CN108947316A - A kind of mortar plasticising water-retaining agent and its production technology - Google Patents

A kind of mortar plasticising water-retaining agent and its production technology Download PDF

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Publication number
CN108947316A
CN108947316A CN201810993024.XA CN201810993024A CN108947316A CN 108947316 A CN108947316 A CN 108947316A CN 201810993024 A CN201810993024 A CN 201810993024A CN 108947316 A CN108947316 A CN 108947316A
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CN
China
Prior art keywords
mortar
diatomite
retaining agent
bentonite
metakaolin
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201810993024.XA
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Chinese (zh)
Inventor
沈池清
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TONGXIANG ZHENGCHANG NEW MATERIAL CO Ltd
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TONGXIANG ZHENGCHANG NEW MATERIAL CO Ltd
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Priority to CN201810993024.XA priority Critical patent/CN108947316A/en
Publication of CN108947316A publication Critical patent/CN108947316A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/46Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
    • C04B2103/465Water-sorbing agents, hygroscopic or hydrophilic agents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of mortar plasticising water-retaining agent and its production technologies, by mass percentage, including following components, bentonite: 25-35%, metakaolin: 25-35%, cellulose ether: 1-3%, diatomite: 25-40%.Mortar plasticising water-retaining agent and its production technology improve water retentivity of mortar, lubricity, the workability of component improved stability mortar and the requirement for meeting mechanical execution, impervious, the anti-accumulation of salt in the surface soil, the anti-freezing property of mortar are improved simultaneously, and improves the compression strength of mortar.

Description

A kind of mortar plasticising water-retaining agent and its production technology
Technical field:
It is especially a kind of mortar plasticising water-retaining agent and its production technology the present invention relates to the field of building materials.
Background technique:
As national urbanization constantly promotes, annual construction material dosage is extremely huge, and mortar is (sand in construction material One of slurry, concrete, materials for wall) three big main materials, energy-saving development premixing mortar is very urgent, and it is sustainable to meet country Development tactics is classified as one of the project of focus development by country, forbids as quotient sends [2007] No. 205 elsewhere about in urban The appearance of Site mortar notice, China has 1000 Duo Jia premixing mortar manufacturing enterprises and is constructed and put into operation at present, mortar addition Agent is to influence one of the principal element of mortar quality, and the superiority and inferiority of grout additive can seriously affect the development of this industry.
Summary of the invention:
The technical problem to be solved by the invention is to provide one kind to improve water retentivity of mortar, lubricity, component stability Improve the workability of mortar and meet the requirement of mechanical execution, while improving impervious, the anti-accumulation of salt in the surface soil, the anti-freezing property of mortar, and The mortar for improving the compression strength of mortar is plasticized water-retaining agent.
The technical solution of the invention is as follows, provides a kind of mortar plasticising water-retaining agent, by mass percentage, including it is following Component, bentonite: 25-35%, metakaolin: 25-35%, cellulose ether: 1-3%, diatomite: 25-40%.
Preferably, by mass percentage, including following components, bentonite: 30%, metakaolin: 31.5%, fiber Plain ether: 1.5%, diatomite: 37%.
Preferably, bentonite is sodium bentonite made of being modified, kaolin is metakaolin, and diatomite is in acidleach With the diatomite of processing, cellulose ether is hydroxyethylmethylcellulose.
The present invention also provides a kind of production technologies of mortar plasticising water-retaining agent, include the following steps:
The first step, raw material preparation mix inorganic salts in bentonite, are expressed in dry kiln through double helix mixing, Roasted in 550-650 DEG C of kiln body in mixing, be fired mixing bentonite it is cool postpone it is levigate to more than 500 mesh by ball mill It is spare;Acidleach processing is carried out to diatomite with dilute sulphuric acid, separates iron aluminium impurity in diatomite, while decomposing in diatomite inner hole Organic matter, increase internal surface area, improve the attraction performance of diatomite, in lime and extra acid, neutralize to obtain through lime Drying is levigate spare to more than 500 mesh storing again for calcium sulfate;
Modified alta-mud, metakaolin, the acid diatomite neutralized, hydroxyethylmethylcellulose are distinguished spiral shell by second step Rotation is transported on electrical metering device and weighs in proportion, then with plough coulter type mixing machine mechanical stirring it is uniform after packed or dissipated It is packed into library, mixing time is no less than 2min, wherein modified alta-mud weight percent is 30%, metakaolin weight percent For 31.5%, cellulose ether weight percent be 1.5%, diatomite weight percent is 37%.
The beneficial effects of the present invention are: have good anti-sag, water conservation and it is easy, subtract modeling barrier performance.Therefore the present invention It has the advantage that 1 present invention meets JG/T164-2004 " masonry mortar plasticizer " standard requirements, meets newest " pre- sand cutting Slurry " GB/T25181-2010 standard premixing build, plastering, ground mortar performance indexes.The present invention and traditional lime Class, bleed class additive is compared that there is adhesion strength to improve, water-fast, freezing and thawing performance is good;Subtract modeling, cracking resistance, anti-with good The accumulation of salt in the surface soil, antiseepage, endurance quality;With sag resistance, pumping, implementable automatic arc spraying;For sea sand, Machine-made Sand, natural Well adapting to property of sand;Mortar of the invention is plasticized water-retaining agent, is a kind of additive for premixing dry-mixed mortar, makes mortar With it is good and easy, subtract modeling, antiseepage, the anti-accumulation of salt in the surface soil, anti-freezing property, improve the durability of building;Good sag resistance, pump The property sent mitigates construction worker's labor intensity, improving makes work efficiency rate in the implementable automatic arc spraying in construction site.
Specific embodiment:
The invention will be further described With reference to embodiment:
A kind of mortar plasticising water-retaining agent, by mass percentage, including following components, bentonite: 30%, metakaolin: 31.5%, cellulose ether: 1.5%, diatomite: 37%.Wherein, bentonite is sodium bentonite made of being modified, and kaolin is Metakaolin, diatomite are the diatomite of acidleach neutralisation treatment, and cellulose ether is hydroxyethylmethylcellulose.
Preparation method is as follows, and a kind of production technology of mortar plasticising water-retaining agent includes the following steps:
Inorganic salts are uniformly mixed in bentonite and are modified processing by the first step, raw material preparation, and are deposited with plastic foil covering 7 days or more (so that the sodium ion in inorganic salts enters in the layer structure of montmorillonite) is put, is expressed to through double helix mixing dry In dry kiln, in 550-650 DEG C of kiln body while mixing while roast, be fired mixing bentonite it is cool postpone it is levigate extremely by ball mill It is more than 500 mesh spare;Acidleach processing is carried out to diatomite with dilute sulphuric acid, separates iron aluminium impurity in diatomite, while decomposing silicon Organic matter in diatomaceous earth inner hole increases internal surface area, improves the attraction performance of diatomite, in lime and extra acid, through stone Ash neutralize obtain calcium sulfate again drying it is levigate to the calcium sulfate more than 500 mesh, neutralized through lime can in metakaolin Active silica, aluminum oxide form new silicate mineral;
Modified alta-mud, metakaolin, the acid diatomite neutralized, hydroxyethylmethylcellulose are distinguished spiral shell by second step Rotation is transported on electrical metering device and weighs in proportion, then with plough coulter type mixing machine mechanical stirring it is uniform after packed or dissipated It is packed into library, mixing time is no less than 2min.
The effect of each material in the present invention
Bentonite has hygroscopicity and thickening effect;The water of adsorbable 8~15 times of own vols of dilatancy, bentonite, Volume expansion is up to several times to 40 times;It can be dispersed into as a form of gel and suspension in an aqueous medium, there is suspension;This medium is molten Liquid has certain viscosity, plasticity;There is stronger cation exchange capacity (CEC) and there is the repellency to acid ion.
Metakaolin is a kind of artificial pozzolanic material of high activity, can be with Ca (OH)2(CH) and water generation volcanic ash is anti- It answers, generates the hydrated product similar with cement.Using this feature, when being used as grout additive, in cement hydration process The CH of generation reacts, and can improve certain performances of mortar.Mainly AS2, CH reacted with water, with AS2The ratio and reaction of/CH The difference of temperature can generate different hydrated products, active silica and active aluminum oxide and mortar in metakaolin The calcium oxide being precipitated when middle hydrated cementitious generates new silicate mineral, improves compression strength, effectively inhibits the accumulation of salt in the surface soil, improves simultaneously Impermeability.
Ethoxyl methyl cellulose ether: the effects of increasing water conservation, suspending, thicken, stablizing is affected by temperature small.
Diatomite: having the characteristics such as superfluorescent fiber, Porous, and ultra tiny boring ratio charcoal is 5000 to 6000 times out more. When humidity rises, ultra micro pore can moisture content in automatic absorption mortar, stored.If the moisture content in mortar It reduces, humidity decline, diatomite can release the moisture content being stored in ultra micro pore, play water retention.
Present invention volume 0.5~1.0% in premixing mortar, up to 92% or more, remaining indices reaches water retention National standard meets the performance requirement manually or mechanically constructed, solves the problems, such as premixing mortar use, construction efficiency 3~5 times are improved, the development for pushing the sector is conducive to.
Specifically used method of the invention is as follows: the building mortar of Site, mortar of the invention can be retained thick dose It is added before adding water and stirring, is added water and stirred 3~5 minutes together with the materials such as cement bonded sand.Mortar plasticising water-retaining agent is being built Dosage in mortar is 0.5~1.0%.When the common dry-mixed mortar of premixing dry-mixed mortar plant produced, the present invention is transported to pre- It mixes in dry-mixed mortar factories library, by different mortar kind mortar mix ratio setting ratios, enters mixing through electronic measurement and set Standby to be stirred, mixing time was at 2 minutes or more, to guarantee product quality.Mortar modifier mixing in common dry-mixed mortar Amount is 0.5~1.0%.
For proof reliability of the invention, performance indexes of the invention is detected, detection method and foundation: " building mortar basic performance tests method " JGJ/70-2009, JG/T164-2004 " masonry mortar plasticizer ", JC/T2389- 2017 " premixing mortar water-retaining agent ", " premixing mortar " GB/T25181-2010 standard.As a result as follows:
Mortar plasticising water-retaining agent of the invention have good anti-sag, water conservation and it is easy, subtract modeling barrier performance.Therefore originally Invention has the advantage that 1 present invention meets JG/T164-2004 " masonry mortar plasticizer " standard requirements, meets newest " pre- Sand cutting slurry " GB/T25181-2010 standard premixing build, plastering, ground mortar performance indexes.With traditional lime, Bleed class additive is compared, and there is adhesion strength to improve, water-fast, freezing and thawing performance is good;With it is good subtract modeling, cracking resistance, resist it is general Alkali, antiseepage, endurance quality;With sag resistance, pumping, implementable automatic arc spraying;For sea sand, Machine-made Sand, natural sand Well adapting to property.
In conclusion mortar of the invention is plasticized water-retaining agent, it is a kind of additive for premixing dry-mixed mortar, makes mortar With it is good and easy, subtract modeling, antiseepage, the anti-accumulation of salt in the surface soil, anti-freezing property, improve the durability of building;Good sag resistance, pump The property sent mitigates construction worker's labor intensity, improving makes work efficiency rate in the implementable automatic arc spraying in construction site.

Claims (4)

1. a kind of mortar is plasticized water-retaining agent, it is characterised in that: by mass percentage, including following components, bentonite: 25- 35%, metakaolin: 25-35%, cellulose ether: 1-3%, diatomite: 25-40%.
2. mortar according to claim 1 is plasticized water-retaining agent, it is characterised in that: in percentage terms, including following components, it is swollen Profit soil: 30%, metakaolin: 31.5%, cellulose ether: 1.5%, diatomite: 37%.
3. mortar according to claim 1 is plasticized water-retaining agent, it is characterised in that: bentonite is Na-bentonite made of being modified Soil, kaolin are metakaolin, and diatomite is the diatomite of acidleach neutralisation treatment, and cellulose ether is hydroxyethylmethylcellulose.
4. a kind of production technology of mortar plasticising water-retaining agent, characterized by the following steps:
The first step, raw material preparation mix inorganic salts in bentonite, are expressed in dry kiln through double helix mixing, in 400-600 Roasted in DEG C kiln body in mixing, be fired mixing bentonite it is cool postpone it is levigate spare to -650 mesh of 550 mesh by ball mill; Acidleach processing is carried out to diatomite with dilute sulphuric acid, separates iron aluminium impurity in diatomite, while decomposing having in diatomite inner hole Machine object, in lime and extra acid, through lime neutralize to obtain calcium sulfate dry again it is levigate store to 500~600 mesh it is spare;
Modified alta-mud, metakaolin, the acid diatomite neutralized, hydroxyethylmethylcellulose are respectively screw defeated by second step It is sent on electrical metering device and weighs in proportion, mixed subsequently into mixing machine, incorporation time 2min or more, wherein modification is swollen The native weight percent of profit is 30%, metakaolin weight percent is 31.5%, cellulose ether weight percent is 1.5%, silicon Diatomaceous earth weight percent is 37%.
CN201810993024.XA 2018-08-29 2018-08-29 A kind of mortar plasticising water-retaining agent and its production technology Pending CN108947316A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109677040A (en) * 2018-12-29 2019-04-26 中国非金属矿工业有限公司 Anti-corrosion prehydration mineral impervious material of a kind of anti-freezing type height and preparation method thereof
CN110642567A (en) * 2019-08-28 2020-01-03 桐乡正昶新型材料有限公司 Saltpetering-resistant mortar and preparation method thereof
CN111153651A (en) * 2020-01-09 2020-05-15 杭州市园林绿化股份有限公司 Anti-efflorescence cement mortar and maintenance method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007720A (en) * 2007-01-25 2007-08-01 上海市建筑科学研究院(集团)有限公司 Highly effective water-keeping thickening material and cement mortar produced therefrom
CN102134158A (en) * 2011-04-18 2011-07-27 宁波荣山新型材料有限公司 Water-retaining thickening agent for composite dry mortars and preparation method thereof
CN103113038A (en) * 2013-01-31 2013-05-22 沈池清 Mortar water-retaining and thickening agent and preparation method thereof
KR20150121329A (en) * 2014-04-18 2015-10-29 화인미셀공업(주) Expanded mortar and method for fabricating thereof

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN101007720A (en) * 2007-01-25 2007-08-01 上海市建筑科学研究院(集团)有限公司 Highly effective water-keeping thickening material and cement mortar produced therefrom
CN102134158A (en) * 2011-04-18 2011-07-27 宁波荣山新型材料有限公司 Water-retaining thickening agent for composite dry mortars and preparation method thereof
CN103113038A (en) * 2013-01-31 2013-05-22 沈池清 Mortar water-retaining and thickening agent and preparation method thereof
KR20150121329A (en) * 2014-04-18 2015-10-29 화인미셀공업(주) Expanded mortar and method for fabricating thereof

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Title
赵云龙等: "《石膏应用技术问答》", 30 September 2016, 中国建材工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109677040A (en) * 2018-12-29 2019-04-26 中国非金属矿工业有限公司 Anti-corrosion prehydration mineral impervious material of a kind of anti-freezing type height and preparation method thereof
CN110642567A (en) * 2019-08-28 2020-01-03 桐乡正昶新型材料有限公司 Saltpetering-resistant mortar and preparation method thereof
CN111153651A (en) * 2020-01-09 2020-05-15 杭州市园林绿化股份有限公司 Anti-efflorescence cement mortar and maintenance method

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Address after: 314511 Zhejiang, Jiaxing, Tongxiang, Chong Fu town, North San Li Qiao West.

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