CN108975473A - A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent - Google Patents
A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent Download PDFInfo
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- CN108975473A CN108975473A CN201810948536.4A CN201810948536A CN108975473A CN 108975473 A CN108975473 A CN 108975473A CN 201810948536 A CN201810948536 A CN 201810948536A CN 108975473 A CN108975473 A CN 108975473A
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- chloride
- iron
- ammonium chloride
- flocculation agent
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5263—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses a kind of high-efficiency environment friendlies to cultivate Water warfare composite flocculation agent, is made of according to parts by weight following raw material: 0.3~0.6 part of Hydrated copper chloride, 1.3~1.8 parts of polymerization oxidation iron, 2.3~2.7 parts of complex microorganism, 1.1~1.6 parts of sodium hypochlorite, 1.8~2.4 parts of polymeric aluminum sulfate iron, 7~12 parts of inorganic silicate, 60~80 parts of diatomite, boric acid account for 0.2~0.7 part, 1.7~2.3 parts of polyferric chloride, 4~9 parts of inorganic phosphate, 0.3~0.7 part of zinc sulfate, 7~12 parts of active carbon and 0.1~0.4 part of benzyl chloride etc..The features such as flocculant of the invention can double up efficiency, and price is lower, quality is stable, reduction of speed degree is fast, and effluent quality is good, and dosage is few.
Description
Technical field
The present invention relates to sewage treatment correlative technology fields more particularly to a kind of high-efficiency environment friendly to cultivate the compound wadding of Water warfare
Solidifying agent.
Background technique
Flocculant is mainly to have in the group of positive (negative) electrical property and in some water with bearing (just) electrical be difficult to point
From some particles or be particle, reduce its potential, be at unstable state, and make these using its aggregation property
Particle is concentrated, and is separated by physics or chemical method.The medicament for generally reaching this purpose and using, referred to as
Flocculant.Flocculant is mainly used in water supply and sewage treatment field.Chemical agent coagulating sedimentation is universal in water treatment technology
The method used.This method have the characteristics that small investment, take up little area, operating cost is low, wide adaptability.In water process coagulating sedimentation
In be broadly directed to flocculant and feed intake opportunity, the environmental Kuznets Curves that feed intake, inventory, stimulation effect etc., to reach suitable flocculation effect
Fruit meets the requirement to water process.
Flocculant is mainly used in water supply and sewage treatment field, can totally be divided into inorganic flocculating agent according to its chemical component
With two class of organic flocculant.Wherein inorganic flocculating agent includes inorganic flocculant and inorganic polymer flocculant again；Organic flocculant
It again include Syn-Organic flocculants, natural organic high-molecular flocculant and microbial flocculant.Oilfield sewage at present
Purifying widely used method is flocculent precipitation, that is, flocculant is added into water, and inorganic flocculating agent is used alone, exists
Dosage is big, and it is more to generate precipitating in water, is also easy to produce a large amount of sludge and dross, and to the anti-corrosion of medicine machine, pipeline have compared with
The disadvantages of high request, has been difficult to meet the requirement of water process.
Current flocculant preparation cost is high, and flocculating effect is poor, is further improved.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of high-efficiency environment friendly cultivation water proposed
Composite flocculation agent is used in purification.
To achieve the goals above, present invention employs following technical solutions:
A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent, is made of according to parts by weight following raw material: Hydrated copper chloride 0.3
~0.6 part, 0.8~1.7 part of polyacrylamide, 1.2~1.8 parts of sodium carboxymethylcellulose, 1.4~1.8 parts of iron chloride, chitosan
5~10 parts, 1.4~2.2 parts of citric acid, 0.2~0.6 part of Peracetic acid, 1.3~1.7 parts of polyaluminium molybdenum, polymerization oxidation iron
1.3~1.8 parts, 2.3~2.7 parts of complex microorganism, 1.1~1.6 parts of sodium hypochlorite, 1.8~2.4 parts of polymeric aluminum sulfate iron, nothing
7~12 parts of machine silicate, 60~80 parts of diatomite, boric acid account for 0.2~0.7 part, 1.7~2.3 parts of polyferric chloride, Phos
4~9 parts of hydrochlorate, 0.3~0.7 part of zinc sulfate, 10~20 parts of bentonite, 20~30 parts of zeolite, 0.1~0.5 part of ammonium chloride, methyl
0.5~0.9 part of acrylyl oxy-ethyl-trimethyl salmiac, 7~12 parts of active carbon and 0.1~0.4 part of benzyl chloride.
A kind of above-mentioned high-efficiency environment friendly cultivates Water warfare composite flocculation agent, is made of according to parts by weight following raw material: water
0.3~0.5 part of copper chloride of conjunction, 0.8~1.6 part of polyacrylamide, 1.2~1.7 parts of sodium carboxymethylcellulose, iron chloride 1.4~
1.7 parts, 5~9 parts of chitosan, 1.4~2.1 parts of citric acid, 0.2~0.5 part of Peracetic acid, 1.3~1.6 parts of polyaluminium molybdenum,
1.3~1.7 parts of polymerization oxidation iron, 2.3~2.6 parts of complex microorganism, 1.1~1.5 parts of sodium hypochlorite, polymeric aluminum sulfate iron 1.8
~2.3 parts, 7~11 parts of inorganic silicate, 60~79 parts of diatomite, boric acid account for 0.2~0.6 part, polyferric chloride 1.7~
2.2 parts, 4~8 parts of inorganic phosphate, 0.3~0.6 part of zinc sulfate, 10~19 parts of bentonite, 20~29 parts of zeolite, ammonium chloride 0.1
~0.4 part, 0.5~0.8 part of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 7~11 parts of active carbon and benzyl chloride 0.1~0.3
Part.
A kind of above-mentioned high-efficiency environment friendly cultivates Water warfare composite flocculation agent, is made of according to parts by weight following raw material: water
0.4~0.5 part of copper chloride of conjunction, 0.9~1.6 part of polyacrylamide, 1.3~1.7 parts of sodium carboxymethylcellulose, iron chloride 1.5~
1.7 parts, 6~9 parts of chitosan, 1.5~2.1 parts of citric acid, 0.3~0.5 part of Peracetic acid, 1.4~1.6 parts of polyaluminium molybdenum,
1.4~1.7 parts of polymerization oxidation iron, 2.4~2.6 parts of complex microorganism, 1.2~1.5 parts of sodium hypochlorite, polymeric aluminum sulfate iron 1.9
~2.3 parts, 8~11 parts of inorganic silicate, 61~79 parts of diatomite, boric acid account for 0.3~0.6 part, polyferric chloride 1.8~
2.2 parts, 5~8 parts of inorganic phosphate, 0.4~0.6 part of zinc sulfate, 11~19 parts of bentonite, 21~29 parts of zeolite, ammonium chloride 0.2
~0.4 part, 0.6~0.8 part of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 8~11 parts of active carbon and benzyl chloride 0.2~0.3
Part.
A kind of above-mentioned high-efficiency environment friendly cultivates Water warfare composite flocculation agent, is made of according to parts by weight following raw material: water
Close 0.45 part of copper chloride, 1.25 parts of polyacrylamide, 1.5 parts of sodium carboxymethylcellulose, 1.6 parts of iron chloride, 7.5 parts of chitosan,
It is 1.8 parts of citric acid, 0.4 part of Peracetic acid, 1.5 parts of polyaluminium molybdenum, 1.55 parts of polymerization oxidation iron, 2.5 parts of complex microorganism, secondary
1.35 parts of sodium chlorate, 2.1 parts of polymeric aluminum sulfate iron, 9.5 parts of inorganic silicate, 70 parts of diatomite, boric acid account for 0.45 part, polymerization three
2 parts of iron chloride, 6.5 parts of inorganic phosphate, 0.5 part of zinc sulfate, 15 parts of bentonite, 25 parts of zeolite, 0.3 part of ammonium chloride, methyl-prop
0.7 part of alkene acyloxyethyl trimethyl ammonium chloride, 9.5 parts of active carbon and 0.25 part of benzyl chloride.
Compared with prior art, the invention has the benefit that
A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent of the invention is when being used in combination with easy to use, component is simple
Single, raw material sources are extensive, low in cost, and it is convenient to produce and use, and inventory is small, can double up efficiency, and price is lower, matter
Amount is stablized, and reduction of speed degree is fast, effluent quality is good, stimulation effect well can long-term preservation, flocculating effect is good, the floccule body body of generation
Big and structure is closely knit, be easy to water body separate so that wastewater treatment efficiency be improved significantly, and dosage reduces and dosage
It is few, there is good adaptability, and strong operability to natural environment, regeneration efficiency is high, and may be implemented to recycle for a long time makes
With scheme, the energy and raw material are not only saved, but also is good for the environment, the beneficial effects such as labor intensity are reduced.
Specific embodiment
Embodiment 1
A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent, is made of according to parts by weight following raw material: Hydrated copper chloride 0.3
Part, 0.8 part of polyacrylamide, 1.2 parts of sodium carboxymethylcellulose, 1.4 parts of iron chloride, 5 parts of chitosan, 1.4 parts of citric acid, peroxide
0.2 part of acetic acid, 1.3 parts of polyaluminium molybdenum, 1.3 parts of polymerization oxidation iron, 2.3 parts of complex microorganism, 1.1 parts of sodium hypochlorite, polymerization
1.8 parts of aluminium iron sulfate, 7 parts of inorganic silicate, 60 parts of diatomite, boric acid account for 0.2 part, 1.7 parts of polyferric chloride, inorganic phosphate
4 parts of salt, 0.3 part of zinc sulfate, 10 parts of bentonite, 20 parts of zeolite, 0.1 part of ammonium chloride, methylacryoyloxyethyl trimethyl ammonia chloride
0.5 part of ammonium, 7 parts of active carbon and 0.1 part of benzyl chloride.
Embodiment 2
A kind of above-mentioned high-efficiency environment friendly cultivates Water warfare composite flocculation agent, is made of according to parts by weight following raw material: hydration chlorine
Change 0.6 part of copper, 1.7 parts of polyacrylamide, 1.8 parts of sodium carboxymethylcellulose, 1.8 parts of iron chloride, 10 parts of chitosan, citric acid
2.2 parts, 0.6 part of Peracetic acid, 1.7 parts of polyaluminium molybdenum, 1.8 parts of polymerization oxidation iron, 2.7 parts of complex microorganism, sodium hypochlorite
1.6 parts, 2.4 parts of polymeric aluminum sulfate iron, 12 parts of inorganic silicate, 80 parts of diatomite, boric acid account for 0.7 part, polyferric chloride 2.3
Part, 9 parts of inorganic phosphate, 0.7 part of zinc sulfate, 20 parts of bentonite, 30 parts of zeolite, 0.5 part of ammonium chloride, methylacryoyloxyethyl
0.9 part of trimethyl ammonium chloride, 12 parts of active carbon and 0.4 part of benzyl chloride.
Embodiment 3
A kind of above-mentioned high-efficiency environment friendly cultivates Water warfare composite flocculation agent, is made of according to parts by weight following raw material: hydration chlorine
Change 0.45 part of copper, 1.25 parts of polyacrylamide, 1.5 parts of sodium carboxymethylcellulose, 1.6 parts of iron chloride, 7.5 parts of chitosan, lemon
Sour 1.8 parts, 0.4 part of Peracetic acid, 1.5 parts of polyaluminium molybdenum, 1.55 parts of polymerization oxidation iron, 2.5 parts of complex microorganism, hypochlorous acid
1.35 parts of sodium, 2.1 parts of polymeric aluminum sulfate iron, 9.5 parts of inorganic silicate, 70 parts of diatomite, boric acid account for 0.45 part, polymerization tri-chlorination
2 parts of iron, 6.5 parts of inorganic phosphate, 0.5 part of zinc sulfate, 15 parts of bentonite, 25 parts of zeolite, 0.3 part of ammonium chloride, methacryl
0.7 part of oxy-ethyl-trimethyl salmiac, 9.5 parts of active carbon and 0.25 part of benzyl chloride.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (4)
1. a kind of high-efficiency environment friendly cultivates Water warfare composite flocculation agent, which is characterized in that be made of according to parts by weight following raw material:
0.3~0.6 part of Hydrated copper chloride, 0.8~1.7 part of polyacrylamide, 1.2~1.8 parts of sodium carboxymethylcellulose, iron chloride 1.4
~1.8 parts, 5~10 parts of chitosan, 1.4~2.2 parts of citric acid, 0.2~0.6 part of Peracetic acid, polyaluminium molybdenum 1.3~1.7
Part, 1.3~1.8 parts of polymerization oxidation iron, 2.3~2.7 parts of complex microorganism, 1.1~1.6 parts of sodium hypochlorite, polymeric aluminum sulfate iron
1.8~2.4 parts, 7~12 parts of inorganic silicate, 60~80 parts of diatomite, boric acid account for 0.2~0.7 part, polyferric chloride 1.7
~2.3 parts, 4~9 parts of inorganic phosphate, 0.3~0.7 part of zinc sulfate, 10~20 parts of bentonite, 20~30 parts of zeolite, ammonium chloride
0.1~0.5 part, 0.5~0.9 part of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 7~12 parts of active carbon and benzyl chloride 0.1~
0.4 part.
2. a kind of high-efficiency environment friendly according to claim 1 cultivates Water warfare composite flocculation agent, which is characterized in that according to weight
Amount part is made of following raw material: 0.3~0.5 part of Hydrated copper chloride, 0.8~1.6 part of polyacrylamide, sodium carboxymethylcellulose
1.2~1.7 parts, 1.4~1.7 parts of iron chloride, 5~9 parts of chitosan, 1.4~2.1 parts of citric acid, 0.2~0.5 part of Peracetic acid,
1.3~1.6 parts of polyaluminium molybdenum, 1.3~1.7 parts of polymerization oxidation iron, 2.3~2.6 parts of complex microorganism, sodium hypochlorite 1.1~
1.5 parts, 1.8~2.3 parts of polymeric aluminum sulfate iron, 7~11 parts of inorganic silicate, 60~79 parts of diatomite, boric acid account for 0.2~0.6
Part, 1.7~2.2 parts of polyferric chloride, 4~8 parts of inorganic phosphate, 0.3~0.6 part of zinc sulfate, 10~19 parts of bentonite, boiling
20~29 parts of stone, 0.1~0.4 part of ammonium chloride, 0.5~0.8 part of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, active carbon 7~
11 parts and 0.1~0.3 part of benzyl chloride.
3. a kind of high-efficiency environment friendly according to claim 1 cultivates Water warfare composite flocculation agent, which is characterized in that according to weight
Amount part is made of following raw material: 0.4~0.5 part of Hydrated copper chloride, 0.9~1.6 part of polyacrylamide, sodium carboxymethylcellulose
1.3~1.7 parts, 1.5~1.7 parts of iron chloride, 6~9 parts of chitosan, 1.5~2.1 parts of citric acid, 0.3~0.5 part of Peracetic acid,
1.4~1.6 parts of polyaluminium molybdenum, 1.4~1.7 parts of polymerization oxidation iron, 2.4~2.6 parts of complex microorganism, sodium hypochlorite 1.2~
1.5 parts, 1.9~2.3 parts of polymeric aluminum sulfate iron, 8~11 parts of inorganic silicate, 61~79 parts of diatomite, boric acid account for 0.3~0.6
Part, 1.8~2.2 parts of polyferric chloride, 5~8 parts of inorganic phosphate, 0.4~0.6 part of zinc sulfate, 11~19 parts of bentonite, boiling
21~29 parts of stone, 0.2~0.4 part of ammonium chloride, 0.6~0.8 part of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, active carbon 8~
11 parts and 0.2~0.3 part of benzyl chloride.
4. a kind of high-efficiency environment friendly according to claim 1 cultivates Water warfare composite flocculation agent, which is characterized in that according to weight
Amount part is made of following raw material: 0.45 part of Hydrated copper chloride, 1.25 parts of polyacrylamide, 1.5 parts of sodium carboxymethylcellulose, chlorination
1.6 parts of iron, 7.5 parts of chitosan, 1.8 parts of citric acid, 0.4 part of Peracetic acid, 1.5 parts of polyaluminium molybdenum, polymerization oxidation iron 1.55
Part, 2.5 parts of complex microorganism, 1.35 parts of sodium hypochlorite, 2.1 parts of polymeric aluminum sulfate iron, 9.5 parts of inorganic silicate, diatomite 70
Part, boric acid account for 0.45 part, 2 parts of polyferric chloride, 6.5 parts of inorganic phosphate, 0.5 part of zinc sulfate, 15 parts of bentonite, zeolite 25
Part, 0.3 part of ammonium chloride, 0.7 part of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 9.5 parts of active carbon and 0.25 part of benzyl chloride.
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|---|---|---|---|
| CN201810948536.4A CN108975473A (en) | 2018-08-20 | 2018-08-20 | A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent |
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| CN201810948536.4A CN108975473A (en) | 2018-08-20 | 2018-08-20 | A kind of high-efficiency environment friendly cultivation Water warfare composite flocculation agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111547828A (en) * | 2020-04-10 | 2020-08-18 | 佛山华清智业环保科技有限公司 | Composite flocculant and preparation method and application thereof |
-
2018
- 2018-08-20 CN CN201810948536.4A patent/CN108975473A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111547828A (en) * | 2020-04-10 | 2020-08-18 | 佛山华清智业环保科技有限公司 | Composite flocculant and preparation method and application thereof |
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Application publication date: 20181211 |