CN108953437A - Brake disc with tungsten carbide chromium-base alloy ceramic coating - Google Patents

Brake disc with tungsten carbide chromium-base alloy ceramic coating Download PDF

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Publication number
CN108953437A
CN108953437A CN201810917214.3A CN201810917214A CN108953437A CN 108953437 A CN108953437 A CN 108953437A CN 201810917214 A CN201810917214 A CN 201810917214A CN 108953437 A CN108953437 A CN 108953437A
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CN
China
Prior art keywords
brake disc
tungsten carbide
ceramic coating
base alloy
alloy ceramic
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810917214.3A
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Chinese (zh)
Inventor
王占庆
王冶
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Individual
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Individual
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Priority to CN201810917214.3A priority Critical patent/CN108953437A/en
Publication of CN108953437A publication Critical patent/CN108953437A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • F16D69/027Compositions based on metals or inorganic oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/129Flame spraying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0034Materials; Production methods therefor non-metallic
    • F16D2200/0039Ceramics
    • F16D2200/0047Ceramic composite, e.g. C/C composite infiltrated with Si or B, or ceramic matrix infiltrated with metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0082Production methods therefor

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

Brake disc with tungsten carbide chromium-base alloy ceramic coating, the invention belongs to brake system fields, it will solve the problems, such as that the heat resistant and wear resistant performance of existing brake disc is to be improved.It is that thermal jet is coated with tungsten carbide cobalt chrome based alloy ceramic coating or WC coating on the rubbing surface of brake disc that the present invention, which has the brake disc of tungsten carbide chromium-base alloy ceramic coating, the constituent and content of tungsten carbide chromium-base alloy ceramic coating: 86wt%WC, 10wt%Co and 4wt%Cr.The present invention manufactures one layer using hot-spraying technique and contains tungsten carbide cobalt chrome ceramal rubbing surface, it reaches wear-resisting, high temperature resistant, anti-corrosion, acid and alkali-resistance, oxidation resistant purpose, ceramic layer is in certain temperature, the phenomenon that " heat fade " will not be generated, can work normally in thousand degree of hot environments, extend the service life of brake disc.

Description

Brake disc with tungsten carbide chromium-base alloy ceramic coating
Technical field
The invention belongs to brake system fields, and in particular to have Wear-resistant, high-temperature resistant, the brake disc of antiseptic and rustproof coating.
Background technique
Automobile brake disc is one of integrally-built critical component of locomotive, concerning arrive most crucial safety problem.
The brake system course of work of automobile is to clamp brake disc by brake callipers to realize braking, can regard as The process of one energy conversion, the high-speed rotating kinetic energy of wheel are converted into the thermal energy of wheel and brake system, nothing by friction Brake system or tire and brake block all have power limit to heat by being, once heat is more than this limit, Jiu Huifa Raw " heat fade ", braking strength just will be greatly reduced, or even cause brake failure, it may occur that serious safety accident.This is Because the mutual power between temperature more macromolecule is bigger in physics, when temperature sharply increases, the molecule in brake disc is just Sizable gravitation and repulsion can be born, both power can allow brake disc superficial expansion, and tend to planarize, coefficient of friction meeting It reduces rapidly, while the brake rubber block on clamp can also generate same variation, is as a result exactly braking quality sharp fall, influence Driving safety.
The brake disc generally used now, using gray cast iron 250 (HT250) standard in China, equivalent U.S. G3000 mark Standard, the common brake disc of the manufacturing.There are Railway Projects for it:
(1) its material is wear-resisting, high temperature resistant, and rust resistance is poor.
(2) it because of the material that it is used, determines that thermal stress, transformation stress and the frictional force of its alternating hot and cold are poor, is easy to produce Heat fatigue crack causes brake disc to fail because of heat fatigue cracking and excessive wear.
Summary of the invention
The invention aims to solve the problems, such as that the heat resistant and wear resistant performance of existing brake disc is to be improved, and provide one Kind has the brake disc of tungsten carbide chromium-base alloy ceramic coating.
It is the thermal spraying on the rubbing surface of brake disc that the present invention, which has the brake disc of tungsten carbide chromium-base alloy ceramic coating, There are tungsten carbide chromium-base alloy ceramic coating or WC coating, the constituent and hundred of the tungsten carbide chromium-base alloy ceramic coating Divide content: 86wt%WC, 10wt%Co and 4wt%Cr.
The present invention prepares ceramic coating using hot-spraying technique technology, and according to standard GB/T/T19823-2005 rule Fixed, on common brake disc (HT250) organism material surface, one layer of manufacture contains tungsten carbide cobalt chrome ceramal rubbing surface, makes it Reach wear-resisting, high temperature resistant, anti-corrosion, acid and alkali-resistance, oxidation resistant purpose, ceramic layer will not generate " heat fade " in certain temperature The phenomenon that, it can be worked normally in thousand degree of hot environments, the service life of brake disc can be extended, improve brake and safety Can, it is such as proper use of lifelong without replacement.Material is saved in the fabrication process, it is energy saving, promote environmental protection.
Detailed description of the invention
Fig. 1 is the side view of brake disc, wherein the rubbing surface of 1-brake disc, 2-hubs;
Fig. 2 is the front view of brake disc, wherein the rubbing surface of 1-brake disc, 2-hubs.
Specific embodiment
Specific embodiment 1: it is to brake that present embodiment, which has the brake disc of tungsten carbide chromium-base alloy ceramic coating, Thermal jet is coated with tungsten carbide cobalt chrome based alloy ceramic coating or WC coating, the tungsten carbide chromium-base alloy ceramics on the rubbing surface of disk The constituent and percentage composition of coating: 86wt%WC, 10wt%Co and 4wt%Cr.
Present embodiment have tungsten carbide chromium-base alloy ceramic coating brake disc is wear-resisting, high temperature resistant, corrosion-resistant, salt tolerant Mist does not corrode, and has heat insulating function.The high temperature deformation of brake disc is not easy to cause using hot-spraying technique.
Specific embodiment 2: the present embodiment is different from the first embodiment in that being sprayed on the hub surface of brake disc Apply VK-L08 (two-component) nano paint.
Be sprayed with heat insulation nano coating in present embodiment hub, the VL-L08 two-component nano paint of antirust, isolation and its Connected component conducts thermal energy.
Specific embodiment 3: the present embodiment is different from the first and the second embodiment in that the disk thermal jet of brake disc Sandblasting roughening treatment is first passed through before applying in advance.
Specific embodiment 4: will before thermal spraying unlike one of present embodiment and specific embodiment one to three Brake disc is preheated to 100~150 DEG C.
The purpose of present embodiment preheating is the moisture and moisture in order to eliminate the surface of workpiece, improves spraying particle and work Interface temperature when part contacts, to improve the bond strength of coating Yu workpiece body.
Specific embodiment 5: present embodiment thermal jet described unlike specific embodiment one or four is painted with Plasma spray, flame-spraying, electric arc spraying or electric heating spraying.
Specific embodiment 6: flame described unlike one of present embodiment and specific embodiment one to five sprays It is painted with supersonic flame spraying, control flame speed is 2000~2200m/s, and flame temperature is 4800~5200 DEG C.
Specific embodiment 7: when present embodiment controls supersonic flame spraying unlike specific embodiment six Kerosene pressure is 1.2MPa, and kerosene oil flow is 20~60L/H, and oxygen pressure 1.6MPa, oxygen flow is 20~60m3/H。
Specific embodiment 8: by tungsten carbide cobalt chrome unlike one of present embodiment and specific embodiment two to seven Based alloy ceramic coating is sprayed on the rubbing surface of brake disc, and the coating thickness of tungsten carbide chromium-base alloy ceramic coating is 0.1 ~0.15mm.
Specific embodiment 9: thermal jet unlike one of present embodiment and specific embodiment two to eight is coated with carbonization The brake disc of tungsten-cobalt chromium-base alloy ceramic coating is handled by polishing grinding.
Embodiment: the method that tungsten carbide chromium-base alloy ceramic coating is prepared on the present embodiment brake disc follows these steps reality It is existing:
One, brake disc HT250 workpiece is checked, determines that flawless at disk and outer circumferential edge, X-ray are detected not damaged;
Two, mechanical derusting by sandblasting, degreasing, greasy dirt are carried out in brake disc metal surface;
Three, brake panel surface is preheating to 110 DEG C, then uses supersonic velocity flame plating equipment, control supersonic flame Kerosene pressure is 1.2MPa, kerosene oil flow 30L/H, oxygen pressure 1.6MPa, oxygen flow 30m when spraying3/ H, carrier gas Pressure is 0.35MPa, carrier gas flux 5L/min, powder feeding atmospheric pressure 1.2MPa, powder feeding gas flow 500L/h, control flame speed Degree is 2100m/s, and flame temperature is 5000 DEG C, and 0.1mm tungsten carbide chromium-base alloy ceramics are sprayed on the rubbing surface 1 of brake disc Coating;
Four, VK-L08 nano paint is sprayed on 2 surface of the hub of brake disc;
Five, polishing grinding carries out inspection amount examination by technique requirement to standard size and finish.
VK-L08 nano paint described in the present embodiment purifies Science and Technology Ltd., the tungsten carbide purchased from Hangzhou intelligence titanium The constituent and percentage composition of cobalt chromium-base alloy ceramic coating: 86wt%WC, 10wt%Co and 4wt%Cr.
The tungsten carbide chromium-base alloy ceramic coating that the present embodiment obtains include it is following the utility model has the advantages that
A. coating uniform, gap is small, density is good, and coating reaches design requirement, and adhesive force is strong, and coating is in grey black, Hard wear resistant, non-corroding.
B. the brake disc with ceramic coating is compared with common brake disc, its advantage is that anti-cavitation, does not corrode, wear-resisting promotion 5-6 times, high temperature resistant improves 3 times, and salt spray resistance silt erosion performance is more preferable, has good economic and practical, has reached than common Brake disc performance more preferably purpose, protects the body of brake disc, prolongs the service life, and guarantees for a long time, long range driving status Under, brake disc does not have " heat fade " at a temperature of thousand degree, guarantees that braking quality is stablized, it is ensured that driving safety, personal safety.
Using supersonic flame spraying technology on common brake disc (HT250), 86% (WC)+10% (Co)+4% is prepared (Cr) alloy coat, by X-ray diffractometer and scanning electron microscope carries out object phase constituent to coating and tissue topography analyzes, and surveys Determine the porosity of coating, bond strength, microscope hardness and electrochemical corrosion performance, the results showed that;The porosity of coating is small, Bond strength and microscope hardness increase substantially, and the wear-resisting of coating, corrosion-and high-temp-resistant are high.
The major parameter of tungsten carbide chromium-base alloy ceramic coating:
1, porosity < 1%;
2, hardness HV0.3:1200-1400;
3, roughness: 3.5-5.5 μm;
4, deposition: 45-60%;
5, bond strength: > 80Mpa.

Claims (9)

1. the brake disc with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that this has tungsten carbide chromium-base alloy pottery The brake disc of porcelain coating is that thermal jet is coated with tungsten carbide cobalt chrome based alloy ceramic coating or WC coating, institute on the rubbing surface of brake disc State the constituent and percentage composition of tungsten carbide chromium-base alloy ceramic coating: 86wt%WC, 10wt%Co and 4wt%Cr.
2. the brake disc according to claim 1 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that stopping The hub surface of hull sprays VK-L08 nano paint.
3. the brake disc according to claim 1 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that brake Sandblasting roughening treatment is first passed through before the disk thermal spraying of disk in advance.
4. the brake disc according to claim 1 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that thermal jet Brake disc is preheated to 100~150 DEG C before painting.
5. the brake disc according to claim 1 or 4 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that institute The thermal jet stated is painted with plasma spraying, flame-spraying, electric arc spraying or electric heating spraying.
6. the brake disc according to claim 5 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that described Flame-spraying be supersonic flame spraying, control flame speed be 2000~2200m/s, flame temperature be 4800~5200 ℃。
7. the brake disc according to claim 6 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that control Kerosene pressure is 1.2MPa when supersonic flame spraying, and kerosene oil flow is 20~60L/H, oxygen pressure 1.6MPa, oxygen stream Amount is 20~60m3/H。
8. the brake disc according to claim 1 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that by carbon Change tungsten-cobalt chromium-base alloy ceramic coating to be sprayed on the rubbing surface of brake disc, the spraying of tungsten carbide chromium-base alloy ceramic coating is thick Degree is 0.1~0.15mm.
9. the brake disc according to claim 1 with tungsten carbide chromium-base alloy ceramic coating, it is characterised in that thermal jet The brake disc for being coated with tungsten carbide chromium-base alloy ceramic coating is handled using polishing grinding.
CN201810917214.3A 2018-08-13 2018-08-13 Brake disc with tungsten carbide chromium-base alloy ceramic coating Pending CN108953437A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810917214.3A CN108953437A (en) 2018-08-13 2018-08-13 Brake disc with tungsten carbide chromium-base alloy ceramic coating

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Application Number Priority Date Filing Date Title
CN201810917214.3A CN108953437A (en) 2018-08-13 2018-08-13 Brake disc with tungsten carbide chromium-base alloy ceramic coating

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CN108953437A true CN108953437A (en) 2018-12-07

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115190916A (en) * 2019-12-30 2022-10-14 C4激光技术有限公司 Brake disc with wear and corrosion resistance and method for producing same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104195492A (en) * 2014-09-02 2014-12-10 北京矿冶研究总院 Wear-resistant and corrosion-resistant coating material and preparation method thereof, and coating and preparation method thereof
CN104513944A (en) * 2014-05-04 2015-04-15 水利部产品质量标准研究所 Rare earth doped nanometer composite ceramic coating and production technology thereof
CN204387165U (en) * 2014-11-28 2015-06-10 广东新劲刚新材料科技股份有限公司 A kind of wear-resisting brake disc
CN105349933A (en) * 2015-11-11 2016-02-24 无锡清杨机械制造有限公司 Preparation method of metal ceramic coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104513944A (en) * 2014-05-04 2015-04-15 水利部产品质量标准研究所 Rare earth doped nanometer composite ceramic coating and production technology thereof
CN104195492A (en) * 2014-09-02 2014-12-10 北京矿冶研究总院 Wear-resistant and corrosion-resistant coating material and preparation method thereof, and coating and preparation method thereof
CN204387165U (en) * 2014-11-28 2015-06-10 广东新劲刚新材料科技股份有限公司 A kind of wear-resisting brake disc
CN105349933A (en) * 2015-11-11 2016-02-24 无锡清杨机械制造有限公司 Preparation method of metal ceramic coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115190916A (en) * 2019-12-30 2022-10-14 C4激光技术有限公司 Brake disc with wear and corrosion resistance and method for producing same
CN115190916B (en) * 2019-12-30 2024-04-09 C4激光技术有限公司 Brake disc with wear resistance and corrosion resistance and method for producing the same

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Application publication date: 20181207