:
Step 1 prepares modcfied faujasite: faujasite being first acidified, Re-boostering test is subsequently added in deionized water
It is stirred cleaning, until cleaning solution is neutrality, the faujasite after cleaning is ground, 240-300 mesh is crossed, is then added
It is spare into magnetic stirring apparatus, then the lauryl sodium sulfate of addition faujasite gross mass 6-10% is stirred thereto,
Speed of agitator rises to 65-75r/min, stirs 15-25min, nanofiber powder is then added, carry out ultrasonic disperse 15-25min,
It then filters, dry again, ground 30-70 mesh is spare；
The preparation of the composite modified faujasite of polypropylene fibre: step 2 modification octahedral prepared by polypropylene, step 1 is boiled
Stone is mixed according to weight ratio 85:15, then carries out blending extrusion, and extrusion temperature is 165-175 DEG C, subsequent re-dry, then
It is sent into multi-functional melt spinning machine, forms birth fiber, wherein 220-230 DEG C of spinning temperature, winding speed 152-
154m/min；4 times of fiber post-tensioning of birth, 123-125 DEG C of draft temperature, setting temperature is 130 DEG C to get spare fiber, with
Spare fiber is subjected to sided corona treatment again afterwards, sided corona treatment power is 5Kw, and treatment temperature is 25 DEG C, and the processing time is 10min,
Up to the composite modified faujasite of polypropylene fibre.
2. a kind of environmental type tile binding material according to claim 1, which is characterized in that the environmental type porcelain
Brick bonding agent includes the raw material of following parts by weight:
24-27 parts of portland cement gathers materials that 45-51 parts of compound object, polypropylene fibre are faujasite 13-15 parts composite modified, change
Property 6-9 parts of rice hull ash, 1.4-1.8 parts of pyrophyllite powder, 2-3 parts of nano-composition, 0.6-0.8 parts of nano-graphene powder, inorganic touching
Become agent 0.2-0.3 parts, 0.3-0.5 parts of water-reducing agent, 14-18 parts of deionized water.
3. a kind of environmental type tile binding material according to claim 2, which is characterized in that the environmental type porcelain
Brick bonding agent includes the raw material of following parts by weight:
25 parts of portland cement, 14 parts of the composite modified faujasite of 48 parts of compound object, polypropylene fibre that gathers materials, modified rice hull ash 7
Part, 1.5 parts of pyrophyllite powder, 2 parts of nano-composition, 0.7 part of nano-graphene powder, 0.2 part of inorganic thixotropic agent, water-reducing agent 0.35
Part, 16 parts of deionized water.
4. a kind of environmental type tile binding material according to claim 1, which is characterized in that the compound object that gathers materials is
The compound object that coarse aggregate, fine aggregate are formed according to weight ratio 1:9, wherein coarse aggregate is granite stones, and fine aggregate is quartz sand.
5. a kind of environmental type tile binding material according to claim 1, which is characterized in that the polypropylene fibre is multiple
Nanofiber powder is nanofiber powder R51 in the preparation method of allocation modifier faujasite.
6. a kind of environmental type tile binding material according to claim 1, which is characterized in that the rice hull ash preparation side
Method is that rice husk is carried out to high temperature sintering, and calcination temperature is 750-850 DEG C of formation rice hull ash, and rice hull ash is then added to deionization
It in water, is added while stirring, then adds the lignin of rice hull ash total amount 12-18%, continue to stir 6-12min, then take out again
It is filter, dry, it is re-fed into steam blasting machine material bin, is passed through saturated vapor, pressure 1.1-1.5MPa, time 20-30s,
Carry out pressure release then to get rice hull ash.
7. a kind of environmental type tile binding material according to claim 1, which is characterized in that the nano-composition is
Nanometer calcium carbonate, nano-ceramic powder are formed according to weight ratio 4:1, and wherein the partial size of nanometer calcium carbonate is 40nm, nano-ceramic powder
Partial size is 60nm.
8. a kind of environmental type tile binding material according to claim 1, which is characterized in that the inorganic thixotropic agent is
Fumed silica, water-reducing agent are polycarboxylate water-reducer.
9. a kind of prepare the method such as the described in any item environmental type tile binding materials of claim 1-8, which is characterized in that
The following steps are included:
Step 1, by portland cement, the composite modified faujasite of polypropylene fibre, modified rice hull ash, nano-composition, nanometer
Graphene powder, progress is dry-mixed to be stirred at low speed, and obtains premix A；
Premix A, pyrophyllite powder, the compound object that gathers materials that step 1 obtains are carried out high-speed stirred, obtain premix B by step 2；
Step 3, by step 2 premix B, inorganic thixotropic agent, water-reducing agent, deionized water carry out it is secondary stir at low speed, i.e.,
Obtain tile binding material of the invention.
10. a kind of preparation method of environmental type tile binding material according to claim 9, which is characterized in that described
Step 1 is dry-mixed to stir at low speed middle speed of agitator as 55-65r/min, mixing time 25min；It is stirred in step 2 high-speed stirred
Revolving speed is 105-115r/min, mixing time 10min；The secondary speed of agitator stirred at low speed is 35-45r/ in step 3
Min, mixing time 35min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810988863.2A CN108975821A (en) | 2018-08-28 | 2018-08-28 | A kind of environmental type tile binding material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810988863.2A CN108975821A (en) | 2018-08-28 | 2018-08-28 | A kind of environmental type tile binding material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108975821A true CN108975821A (en) | 2018-12-11 |
Family
ID=64546624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810988863.2A Pending CN108975821A (en) | 2018-08-28 | 2018-08-28 | A kind of environmental type tile binding material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108975821A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022207350A1 (en) * | 2021-04-01 | 2022-10-06 | Refratechnik Holding Gmbh | Batch for producing a refractory unfired molded body, molded body of this type, method for producing the molded body, lining of a furnace, and furnace |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2842925A1 (en) * | 2013-09-03 | 2015-03-04 | HeidelbergCement AG | Calcium sulfoaluminate composite binders |
| CN107162523A (en) * | 2017-05-09 | 2017-09-15 | 深圳市奇信建设集团股份有限公司 | Tile binding material and preparation method thereof |
| CN108439923A (en) * | 2018-05-11 | 2018-08-24 | 厦门力嘉诚防水工程有限公司 | A kind of graphene characteristic glue for tile |
-
2018
- 2018-08-28 CN CN201810988863.2A patent/CN108975821A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2842925A1 (en) * | 2013-09-03 | 2015-03-04 | HeidelbergCement AG | Calcium sulfoaluminate composite binders |
| CN107162523A (en) * | 2017-05-09 | 2017-09-15 | 深圳市奇信建设集团股份有限公司 | Tile binding material and preparation method thereof |
| CN108439923A (en) * | 2018-05-11 | 2018-08-24 | 厦门力嘉诚防水工程有限公司 | A kind of graphene characteristic glue for tile |
Non-Patent Citations (5)
| Title |
|---|
| 中国科学技术协会主编: "《学科发展报告综合卷 2016-2017》", 31 March 2018, 中国科学技术出版社 * |
| 张明龙，张琼妮著: "《国外材料领域创新进展》", 30 June 2015, 知识产权出版社 * |
| 牟浩，徐建军，叶光斗，刘鹏清: "微硅粉改性聚丙烯纤维的制备与性能研究", 《合成纤维工业》 * |
| 祖立武主编: "《化学纤维成型工艺学》", 30 September 2014, 哈尔滨工业大学出版社 * |
| 郑水林等编著: "《非金属矿加工技术与设备》", 30 June 1998, 中国建材工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022207350A1 (en) * | 2021-04-01 | 2022-10-06 | Refratechnik Holding Gmbh | Batch for producing a refractory unfired molded body, molded body of this type, method for producing the molded body, lining of a furnace, and furnace |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110128075A (en) | A kind of C30 tailing sand concrete and preparation method thereof | |
| WO2011150608A1 (en) | Composition used for high strength and watertight concrete | |
| CN104261723A (en) | Dry powder additive for masonry and rendering mortar and production technique thereof | |
| CN109160791A (en) | A kind of recycled fine aggregate High-strength self-compaction concrete | |
| CN106673553B (en) | A kind of low cost ceramic tile adhesive and preparation method thereof | |
| CN106277979B (en) | A kind of high-intensity inorganic quartzite slate and its preparation and application | |
| CN115108796B (en) | Light plastering gypsum and preparation method thereof | |
| AU2011317284B2 (en) | Clay-bearing manufactured sands for hydratable cementitious compositions | |
| CN108178583A (en) | Clear-water concrete and preparation method thereof | |
| CN108101392B (en) | A kind of explosion-proof cement and preparation method thereof | |
| CN108975821A (en) | A kind of environmental type tile binding material and preparation method thereof | |
| CN108467232A (en) | A kind of ceramic tile bond and its preparation process containing granite waste stone dust | |
| CN108117340A (en) | A kind of high-strength slab products of haydite and preparation method thereof | |
| CN110372271A (en) | A kind of dry mixing plastering mortar and preparation method thereof | |
| CN114455891A (en) | Low-carbon concrete and preparation process thereof | |
| CN114105557B (en) | Plastering mortar and preparation method thereof | |
| CN110357501A (en) | A kind of concrete waste material concrete and preparation method thereof | |
| CN108017334A (en) | A kind of artificial reef material based on granite ballast powder and preparation method thereof | |
| CN111517727A (en) | Concrete for underwater engineering and preparation method thereof | |
| CN106746794B (en) | A kind of inorganic cement and preparation method thereof | |
| CN108191352A (en) | The light masonry mortar prepared using discarded clay brick | |
| CN115974508B (en) | Anti-whiskering stain-resistant waterproof decoration integrated mortar and preparation process thereof | |
| CN107778023A (en) | Noise-reducing concrete | |
| CN107777927A (en) | concrete for road | |
| CN106746860B (en) | A kind of wet mixing mortar modifying agent of environmental protection and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181211 |