CN108949169A - A kind of illuminating agent for submerged combustion - Google Patents
A kind of illuminating agent for submerged combustion Download PDFInfo
- Publication number
- CN108949169A CN108949169A CN201811000691.XA CN201811000691A CN108949169A CN 108949169 A CN108949169 A CN 108949169A CN 201811000691 A CN201811000691 A CN 201811000691A CN 108949169 A CN108949169 A CN 108949169A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- powder
- barium
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
Abstract
The invention discloses a kind of illuminating agents for submerged combustion.Feature is: including barium sulfate, barium nitrate, magnesium powder, aluminium powder, manganese dioxide, Linseed oil, the weight part ratio of mentioned component are as follows: barium sulfate 30-60 parts by weight；Barium nitrate 30-50 parts by weight；Magnesium powder 16-32 parts by weight；Aluminium powder 12-24 parts by weight；Manganese dioxide 2-4 parts by weight；Linseed oil 8-10 parts by weight.The present invention is with having many advantages, such as that manufacturing cost and use cost are low, and good economy performance, safe and reliable, burning brightness is high, illumination is bright, sight is clear.
Description
Technical field
The present invention relates to a kind of illuminating agents for submerged combustion.
Background technique
In the prior art, underwater operation illumination is typically all to make light source using power supply, is illuminated with LED lamp or halogenic lamps and lanterns
Operation.But charging underwater operation, there are security hidden troubles, and are made under water in the lake of not power sourcing equipment, rivers location
Industry is with regard to extremely difficult, though there is high-energy battery for provisional illumination, cost is high, less economical.In view of the above-mentioned problems,
Present inventor has carried out years of researches experiment, in experiments it is found that handhold rod type transparent carrier point under water is made using fireworks
Combustion combustion system can solve provisional to slip into the urgent needs such as detection, rescue work under water.
Summary of the invention
Above-mentioned in the prior art for solution, the problems of underwater operation, the present invention will use existing fireworks fireworks drug
Combustion system realizes submerged combustion lighting homework, and not only illumination intensity effect is good, and light ratio using power supply illuminate at
This is low, convenient and practical, safe and reliable.
The purpose of the present invention can be reached by following technical solution:
A kind of illuminating agent for submerged combustion, is characterized in that: including barium sulfate, barium nitrate, magnesium powder, aluminium powder, titanium dioxide
Manganese, Linseed oil, the weight fraction ratio of mentioned component are as follows: barium sulfate 30-60 parts by weight；Barium nitrate 30-50 parts by weight；Magnesium powder
16-32 parts by weight；Aluminium powder 12-24 parts by weight；Manganese dioxide 2-4 parts by weight；Linseed oil 8-10 parts by weight.
In embodiments of the present invention, each component preferred weight portion rate of the illuminating agent are as follows: 50 parts by weight of barium sulfate；
40 parts by weight of barium nitrate；25 parts by weight of magnesium powder；18 parts by weight of aluminium powder；4 parts by weight of manganese dioxide；9 parts by weight of Linseed oil.
Wherein the barium sulfate in above-mentioned component, barium are alkali earth metals, are elements active in alkaline-earth metal, are weeks
The element of the period 6 of II A race, chemical elemental symbol are Ba in phase table.It is a kind of soft alkaline earth gold for having silvery white gloss
Belong to.The most common mineral are barite (barium sulfate) to barium in nature, not soluble in water.The compound of barium can be used for manufacturing pyrotechnics
In green.Barium sulfate and potassium chlorate, magnesium powder, rosin etc., which mix, can be used to manufacture signal flare and pyrotechnics, use in the present invention
It is good pyrotechnics incendiary agent in production fireworks stick illumination；
Barium nitrate in the component, relative molecular mass 261.35.Chemical formula Ba (NO3)2, belong to inorganic salts classification, there is strong oxygen
The property changed, it is combustion-supporting, because heat resolve releases oxygen, can cause to burn with sulphur, phosphorus, organic matter contact, 592 DEG C of fusing point, density
3.24g/cm3 is used as oxidant in the present invention, has explosivity with the flashlight powder that aluminium powder is mixed to get；It is used in the present invention
The oxidation of composition and combustion-supporting effect.
Magnesium powder in the component, the chemical formula Mg of magnesium, relative atomic mass 24.3050 belong to active metal simple substance.Due to
For the oxide properties of magnesium as calcium between " alkalinity " and " soil nature ", therefore referred to as alkali earth metal, appearance character is silver
The powder of white metal gloss, not soluble in water, fusing point (DEG C) 648, boiling point (DEG C) 1107, relative density (water=1) 1.74, burning
Heat (kJ/mol) 609.7, ignition temperature (DEG C) 480 ~ 510.It is with stronger reproducibility.Can be generated when burning dazzle the eyes it is white
Light, magnesium can directly with chemical combination, magnesium energy and the N such as nitrogen, sulphur and halogen2And O2Reaction, magnesium are reacted with oxide: 2Mg+CO2=light=
2MgO+C.Magnesium is indispensable constituent in firebomb and flare；It is mainly used for the luminous lighting that burns in the present invention.
Aluminium powder in the component, the chemical formula AI of aluminium are insoluble in water, relative density 2.70, relative atomic mass
26.981539,660 DEG C of fusing point, 2327 DEG C of boiling point, metal simple-substance has ductility.Aluminium Combustion Energy in oxygen releases a large amount of heat
With dazzling light, it is usually used in ignition mixture and illumination mixture (as containing barium nitrate 68%, aluminium powder 28%)；It is mainly used in the present invention
White-light illuminating is issued in burning.
The middle manganese dioxide of the component, chemical formula MnO2, molecular weight 86.94,535 DEG C of decomposition temperature, relative density (water
=1) 5.03, it is insoluble in water.Manganese dioxide is amphoteric oxide, and manganese dioxide is a kind of strong oxidizer in acid medium, is met strong
Reducing agent is shown as when agent.Itself does not burn, but combustion-supporting, can be used as catalyst, is used to be catalyzed in the present invention, combustion-supporting effect.
Linseed oil component in the present invention is to play waterproofing agent and adhesive in the composition.
The remarkable advantage and good effect that the present invention has are:
1, the illuminating agent combination of bright illuminating effect can be issued by solving submerged combustion using technical solution of the present invention optimization, be made
The light for chemically reacting and generating fireworks is generated when each component in illuminating agent composition is blended in submerged combustion, light efficiency is good, light
It is long according to the time, convenient for the region location operation of underwater passive facility；
2, due to using the present invention, under water when operation it is easy to carry, loading weight is light, overcome need to bear in the prior art it is heavy
High-energy battery/storage battery of weight and the defect of illuminator, while also solving the anti-of underwater power source lighting apparatus and power lead
Water Anticorrosion Problems, and can achieve the purpose that equal illumination effect；
3, have manufacturing cost and use cost low using the present invention, good economy performance, safe and reliable, burning brightness
The advantages that high, illumination becomes clear, sight is clear.
The present invention is as a kind of illuminating agent for submerged combustion through national fireworks and firecrackers product quality supervision and inspection center
Testing result see the table below 1:
Table 1: national fireworks and firecrackers product quality supervision and inspection center fireworks safety performance detection report.
NO:WA20180718 client or individual: pictograph fine work fireworks Manufacturing Co., Ltd of Liuyang City
。
Specific embodiment
Below in conjunction with specific embodiment, invention is further described in detail.
A kind of illuminating agent for submerged combustion, its main feature is that: including barium sulfate, barium nitrate, magnesium powder, aluminium powder, titanium dioxide
Manganese, Linseed oil, the weight part ratio of mentioned component are as follows: barium sulfate 30-60 parts by weight；Barium nitrate 30-50 parts by weight；Magnesium powder 16-
32 parts by weight；Aluminium powder 12-24 parts by weight；Manganese dioxide 2-4 parts by weight；Linseed oil 8-10 parts by weight.
Wherein the barium sulfate in above-mentioned component, barium are alkali earth metals, are elements active in alkaline-earth metal, are the periods
The element of the period 6 of II A race, chemical elemental symbol are Ba in table.It is a kind of soft alkaline earth gold for having silvery white gloss
Belong to.The most common mineral are barite (barium sulfate) to barium in nature, not soluble in water.The compound of barium can be used for manufacturing pyrotechnics
In green.Barium sulfate is mixed with potassium chlorate, magnesium powder, rosin can be used to manufacture signal flare and pyrotechnics, be used in the present invention
The illumination of fireworks stick is made, is good pyrotechnics incendiary agent；
Barium nitrate in the component, relative molecular mass 261.35.Chemical formula Ba (NO3)2, belong to inorganic salts classification, there is strong oxygen
The property changed, it is combustion-supporting, because heat resolve releases oxygen, can cause to burn with sulphur, phosphorus, organic matter contact, 592 DEG C of fusing point, density
3.24g/cm3 is used as oxidant in the present invention, has explosivity with the flashlight powder that aluminium powder is mixed to get；
Magnesium powder in the component, the chemical formula Mg of magnesium, relative atomic mass 24.3050 belong to active metal simple substance.Due to magnesium
Oxide properties are as calcium between " alkalinity " and " soil nature ", therefore referred to as alkali earth metal, appearance character are silvery white
The powder of metallic luster, not soluble in water, fusing point (DEG C) 648, boiling point (DEG C) 1107, relative density (water=1) 1.74, the combustion heat
(kJ/mol) 609.7, ignition temperature (DEG C) 480 ~ 510.It is with stronger reproducibility.The white light dazzle the eyes can be generated when burning,
Magnesium can directly with chemical combination, magnesium energy and the N such as nitrogen, sulphur and halogen2And O2Reaction, magnesium are reacted with oxide: 2Mg+CO2=light=2MgO+
C.Magnesium is indispensable constituent in firebomb and flare；
Aluminium powder in the component, the chemical formula AI of aluminium are insoluble in water, relative density 2.70, relative atomic mass
26.981539,660 DEG C of fusing point, 2327 DEG C of boiling point, metal simple-substance has ductility.Aluminium Combustion Energy in oxygen releases a large amount of heat
With dazzling light, it is usually used in ignition mixture and illumination mixture (as containing barium nitrate 68%, aluminium powder 28%)；
The middle manganese dioxide of the component, chemical formula MnO2, molecular weight 86.94,535 DEG C of decomposition temperature, relative density (water=1)
5.03, it is insoluble in water.Manganese dioxide is amphoteric oxide, and manganese dioxide is a kind of strong oxidizer in acid medium, meets and strengthens
Reducing agent is shown as when agent.Itself does not burn, but combustion-supporting, can be used as catalyst.
Linseed oil component in the present invention is to play waterproofing agent and adhesive in the composition.
Embodiment 1:
In the preparation present invention, preferably following each component presses its weight fraction ratio are as follows: takes 30 parts by weight of barium sulfate；50 weight of barium nitrate
Part；30 parts by weight of magnesium powder；20 parts by weight of aluminium powder；3 parts of manganese dioxide；8 parts of Linseed oil, above-mentioned component forms through mixing and this is made
The submerged combustion illuminating agent of invention.
Embodiment 2:
In the preparation present invention, preferably following each component presses its weight fraction ratio are as follows: takes 60 parts by weight of barium sulfate；30 weight of barium nitrate
Part；16 parts by weight of magnesium powder；12 parts by weight of aluminium powder；2 parts of manganese dioxide；10 parts of Linseed oil, above-mentioned component is made through mixing composition
Submerged combustion illuminating agent of the invention.
Embodiment 3:
In the preparation present invention, preferably following each component presses its weight fraction ratio are as follows: takes 50 parts by weight of barium sulfate；40 weight of barium nitrate
Part；25 parts by weight of magnesium powder；18 parts by weight of aluminium powder；4 parts of manganese dioxide；9 parts of Linseed oil, above-mentioned component forms through mixing and this is made
The submerged combustion illuminating agent of invention.
It can be seen that from above multiple embodiments and be designed as burning illumination load by using the transparent tube body of explosion prevention function
Body enables the composition illuminating agent of above-mentioned component to burn in transparent tube body luminous lighting, can thoroughly solve non-transformer situation
Lower underwater operation illumination, present invention is equally applicable to fields or high-altitude night work to illuminate, and can be also used for transparent pipe stick or cigarette
The burning of flower new varieties issues assorted bright.Underwater operation illumination light-emitting effect can also be changed and improved simultaneously, has burning not quick-fried
It is fried, safe and reliable, illumination brightness effect it is good the features such as.
But above embodiment described in the invention is merely illustrative of the technical solution of the present invention and should not be understood as pair
The present invention imposes any restrictions.Those skilled in the art should understand that there is the present invention well known multiple material to substitute/replace
Change, without departing from essential meaning of the invention under the premise of, should all cover within the protection scope of the present invention.
Claims (2)
1. a kind of illuminating agent for submerged combustion, it is characterised in that: including barium sulfate, barium nitrate, magnesium powder, aluminium powder, titanium dioxide
Manganese, Linseed oil, the weight fraction ratio of mentioned component are as follows:
Barium sulfate 30-60 parts by weight；
Barium nitrate 30-50 parts by weight；
Magnesium powder 16-32 parts by weight；
Aluminium powder 12-24 parts by weight；
Manganese dioxide 2-4 parts by weight；
Linseed oil 8-10 parts by weight.
2. a kind of illuminating agent for submerged combustion according to claim 1, it is characterised in that: the illuminating agent it is preferred
Weight fraction ratio are as follows:
50 parts by weight of barium sulfate；
40 parts by weight of barium nitrate；
25 parts by weight of magnesium powder；
18 parts by weight of aluminium powder；
4 parts by weight of manganese dioxide；
9 parts by weight of Linseed oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811000691.XA CN108949169A (en) | 2018-08-30 | 2018-08-30 | A kind of illuminating agent for submerged combustion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811000691.XA CN108949169A (en) | 2018-08-30 | 2018-08-30 | A kind of illuminating agent for submerged combustion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108949169A true CN108949169A (en) | 2018-12-07 |
Family
ID=64474707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811000691.XA Pending CN108949169A (en) | 2018-08-30 | 2018-08-30 | A kind of illuminating agent for submerged combustion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108949169A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114383066A (en) * | 2021-12-13 | 2022-04-22 | 北京动力机械研究所 | Torch combustion surface protection flame stabilizing device and underwater transmission torch |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1686971A (en) * | 2005-04-06 | 2005-10-26 | 刘成忠 | Powder of firecracker prepared from potassium perchlorate |
| CN102925120A (en) * | 2012-11-08 | 2013-02-13 | 中国人民解放军理工大学 | Thermit and preparation method thereof |
| CN103214322A (en) * | 2013-05-15 | 2013-07-24 | 浏阳市合力高科发展有限公司 | Sulfur-smoke-free powder composition and preparation method thereof |
-
2018
- 2018-08-30 CN CN201811000691.XA patent/CN108949169A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1686971A (en) * | 2005-04-06 | 2005-10-26 | 刘成忠 | Powder of firecracker prepared from potassium perchlorate |
| CN102925120A (en) * | 2012-11-08 | 2013-02-13 | 中国人民解放军理工大学 | Thermit and preparation method thereof |
| CN103214322A (en) * | 2013-05-15 | 2013-07-24 | 浏阳市合力高科发展有限公司 | Sulfur-smoke-free powder composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 中国人民解放军总参谋部兵种部防化编研室: "《核化生防护大辞典》", 31 July 2000, 上海辞书出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114383066A (en) * | 2021-12-13 | 2022-04-22 | 北京动力机械研究所 | Torch combustion surface protection flame stabilizing device and underwater transmission torch |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ellern | Military and civilian pyrotechnics | |
| Davy | VIII. Some new experiments and observations on the combustion of gaseous mixtures, with an account of a method of preserving a continued light in mixtures of inflammable gases and air without flame | |
| Sabatini | A review of illuminating pyrotechnics | |
| CN108949169A (en) | A kind of illuminating agent for submerged combustion | |
| Howard | XI. On a new fulminating mercury | |
| Glück et al. | Flare or strobe: a tunable chlorine-free pyrotechnic system based on lithium nitrate | |
| US5049306A (en) | Oxygen generating candles | |
| US3788908A (en) | Tracer incendiary composition of alkylaluminum,inorganic oxidizer,and zirconium | |
| US4841865A (en) | Smoke composition and method of making same | |
| US2149694A (en) | Spontaneously inflammable flashlight composition and method of preparation | |
| CN102701893A (en) | Novel sulphur-free explosive for firecracker | |
| US4129465A (en) | Smoke-generating composition | |
| US1244940A (en) | Smoke-producing compound. | |
| CN1420109A (en) | Blue light agent | |
| Wisniak | Edmund Davy | |
| Eckley | Elementary riddles | |
| Miller | Elements of Chemistry: Theoretical and Practical: Inorganic chemistry | |
| Nuckolls | Chemistry of Combustion | |
| US3788907A (en) | Tracer incendiary materials including liquid alkylaluminum and compatible inorganic oxidizer | |
| FOWLER | CALCIUM CARBIDE AND ACETYLENE.(INCLUDING APPENDIX AND PLATE AT BACK OF VOLUME). | |
| GB2206343A (en) | Smoke producing composition for pyrotechnic markers | |
| Davis | The Early Use of Potassium Chlorate in Pyrotechny: Dr. Moritz Meyer's Colored Flame Compositions | |
| US3630939A (en) | Compositions and methods for the production of chemiluminescent cold light | |
| Davy | On the Safety Lamp for Preventing Explosions in Mines, Houses Lighted by Gas, Spirit Warehouses, Or Magazines in Ships, Etc.: With Some Researches on Flame | |
| KR890002832B1 (en) | A process for the producing of a briquet which have burning efficiency and gas safety |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181207 |
|
| WD01 | Invention patent application deemed withdrawn after publication |