CN108948767A - A kind of preparation process of expansion type flame-retarding particieboard - Google Patents

A kind of preparation process of expansion type flame-retarding particieboard Download PDF

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Publication number
CN108948767A
CN108948767A CN201810793749.4A CN201810793749A CN108948767A CN 108948767 A CN108948767 A CN 108948767A CN 201810793749 A CN201810793749 A CN 201810793749A CN 108948767 A CN108948767 A CN 108948767A
Authority
CN
China
Prior art keywords
retarding
expansion type
particieboard
type flame
wood shavings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810793749.4A
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Chinese (zh)
Inventor
李洪飞
王迪
王利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing University of Chemical Technology
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Beijing University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing University of Chemical Technology filed Critical Beijing University of Chemical Technology
Priority to CN201810793749.4A priority Critical patent/CN108948767A/en
Publication of CN108948767A publication Critical patent/CN108948767A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/02Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/10Moulding of mats
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Forests & Forestry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The present invention relates to a kind of novel fire-resistant-chipboard production technologies, belong to functional wood material scope.It is characterized in that first by adhesive (6%-15%) and polyphosphoric acid amine (5-10%), pentaerythrite (2-5%), melamine (2-5%), auxiliary agent (1-3.5%), smoke suppressant (2-5%), curing agent (1%), which is put into stir at low speed in instrument, uniformly to be mixed, it then again will be in mixture and wood shavings (60%) blender, so that mixture is uniformly mixed in wood shavings, then assembly is put into hot press and is hot pressed into plate.The invention, so that particieboard has the effect of fire-retardant, there is biggish meaning under the premise of guaranteeing particieboard mechanical property in practical applications.

Description

A kind of preparation process of expansion type flame-retarding particieboard
Technical field
The present invention relates to a kind of preparation of fire-resistant-chipboard, especially a kind of preparation of expansion type flame-retarding particieboard.
Background technique
Due to the shortage of timber resources, demand of the people to timber increasingly increases, so particieboard development is very rapid. Particieboard has excellent performance: firstly, particieboard structure is uniform, and having good processing performance;Secondly, particieboard source Extensively;Finally, particieboard production cost is low.But timber itself belongs to combustibles, the application of the particieboard of this problem limitation, So studying fire-retardant shaving board becomes key especially.
Expansion shaving board is made of wood shavings, expansion type flame retardant, filler and various auxiliary agents.In combustion, Carbon source in expansion type flame retardant mainly generates layer of charcoal, and dehydration occurs for acid source, promotes into charcoal, gas source generates non-ignitable or difficult Combustion gas body, waters down oxygen concentration, to play the heat-insulated effect of fire insulation.Expansion shaving board not only has good fire-retardant effect Fruit, and halogens is not contained, meet environmental requirement;Expansion shaving board is at low cost, and performance is good, increasingly by researcher With the attention of enterprise, it is widely used at present.
The present invention is using wood shavings as matrix, and smoke suppressant is as a kind of filler, in the process of burning, reduces smoke Amount escapes from the fire scene for people in fire and provides advantage, and smoke suppressant makes the flame-retardant smoke inhibition of expansion type flame-retarding particieboard Effect is largely improved;Also has the effect of catalysis carbon-forming simultaneously.
It is an object of the invention to improve the flame retarding and smoke suppressing properties of existing fire-resistant-chipboard, provide a kind of fire-retardant better than tradition The expansion type flame-retarding particieboard of the suppression cigarette of particieboard.
The purpose of the present invention can be achieved through the following technical solutions:
The component and content of the fireproof coating:
Wood shavings (60%), adhesive (6%-15%) polyphosphoric acid amine (5-10%), pentaerythrite (2-5%), melamine (2-5%), auxiliary agent (1-3.5%), smoke suppressant (2-5%), curing agent (1%).
Wood shavings of the present invention are bamboo and woods fiber wood shavings, one of wooden shavings such as Aspen wood shavings or several mixtures.
Smoke suppressant of the present invention is that manganese chloride, copper chloride, iron chloride is one such or several mixtures.
Auxiliary agent of the present invention includes into dispersing agent, diluent, defoaming agent.
Adhesive of the present invention is Lauxite of the solid content in 50%-60%.The invention the following steps are included:
(1) it matches and stocks up according to following components: wood shavings (60%), adhesive (6%-15%) polyphosphoric acid amine (5-10%), Pentaerythrite (2-5%), melamine (2-5%), auxiliary agent (1-3.5%), smoke suppressant (2-5%), curing agent (1%).
(2) by adhesive, fire proofing additive, the mixing such as curing agent is put into stirring instrument and stirs at low speed, is uniformly mixed it, Then mixture and wood shavings are mixed and are put into that stirrer for mixing is uniform, next puts it into assembly in mold, finally by base and Finger gauge is put into hot press, 150 DEG C -180 DEG C at a temperature of hot pressing 6-10 minutes, just prepared a kind of expansion type flame-retarding plane Card.
Advantages of the present invention:
Wood shavings used in the present invention derive from residue, from a wealth of sources and protection forest resourceies.
Smoke suppressant used in the present invention can effectively reduce smoke amount, while being produced by thermal decomposition in combustion process Raw hydrogen chloride, catalysis carbon-forming improve charring layer intensity, have completely cut off the conduction of heat, extended the resistance to combustion time.
Specific embodiment
Example one:
Each component content:
Wood shavings (60%), polyphosphoric acid amine (10%), pentaerythrite (5%), melamine (5%), smoke suppressant (3%), glue Glutinous agent (12%), auxiliary agent (4%), curing agent (1%).
Preparation method:
By adhesive, fire proofing additive, the mixing such as curing agent is put into stirring instrument and stirs at low speed, is uniformly mixed it, then Mixture and wood shavings are mixed and are put into that stirrer for mixing is uniform, next puts it into assembly in mold, finally by base and thickness Rule be put into hot press, 170 DEG C at a temperature of hot pressing 8 minutes, just prepared a kind of expansion type flame-retarding particieboard.
Example two:
Wood shavings (60%), polyphosphoric acid amine (8%), pentaerythrite (4%), melamine (4%), smoke suppressant (5%), gluing Agent (14%), auxiliary agent (4%), curing agent (1%).
Preparation method:
By adhesive, fire proofing additive, the mixing such as curing agent is put into stirring instrument and stirs at low speed, is uniformly mixed it, then Mixture and wood shavings are mixed and are put into that stirrer for mixing is uniform, next puts it into assembly in mold, finally by base and thickness Rule be put into hot press, 175 DEG C at a temperature of hot pressing 8 minutes, just prepared a kind of expansion type flame-retarding particieboard.
Example three:
Wood shavings (60%), polyphosphoric acid amine (10%), pentaerythrite (5%), melamine (5%), smoke suppressant (5%), glue Glutinous agent (10%), auxiliary agent (4%), curing agent (1%).
Preparation method:
By adhesive, fire proofing additive, the mixing such as curing agent is put into stirring instrument and stirs at low speed, is uniformly mixed it, then Mixture and wood shavings are mixed and are put into that stirrer for mixing is uniform, next puts it into assembly in mold, finally by base and thickness Rule be put into hot press, 180 DEG C at a temperature of hot pressing 8 minutes, just prepared a kind of expansion type flame-retarding particieboard.

Claims (7)

1. a kind of expansion type flame-retarding particieboard preparation method, it is characterised in that: the component and content of the fire-resistant-chipboard: wood shavings (60%), adhesive (6%-15%) polyphosphoric acid amine (5-10%), pentaerythrite (2-5%), melamine (2-5%), auxiliary agent (1-3.5%), smoke suppressant (2-5%), curing agent (1%).
2. a kind of expansion type flame-retarding particieboard according to claim 1, which is characterized in that the wood shavings are that bamboo and wood is fine Tie up wood shavings, one of wooden shavings such as Aspen wood shavings or several mixtures.
3. a kind of expansion type flame-retarding particieboard according to claim 1, which is characterized in that the adhesive is to contain admittedly Measure the Lauxite in 50%-60%.
4. a kind of expansion type flame-retarding particieboard according to claim 1, which is characterized in that the auxiliary agent includes dispersion Agent, diluent, defoaming agent.
5. a kind of expansion type flame-retarding particieboard according to claim 1, which is characterized in that the smoke suppressant is chlorination Manganese, copper chloride, iron chloride is one such or several mixtures.
6. a kind of expansion type flame-retarding particieboard according to claim 1, which is characterized in that the curing agent is chlorination One of ammonium salts such as ammonium, ammonium sulfate or several mixtures.
7. a kind of expansion type flame-retarding particieboard according to claim 1, which is characterized in that this method includes following step It is rapid:
(1) it matches and stocks up according to following components: wood shavings (60%), adhesive (6%-15%) polyphosphoric acid amine (5-10%), season penta Tetrol (2-5%), melamine (2-5%), auxiliary agent (1-3.5%), smoke suppressant (2-5%), curing agent (1%).
(2) by adhesive, fire proofing additive, the mixing such as curing agent is put into stirring instrument and stirs at low speed, is uniformly mixed it, then Mixture and wood shavings are mixed and are put into that stirrer for mixing is uniform, next puts it into assembly in mold, finally by base and thickness Rule be put into hot press, 150 DEG C -180 DEG C at a temperature of hot pressing 6-10 minutes, just prepared a kind of expansion type flame-retarding wood shavings Plate.
CN201810793749.4A 2018-07-19 2018-07-19 A kind of preparation process of expansion type flame-retarding particieboard Pending CN108948767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810793749.4A CN108948767A (en) 2018-07-19 2018-07-19 A kind of preparation process of expansion type flame-retarding particieboard

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810793749.4A CN108948767A (en) 2018-07-19 2018-07-19 A kind of preparation process of expansion type flame-retarding particieboard

Publications (1)

Publication Number Publication Date
CN108948767A true CN108948767A (en) 2018-12-07

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ID=64481936

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810793749.4A Pending CN108948767A (en) 2018-07-19 2018-07-19 A kind of preparation process of expansion type flame-retarding particieboard

Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110253811A (en) * 2019-05-25 2019-09-20 北京化工大学 A kind of preparation process of lightweight formaldehyde-free wood-plastic flame-proof sheet material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110253811A (en) * 2019-05-25 2019-09-20 北京化工大学 A kind of preparation process of lightweight formaldehyde-free wood-plastic flame-proof sheet material

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Application publication date: 20181207