CN108948916A - Conducting paint composite - Google Patents
Conducting paint composite Download PDFInfo
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- CN108948916A CN108948916A CN201810658345.4A CN201810658345A CN108948916A CN 108948916 A CN108948916 A CN 108948916A CN 201810658345 A CN201810658345 A CN 201810658345A CN 108948916 A CN108948916 A CN 108948916A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of conducting paint composites, it is related to conductive coating technical field, including following raw material: acrylic resin, gum dammar, GaAs, Dead Sea mud, perovskite powder, acetylbutyrylcellulose, shepardite chopped strand, diethylene glycol dibenzoate, dimethyl sulfoxide, snail mucus, promotor, crosslinking agent, coupling agent.Prepared by conductive coating of the invention convenient, and workability is excellent, conducts electricity very well, environmental and durable, has excellent electromagnetic shielding performance, application field is extensive.
Description
Technical field
The present invention relates to conductive coating technical fields, and in particular to a kind of conducting paint composite.
Background technique
Conductive coating is that one kind is coated on the grounds such as non-conductive polymer material, and has conduction electric current and exclusion accumulation
The new special functional coating of electrostatic charge ability.In the world conductive coating earliest be silver and epoxy resin made of,
China also gradually begins one's study conductive coating in the fifties in last century, at present conductive coating have been widely used electronics industry,
The various aspects technical field such as building industry and aeronautical technology, conductive connection, the connection such as integrated circuit component are nonweldable
Place, plastic stent, airplane hidden material, the conductive film of shielding high frequency magnetic field etc., practical value is high.
Domestic conductive coating existing currently on the market mostly using epoxy resin as carrier, incorporation nickel powder, copper powder, silver powder and
The packing materials such as carbon black, due to starting evening, technology is not mature enough, and the conductive coating conductance and comprehensive performance being prepared are not
Very well, the high price conductive coating for much depending on the developed countries such as Japan, the U.S. greatly reduces domestic market competitiveness, resistance
The growth momentum of conductive coating or even electronic industry at home is hindered.Therefore, a kind of high-performance, low cost, green ring are developed
The conductive coating of guarantor be quite it is necessary to.
The patent application of Publication No. CN106366880A discloses a kind of denatured conductive coating, by it is following by weight
The raw material of meter forms: 50-60 parts of fluorographites, 10-12 parts of silicon nitrides, 7-8 parts of silicon carbide whiskers, 5-8 parts of zirconium dioxides, 8-9
Part silica, 20-22 parts of graphite fibres, 5-8 parts of polyvinyl alcohol, 2-5 parts of triethylsilanes, 3-5 parts of triethyl borates, 4-6
Part gold sodium sulfide, 6-8 parts of cetyl trimethylammonium bromides, 5-6 parts of lauryl sodium sulfate, 40-45 parts of ethyl vinyl acetate second
Alkene copolymer, 40-50 part terpene resin, 60-80 parts of alkyd resins, 50-60 parts of furane resins, 50-60 parts of polyester resin, 35-
38 parts of Petropols, 6-8 parts of ethyl acetate, 3-5 parts of potassium chloride, 4-8 parts of dimethyl silicone polymers, 5-8 parts of polystyrene, 16-
18 parts of silicone oil, 5-8 parts of sodium alkyl benzene sulfonates, 6-8 parts of 1,2- propylene glycol, 8-10 parts of powdered whitings, 80-100 parts of deionized waters.
Electron-transport efficiency and coating mechanical strength can be improved in this kind of denatured conductive coating, but its impact resistance and bendability are poor.
The patent application for authorizing Publication No. CN103333574B, discloses a kind of anti-shielding conductive coating, including following
Component: the acrylic resin of 20-25wt%, the conducting powder of 15-20wt%, the auxiliary agent of 1.5-3.5wt%, 57-63wt% it is molten
Agent.This kind of conductive coating adhesion is good, and wide adaptability, shielding properties is excellent, but its resistance to hydrochlorate corrosivity is poor.
Summary of the invention
The purpose of the present invention is to provide a kind of conducting paint composite, this kind of conductive coating high comprehensive performances.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of conducting paint composite, including following raw material by weight:
46-52 parts of acrylic resin；
20-24 parts of gum dammar；
2-3.5 parts of GaAs；
Mud 6.5-8.5 parts of the Dead Sea；
4-6 parts of perovskite powder；
1-2 parts of acetylbutyrylcellulose；
1.5-2.5 parts of shepardite chopped strand；
0.3-0.5 parts of diethylene glycol dibenzoate；
9-13 parts of dimethyl sulfoxide；
3-5 parts of snail mucus；
0.65-0.85 parts of promotor；
0.95-1.35 parts of crosslinking agent；
0.5-0.7 parts of coupling agent.
Further, aforementioned coating composition is made of following raw material by weight:
46 parts of acrylic resin；
20 parts of gum dammar；
2 parts of GaAs；
6.5 parts of Dead Sea mud；
4 parts of perovskite powder；
1 part of acetylbutyrylcellulose；
1.5 parts of shepardite chopped strand；
0.3 part of diethylene glycol dibenzoate；
9 parts of dimethyl sulfoxide；
3 parts of snail mucus；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.5 part of coupling agent.
Further, aforementioned coating composition is made of following raw material by weight:
52 parts of acrylic resin；
24 parts of gum dammar；
3.5 parts of GaAs；
8.5 parts of Dead Sea mud；
6 parts of perovskite powder；
2 parts of acetylbutyrylcellulose；
2.5 parts of shepardite chopped strand；
0.5 part of diethylene glycol dibenzoate；
13 parts of dimethyl sulfoxide；
5 parts of snail mucus；
0.85 part of promotor；
1.35 parts of crosslinking agent；
0.7 part of coupling agent.
Preferably, above-mentioned promotor is filled using tetramethyl thiourea, promotor 962, promotor LTH according to weight ratio 3:5:2
It point is blended.
Preferably, above-mentioned promotor is filled using tetramethyl thiourea, promotor 962, promotor LTH according to weight ratio 5:7:4
It point is blended.
Preferably, above-mentioned crosslinking agent is sufficiently blended to obtain using Diacetone Acrylamide, amino resins according to weight ratio 1:2
's.
Preferably, above-mentioned crosslinking agent is sufficiently blended to obtain using Diacetone Acrylamide, amino resins according to weight ratio 3:4
's.
Preferably, above-mentioned coupling agent is even using anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare earth
Connection agent is sufficiently blended according to weight ratio 1:3:1.
Preferably, above-mentioned coupling agent is even using anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare earth
Connection agent is sufficiently blended according to weight ratio 3:5:2.
Further, above-mentioned coating the preparation method is as follows:
I: Dead Sea mud and perovskite powder are taken, the RO water of weight percent 121% is added, grinding stirring makes it completely dissolved,
83 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 11min at a temperature of 83 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 70% that parts by weight 60% are added is sufficiently mixed
It closes, adds gum dammar mixing, and be heated to 85 DEG C, snail is added after it is cooled to 50 DEG C in insulated and stirred 10min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added
The promotor and coupling agent of remaining weight number are sufficiently mixed, and are heated to 82 DEG C, and GaAs is added and acetate butyrate is fine
Dimension element is sufficiently mixed, and insulated and stirred 9min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.095MPa, temperature is 72 DEG C
Under the conditions of be mixed 180min, crosslinking agent is added when 42s before stirring terminates, during which agitator tank speed of agitator is set as 500r/
min。
The present invention is with following the utility model has the advantages that conductive coating of the invention prepares simple and convenient, phase between each material component
Capacitive can be good, and properties of product are stablized, and easily stores；Changed by the creativeness of ingenious selection and its preparation process to raw materials for production
Into the cooperative interaction of the compositions such as acrylic resin, gum dammar, GaAs, Dead Sea mud, perovskite powder, reaches in raw material
Following effect:
(1) electromagnetic wave shielding: electromagnetic shielding performance is good, and shield effectiveness is high, reduces electromagnetic radiation transmitting to brushing material
Interference damage；
(2) feature of environmental protection: the pernicious gases such as no radon, formaldehyde, benzene and irritation peculiar smell generate, and contamination hazard is small, environmentally protective,
It is healthy and safe；
(3) coating: curing and drying speed is fast, is adaptable to shape in any shape complicated interface with object, after brushing not
The problems such as will appear sagging, out-of-flatness, Wu Erdao is accessible, easy for construction；
(4) durability: the crosslinking of paint film structure sheaf is firm, and long service life, wear-resisting scratch-resistant, stain resistant is strong, and has
Excellent weatherability and resistance to hydrochlorate corrosivity, adhesive force is strong, water proof fire retardant, and flexibility is good, and resist bending will not after impact extruded
There is surface layer to fall off, crack and other issues, paint film complete and smooth, without bulge loosening；
(5) electric conductivity: resistivity is low, and electric conductivity is stablized, and surface layer has good antistatic property, reliable and secure, application
Occasion field is extensive.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
It all raw materials in embodiment and its produces composition and can be obtained by disclosed commercially available channel；
Embodiment 1
The present embodiment is related to a kind of conducting paint composite and preparation method thereof, and the coating is by following original by weight
Material composition:
46 parts of acrylic resin；
20 parts of gum dammar；
2 parts of GaAs；
6.5 parts of Dead Sea mud；
4 parts of perovskite powder；
1 part of acetylbutyrylcellulose；
1.5 parts of shepardite chopped strand；
0.3 part of diethylene glycol dibenzoate；
9 parts of dimethyl sulfoxide；
3 parts of snail mucus；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.5 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 1 below:
Table 1
The preparation method of the present embodiment coating follows the steps below:
I: Dead Sea mud and perovskite powder are taken, the RO water of weight percent 121% is added, grinding stirring makes it completely dissolved,
83 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 11min at a temperature of 83 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 70% that parts by weight 60% are added is sufficiently mixed
It closes, adds gum dammar mixing, and be heated to 85 DEG C, snail is added after it is cooled to 50 DEG C in insulated and stirred 10min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added
The promotor and coupling agent of remaining weight number are sufficiently mixed, and are heated to 82 DEG C, and GaAs is added and acetate butyrate is fine
Dimension element is sufficiently mixed, and insulated and stirred 9min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.095MPa, temperature is 72 DEG C
Under the conditions of be mixed 180min, crosslinking agent is added when 42s before stirring terminates, during which agitator tank speed of agitator is set as 500r/
min。
Embodiment 2
The present embodiment is related to a kind of conducting paint composite and preparation method thereof, and the coating is by following original by weight
Material composition:
48 parts of acrylic resin；
21 parts of gum dammar；
2.4 parts of GaAs；
7 parts of Dead Sea mud；
4.5 parts of perovskite powder；
1.2 parts of acetylbutyrylcellulose；
1.8 parts of shepardite chopped strand；
0.35 part of diethylene glycol dibenzoate；
10 parts of dimethyl sulfoxide；
3.5 parts of snail mucus；
0.7 part of promotor；
1.05 parts of crosslinking agent；
0.55 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 2 below:
Table 2
The preparation method of the present embodiment coating follows the steps below:
I: Dead Sea mud and perovskite powder are taken, the RO water of weight percent 122% is added, grinding stirring makes it completely dissolved,
84 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 10.5min at a temperature of 84 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 72% that parts by weight 62% are added is sufficiently mixed
It closes, adds gum dammar mixing, and be heated to 86 DEG C, snail is added after it is cooled to 52 DEG C in insulated and stirred 9.5min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added
The promotor and coupling agent of remaining weight number are sufficiently mixed, and are heated to 83 DEG C, and GaAs is added and acetate butyrate is fine
Dimension element is sufficiently mixed, and insulated and stirred 8.5min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.1MPa, temperature is 74 DEG C of items
175min is mixed under part, crosslinking agent is added when 44s before stirring terminates, during which agitator tank speed of agitator is set as 550r/
min。
Embodiment 3
The present embodiment is related to a kind of conducting paint composite and preparation method thereof, and the coating is by following original by weight
Material composition:
49 parts of acrylic resin；
22 parts of gum dammar；
2.7 parts of GaAs；
7.5 parts of Dead Sea mud；
5 parts of perovskite powder；
1.5 parts of acetylbutyrylcellulose；
2 parts of shepardite chopped strand；
0.4 part of diethylene glycol dibenzoate；
11 parts of dimethyl sulfoxide；
4 parts of snail mucus；
0.75 part of promotor；
0.15 part of crosslinking agent；
0.6 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 3 below:
Table 3
The preparation method of the present embodiment coating follows the steps below:
I: Dead Sea mud and perovskite powder are taken, the RO water of weight percent 123% is added, grinding stirring makes it completely dissolved,
85 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 10min at a temperature of 85 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 73% that parts by weight 63% are added is sufficiently mixed
It closes, adds gum dammar mixing, and be heated to 87 DEG C, snail is added after it is cooled to 53 DEG C in insulated and stirred 9min
Mucus is sufficiently mixed, and obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added
The promotor and coupling agent of remaining weight number are sufficiently mixed, and are heated to 84 DEG C, and GaAs is added and acetate butyrate is fine
Dimension element is sufficiently mixed, and insulated and stirred 8min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.105MPa, temperature is 75 DEG C
Under the conditions of be mixed 170min, crosslinking agent is added when 45s before stirring terminates, during which agitator tank speed of agitator is set as 600r/
min。
Embodiment 4
The present embodiment is related to a kind of conducting paint composite and preparation method thereof, and the coating is by following original by weight
Material composition:
50 parts of acrylic resin；
23 parts of gum dammar；
3.0 parts of GaAs；
8 parts of Dead Sea mud；
5.5 parts of perovskite powder；
1.6 parts of acetylbutyrylcellulose；
2.2 parts of shepardite chopped strand；
0.45 part of diethylene glycol dibenzoate；
12 parts of dimethyl sulfoxide；
4.5 parts of snail mucus；
0.8 part of promotor；
1.25 parts of crosslinking agent；
0.65 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 4 below:
Table 4
The preparation method of the present embodiment coating follows the steps below:
I: Dead Sea mud and perovskite powder are taken, the RO water of weight percent 124% is added, grinding stirring makes it completely dissolved,
86 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 9.5min at a temperature of 86 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 74% that parts by weight 64% are added is sufficiently mixed
It closes, adds gum dammar mixing, and be heated to 88 DEG C, snail is added after it is cooled to 54 DEG C in insulated and stirred 8.5min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added
The promotor and coupling agent of remaining weight number are sufficiently mixed, and are heated to 85 DEG C, and GaAs is added and acetate butyrate is fine
Dimension element is sufficiently mixed, and insulated and stirred 7.5min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.11MPa, temperature is 76 DEG C of items
165min is mixed under part, crosslinking agent is added when 46s before stirring terminates, during which agitator tank speed of agitator is set as 650r/
min。
Embodiment 5
The present embodiment is related to a kind of conducting paint composite and preparation method thereof, and the coating is by following original by weight
Material composition:
52 parts of acrylic resin；
24 parts of gum dammar；
3.5 parts of GaAs；
8.5 parts of Dead Sea mud；
6 parts of perovskite powder；
2 parts of acetylbutyrylcellulose；
2.5 parts of shepardite chopped strand；
0.5 part of diethylene glycol dibenzoate；
13 parts of dimethyl sulfoxide；
5 parts of snail mucus；
0.85 part of promotor；
1.35 parts of crosslinking agent；
0.7 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 5 below:
Table 5
The preparation method of the present embodiment coating follows the steps below:
I: Dead Sea mud and perovskite powder are taken, the RO water of weight percent 125% is added, grinding stirring makes it completely dissolved,
87 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 9min at a temperature of 87 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 75% that parts by weight 65% are added is sufficiently mixed
It closes, adds gum dammar mixing, and be heated to 89 DEG C, snail is added after it is cooled to 55 DEG C in insulated and stirred 8min
Mucus is sufficiently mixed, and obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added
The promotor and coupling agent of remaining weight number are sufficiently mixed, and are heated to 86 DEG C, and GaAs is added and acetate butyrate is fine
Dimension element is sufficiently mixed, and insulated and stirred 7min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.115MPa, temperature is 78 DEG C
Under the conditions of be mixed 160min, crosslinking agent is added when 48s before stirring terminates, during which agitator tank speed of agitator is set as 700r/
min。
Comparative example 1
This comparative example is related to a kind of conductive coating, and compared to embodiment 1, promotor is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 1.
Comparative example 2
This comparative example is related to a kind of conductive coating, and compared to embodiment 2, crosslinking agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 2.
Comparative example 3
This comparative example is related to a kind of conductive coating, and compared to embodiment 3, coupling agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 3.
Comparative example 4
This comparative example is related to a kind of conductive coating, and compared to embodiment 4, which removes promotor in composition, crosslinking
Agent, the application of coupling agent, anti-cracking agent, other compositions, content and preparation method thereof are same as Example 5.
Comparative example 5
This comparative example is related to a kind of preparation method of conductive coating, and compared to embodiment 5, there is only preparation methods not
Together, other compositions and its content are same as Example 5 in coating, the conductive coating of this comparative example the preparation method is as follows: will
Other all raw materials of the raw material in addition to crosslinking agent are delivered in agitator tank jointly, vacuum degree be 0.115MPa, temperature 78
160min is mixed under the conditions of DEG C, crosslinking agent is added when 48s before stirring terminates, during which agitator tank speed of agitator is set as
700r/min。
Comparative example 6
This comparative example is related to a kind of denatured conductive coating, is made of following raw material by weight: 50 parts of fluorination stones
Ink, 10 parts of silicon nitrides, 7 parts of silicon carbide whiskers, 5 parts of zirconium dioxides, 8 parts of silica, 20 parts of graphite fibres, 5 parts of polyvinyl alcohol,
2 parts of triethylsilanes, 3 parts of triethyl borates, 4 parts of gold sodium sulfides, 6 parts of cetyl trimethylammonium bromides, 5 parts of dodecyls
Sodium sulphate, 40 parts of ethylene-vinyl acetate copolymers, 40 parts of terpene resins, 60 parts of alkyd resins, 50 parts of furane resins, 50 parts it is poly-
Ester resin, 35 parts of Petropols, 6 parts of ethyl acetate, 3 parts of potassium chloride, 4 parts of dimethyl silicone polymers, 5 parts of polystyrene, 16 parts
Silicone oil, 5 parts of sodium alkyl benzene sulfonates, 6 parts of 1,2- propylene glycol, 8 parts of powdered whitings, 80 parts of deionized waters.
Implementation result
For the beneficial effect for verifying the present invention, following property is carried out to coating made from above-described embodiment 1-5 and comparative example 1-6
The detection of energy index, particular content see the table below shown in 6；
It wherein, is the performance for preferably embodying coating in the present embodiment and comparative example, project 1-8 uses for reference JG-T224- in table
The examination criteria and method of anticorrosive paint in 2007；
Project 9 is detected using period soaking corrosion test box；
Project 10 is detected using volume resistivity analyzer；
Project 11 uses for reference GB/T 30142-2013 plane electromagnetic shielding material shield effectiveness measurement method；
Table 6: embodiment
Table 7: comparative example (comparative example 1-6 respectively corresponds 1#-6#)
As shown in upper table 6 and table 7, conductive coating of the invention is significantly better than that comparative example in performance in all respects, has
Progress and promotion significantly, application performance is more preferable, and functional stronger, application field is wider, and the service life is longer.
In conjunction with the excellent effect of the present invention, applicant is illustrated constituent part and preparation method of the invention:
(1) it shepardite chopped strand: firstly, shepardite chopped strand is particularly suitable for conductive coating system of the invention, adopts
Traditional polymer composite fiber is replaced with it, such as: polypropylene anti-crack fiber, there are two aspects to consider: one is reduction of
Raw material, composite fibre price are expensive compared to brucite fiber；Second is that the resistance to bend(ing) and anti-impact of coating can be further improved
Hitting property, strength character are more excellent；
(2) snail mucus: the mucus that snail mucus is secreted out of as animal body, application field is relatively narrow at present, mostly makes up
Product field, still, applicant has been surprisingly found that in development process, cooperates with interaction with base-materials, fillers such as acrylic resins,
The adhesive force and film forming of finished product coating can be significantly improved, while also improving the corrosion-resistant equal physics and chemistry of film surface
Energy；
(3) promotor: tetramethyl thiourea, promotor 962, promotor LTH are provided with certain reaction promotion functions, but
In order to adapt to the formation of coating system of the invention, found through many experiments, using above-mentioned composition according to weight ratio (3-5): (5-
7): the compound accelerant that (2-4) is blended, the quick and stable of reaction system when can not only realize coating preparation, moreover it is possible to have
Effect promotes the adhesive force and physicochemical property of finished product coating system；
(4) crosslinking agent: Diacetone Acrylamide, amino resins are common crosslinking agent, and applicant is in development process
It was found that the addition of Diacetone Acrylamide or amino resins list composition is difficult to reach the beneficial effect of this coating system, by skilful
Wonderfully by above two composition according to weight ratio (1-3): the product that (2-4) is sufficiently blended can admirably achieve this hair
Bright technical effect and purpose obtains the more excellent performances such as water-fast, corrosion-resistant.
(5) coupling agent: epoxy silane coupling KH-560 is most common coupling agent in coating system, is most being started
Test in, the compatibility and interface characteristics, the finished product prepared that are difficult to improve separately as coupling agent of the invention between raw material
Coating property is bad, and then, application people have been surprisingly found that is contained in anti-settling Aluminate ASA can be with active hydrogen reaction
Group can occur bonding action with the inorganic filler in this coating system, can substantially improve red halloysite, periclase powder, ultra-fine six
The compatibility and binding force of square boron nitride nanometer granular filler and acrylic resin and furane resins, coordinated rare-earth coupling agent
According to weight ratio (1-3): (3-5): (1-2) is blended, and is not only stablized coating system of the invention, is reached result of prevention, may be used also
Improve the adhesive strength of coating system.
(6) agitator tank revolving speed: the final speed of agitator of coating system of the present invention is worthy of careful study, optimum interval 500-
700r/min is lower than the revolving speed section, reacts insufficient, it is difficult to embody the beneficial effect of finished product coating；Higher than the revolving speed section,
Production cost will be will increase, or even cause the reduction or missing of comprehensive performance.
Certainly, because of the requirement of the mentality of designing and goal of the invention of coating of the present invention, remaining of the invention component selection and contain
Amount selection is obviously also non-obvious, and those skilled in the art combine the prior art that can readily occur in absolutely not.This is at this
Have further embodiment in terms of the preparation method of invention coating, in conjunction with the embodiment of the present invention it can be seen that, preparation of the invention
Method uses four steps designs, and raw material is added by several times in batches, and step is simple and orderly, rather than uses the one of prior art routine
(such as comparative example 5) is added in secondary property, and this preparation process is adapted with the special proportion of coating components of the present invention, only with adopting
With this technique, it just can guarantee that the smooth sequential of reaction system carries out, ensure the superiority for the coating property finally prepared.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of conducting paint composite, which is characterized in that including following raw material by weight:
46-52 parts of acrylic resin；
20-24 parts of gum dammar；
2-3.5 parts of GaAs；
Mud 6.5-8.5 parts of the Dead Sea；
4-6 parts of perovskite powder；
1-2 parts of acetylbutyrylcellulose；
1.5-2.5 parts of shepardite chopped strand；
0.3-0.5 parts of diethylene glycol dibenzoate；
9-13 parts of dimethyl sulfoxide；
3-5 parts of snail mucus；
0.65-0.85 parts of promotor；
0.95-1.35 parts of crosslinking agent；
0.5-0.7 parts of coupling agent.
2. a kind of conducting paint composite according to claim 1, which is characterized in that by following raw material by weight
Composition:
46 parts of acrylic resin；
20 parts of gum dammar；
2 parts of GaAs；
6.5 parts of Dead Sea mud；
4 parts of perovskite powder；
1 part of acetylbutyrylcellulose；
1.5 parts of shepardite chopped strand；
0.3 part of diethylene glycol dibenzoate；
9 parts of dimethyl sulfoxide；
3 parts of snail mucus；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.5 part of coupling agent.
3. a kind of conducting paint composite according to claim 1, which is characterized in that by following raw material by weight
Composition:
52 parts of acrylic resin；
24 parts of gum dammar；
3.5 parts of GaAs；
8.5 parts of Dead Sea mud；
6 parts of perovskite powder；
2 parts of acetylbutyrylcellulose；
2.5 parts of shepardite chopped strand；
0.5 part of diethylene glycol dibenzoate；
13 parts of dimethyl sulfoxide；
5 parts of snail mucus；
0.85 part of promotor；
1.35 parts of crosslinking agent；
0.7 part of coupling agent.
4. a kind of conducting paint composite according to claim 1, which is characterized in that the promotor is tetramethyl sulphur
Urea, promotor 962, promotor LTH are sufficiently blended according to weight ratio 3:5:2.
5. a kind of conducting paint composite according to claim 1, which is characterized in that it is characterized in that, the promotor
It is sufficiently blended for tetramethyl thiourea, promotor 962, promotor LTH according to weight ratio 5:7:4.
6. a kind of conducting paint composite according to claim 1, which is characterized in that the crosslinking agent is diacetone acrylamide
Amide, amino resins are sufficiently blended according to weight ratio 1:2.
7. a kind of conducting paint composite according to claim 1, which is characterized in that the crosslinking agent is diacetone acrylamide
Amide, amino resins are sufficiently blended according to weight ratio 3:4.
8. a kind of conducting paint composite according to claim 1, which is characterized in that the coupling agent is anti-settling aluminium
Acid esters ASA, epoxy silane coupling KH-560, rare-earth coupling agent are sufficiently blended according to weight ratio 1:3:1.
9. a kind of conducting paint composite according to claim 1, which is characterized in that the coupling agent is anti-settling aluminium
Acid esters ASA, epoxy silane coupling KH-560, rare-earth coupling agent are sufficiently blended according to weight ratio 3:5:2.
10. a kind of conducting paint composite according to claim 1, which is characterized in that the preparation method of the coating is such as
Under:
I: taking Dead Sea mud and perovskite powder, the RO water of weight percent 121% is added, grinding stirring makes it completely dissolved, heats
83 DEG C are warming up to, acrylic resin is added and mixes, and insulated and stirred 11min at a temperature of 83 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 70% that parts by weight 60% are added is sufficiently mixed, then
Gum dammar is added to mix, and is heated to 85 DEG C, snail mucus is added after it is cooled to 50 DEG C in insulated and stirred 10min
It is sufficiently mixed, obtains mixed material B；
III: dimethyl sulfoxide being added into mixed material B and diethylene glycol dibenzoate mixes, then under agitation, is added remaining
The promotor and coupling agent of parts by weight are sufficiently mixed, and are heated to 82 DEG C, and GaAs and acetylbutyrylcellulose is added
It is sufficiently mixed, and insulated and stirred 9min, obtains mixing C；
IV: mixing C and shepardite chopped strand being poured into agitator tank, vacuum degree is 0.095MPa, temperature is 72 DEG C of conditions
Crosslinking agent is added when 42s before stirring terminates in lower mixing 180min, and during which agitator tank speed of agitator is set as 500r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810658345.4A CN108948916A (en) | 2018-06-25 | 2018-06-25 | Conducting paint composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810658345.4A CN108948916A (en) | 2018-06-25 | 2018-06-25 | Conducting paint composite |
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| CN108948916A true CN108948916A (en) | 2018-12-07 |
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| CN201810658345.4A Withdrawn CN108948916A (en) | 2018-06-25 | 2018-06-25 | Conducting paint composite |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116855162A (en) * | 2023-07-11 | 2023-10-10 | 江苏天时新材料科技有限公司 | Scratch-resistant automobile paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101351112A (en) * | 2007-07-18 | 2009-01-21 | 太阳油墨制造株式会社 | Light-permeable conductive film |
| CN104263159A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly water-based coating for preparing glitter powder, and preparation method thereof |
-
2018
- 2018-06-25 CN CN201810658345.4A patent/CN108948916A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101351112A (en) * | 2007-07-18 | 2009-01-21 | 太阳油墨制造株式会社 | Light-permeable conductive film |
| CN104263159A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly water-based coating for preparing glitter powder, and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116855162A (en) * | 2023-07-11 | 2023-10-10 | 江苏天时新材料科技有限公司 | Scratch-resistant automobile paint and preparation method thereof |
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Application publication date: 20181207 |