CN108975770A - A kind of modified ceramic core material - Google Patents

A kind of modified ceramic core material Download PDF

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Publication number
CN108975770A
CN108975770A CN201811031308.7A CN201811031308A CN108975770A CN 108975770 A CN108975770 A CN 108975770A CN 201811031308 A CN201811031308 A CN 201811031308A CN 108975770 A CN108975770 A CN 108975770A
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CN
China
Prior art keywords
powder
ceramic core
quartz glass
spherical shape
glass spherical
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Pending
Application number
CN201811031308.7A
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Chinese (zh)
Inventor
陈芳妹
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Individual
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Individual
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Publication date
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Priority to CN201811031308.7A priority Critical patent/CN108975770A/en
Publication of CN108975770A publication Critical patent/CN108975770A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention belongs to ceramic core manufacturing technologies, are related to a kind of ceramic core material of modification.It is characterized by: the weight percent of the material prescription are as follows: zircon flour: 0%~30%;Mullite powder: 0%~30%;Quartz glass spherical shape powder: 0.5%~60%: surplus is fused silica powder.The invention proposes a kind of ceramic core materials of modification, not only can control the sintering shrinkage of ceramic core, but also reduce the liquidity value added of ceramic core slurry, avoid the influence to ceramic core depoling performance.

Description

A kind of modified ceramic core material
Technical field
The invention belongs to ceramic core manufacturing technologies, are related to a kind of modified ceramic core material.
Background technique
With the continuous improvement of aero-engine performance, turbine hollow blade is increasingly becoming the essential structure of aero-engine Part, the key of manufacturing technology is the accurate control shape of hollow blade, and ceramic core is the key that hollow blade accurately controls shape Material.The superiority and inferiority of type core comprehensive performance, is directly related to casting qualification rate, wall thickness dimension and the surface quality of blade, and material The factors such as ingredient, powder granularity and sintering degree can all influence the comprehensive performance of type core.A kind of current ceramic core material Formula referring to Chinese patent application " using the compound ceramic core material of inorfil " (application number 200510047860.1), This ceramic core material controls the sintering shrinkage of ceramic core by adding inorfil in formula.Its shortcomings that Be: addition inorfil can lose the mobility of type core slurry, lead to ceramic core difficult forming, or even will affect the de- of type core Core performance.
Summary of the invention
The purpose of the present invention is: propose a kind of modified ceramic core material, to can control ceramic core sintering shrinkage, The liquidity value added for reducing ceramic core slurry avoids the depoling performance for influencing ceramic core.
The technical scheme is that a kind of modified ceramic core material, it is characterised in that: the weight hundred of the material prescription Divide ratio are as follows: zircon flour: 0%~30%;Mullite powder: 0%~30%;Quartz glass spherical shape powder: 0.5%~60%: surplus For fused silica powder;The purity of fused silica powder and quartz glass spherical shape powder is not less than 99.8%;In quartz glass spherical shape powder It is worth granularity D50 in the range of 3.5 μm~50 μm.
The invention has the advantages that proposing a kind of modified ceramic core material, the sintering shrinkage of ceramic core both can control Rate, and the liquidity value added of ceramic core slurry is reduced, avoid the depoling performance for influencing ceramic core.
Specific embodiment
The present invention is described in further details below.A kind of modified ceramic core material, it is characterised in that: the material is matched The weight percent of side are as follows: zircon flour: 0%~30%;Mullite powder: 0%~30%;Quartz glass spherical shape powder: 0.5%~ 60%: surplus is fused silica powder;The purity of fused silica powder and quartz glass spherical shape powder is not less than 99.8%;Quartz glass ball The median particle D50 of shape powder is in the range of 3.5 μm~50 μm.
The working principle of the invention is: (1) the quartz glass spherical shape powder Surface Crystallization tendency added is big, is not easy and neighbouring Grain sintering fusion, to play the role of suppressive core sintering shrinkage;(2) addition quartz glass spherical shape powder is without anisotropy, no The mobility of loss type core slurry, in addition in granularity, additive amount situation appropriate can also increment type core slurry mobility, keep away Exempt to add influence of the fiber to slurry fluidity;(3) molten mistake of the quartz glass spherical shape powder in high-temperature alkali melt is good, not shadow The depoling ability of type core is rung, so that the additive amount of quartz glass spherical shape powder is not required to be limited by depoling.Test proves, using this The sintering shrinkage of the ceramic core of invention formula preparation is controllable between 0.1%~1.5%.
The present invention controls ceramic core sintering shrinkage by adjusting the additive amount and granularity of quartz glass spherical shape powder to meet The different of rate require.Specific implementation method is as follows.
A kind of modified ceramic core material, it is characterised in that: the weight percent of the material prescription are as follows: zircon flour, not Carry out any mixed powder of any one powder of mountain flour or zircon flour, mullite powder: 20%~30%;Quartz glass is spherical Powder: 1%~25%: surplus is fused silica powder;Range of the median particle D50 of quartz glass spherical shape powder at 3.5 μm~10 μm It is interior.
A kind of modified ceramic core material, it is characterised in that: the weight percent of the material prescription are as follows: zircon flour or not Carry out any mixed powder of any one powder of mountain flour or zircon flour or mullite powder: 5%~10%;Quartz glass is spherical Powder: 10%~45%: surplus is fused silica powder;Range of the median particle D50 of quartz glass spherical shape powder at 20 μm~40 μm It is interior.
Embodiment 1
By type core raw material, weight percent is uniformly mixed according to the following recipe: zircon flour 30%, quartz glass spherical shape powder 1%, surplus is fused silica powder;Wherein the median particle D50 of quartz glass spherical shape powder is 4 μm.By paraffin, beeswax, polyethylene 93:5:2 by weight percentage is melted into wax liquor at 120 DEG C, and after uniform stirring 12h, powder material that will be uniformly mixed is added In wax liquor, then uniform stirring 12h, forming core slurry processed, it pours out cooling and type core material block is made.
Embodiment 2
By type core raw material, weight percent is uniformly mixed according to the following recipe: zircon flour 30%, quartz glass spherical shape powder 15%, surplus is fused silica powder;Wherein the median particle D50 of quartz glass spherical shape powder is 4 μm.By paraffin, beeswax, polyethylene 93:5:2 by weight percentage is melted into wax liquor at 120 DEG C, and after uniform stirring 12h, powder material that will be uniformly mixed is added In wax liquor, then uniform stirring 12h, forming core slurry processed, it pours out cooling and type core material block is made.
Embodiment 3
By type core raw material, weight percent is uniformly mixed according to the following recipe: zircon flour 20%, quartz glass spherical shape powder 10%, surplus is fused silica powder;Wherein the median particle D50 of quartz glass spherical shape powder is 8 μm.By paraffin, beeswax, polyethylene 93:5:2 by weight percentage is melted into wax liquor at 120 DEG C, and after uniform stirring 12h, powder material that will be uniformly mixed is added In wax liquor, then uniform stirring 12h, forming core slurry processed, it pours out cooling and type core material block is made.
Embodiment 4
By type core raw material, weight percent is uniformly mixed according to the following recipe: quartz glass spherical shape powder 35%, surplus is stone English glass powder;Wherein the median particle D50 of quartz glass spherical shape powder is 20 μm.By weight percentage by paraffin, beeswax, polyethylene 93:5:2 is melted into wax liquor at 120 DEG C, after uniform stirring 12h, uniformly mixed powder material is added in wax liquor, then uniformly 12h is stirred, forming core slurry processed pours out cooling and type core material block is made.
Embodiment 5
By type core raw material, weight percent is uniformly mixed according to the following recipe: quartz glass spherical shape powder 35%, surplus is stone English glass powder;Wherein the median particle D50 of quartz glass spherical shape powder is 35 μm.By weight percentage by paraffin, beeswax, polyethylene 93:5:2 is melted into wax liquor at 120 DEG C, after uniform stirring 12h, uniformly mixed powder material is added in wax liquor, then uniformly 12h is stirred, forming core slurry processed pours out cooling and type core material block is made.
Table 1

Claims (3)

1. a kind of ceramic core material of modification, it is characterised in that: the weight percent of the material prescription are as follows: zircon flour: 0% ~30%;Mullite powder: 0%~30%;Quartz glass spherical shape powder: 0.5%~60%: surplus is fused silica powder;Quartzy glass The purity of glass powder and quartz glass spherical shape powder is not less than 99.8%;The median particle D50 of quartz glass spherical shape powder is 3.5 μm~50 In the range of μm;Zircon flour, white alundum powder and mullite powder are not simultaneously 0%.
2. a kind of ceramic core material of modification according to claim 1, it is characterised in that: the weight hundred of the material prescription Divide ratio are as follows: zircon flour or any of any one powder of mullite powder or zircon flour, white alundum powder or mullite powder mix Conjunction powder: 20%~30%;Quartz glass spherical shape powder: 1%~25%: surplus is fused silica powder;Quartz glass spherical shape powder Median particle D50 is in the range of 3.5 μm~10 μm.
3. a kind of ceramic core material of modification according to claim 1, it is characterised in that: the weight hundred of the material prescription Divide ratio are as follows: any one powder of zircon flour, white alundum powder or mullite powder or any of zircon flour or mullite powder mix Conjunction powder: 5%~10%;Quartz glass spherical shape powder: 10%~45%: surplus is fused silica powder;Quartz glass spherical shape powder Median particle D50 is in the range of 20 μm~40 μm.
CN201811031308.7A 2018-09-05 2018-09-05 A kind of modified ceramic core material Pending CN108975770A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811031308.7A CN108975770A (en) 2018-09-05 2018-09-05 A kind of modified ceramic core material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811031308.7A CN108975770A (en) 2018-09-05 2018-09-05 A kind of modified ceramic core material

Publications (1)

Publication Number Publication Date
CN108975770A true CN108975770A (en) 2018-12-11

Family

ID=64544883

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811031308.7A Pending CN108975770A (en) 2018-09-05 2018-09-05 A kind of modified ceramic core material

Country Status (1)

Country Link
CN (1) CN108975770A (en)

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Application publication date: 20181211

WD01 Invention patent application deemed withdrawn after publication