CN108975608A - It is a kind of using SNAD-MBBR technology as the side biological treatment of core processing sludge-digestion liquid - Google Patents
It is a kind of using SNAD-MBBR technology as the side biological treatment of core processing sludge-digestion liquid Download PDFInfo
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- CN108975608A CN108975608A CN201810830542.XA CN201810830542A CN108975608A CN 108975608 A CN108975608 A CN 108975608A CN 201810830542 A CN201810830542 A CN 201810830542A CN 108975608 A CN108975608 A CN 108975608A
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- snad
- sludge
- mbbr
- digestion liquid
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5281—Installations for water purification using chemical agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
Abstract
The present invention relates to a kind of using SNAD-MBBR technology as the side biological treatment of core processing sludge-digestion liquid.The invention mainly comprises coagulating sedimentation and SNAD-MBBR two parts.Firstly, sludge-digestion liquid enters coagulative precipitation tank, flocculation reaction is occurred by dosing coagulant;Then, the water outlet after primary sedimentation tank removes oil removal enters biological denitrificaion unit.Remaining organic carbon source and most nitrogen are effectively removed in the segment process in sludge-digestion liquid;Finally, sludge-digestion liquid after treatment is discharged into sewage treatment plant.The present invention has many advantages, such as that operation energy consumption is low, treatment effeciency is high, secondary pollution is small and occupied area is small, while alleviating the nitrogen load impact to sewage treatment plant, and reduce the operating cost of water factory.The present invention can become the preferred technique of high ammonia nitrogen, low ratio of carbon to ammonium waste water side biological treatment.
Description
Technical field
The invention belongs to field of environment engineering more particularly to the biological denitrification process and dress of high ammonia nitrogen, low ratio of carbon to ammonium waste water
It sets.
Background technique
The anaerobic digestion of the excess sludge of urban wastewater treatment firm is the effective of current cities and towns excess sludge stabilization processes
Measure, the technology have the advantages that recycle the energy, wastes reduction and innoxious.In anaerobic digestion process, anaerobic bacteria is decomposed
Organic matter in sludge generates methane gas, as energy recovery.Meanwhile the deamination of microorganism can release nitrogen
(mainly based on ammonia nitrogen and a small amount of organic nitrogen).After dehydration, the nitrogen overwhelming majority can remain in sludge-digestion liquid, so
Nitrogen content in digestive juice is very high (500-2000mg/L).Sludge-digestion liquid shows the characteristics of high ammonia nitrogen, low C/N, existing
Sewage treatment plant be difficult effectively to handle it.In recent years, domestic and international researcher proposed at sludge-digestion liquid side
Then reason technology discharges it into sewage that is, using most nitrogen in Process of Biological Nitrogen Removal removal sludge-digestion liquid again
Treatment plant is handled together with sanitary sewage.The research of side processing technique and application to high ammonia nitrogen, low ratio of carbon to ammonium waste water it is effective
Processing is of great significance.
Nitrosation technology has the advantages that low energy consumption, operating cost is small compared with the technology of nitrification.Sludge-digestion liquid temperature is high,
The ratio of ammonia nitrogen and basicity is suitable, is easier to realize stable nitrosation process by controlling service condition, is anaerobism ammonia oxygen
Chemical industry skill provides suitable water inlet.For Anammox technology compared with nitrification-denitrification technology, it does not need additional organic carbon
Source does not need to add medicament, saves a large amount of operating cost, avoid secondary pollution without aeration.Therefore, nitrosation and
Anammox technology is the used technical way of current sludge-digestion liquid side processing.Anaerobic ammonium oxidizing bacteria vulnerable to
The problems such as environment influences and the sludge doubling time is long greatly limits the extensive use of this technology.Especially handle
When actual waste water, water quality is complicated and water fluctuates the starting speed and bacterial activity that can all influence anaerobic ammonia oxidation reactor.Cause
This, nitrosation at present and Anammox technology are faced using challenge.
Summary of the invention
To make up prior art deficiency, it is an object of the present invention to provide it is a kind of efficiently, low-cost processes sludge-digestion liquid be
System and technique, the present invention can realize the quick start and subsequent stable operation of anaerobic ammonia oxidation reactor simultaneously, and improve and detest
Application range of the anaerobic ammonium oxidation technology in actual waste water denitrogenation field.Low energy consumption for the process operation, removal efficiency is high, secondary pollution
It is small.
Inventive concept of the invention is: sludge-digestion liquid initially enters coagulative precipitation tank, is flocculated by adding medicament
Reaction;Then, the water outlet after primary sedimentation tank removes oil removal enters biological denitrificaion unit.The core of biological denitrificaion unit is SNAD
(while nitrosation, Anammox and denitrification)-MBBR (moving bed biofilm reactor), it is remaining in sludge-digestion liquid to have
Machine carbon source and most nitrogen are effectively removed in the segment process;Finally, sludge-digestion liquid row after treatment
Enter sewage treatment plant.Technique initial stage, sludge-digestion liquid enter biological denitrificaion unit after diluting, with the raising of removal rate, gradually
Reduce sludge-digestion liquid extension rate, improves water inlet total nitrogen load.In SNAD-MBBR unit, nitrite bacteria utilizes oxygen
By water part NH4 +- N is converted into NO2 -- N, then ANAMMOX bacterium is by the NO of generation2 -- N and residue NH4 +- N is converted into N2, real
Now to the removal of nitrogen most of in waste water.Denitrifying bacteria is using the COD in waste water as electron donor, in anaerobism or anoxic item
Under part, by the NO of generation3 -- N and remaining NO2 -- N is reduced into N2, realize further denitrogenation.Inside SNAD-MBBR unit
Biomembrane can be formed on biologic packing material, reduce sludge loss.Meanwhile the spatial distribution of biomembrane is anaerobic and aerobic on filler
Bacterium provides advantageous life condition, realizes denitrogenation and removes the COD in waste water.
Primary and foremost purpose of the present invention is the sludge digestion liquid treating system being claimed using SNAD-MBBR as core technology, should
System includes sequentially connected coagulative precipitation tank, primary sedimentation tank, SNAD-MBBR unit and secondary settling tank, and the coagulative precipitation tank is built-in
There is blender, mud scraper is equipped in primary sedimentation tank, the water after precipitating carries out removal of carbon and nitrogen in SNAD-MBBR unit.
Sump is additionally provided in above system, sump A is connect with primary sedimentation tank, the water overflow after making precipitating to sump A.
Sump B is connect with secondary settling tank.
Be additionally provided with inclined-plate clarifying basin in above system, the inclined-plate clarifying basin can be used this field it is any can play it is heavy
Form sediment, separate, going the sedimentation basin of oil removal function.
Above-mentioned SNAD-MBBR unit is circle or rectangular, preferably rectangular.PH is equipped with inside SNAD-MBBR unit to pop one's head in
And blender, the blender are vertical stirrer, are located at SNAD-MBBR unit middle position, biologic packing material is suspended in SNAD-
Inside MBBR unit.
The treatment process are as follows: sludge-digestion liquid enters coagulative precipitation tank by water pump, and coagulative precipitation tank center is equipped with stirring
Device carries out flocculation reaction by dosing pump dosing coagulant thereto.Coagulative precipitation tank is discharged overflow to primary sedimentation tank, goes out after precipitating
Water overflow to sump A, primary sedimentation tank periodically carries out spoil disposal.Then boosted pump, which is mentioned by sump A to SNAD-MBBR unit, carries out
Removal of carbon and nitrogen is finally discharged and is discharged into sewage treatment plant through secondary settling tank.
Preferably, aeration quantity being adjusted according to inflow, the DO concentration controlled in SNAD-MBBR unit is no more than 0.8mg/L,
At 25-30 DEG C, pH is 20- in 7.0-7.3, hydraulic detention time 24-48h, biologic packing material packing ratio for water temperature control in pond
50%, more preferable 30%.
Further, into coagulative precipitation tank, dosing coagulant is 0.1-1.0mg/L, and concentration of suspension can after coagulating sedimentation
It is down to 100mg/L.
The utility model has the advantages that
Sludge-digestion liquid and coagulant are carried out coagulating sedimentation by the present invention, and can not only removing oil removal, there are also dephosphorizations to imitate simultaneously
Fruit can reduce the dephosphorization expense in later period in this way;SNAD-MBBR unit concentrates on three kinds of bioprocess in one reactor,
Occupied area is reduced, it can be to avoid the organic carbon source and NO in sewage using SNAD technology2 -- N is living to anaerobic ammonium oxidizing bacteria
Property generate inhibition, guarantee the stability of system, and can be further improved nitrogen removal rate.MBBR technique can be very good to be enriched with
The anaerobic ammonium oxidizing bacteria of slow growth shortens the reactor start-up period, the biomass balance of denitrogenation flora, dimension in guarantee system
System is held to run steadily in the long term.It entirely processes into without adding carbon source and basicity medicament, operating cost is low;Biologic packing material can
Oxygen utilization rate is improved, while can be good at the slow anaerobic ammonium oxidizing bacteria of enrichment and growth, accelerates the starting of reactor;It should
Technique by a small amount of COD contained in waste water while can also remove while denitrogenation.In conclusion the present invention has operation energy consumption
Low, the advantages that treatment effeciency is high, secondary pollution is small and occupied area is small, while alleviating the nitrogen load punching to sewage treatment plant
It hits, and reduces the operating cost of water factory.The present invention can become the preferred work of high ammonia nitrogen, low ratio of carbon to ammonium waste water side biological treatment
Skill.
Detailed description of the invention
Fig. 1 is using SNAD-MBBR as the sludge-digestion liquid integral bio denitrification process flow chart of core technology;
2 processing system structural schematic diagram of Fig. 2 embodiment of the present invention.
In figure: 1, dosing pump, 2, coagulative precipitation tank, 3, primary sedimentation tank, 4, SNAD-MBBR unit, 5, heater, 6, perforation exposure
Tracheae, 7, pH probe, 8, sludge reflux pump, 9, sludge discharge pipeline, 10, secondary settling tank, 11, mud scraper, 12, biologic packing material, 13, stirring
Device, 14, sump A, 15, sump B
Specific embodiment
The present invention is described in detail below by the drawings and specific embodiments, but is not limited the scope of the invention.
Embodiment 1
The side biological treatment system of sludge-digestion liquid, including sequentially connected dosing pump 1, coagulative precipitation tank 2, primary sedimentation tank
3, SNAD-MBBR unit 4 and secondary settling tank 10 are provided with blender 13 in the coagulative precipitation tank 2, for mixing coagulant and dirt
Mud digestive juice is equipped with overflow weir at the top of the primary sedimentation tank 3, and bottom is in cone bucket shape, mud scraper 11 is equipped in primary sedimentation tank 3, first
Heavy 3 bottom of pond is equipped with sludge discharge pipeline 9, and primary sedimentation tank 3 is discharged in the sludge for isolating mud scraper 11, and primary sedimentation tank 3 is discharged overflow
To SNAD-MBBR unit 4, it is equipped with heater 5 in SNAD-MBBR unit 4, is equipped with perforation in 4 bottom of SNAD-MBBR unit and exposes
Tracheae 6 is equipped with pH probe 7, blender 13 inside SNAD-MBBR unit 4, and it is mono- that online pH probe 7 is inserted directly into SNAD-MBBR
In first pond, vertical stirrer 13 is located at SNAD-MBBR unit cells middle position.Biologic packing material 12 is suspended in SNAD-MBBR unit 4
Inside, 10 bottom of secondary settling tank are in cone bucket shape, and inside is equipped with mud scraper 11, and 10 base sludge of secondary settling tank is back to by sludge reflux pump 8
In SNAD-MBBR unit 4, the sludge-digestion liquid after secondary settling tank 10 precipitates is discharged into sewage treatment plant.
The side biological treatment of above-mentioned sludge-digestion liquid, specifically includes the following steps:
(1) sludge-digestion liquid enters coagulative precipitation tank 2 first, and coagulant is pumped into coagulative precipitation tank 2 by dosing pump 1
In, coagulant is thoroughly mixed with sludge-digestion liquid under the action of blender 13, and suspended matter is sent out in coagulant and sludge-digestion liquid
Enter primary sedimentation tank 3 after raw flocculation reaction.
(2) suspended matter is sink to bottom of pond in primary sedimentation tank 3, and supernatant enters subsequent biochemical unit.It is outstanding that the process goes out water management
Floating object concentration is no more than 100mg/L.Primary sedimentation tank 3 is provided with mud scraper, periodically passes through 9 spoil disposal of sludge discharge pipeline.
(3) primary sedimentation tank 3 is discharged overflow to SNAD-MBBR unit, and air enters reactor, control by boring aeration pipe 6
The reactor dissolved oxygen is lower than 0.8mg/L, and temperature maintains 25-30 DEG C by heater 5, according to the feedback information control of probe 7
PH processed is 7.0-7.3, hydraulic detention time 48h.Biologic packing material is housed inside SNAD-MBBR unit, biologic packing material is filled out
It fills than for 20-50%, preferably 30%, filler is in suspended state under the collective effect of blender and aeration.Shape on biologic packing material
At biomembrane, biomembrane outer layer is aerobic nitrosatedization bacterium, and internal layer is denitrifying bacterium and anaerobic ammonia oxidizing bacteria.To SNAD-MBBR
The biologic packing material that 30% is added in unit, reduces sludge loss, shortens the starting time of reactor.
(4) sludge-digestion liquid after SNAD-MBBR cell processing flows into secondary settling tank 10, is discharged into sewage treatment after precipitation
Factory, 10 base sludge of secondary settling tank are back in SNAD-MBBR unit by sludge reflux pump 8, reflux ratio 50%.
Embodiment 2
The side biological treatment system of sludge-digestion liquid, including sequentially connected dosing pump 1, coagulative precipitation tank 2, primary sedimentation tank
3, sump A 14, SNAD-MBBR unit 4, secondary settling tank 10 and sump B 15, sludge-digestion liquid are stored in digestive juice reservoir
In, sludge-digestion liquid flows into coagulative precipitation tank 2 by pipeline, blender 13 is provided in the coagulative precipitation tank 2, for mixing
Coagulant and sludge-digestion liquid are equipped with overflow weir at the top of the primary sedimentation tank 3, and bottom is in cone bucket shape, are equipped in primary sedimentation tank 3 and scrape mud
Machine 11 is equipped with sludge discharge pipeline 9 in 3 bottom of primary sedimentation tank, and primary sedimentation tank 3, primary sedimentation tank 3 is discharged in the sludge for isolating mud scraper 11
Overflow is discharged to sump A 14, boosted pump mentions the water in sump A 14 to SNAD-MBBR unit 4, in SNAD-MBBR
It is equipped with heater 5 in unit 4, is equipped with boring aeration pipe 6 in 4 bottom of SNAD-MBBR unit, is set inside SNAD-MBBR unit 4
There are pH probe 7, blender 13, biologic packing material 12 is suspended in inside SNAD-MBBR unit 4, and 10 bottom of secondary settling tank is in cone bucket shape, interior
Portion is equipped with mud scraper 11, and 10 base sludge of secondary settling tank is back in SNAD-MBBR unit 4 by sludge reflux pump 8, and secondary settling tank 10 precipitates
Water overflow afterwards is finally discharged into sewage treatment plant to sump B 15.
Application examples
It is process object with the sludge-digestion liquid of Dalian Dong Taixia man river sludge treatment plant, establishes with SNAD-MBBR technology
For the Practical Project of core.Factory's sludge-digestion liquid total nitrogen content is 1500-1800mg/L, is all ammonia nitrogen substantially, COD content is
600-800mg/L, most of is difficult for biological degradation.The sludge-digestion liquid suspension content generated after dehydration is very high, thus into
It needs to be pre-processed before entering biochemical treatment system.Specific step is as follows for processing:
(1) sludge-digestion liquid enters conditioning tank, stabilizing water quantity water quality first.Conditioning tank dischargeable capacity 200m3, pond center dress
There is blender.Sludge-digestion liquid enters coagulative precipitation tank 2 by intake pump by conditioning tank, which is
40m3, the center of coagulative precipitation tank 2 is equipped with blender 13, adds Polyferric Sulfate thereto by dosing pump 1, carry out coagulating.Coagulation
Sedimentation basin 2 is discharged overflow to primary sedimentation tank 3,3 dischargeable capacity 100m of primary sedimentation tank3, spoil disposal periodically is carried out to primary sedimentation tank 3.
(2) sludge-digestion liquid overflow after precipitation is to sump A 14, and then boosted pump is mentioned to inclined-plate clarifying basin, into
One step removes oil removal, and treated goes out aqueous suspension control in 100mg/L or less.The preprocessed sludge gone after oil removal
Digestive juice a part through the distribution well of inclined-plate clarifying basin enter SNAD-MBBR unit carry out biological denitrificaion reaction, inflow according to
Biochemical treatment situation is adjusted, and another part is then discharged into digestive juice reservoir.
(3) SNAD-MBBR unit is rectangular, dischargeable capacity 800m3, biologic packing material packing ratio is 35%, and bottom is equipped with exposure
Tracheae is equipped with two blenders in pond.By the pH value of 7 monitoring reaction system of pH probe, controlled according to the feedback information of probe 7
PH is 7.0-7.3, maintains the reaction temperature in reactor to stablize at 25-30 DEG C by temperature heater 5, passes through boring aeration pipe
The dissolved oxygen amount of 6 control reaction gas, makes it below 0.8mg/L, hydraulic detention time 48h.It sinks through the pond SNAD water outlet overflow to two
Pond, overflow is finally discharged into urban wastewater treatment firm to sump B 15 again after precipitation.
The engineering sludge-digestion liquid treating capacity is about 600m3/ d, nitrogen removal rate reach 75%, and water outlet COD is lower than
300mg/L, effective solution sludge-digestion liquid in line sewage treatment plant impacts caused by water factory.
The preferable specific embodiment of the above, only the invention, but the protection scope of the invention is not
It is confined to this, anyone skilled in the art is in the technical scope that the invention discloses, according to the present invention
The technical solution of creation and its inventive concept are subject to equivalent substitution or change, should all cover the invention protection scope it
It is interior.
Claims (7)
1. a kind of using SNAD-MBBR technology as the side biological treatment system of core processing sludge-digestion liquid, which is characterized in that should
System includes sequentially connected coagulative precipitation tank (2), primary sedimentation tank (3), SNAD-MBBR unit (4) and secondary settling tank (10), described mixed
Solidifying sedimentation basin (2) are provided with blender (13), are equipped with mud scraper (11) in primary sedimentation tank (3), and the water after precipitating is in SNAD-MBBR
Unit (4) carries out removal of carbon and nitrogen.
2. processing system according to claim 1, which is characterized in that the system is additionally provided with sump, sump A (14) with
Primary sedimentation tank (3) connection, sump B (15) are connect with secondary settling tank (10).
3. processing system according to claim 1, which is characterized in that be additionally provided with inclined-plate clarifying basin in above system.
4. processing system according to claim 1, which is characterized in that SNAD-MBBR unit (4) is circle or rectangular,
Boring aeration pipe (6), pH probe (7) and blender (13), blender (13) is equipped with inside SNAD-MBBR unit (4) to be located at
SNAD-MBBR unit (4) middle position, it is internal that biologic packing material (12) is suspended in SNAD-MBBR unit (4).
5. a kind of processing system as described in claim 1 handles sludge-digestion liquid technique, which is characterized in that sludge-digestion liquid is logical
It crosses water pump and enters coagulative precipitation tank (2), by dosing pump (1) dosing coagulant thereto, carry out flocculation reaction, coagulative precipitation tank
(2) water outlet overflow is to primary sedimentation tank (3), and water outlet mentions to SNAD-MBBR unit (4) and carries out removal of carbon and nitrogen after precipitating, finally water outlet warp
Secondary settling tank (10) is discharged into sewage treatment plant.
6. technique according to claim 5, which is characterized in that adjust aeration quantity according to inflow, control SNAD-MBBR is mono-
DO concentration in first (4) is no more than 0.8mg/L, in pond water temperature control be in 7.0-7.3, hydraulic detention time in 25-30 DEG C, pH
48h, biologic packing material (12) packing ratio are 30%.
7. technique according to claim 5, which is characterized in that dosing coagulant is 1.0mg/ in coagulative precipitation tank (2)
L, concentration of suspension can be down to 100mg/L after coagulating sedimentation.
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Citations (3)
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US7147777B1 (en) * | 2005-05-09 | 2006-12-12 | Eimco Water Technologies Llc | Wastewater treatment system with membrane separators and provision for storm flow conditions |
CN103880195A (en) * | 2014-03-23 | 2014-06-25 | 北京工业大学 | Method for synchronously culturing nitrosified, anammox and denitrified granule sludge |
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2018
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US7147777B1 (en) * | 2005-05-09 | 2006-12-12 | Eimco Water Technologies Llc | Wastewater treatment system with membrane separators and provision for storm flow conditions |
CN103880195A (en) * | 2014-03-23 | 2014-06-25 | 北京工业大学 | Method for synchronously culturing nitrosified, anammox and denitrified granule sludge |
CN107324497A (en) * | 2017-08-17 | 2017-11-07 | 成都信息工程大学 | A kind of startup method of coupling denitrification Canon PROCESS FOR TREATMENTs pig farm biogas slurry |
Non-Patent Citations (1)
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XIAOCHEN XU等: "Start-up of a full-scale SNAD-MBBR process for treating sludge digester liquor", 《CHEMICAL ENGINEERING JOURNAL》 * |
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Application publication date: 20181211 |