CN108948931A - A kind of garden rattan chair durability environ mental protective paint - Google Patents
A kind of garden rattan chair durability environ mental protective paint Download PDFInfo
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- CN108948931A CN108948931A CN201810659072.5A CN201810659072A CN108948931A CN 108948931 A CN108948931 A CN 108948931A CN 201810659072 A CN201810659072 A CN 201810659072A CN 108948931 A CN108948931 A CN 108948931A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to chemical material technical fields, disclose a kind of garden rattan chair durability environ mental protective paint, acrylic resin polymerization process is modified using inorganic nano-particle, participate in it in high molecular weight reactive chain, the polyacrylate with good characteristic is formed in the specific period, it will not cause damages simultaneously to environment, paint film adhesion is good, weatherability is strong, with good storage stability, light resistance and resistance to outdoor aging are excellent, it is nontoxic, it does not cause damages to environment, convenient and quick construction, invention significantly improves the durabilities of wood paint, reduce the replacement speed of paint film, it is able to extend the service life of garden rattan chair, greatly meet the demand of people, it can be realized the realistic meaning for improving outdoor goods quality and performance, it is a kind of technical solution being extremely worth of widely use.
Description
Technical field
The invention belongs to chemical material technical fields, and in particular to a kind of garden rattan chair durability environ mental protective paint.
Background technique
Wood paint refers to a kind of lacquer type organic coating on woodwork, there is polyester, polyurethane paint etc., can be divided into aqueous and oily
Property.Bloom, semi-matte, dumb light can be divided by gloss.Furniture lacquer, floor paint etc. can be divided by purposes.It is high into eighties of last century
The significant achievement of molecular science theory and succeeding in developing for various high-molecular compounds are put into production, and are started for paint development
New era.The twenties in last century has succeeded in developing the alkyd resin for being dedicated as the film forming matter of coating, various newly developed from this
Synthetic resin be applied quickly in coating, enter coating to synthesize the epoch based on film forming matter.1980, entirely
World's coating annual output is more than 20,000,000 tons, and the coating year of developed country, consumption reached 10kg or more, modern coating per capita
Industry has become an important industry of modern chemical industry.
Garden rattan chair as leisure and ornamental woodwork articles, due in outdoor particular surroundings, need to its into
The protection of row japanning.And the requirement for paint film is higher, not only needs comprehensive protective, it is also necessary to cope with weather change
Change, colour-fast, performances, the existing reinforcing wood paint such as fall off cannot be considered in terms of environmental protection while pursuing being outstanding durability performance
The problem of property, great burden is caused to environment.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of garden rattan chair durability environ mental protective paint is provided, is had good
Good storage stability, light resistance and resistance to outdoor aging are excellent, nontoxic, do not cause damages to environment, convenient and quick construction.
The present invention is achieved by the following technical solutions:
A kind of garden rattan chair durability environ mental protective paint, is made of following component: methyl methacrylate 28-30 in parts by weight
Part, 12-16 parts of methacrylic acid, 10-12 parts of hydroxy-ethyl acrylate, 8-12 parts of acrylic acid, 0.3-0.4 parts of inorganic modifier, idol
1.0-1.3 parts of nitrogen bis-isobutyronitrile, 4-5 parts of isopropanol, 1.3-1.5 parts of calgon, 2.0-2.2 parts of diethanol amine, dibutyl naphthalene
1.0-1.5 parts of sodium sulfonate, 2.0-3.0 parts of ammonium hydroxide, water 160-180；The preparation method of the inorganic modifier the following steps are included:
(1) aluminium-hydroxide powder being dispersed in acetic acid aqueous solution, dispersion quality ratio is 1:7.0-8.0, it is heated to 40-50 DEG C,
It stirs 20-30 minutes, is set in a round bottom flask under 500-600 revs/min, stir lower persistently overheating to 120-130 DEG C, be added
Account for the ammonium persulfate of aluminium-hydroxide powder mass fraction 1.5-2.0%, insulation reaction 2-3 hours；
(2) reaction solution that step (1) obtains is placed in reaction kettle by high-speed stirred, adds and accounts for reaction solution quality 0.6-
0.8% butyl acetate is 120-140 DEG C in reaction kettle, starting blender, setting reaction temperature, and the reaction time is that 12-15 is small
When, preserving heat after reaction ends 2-3 hours, then Temperature fall, successively used deionized water and dehydrated alcohol for obtained reactant
Cleaning 3-4 times is subsequently placed in drying 10-12 hours in baking oven, and obtained dried object is the inorganic modifier.
It is further described as to above scheme, the inorganic modifier is warming up to 70- in the mixing of polymerization reaction material
It is added at 75 DEG C.
It is further described as to above scheme, the azodiisobutyronitrile is divided into 3 times and has added, every minor tick
1.0-1.5 hour.
It is further described as to above scheme, step (1) the acetic acid aqueous solution pH value is in 5.0-5.5 range.
It is further described as to above scheme, the inorganic modifier particle size that step (2) is prepared is in 10-50
Between nanometer.
It is further described as to above scheme, step (2) the high-speed stirred speed is 1500-1800 revs/min.
It is further described as to above scheme, step (2) oven temperature is 80-90 DEG C.
The present invention has the advantage that solve the existing garden rattan chair wood paint feature of environmental protection and durability compared with prior art
The problem of cannot taking into account, the present invention provides a kind of garden rattan chair durability environ mental protective paints, using inorganic nano-particle to propylene
Acid resin polymerization process is modified, and participates in it in high molecular weight reactive chain, and being formed in the specific period has excellent spy
Property polyacrylate, while will not cause damages to environment, paint film adhesion is good, and weatherability is strong, has good stable storage
Property, light resistance and resistance to outdoor aging are excellent, nontoxic, do not cause damages to environment, convenient and quick construction, and the present invention is significant
The durability for improving wood paint reduces the replacement speed of paint film, is able to extend the service life of garden rattan chair, greatly full
The foot demand of people, can be realized the realistic meaning for improving outdoor goods quality and performance, be that a kind of be extremely worthy to be popularized makes
Technical solution.
Specific embodiment
To make the purpose of the present invention, technical solution and effect clearer, clear and definite, combined with specific embodiments below to this hair
It is bright to be described further, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, is not used to limit
Technical solution provided by the present invention.
Embodiment 1
A kind of garden rattan chair durability environ mental protective paint, is made of following component in parts by weight: 28 parts of methyl methacrylate,
12 parts of methacrylic acid, 10 parts of hydroxy-ethyl acrylate, 8 parts of acrylic acid, 0.3 part of inorganic modifier, 1.0 parts of azodiisobutyronitrile,
4 parts of isopropanol, 1.3 parts of calgon, 2.0 parts of diethanol amine, 1.0 parts of sodium butylnaphthalenesulfonate, 2.0 parts of ammonium hydroxide, water 160；Institute
State the preparation method of inorganic modifier the following steps are included:
(1) aluminium-hydroxide powder is dispersed in acetic acid aqueous solution, dispersion quality ratio be 1:7.0, be heated to 40 DEG C, 500 turns/
Stirring 20 minutes under minute are set in a round bottom flask, are stirred lower persistently overheating to 120 DEG C, are added and account for aluminium-hydroxide powder quality
The ammonium persulfate of score 1.5%, insulation reaction 2 hours；
(2) reaction solution that step (1) obtains is placed in reaction kettle by high-speed stirred, adds and accounts for reaction solution quality 0.6%
Butyl acetate in reaction kettle, starting blender, setting reaction temperature is 120 DEG C, and the reaction time is 12 hours, and reaction terminates
2 hours are kept the temperature afterwards, then Temperature fall, successively uses deionized water and washes of absolute alcohol 3 times for obtained reactant, then set
10 hours dry in baking oven, obtained dried object is the inorganic modifier.
It is further described as to above scheme, the inorganic modifier is warming up to 70 DEG C in the mixing of polymerization reaction material
Shi Tianjia.
It is further described as to above scheme, the azodiisobutyronitrile is divided into 3 times and has added, every minor tick
1.0 hour.
It is further described as to above scheme, step (1) the acetic acid aqueous solution pH value is in 5.0-5.5 range.
It is further described as to above scheme, the inorganic modifier particle size that step (2) is prepared is in 10-50
Between nanometer.
It is further described as to above scheme, step (2) the high-speed stirred speed is 1500 revs/min.
It is further described as to above scheme, step (2) oven temperature is 80 DEG C.
Embodiment 2
A kind of garden rattan chair durability environ mental protective paint, is made of following component in parts by weight: 29 parts of methyl methacrylate,
14 parts of methacrylic acid, 11 parts of hydroxy-ethyl acrylate, 10 parts of acrylic acid, 0.35 part of inorganic modifier, azodiisobutyronitrile 1.1
Part, 4.5 parts of isopropanol, 1.4 parts of calgon, 2.1 parts of diethanol amine, 1.3 parts of sodium butylnaphthalenesulfonate, 2.5 parts of ammonium hydroxide, water
170；The preparation method of the inorganic modifier the following steps are included:
(1) aluminium-hydroxide powder is dispersed in acetic acid aqueous solution, dispersion quality ratio be 1:7.5, be heated to 45 DEG C, 550 turns/
Stirring 25 minutes under minute are set in a round bottom flask, are stirred lower persistently overheating to 125 DEG C, are added and account for aluminium-hydroxide powder quality
The ammonium persulfate of score 1.8%, insulation reaction 2.5 hours；
(2) reaction solution that step (1) obtains is placed in reaction kettle by high-speed stirred, adds and accounts for reaction solution quality 0.7%
Butyl acetate in reaction kettle, starting blender, setting reaction temperature is 130 DEG C, and the reaction time is 13 hours, and reaction terminates
2.5 hours are kept the temperature afterwards, then Temperature fall, successively uses deionized water and washes of absolute alcohol 3 times for obtained reactant, then
Drying 11 hours in baking oven are placed in, obtained dried object is the inorganic modifier.
It is further described as to above scheme, the inorganic modifier is warming up to 72 DEG C in the mixing of polymerization reaction material
Shi Tianjia.
It is further described as to above scheme, the azodiisobutyronitrile is divided into 3 times and has added, every minor tick
1.3 hour.
It is further described as to above scheme, step (1) the acetic acid aqueous solution pH value is in 5.0-5.5 range.
It is further described as to above scheme, the inorganic modifier particle size that step (2) is prepared is in 10-50
Between nanometer.
It is further described as to above scheme, step (2) the high-speed stirred speed is 1600 revs/min.
It is further described as to above scheme, step (2) oven temperature is 85 DEG C.
Embodiment 3
A kind of garden rattan chair durability environ mental protective paint, is made of following component in parts by weight: 30 parts of methyl methacrylate,
16 parts of methacrylic acid, 12 parts of hydroxy-ethyl acrylate, 12 parts of acrylic acid, 0.4 part of inorganic modifier, 1.3 parts of azodiisobutyronitrile,
5 parts of isopropanol, 1.5 parts of calgon, 2.2 parts of diethanol amine, 1.5 parts of sodium butylnaphthalenesulfonate, 3.0 parts of ammonium hydroxide, water 180；Institute
State the preparation method of inorganic modifier the following steps are included:
(1) aluminium-hydroxide powder is dispersed in acetic acid aqueous solution, dispersion quality ratio be 1:8.0, be heated to 50 DEG C, 600 turns/
Stirring 30 minutes under minute are set in a round bottom flask, are stirred lower persistently overheating to 130 DEG C, are added and account for aluminium-hydroxide powder quality
The ammonium persulfate of score 2.0%, insulation reaction 3 hours；
(2) reaction solution that step (1) obtains is placed in reaction kettle by high-speed stirred, adds and accounts for reaction solution quality 0.8%
Butyl acetate in reaction kettle, starting blender, setting reaction temperature is 140 DEG C, and the reaction time is 15 hours, and reaction terminates
3 hours are kept the temperature afterwards, then Temperature fall, successively uses deionized water and washes of absolute alcohol 4 times for obtained reactant, then set
12 hours dry in baking oven, obtained dried object is the inorganic modifier.
It is further described as to above scheme, the inorganic modifier is warming up to 75 DEG C in the mixing of polymerization reaction material
Shi Tianjia.
It is further described as to above scheme, the azodiisobutyronitrile is divided into 3 times and has added, every minor tick
1.5 hour.
It is further described as to above scheme, step (1) the acetic acid aqueous solution pH value is in 5.0-5.5 range.
It is further described as to above scheme, the inorganic modifier particle size that step (2) is prepared is in 10-50
Between nanometer.
It is further described as to above scheme, step (2) the high-speed stirred speed is 1800 revs/min.
It is further described as to above scheme, step (2) oven temperature is 90 DEG C.
Comparative example 1
Difference with embodiment 1 is only that, the preparation addition of inorganic modifier is omitted in environmental protection paint preparation, remaining is consistent.
Comparative example 2
Difference with embodiment 2 is only that the proportion of methyl methacrylate and methacrylic acid is 1:1 in environmental protection paint preparation,
Remaining is consistent.
Comparative example 3
Difference with embodiment 3 is only that, in the preparation of the inorganic modifier, the acetic acid aqueous solution in step (1) is replaced
For the deionized water of equivalent, remaining is consistent.
Comparative example 4
Difference with embodiment 3 is only that, in the preparation of the inorganic modifier, omits the addition of butyl acetate in step (2),
Reaction temperature is set as 180 DEG C, remaining is consistent.
Comparative experiments
Garden rattan chair durability environ mental protective paint is prepared using the method for embodiment 1-3 and comparative example 1-4 respectively, to use conventional evidence
Acrylic resin paint as a control group, uses poplar rattan chair material as subjects, after surface preparation, by each group system
Standby paint vehicle is sprayed at test panels surface, and coating layer thickness is 0.1 millimeter, tests in whole process and keeps irrelevant variable consistent,
Coating paint film after solidification is tested for the property, as a result as shown in the table:
Invention significantly improves the durabilities of wood paint, reduce the replacement speed of paint film, are able to extend making for garden rattan chair
With the service life, the demand of people is greatly met, can be realized the realistic meaning for improving outdoor goods quality and performance, is a kind of
The technical solution being extremely worth of widely use.
Claims (7)
1. a kind of garden rattan chair durability environ mental protective paint, which is characterized in that be made in parts by weight of following component: methyl-prop
28-30 parts of e pioic acid methyl ester, 12-16 parts of methacrylic acid, 10-12 parts of hydroxy-ethyl acrylate, 8-12 parts of acrylic acid, inorganic modifier
0.3-0.4 parts, 1.0-1.3 parts of azodiisobutyronitrile, 4-5 parts of isopropanol, 1.3-1.5 parts of calgon, diethanol amine 2.0-
2.2 parts, 1.0-1.5 parts of sodium butylnaphthalenesulfonate, 2.0-3.0 parts of ammonium hydroxide, water 160-180；The preparation method of the inorganic modifier
The following steps are included:
(1) aluminium-hydroxide powder being dispersed in acetic acid aqueous solution, dispersion quality ratio is 1:7.0-8.0, it is heated to 40-50 DEG C,
It stirs 20-30 minutes, is set in a round bottom flask under 500-600 revs/min, stir lower persistently overheating to 120-130 DEG C, be added
Account for the ammonium persulfate of aluminium-hydroxide powder mass fraction 1.5-2.0%, insulation reaction 2-3 hours；
(2) reaction solution that step (1) obtains is placed in reaction kettle by high-speed stirred, adds and accounts for reaction solution quality 0.6-
0.8% butyl acetate is 120-140 DEG C in reaction kettle, starting blender, setting reaction temperature, and the reaction time is that 12-15 is small
When, preserving heat after reaction ends 2-3 hours, then Temperature fall, successively used deionized water and dehydrated alcohol for obtained reactant
Cleaning 3-4 times is subsequently placed in drying 10-12 hours in baking oven, and obtained dried object is the inorganic modifier.
2. a kind of garden rattan chair durability environ mental protective paint as described in claim 1, which is characterized in that the inorganic modifier is poly-
Close addition when reaction mass mixing is warming up to 70-75 DEG C.
3. a kind of garden rattan chair durability environ mental protective paint as described in claim 1, which is characterized in that the azodiisobutyronitrile is equal
It is divided into 3 times to have added, every minor tick 1.0-1.5 hours.
4. a kind of garden rattan chair durability environ mental protective paint as described in claim 1, which is characterized in that step (1) the acetic acid water
Solution ph is in 5.0-5.5 range.
5. a kind of garden rattan chair durability environ mental protective paint as described in claim 1, which is characterized in that step (2) is prepared
Inorganic modifier particle size is between 10-50 nanometers.
6. a kind of garden rattan chair durability environ mental protective paint as described in claim 1, which is characterized in that step (2) described high-speed stirring
Mixing speed is 1500-1800 revs/min.
7. a kind of garden rattan chair durability environ mental protective paint as described in claim 1, which is characterized in that step (2) the baking oven temperature
Degree is 80-90 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810659072.5A CN108948931A (en) | 2018-06-25 | 2018-06-25 | A kind of garden rattan chair durability environ mental protective paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810659072.5A CN108948931A (en) | 2018-06-25 | 2018-06-25 | A kind of garden rattan chair durability environ mental protective paint |
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| CN108948931A true CN108948931A (en) | 2018-12-07 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103242732A (en) * | 2013-05-11 | 2013-08-14 | 山西华豹涂料有限公司 | Aqueous blackboard paint |
| CN105713132A (en) * | 2016-02-29 | 2016-06-29 | 苏州凯康化工科技有限公司 | High-hardness water-borne wood paint and preparation method thereof |
| CN106497292A (en) * | 2016-11-02 | 2017-03-15 | 常州创索新材料科技有限公司 | A kind of preparation method of environmental protection high adhesion force aqueous woodware paint |
| CN107337978A (en) * | 2016-12-15 | 2017-11-10 | 广东海特高新材料有限公司 | A kind of water-borne wood coating |
| CN107805437A (en) * | 2017-11-16 | 2018-03-16 | 万华化学集团股份有限公司 | It is a kind of to be used to repair aqueous woodware paint of color and preparation method thereof |
-
2018
- 2018-06-25 CN CN201810659072.5A patent/CN108948931A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103242732A (en) * | 2013-05-11 | 2013-08-14 | 山西华豹涂料有限公司 | Aqueous blackboard paint |
| CN105713132A (en) * | 2016-02-29 | 2016-06-29 | 苏州凯康化工科技有限公司 | High-hardness water-borne wood paint and preparation method thereof |
| CN106497292A (en) * | 2016-11-02 | 2017-03-15 | 常州创索新材料科技有限公司 | A kind of preparation method of environmental protection high adhesion force aqueous woodware paint |
| CN107337978A (en) * | 2016-12-15 | 2017-11-10 | 广东海特高新材料有限公司 | A kind of water-borne wood coating |
| CN107805437A (en) * | 2017-11-16 | 2018-03-16 | 万华化学集团股份有限公司 | It is a kind of to be used to repair aqueous woodware paint of color and preparation method thereof |
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Application publication date: 20181207 |
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| RJ01 | Rejection of invention patent application after publication |