CN108954872A - Solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material utilizes system - Google Patents
Solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material utilizes system Download PDFInfo
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- CN108954872A CN108954872A CN201810789143.3A CN201810789143A CN108954872A CN 108954872 A CN108954872 A CN 108954872A CN 201810789143 A CN201810789143 A CN 201810789143A CN 108954872 A CN108954872 A CN 108954872A
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- 239000000126 substance Substances 0.000 title claims abstract description 51
- 239000000463 material Substances 0.000 title claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 38
- 239000008246 gaseous mixture Substances 0.000 claims abstract description 11
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 4
- 239000010935 stainless steel Substances 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000000694 effects Effects 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 12
- 238000005137 deposition process Methods 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 230000004044 response Effects 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims 1
- 238000001228 spectrum Methods 0.000 abstract description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 20
- 238000005516 engineering process Methods 0.000 description 13
- 239000000446 fuel Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 8
- 229910003081 TiO2−x Inorganic materials 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- 238000010248 power generation Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000003760 hair shine Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 241001464837 Viridiplantae Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 125000001967 indiganyl group Chemical group [H][In]([H])[*] 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
- H02S40/40—Thermal components
- H02S40/44—Means to utilise heat energy, e.g. hybrid systems producing warm water and electricity at the same time
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/60—Thermal-PV hybrids
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- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to application of solar, it is desirable to provide a kind of solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material utilizes system.Photo-thermal chemical looping reaction device including the suprasil material in hollow tubular structure, arrival end and CO2And H2The air supply pipe of O gaseous mixture connects, and setting has the TiO of Heat-collecting effect in bottom plane2Base film layer；The thermally conductive cavity of stainless steel material is in hollow tubular structure, and the bottom plane of top planes and photo-thermal chemical looping reaction device is fitted closely to realize that heat conducts；The arrival end of photo-thermal chemical looping reaction device and the outlet end of thermally conductive cavity are located at the same side.Present invention combination solar energy utilizes and heat utilization means, distinguishes wave band to sunlight and utilizes, and realizes that the classification sub-prime of solar energy utilizes, compared with the prior art solar spectrum energy utilization scope is expanded, integral energy utilization efficiency is improved, cascaded utilization of energy theory is embodied, improves energy utilization quality.
Description
Technical field
The invention belongs to application of solar, and in particular to the sun based on heat collection type photo-thermal chemical cycle material
Sub-prime can be classified and utilize system.
Background technique
With social development, the mankind improve energy demand.Currently, global non-renewable energy is constituted based on fossil fuel
Body.However, fossil fuel has non-renewable, and pollute the environment in use process.This promote people find it is renewable and
Renewable energy free from environmental pollution.In numerous energy, expense is low, source is wide, free from environmental pollution etc. excellent because having for solar energy
It puts and is paid close attention to by people.Meanwhile the CO that a large amount of combustion of fossil fuels generate in human development process2Negative shadow is generated to environment
It rings, CO2Emission reduction becomes the topic that countries in the world government pays close attention to jointly.CO at present2There are two types of Technology Ways, i.e. carbon dioxide for emission reduction
Trapping storage (CO2Capture Storage, CCS) with the photosynthesis of manual simulation's nature Green plant carry out CO2's
Convert (CO2Capture Conversion, CCC).Wherein, CCC technology can be by CO2Available hydrocarbon fuel is converted to, is one
The environmental-friendly Energy Conversion Technology of item.
Solar energy is a kind of from a wealth of sources, environmental-friendly non-renewable energy, and energy figure can be determined by spectral wavelength.
The spectral wavelength of solar energy is distinguished by 280nm to 2500nm according to wave band, and 280nm to 380nm belongs to ultraviolet band, and 380nm is arrived
760nm is visible waveband, and the above are infrared bands by 760nm.UV, visible light band of light has high-energy, can be realized solar energy
It utilizes；Infrared band light has fuel factor, can be realized solar thermal utilization.
It is utilized and two class of heat utilization currently, the utilization technology of solar energy can be divided into light.
Solar energy, which is utilized, prepares the technologies such as solar energy fuel including photovoltaic power generation, photochemistry.Solar energy utilization technology
The problem of be, such technology mainly uses UV, visible light wave band, and the light of infrared band can hardly be used, solar spectrum
Utilization scope reduces, and causes the waste of energy.
Solar thermal utilization includes that photo-thermal power generation, heat chemistry prepare the technologies such as solar energy fuel.Solar energy utilization technique
Solar energy can be theoretically fully converted to thermal energy, but in the conversion process, the energy figure of UV, visible light wave band can drop
It is low.
It can be seen that main solar utilization technique does not carry out classification sub-prime utilization to each wave band of solar energy at present, and
It is unreasonable, halfway to lead to the problem of energy utilization.For this technical problem, the present invention proposes a kind of novel based on thermal-arrest
The solar energy hierarchical sub-prime Land use systems of type photo-thermal chemical cycle.
Summary of the invention
The technical problem to be solved by the present invention is to overcome deficiency in the prior art, provide a kind of based on heat collection type photo-thermal
The solar energy hierarchical sub-prime of chemical cycle material utilizes system.
In order to solve the technical problem, solution of the invention is:
A kind of solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material is provided using system, including transparent stone
The photo-thermal chemical looping reaction device of English material；Photo-thermal chemical looping reaction device is in hollow tubular structure, is followed for photo-thermal chemistry
Ring reaction, arrival end and CO2And H2The air supply pipe of O gaseous mixture connects, and outlet end is connected by pipeline with gas-liquid separator；Light
The bottom of thermochemical cycles reactor is a flat surface, and setting has the TiO of Heat-collecting effect on inner surface2Base film layer, should
TiO2Base film layer is to be grown on reactor bottom with vapour deposition process；
The system further includes the thermally conductive cavity of stainless steel material, and thermally conductive cavity is in hollow tubular structure, is used for thermally conductive Jie
Mass flow moves temperature control, and arrival end connects with heat-conducting medium input pipe, and outlet end is connected by output pipe with heat-conducting medium storage tank；
It is a flat surface at the top of thermally conductive cavity, the bottom plane of the top planes and photo-thermal chemical looping reaction device is fitted closely to realize
Heat conduction；The arrival end of photo-thermal chemical looping reaction device and the outlet end of thermally conductive cavity are located at the same side, photo-thermal chemical cycle
The arrival end of the outlet end of reactor and thermally conductive cavity is located at the same side.
In the present invention, the top of the gas-liquid separator sets gaseous product discharge pipe, and bottom passes through product liquid discharge pipe
It is connected to liquid collection tank.
In the present invention, in the CO2And H2Gas flowmeter is set on the air supply pipe of O gaseous mixture, in heat-conducting medium input pipe
Upper setting fluid flowmeter.
In the present invention, valve is respectively set on each pipeline being connected with photo-thermal chemical looping reaction device and thermally conductive cavity.
In the present invention, the TiO2The thickness range of base film layer is between 5nm~5um.
Inventive principle description:
Sunlight divides into infrared band, visible light wave range and ultraviolet light wave band according to wave band, and photo-thermal chemical cycle is base
In the solar energy preparation of fuel technology of photic Lacking oxygen mechanism, realized by high energy ultraviolet and visible light wave range driving.To utilize
TiO2Decompose CO2And H2O prepares CO and H2Reaction for, detailed process are as follows: utilize sunlight high energy ultraviolet and visible light wave range
In TiO2Surface generates photic Lacking oxygen, subsequent CO2And H2The mixed gas of O passes through TiO2Surface is reacted with photic Lacking oxygen, raw
At CO and H2, form complete cycle.
The present invention distinguishes sunlight according to wavelength and applies, real in conjunction with photo-thermal chemical cycle technology and photo-thermal power generation technology
The classification sub-prime of existing solar energy utilizes.Core is that photo-thermal chemical cycle is combined to prepare solar energy fuel and solar energy thermal-power-generating, this
Invention is with TiO2On the one hand base film responds ultraviolet under the conditions of full spectrum light shines as heat collection type photo-thermal chemical cycle material
Visible waveband light carries out photo-thermal chemical cycle and converts CO2And H2The mixed gas of O generates hydrocarbon fuel, by UV, visible light wave band
High-quality energy is stored in the form of hydrocarbon fuel；The unused ultraviolet-visible of another aspect response light thermochemical cycles and infrared
The fuel factor of band of light generates heat, while maintaining photo-thermal chemical cycle required temperature (200 DEG C~600 DEG C), by thermally conductive
Medium (conduction oil or fuse salt) passes into heat-conducting medium storage tank and carries out photo-thermal power generation.
Compared with prior art, the beneficial effects of the present invention are:
1, the present invention combines solar energy utilization and heat utilization means, distinguishes wave band to sunlight and utilizes, realizes solar energy
Classification sub-prime utilize, the UV, visible light optical band in sunlight is utilized by photo-thermal chemical cycle technology, by this portion
Energy is divided to fix with the fuel forms easily stored；By solar energy heating part to can not by the ultraviolet of photo-thermal chemical recycling
See and utilized with infrared band, this portion of energy is fixed in the form of heat power generation or other heat utilizations.
2, the present invention realizes that solar energy hierarchical sub-prime utilizes by photo-thermal chemical cycle and solar energy techniques, compares existing
There is technology to expand solar spectrum energy utilization scope；High energy storaging product is further produced on the basis of original thermal reservoir,
Improve solar conversion efficiency.Integral energy utilization efficiency is improved, cascaded utilization of energy theory is embodied, improves energy utilization product
Matter.
Detailed description of the invention
Fig. 1 is that the solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material in the present invention is illustrated using system
Figure.
In figure: 1CO2And H2The air supply pipe of O gaseous mixture；2 gas flowmeters；3 photo-thermal chemical looping reaction devices；4 gas-liquid separations
Device；5 gaseous product discharge pipes；6 product liquid discharge pipes；7 liquid collection tanks；8 heat-conducting medium input pipes；9 fluid flowmeters；10
Thermally conductive cavity；11 heat-conducting medium storage tanks；(TiO is arranged in its inner surface to 12 reactor bottoms2Base film layer).
Specific embodiment
The present invention is described in further details with example with reference to the accompanying drawing.
As shown in the picture, the solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material utilizes system, including saturating
The photo-thermal chemical looping reaction device 3 of bright quartz material and the thermally conductive cavity 10 of stainless steel material.
Photo-thermal chemical looping reaction device 3 be in hollow tubular structure, be used for photo-thermal chemical looping reaction, arrival end with
CO2And H2The air supply pipe 1 of O gaseous mixture connects, and outlet end is connected by pipeline with gas-liquid separator 4；In CO2And H2O gaseous mixture
Gas flowmeter 2 is set on air supply pipe 1.The top of gas-liquid separator 4 sets gaseous product discharge pipe 5, and bottom passes through product liquid
Discharge pipe 6 is connected to liquid collection tank 7.Reactor bottom 12 is a flat surface, and inner surface is equipped with TiO2Base film layer；TiO2
Base film layer is the inner surface that reactor bottom 12 is grown on vapour deposition process, and thickness range is between 5nm~5um.TiO2
The vapour deposition process growth of base film layer belongs to the prior art.
Thermally conductive cavity 10 is in hollow tubular structure, is used for heat transfer medium flows temperature control, and arrival end is defeated with heat-conducting medium
Enter pipe 8 to connect, outlet end is connected by output pipe with heat-conducting medium storage tank 11, and liquid is arranged on heat-conducting medium input pipe 8
Flowmeter 9；The top of thermally conductive cavity 10 is a flat surface, and the top planes and the bottom plane of photo-thermal chemical looping reaction device 3 are tight
Closely connected conjunction is to realize that heat conducts.
The outlet end of the arrival end of photo-thermal chemical looping reaction device 3 and thermally conductive cavity 10 is located at the same side, and photo-thermal chemistry follows
The arrival end of the outlet end of loop reactor 3 and thermally conductive cavity 10 is located at the same side.With photo-thermal chemical looping reaction device 3 and thermally conductive
Valve is respectively set on the connected each pipeline of cavity 10.
The application method of above system, comprising the following steps:
(1) by CO2Unstripped gas, which introduces, is equipped with H2The bubbler of O, the CO of discharge2And H2O gaseous mixture is laggard through gas flowmeter
Enter photo-thermal chemical looping reaction device 3；By changing CO2Temperature adds pure CO by ventilation bypass2Mode, guarantee enter photo-thermal
The CO of chemical looping reaction device2And H2In O gaseous mixture, CO2And H2The mass ratio of O is 100: 1.
(2) in photo-thermal chemical looping reaction device 3, CO2And H2O gaseous mixture shines in 200~600 DEG C, normal pressure and full spectrum light
Under the conditions of, with TiO2The surface of base film layer contacts concurrent third contact of a total solar or lunar eclipse thermochemical cycles reaction, generates hydrocarbon fuel；
Chemical equation involved in the process are as follows:
1/xTiO2→1/x TiO2-x+1/2O2
1/x TiO2-x+CO2→1/xTiO2+CO
1/x TiO2-x+H2O→1/xTiO2+H2
Reaction product obtains gaseous product and product liquid after gas-liquid separator, enters respectively through respective discharge pipe
Storage tank；
(3) during photo-thermal chemical looping reaction, heat-conducting medium (melting is introduced into thermally conductive cavity 10 using circulating pump
Salt or conduction oil)；TiO2The heat that base film layer is absorbed passes through the bottom conductive of photo-thermal chemical looping reaction device 3 to thermal conductive cavity
Body 10 carries out heat with the heat-conducting medium wherein flowed and exchanges；Flow by controlling heat-conducting medium guarantees photo-thermal chemical reaction
Temperature maintains 200~600 DEG C, and the heat-conducting medium after absorbing photo-thermal is sent to storage tank or heat exchange equipment.
Specific embodiment:
(1) under full spectrum light source irradiation condition, first it is passed through N2Deng creation oxygen-free atmosphere condition, reacted 1.；Then
It is depressed in 27 DEG C of saturated vapors, CO2Carry H2The mixed gas of O is that 30ml/min is passed through photo-thermal chemical looping reaction with total flow
In device 3；Reach 550 DEG C of reaction temperature using illumination, is reacted under normal pressure 2., 3., finally obtain CO, H2Hydrocarbon combustion
Material, chemical equation are as follows:
1/xTiO2→1/x TiO2-x+1/2O2 ①
1/x TiO2-x+CO2→1/xTiO2+CO ②
1/x TiO2-x+H2O→1/xTiO2+H2 ③
Finally, photo-thermal chemical cycle product is passed through in storage tank and is stored.
(2) while carrying out preparation of fuel, the TiO with Heat-collecting effect2Base film layer responds infrared band light, generates
Heat and the fluidised form heat-conducting medium being transferred in thermally conductive cavity 10 (such as fuse salt, conduction oil).Guaranteeing that reaction temperature is 550 DEG C
Under the premise of, the flow 0.5m of heat-conducting medium is controlled by fluid flowmeter 93/ h is sent after absorbing heat heating to storage tank storage,
Or it is fed directly to heat exchange equipment.
The above enumerated are only specific embodiments of the present invention for finally, it should also be noted that.Obviously, the present invention is unlimited
In above embodiments, acceptable there are many deformations.The present invention can be with other without prejudice to spirit or central characteristics of the invention
Concrete form is summarized.Therefore, in all respects, the embodiment above of the invention can only all be considered to the present invention
Explanation and the present invention cannot be limited.Claims indicate the scope of the present invention, and above-mentioned explanation does not point out this hair
Therefore bright range any change within the meaning and scope equivalent to the claims of the present invention, is all considered as wrapping
It includes within the scope of the claims.
Claims (5)
1. a kind of solar energy hierarchical sub-prime based on heat collection type photo-thermal chemical cycle material utilizes system, including suprasil material
Photo-thermal chemical looping reaction device；It is characterized in that, photo-thermal chemical looping reaction device is in hollow tubular structure, it to be used for photo-thermal
Learn circular response, arrival end and CO2And H2The air supply pipe of O gaseous mixture connects, and outlet end passes through pipeline and gas-liquid separator phase
It connects；The bottom of photo-thermal chemical looping reaction device is a flat surface, and setting has the TiO of Heat-collecting effect on inner surface2Base film
Layer, the TiO2Base film layer is to be grown on reactor bottom with vapour deposition process；
The system further includes the thermally conductive cavity of stainless steel material, and thermally conductive cavity is in hollow tubular structure, is used for heat-conducting medium stream
Dynamic temperature control, arrival end connect with heat-conducting medium input pipe, and outlet end is connected by output pipe with heat-conducting medium storage tank；It is thermally conductive
It is a flat surface at the top of cavity, the bottom plane of the top planes and photo-thermal chemical looping reaction device is fitted closely to realize heat
Conduction；The arrival end of photo-thermal chemical looping reaction device and the outlet end of thermally conductive cavity are located at the same side, photo-thermal chemical looping reaction
The arrival end of the outlet end of device and thermally conductive cavity is located at the same side.
2. system according to claim 1, which is characterized in that the top of the gas-liquid separator sets gaseous product discharge
Pipe, bottom is connected to liquid collection tank by product liquid discharge pipe.
3. system according to claim 1, which is characterized in that in the CO2And H2Gas is set on the air supply pipe of O gaseous mixture
Fluid flowmeter is arranged on heat-conducting medium input pipe in flowmeter body.
4. system according to claim 1, which is characterized in that be connected with photo-thermal chemical looping reaction device and thermally conductive cavity
Each pipeline on valve is respectively set.
5. system according to claim 1, which is characterized in that TiO2The thickness range of base film layer is between 5nm~5um.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810789143.3A CN108954872B (en) | 2018-07-18 | 2018-07-18 | Solar energy grading and quality-grading utilization system based on heat collection type photo-thermal chemical circulation material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810789143.3A CN108954872B (en) | 2018-07-18 | 2018-07-18 | Solar energy grading and quality-grading utilization system based on heat collection type photo-thermal chemical circulation material |
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| CN108954872A true CN108954872A (en) | 2018-12-07 |
| CN108954872B CN108954872B (en) | 2020-05-12 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115318095A (en) * | 2022-07-08 | 2022-11-11 | 西南石油大学 | Reactor and method for realizing solar photo-thermal catalysis at stable temperature |
| WO2023284602A1 (en) * | 2021-07-12 | 2023-01-19 | 浙江大学 | Multi-energy coupled complementary and ordered conversion system and method |
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| US20070196261A1 (en) * | 2006-02-21 | 2007-08-23 | Drexel University | Production and uses of carbon suboxides |
| CN101367505A (en) * | 2008-09-19 | 2009-02-18 | 燕山大学 | Method for preparing hydrogen gas by decomposing water with solar energy |
| WO2009158385A2 (en) * | 2008-06-25 | 2009-12-30 | Hydrogen Generation Inc. | Improved process for producing hydrogen |
| CN104449847A (en) * | 2014-12-12 | 2015-03-25 | 浙江大学 | Solar energy-driven carbonaceous matter reaction and reaction product photocatalytic method |
| WO2015109217A1 (en) * | 2014-01-17 | 2015-07-23 | The Board Of Regents Of The University Of Texas System | Tandem photochemical-thermochemical process for hydrocarbon production from carbon dioxide feedstock |
-
2018
- 2018-07-18 CN CN201810789143.3A patent/CN108954872B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070196261A1 (en) * | 2006-02-21 | 2007-08-23 | Drexel University | Production and uses of carbon suboxides |
| WO2009158385A2 (en) * | 2008-06-25 | 2009-12-30 | Hydrogen Generation Inc. | Improved process for producing hydrogen |
| CN101367505A (en) * | 2008-09-19 | 2009-02-18 | 燕山大学 | Method for preparing hydrogen gas by decomposing water with solar energy |
| WO2015109217A1 (en) * | 2014-01-17 | 2015-07-23 | The Board Of Regents Of The University Of Texas System | Tandem photochemical-thermochemical process for hydrocarbon production from carbon dioxide feedstock |
| CN104449847A (en) * | 2014-12-12 | 2015-03-25 | 浙江大学 | Solar energy-driven carbonaceous matter reaction and reaction product photocatalytic method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023284602A1 (en) * | 2021-07-12 | 2023-01-19 | 浙江大学 | Multi-energy coupled complementary and ordered conversion system and method |
| CN115318095A (en) * | 2022-07-08 | 2022-11-11 | 西南石油大学 | Reactor and method for realizing solar photo-thermal catalysis at stable temperature |
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| Publication number | Publication date |
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| CN108954872B (en) | 2020-05-12 |
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