CN108948531A - A kind of polyolefin VOC absorption master batch and preparation method thereof - Google Patents
A kind of polyolefin VOC absorption master batch and preparation method thereof Download PDFInfo
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- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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Abstract
The present invention relates to a kind of polyolefin VOC absorption master batches and preparation method thereof, by weight by 40 parts -60 parts of polyolefin, 30 parts -50 parts of natural clay, 10 parts -16 parts of sodium metasilicate, 0.1 part -0.5 part of coupling agent, 0.1 part -0.3 part of erucyl amide, 0.1 part -0.5 part of antioxidant composition.This technology has synthesized a kind of VOC absorption master batch, it can improve the VOC performance of composite polyolefine material well, this tool has very important significance；And polyolefin VOC obtained adsorbs master batch simple process, cheap, has good promotional value.
Description
Technical field
The invention belongs to technical field of polymer materials, a kind of polyolefin VOC absorption master batch and its preparation side are particularly related to
Method.
Background technique
With the improvement of living standards, requirement of the people to material environmental protection is higher and higher, VOC performance is the one of automotive material
Item important indicator.A kind of polyolefin VOC absorption master batch and preparation method thereof is made in inventor's innovation, improves present polyolefin
VOC performance, this polyolefin VOC absorption master batch not yet see report so far, have very important realistic meaning.
Summary of the invention
The object of the present invention is to provide a kind of polyolefin VOC absorption master batches and preparation method thereof, to improve the VOC of polyolefin
Performance.
The present invention is achieved by the following technical solutions:
A kind of polyolefin VOC absorption master batch, is made of the component of following parts by weight:
The polyolefin is in polypropylene, polyethylene, polybutylene terephthalate (PBT), polystyrene or polyamide 6
It is a kind of.
The coupling agent is carbonic ester coupling agent AC-201.
The antioxidant is three (2,4- di-t-butyl) phenyl-phosphites, four [β-(3,5- di-tert-butyl-hydroxy phenyl)
Propionic acid] pentaerythritol ester or 1,3,5- trimethyls -2,4, one of 6- (3,5- di-t-butyl -4- hydroxyphenylmethyl) benzene or several
The mixing of kind.
The preparation method of any of the above-described polyolefin VOC absorption master batch, comprising the following steps:
(1) 40 parts -60 parts of polyolefin, 30 parts of -50 parts of natural clays, 10 parts of -16 parts of sodium metasilicate, 0.1 part -0.5 are weighed
Part coupling agent, 0.1 part of -0.3 part of erucyl amide, 0.1 part of -0.5 part of antioxidant are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch.
The beneficial effects of the present invention are:
1, this technology has synthesized a kind of VOC absorption master batch, it can improve the VOC of composite polyolefine material well
Can, this tool has very important significance.
2. polyolefin VOC made from this technology adsorbs master batch simple process, cheap, there is good promotional value.
Specific embodiment
Carry out the technical solution that the present invention will be described in detail by the following examples, embodiment below is merely exemplary, only
It can be used to explanation and illustration technical solution of the present invention, and be not to be construed as the limitation to technical solution of the present invention.
Raw material used in present embodiments is as follows:
PBT (model 2002U), Polyplastics；PP (model T30S), Daqing petrochemical；PE (model 5070), Panjin ethylene；
PA6 (model C M1017), toray；PS (model 350), state of Taiwan Province are tall；The large limited public affairs of science and technology are won in natural clay, Anhui
Department；Sodium metasilicate, Xingtai Rui Xin silicon salt Manufacturing Co., Ltd；Coupling agent (model AC-201), the sincere Chemical Co., Ltd. of Nanjing Olympic；Mustard
Sour amide, promote chemical products Co., Ltd in Nantong；Antioxidant (model Irganox168, Irganox1010,
Irganox1330), Switzerland's Ciba.
Test equipment used in each embodiment of the application is as follows:
ZSK30 type double screw extruder, German W&P company；JL-1000 type tensile testing machine, the wide just experiment instrument in Guangzhou
The production of device company；HTL900-T-5B type injection (mo(u)lding) machine, the production of Hai Tai plastics machinery Co., Ltd；XCJ-500 type shock-testing
Machine, the production of Chengde testing machine factory；QT-1196 type tester for elongation, Dongguan City Gao Tai detecting instrument Co., Ltd；QD-GJS-
B12K type high-speed mixer, Beijing perseverance Order instrument and meter Co., Ltd.
In the application, composite polyolefine material is polypropylene (PP), polyethylene (PE), polybutylene terephthalate (PBT)
(PBT), one of polystyrene (PS), polyamide 6 (PA6).
The application provides a kind of polyolefin VOC absorption master batch, is made of the component of following parts by weight:
The coupling agent is carbonic ester coupling agent AC-201.
The antioxidant is three (2,4- di-t-butyl) phenyl-phosphites (abbreviation Irganox168), four of BASF AG
[β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester (abbreviation Irganox1010) or 1,3,5- trimethyl -2,
The mixing of one or more of 4,6- (3,5- di-t-butyl -4- hydroxyphenylmethyl) benzene (abbreviation Irganox1330).
The preparation method of any of the above-described polyolefin VOC absorption master batch, comprising the following steps:
(1) 40 parts -60 parts of polyolefin, 30 parts of -50 parts of natural clays, 10 parts of -16 parts of sodium metasilicate, 0.1 part -0.5 are weighed
Part coupling agent, 0.1 part of -0.3 part of erucyl amide, 0.1 part of -0.5 part of antioxidant are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch.
Embodiment 1
(1) 40 parts of PP, 30 parts of natural clays, 10 parts of sodium metasilicate, 0.1 part of coupling agent AC-201,0.1 part of erucic acid acyl are weighed
Amine, 0.1 part of Irganox168 are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch P1.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 170 DEG C, and two area's temperature are
230 DEG C, three area's temperature are 230 DEG C, and four area's temperature are 230 DEG C, and five area's temperature are 230 DEG C, and six area's temperature are 230 DEG C, head temperature
Degree is 230 DEG C, screw speed 220r/min.
Application examples 1
It takes 10 parts of P1 to be added in 90 parts of polypropylene (PP), stirs 10min through high mixer, be subsequently added into double screw extruder
Middle carry out blending extrusion, obtains PP composite material X1.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 170 DEG C, and two area's temperature are
230 DEG C, three area's temperature are 230 DEG C, and four area's temperature are 230 DEG C, and five area's temperature are 230 DEG C, and six area's temperature are 230 DEG C, head temperature
Degree is 230 DEG C, screw speed 220r/min.
Comparative example 1
It takes in 90 parts of polypropylene (PP), stirs 10min through high mixer, be subsequently added into double screw extruder be blended and squeeze
Out, PP composite material D1 is obtained.
Batten, properties of product data are made with injection molding machine in PP composite material prepared by above application examples 1 and comparative example 1
It is as shown in the table:
As can be seen from the above table: it is more preferable than the VOC performance of unmodified preceding PP that VOC absorption master batch MODIFIED PP is added.
Embodiment 2
(1) 60 parts of PBT, 50 parts of natural clays, 16 parts of sodium metasilicate, 0.5 part of coupling agent AC-201,0.3 part of erucic acid acyl are weighed
Amine, 0.1 part of Irganox168,0.2 part of Irganox1010,0.2 part of Irganox1330 are mixed and stirred for uniformly, being mixed
Material；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch P2.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 200 DEG C, and two area's temperature are
260 DEG C, three area's temperature are 260 DEG C, and four area's temperature are 260 DEG C, and five area's temperature are 260 DEG C, and six area's temperature are 260 DEG C, head temperature
Degree is 260 DEG C, screw speed 300r/min.
Application examples 2
It takes 20 parts of P2 to be added in 80 parts of polybutylene terephthalate (PBT)s (PBT), stirs 10min through high mixer, then
Carry out blending extrusion is added twin-screw extrude, PBT composite X2 is obtained.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 200 DEG C, and two area's temperature are
260 DEG C, three area's temperature are 260 DEG C, and four area's temperature are 260 DEG C, and five area's temperature are 260 DEG C, and six area's temperature are 260 DEG C, head temperature
Degree is 260 DEG C, screw speed 300r/min.
Comparative example 2
It takes in 80 parts of polybutylene terephthalate (PBT)s (PBT), stirs 10min through high mixer, be subsequently added into twin-screw and squeeze
Blending extrusion is carried out in machine out, obtains PBT composite D2.
Batten, properties of product number is made with injection molding machine in PBT composite prepared by above application examples 2 and comparative example 2
According to as shown in the table:
As can be seen from the above table: it is more preferable than the VOC performance of unmodified preceding PBT that VOC absorption master batch modified PBT is added.
Embodiment 3
(1) 50 parts of PE, 40 parts of natural clays, 13 parts of sodium metasilicate, 0.3 part of coupling agent AC-201,0.2 part of erucic acid acyl are weighed
Amine, 0.1 part of Irganox168,0.2 part of Irganox1010 are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch P3.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 120 DEG C, and two area's temperature are
180 DEG C, three area's temperature are 180 DEG C, and four area's temperature are 180 DEG C, and five area's temperature are 180 DEG C, and six area's temperature are 180 DEG C, head temperature
Degree is 180 DEG C, screw speed 300r/min.
Application examples 3
It takes 20 parts of P3 to be added in 80 parts of polyethylene (PE), stirs 10min through high mixer, be subsequently added into double screw extruder
Middle carry out blending extrusion, obtains PE composite material X3.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 120 DEG C, and two area's temperature are
180 DEG C, three area's temperature are 180 DEG C, and four area's temperature are 180 DEG C, and five area's temperature are 180 DEG C, and six area's temperature are 180 DEG C, head temperature
Degree is 180 DEG C, screw speed 300r/min.
Comparative example 3
It takes in 80 parts of polyethylene (PE), stirs 10min through high mixer, be subsequently added into double screw extruder be blended and squeeze
Out, PE composite material D3 is obtained.
Batten, properties of product data are made with injection molding machine in PE composite material prepared by above application examples 3 and comparative example 3
It is as shown in the table:
As can be seen from the above table: it is more preferable than the VOC performance of unmodified preceding PE that VOC absorption master batch modified PE is added.
Embodiment 4
(1) 45 parts of PA6,36 parts of natural clays, 14 parts of sodium metasilicate, 0.2 part of coupling agent AC-201,0.1 part of erucic acid acyl are weighed
Amine, 0.1 part of Irganox1010,0.2 part of Irganox1330 are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch P4.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 230 DEG C, and two area's temperature are
260 DEG C, three area's temperature are 260 DEG C, and four area's temperature are 260 DEG C, and five area's temperature are 260 DEG C, and six area's temperature are 260 DEG C, head temperature
Degree is 250 DEG C, screw speed 320r/min.
Application examples 4
It takes 20 parts of P4 to be added in 80 parts of polyamide 6s (PA6), stirs 10min through high mixer, be subsequently added into twin-screw extrusion
Blending extrusion is carried out in machine, obtains PA6 composite material X4.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 230 DEG C, and two area's temperature are
260 DEG C, three area's temperature are 260 DEG C, and four area's temperature are 260 DEG C, and five area's temperature are 260 DEG C, and six area's temperature are 260 DEG C, head temperature
Degree is 250 DEG C, screw speed 320r/min.
Comparative example 4
It takes in 80 parts of polyamide 6s (PA6), stirs 10min through high mixer, be subsequently added into double screw extruder and be blended
It squeezes out, obtains PA6 composite material D4.
Batten, properties of product number is made with injection molding machine in PA6 composite material prepared by above application examples 4 and comparative example 4
According to as shown in the table:
As can be seen from the above table: it is more preferable than the VOC performance of unmodified preceding PA6 that VOC absorption master batch modified Pa 6 is added.
Embodiment 5
(1) 44 parts of PS, 35 parts of natural clays, 11 parts of sodium metasilicate, 0.1 part of coupling agent AC-201,0.1 part of erucic acid acyl are weighed
Amine, 0.1 part of Irganox1010,0.1 part of Irganox168 are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch P5.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 160 DEG C, and two area's temperature are
200 DEG C, three area's temperature are 200 DEG C, and four area's temperature are 200 DEG C, and five area's temperature are 200 DEG C, and six area's temperature are 200 DEG C, head temperature
Degree is 200 DEG C, screw speed 280r/min.
Application examples 5
It takes 20 parts of P5 to be added in 80 parts of styrene (PS), stirs 10min through high mixer, be subsequently added into double screw extruder
Middle carry out blending extrusion, obtains PS composite material X5.
Wherein, double screw extruder includes six humidity provinces sequentially arranged, and area's temperature is 160 DEG C, and two area's temperature are
200 DEG C, three area's temperature are 200 DEG C, and four area's temperature are 200 DEG C, and five area's temperature are 200 DEG C, and six area's temperature are 200 DEG C, head temperature
Degree is 200 DEG C, screw speed 280r/min.
Comparative example 5
It takes in 80 parts of styrene (PS), stirs 10min through high mixer, be subsequently added into double screw extruder be blended and squeeze
Out, PS composite material D5 is obtained.
Batten, properties of product data are made with injection molding machine in PS composite material prepared by above application examples 5 and comparative example 5
It is as shown in the table:
As can be seen from the above table: it is more preferable than the VOC performance of unmodified preceding PS that the modified PS of VOC absorption master batch is added.
The technical program describes a kind of polyolefin VOC absorption master batch and preparation method thereof, and polyolefine material obtained
There is a degree of improvement in VOC aspect of performance, this has very heavy the application field of extension composite polyolefine material
The meaning wanted.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And deformation, the scope of the present invention are extremely equally limited by appended claims.
Claims (5)
1. a kind of polyolefin VOC adsorbs master batch, which is characterized in that be made of the component of following parts by weight:
2. polyolefin VOC according to claim 1 adsorbs master batch, which is characterized in that the polyolefin is polypropylene, poly- second
One of alkene, polybutylene terephthalate (PBT), polystyrene or polyamide 6.
3. polyolefin VOC according to claim 1 adsorbs master batch, which is characterized in that the coupling agent is carbonic ester coupling
Agent AC-201.
4. polyolefin VOC according to claim 1 adsorbs master batch, which is characterized in that the antioxidant is three (2,4- bis- uncles
Butyl) phenyl-phosphite, four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters or 1,3,5- trimethyls-
The mixing of one or more of 2,4,6- (3,5- di-t-butyl -4- hydroxyphenylmethyl) benzene.
5. the preparation method of any one of the claims 1 to 4 polyolefin VOC absorption master batch, which is characterized in that including following
Step:
(1) 40 parts -60 parts of polyolefin, 30 parts of -50 parts of natural clays, 10 parts of -16 parts of sodium metasilicate, 0.1 part of -0.5 part of idol are weighed
Connection agent, 0.1 part of -0.3 part of erucyl amide, 0.1 part of -0.5 part of antioxidant are mixed and stirred for uniformly, obtaining mixture；
(2) by mixture obtained in step (1) from extruder extruding pelletization to get to VOC adsorb master batch.
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| CN107936604A (en) * | 2017-12-04 | 2018-04-20 | 王文广 | One kind removes VOC masterbatch |
| CN108047546A (en) * | 2017-10-30 | 2018-05-18 | 江苏冠恒新材料科技有限公司 | A kind of smell processing master batch and preparation method thereof |
-
2018
- 2018-07-18 CN CN201810791474.0A patent/CN108948531A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709495A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | High-performance filling master batch used for plastics, and preparation method thereof |
| CN104277278A (en) * | 2013-07-03 | 2015-01-14 | 合肥杰事杰新材料股份有限公司 | Efficient and lasting smell removal agent master batch, and preparation method and application thereof |
| CN108047546A (en) * | 2017-10-30 | 2018-05-18 | 江苏冠恒新材料科技有限公司 | A kind of smell processing master batch and preparation method thereof |
| CN107936604A (en) * | 2017-12-04 | 2018-04-20 | 王文广 | One kind removes VOC masterbatch |
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Address after: 230601 No. 99 Ziyun Road, Hefei Economic and Technological Development Zone, Anhui Province Applicant after: Anhui Jianghuai Automobile Group Limited by Share Ltd Address before: 230601 No. 669 Shixin Road, Taohua Industrial Park, Hefei City, Anhui Province Applicant before: Anhui Jianghuai Automobile Group Limited by Share Ltd |
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Application publication date: 20181207 |
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