CN108947280A - A kind of furnace atmosphere circulation formula lime stone muffle calcination system - Google Patents

A kind of furnace atmosphere circulation formula lime stone muffle calcination system Download PDF

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Publication number
CN108947280A
CN108947280A CN201810948922.3A CN201810948922A CN108947280A CN 108947280 A CN108947280 A CN 108947280A CN 201810948922 A CN201810948922 A CN 201810948922A CN 108947280 A CN108947280 A CN 108947280A
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gas
lime stone
combustion chamber
furnace
lime
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CN201810948922.3A
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CN108947280B (en
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张辉宏
曹和军
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Shijiazhuang Saint Htc Energy Engineering Ltd By Share Ltd
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Shijiazhuang Saint Htc Energy Engineering Ltd By Share Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00Lime, magnesia or dolomite
    • C04B2/10Preheating, burning calcining or cooling
    • C04B2/12Preheating, burning calcining or cooling in shaft or vertical furnaces
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/50Carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/40Production or processing of lime, e.g. limestone regeneration of lime in pulp and sugar mills

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Furnace Details (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of furnace atmosphere circulation formula lime stone muffle calcination systems, belong to technical field of lime production.It includes the circulatory system and heating system, the circulatory system includes cryogenic heat exchanger, high-temperature heat-exchanging and the calcining furnace for constituting loop, the road of working off one's feeling vent one's spleen of calcining furnace is connected with gas exhaust piping by triple valve, injector is additionally provided in circulatory system loop, injector is connected with driving blower;Heating system includes combustion chamber and the air preheater being connected respectively with combustion chamber, gas preheater and regenerator, the outlet of combustion chamber is sequentially connected to the dielectric cavity of high-temperature heat-exchanging, cryogenic heat exchanger, air preheater and gas preheater by pipeline, and the dielectric cavity of regenerator is connected in the gas exhaust piping.The design of calcination system of the present invention is very ingenious, can be improved the quality of lime product, and is attached to production CO2, bring new economic benefit.Meanwhile the heat utilization efficiency of this system is higher, has the characteristics that environmental protection and energy saving, is convenient for marketing, has broad application prospects.

Description

A kind of furnace atmosphere circulation formula lime stone muffle calcination system
Technical field
The invention belongs to technical field of lime production, particularly relate to a kind of furnace atmosphere circulation formula lime stone muffle calcination system.
Background technique
It is obtained currently, industry and civilian lime mainly pass through lime stone and calcine in limekiln.The master that this method uses Wanting equipment is limekiln, is divided into four temperature band in limekiln, is storing band, preheating zone, burning zone and cooling zone, core respectively Heart district is burning zone.Burner noz(zle) is distributed in burning zone, by these Jet control industrial gas, natural gas, fuel oil or The burning of coal dust, is distributed even flame.The high-temperature flue gas that burning generates directly is contacted with lime stone, heating lime stone to 900 After DEG C, CO2Start to be precipitated from lime stone, the CO by the calcining of certain time, inside lime stone2After being precipitated completely, calcine At.
The characteristics of this calcining manners is that the burn high-temperature flue gas of generation is directly contacted with lime stone, heat transfer efficiency It is high.But the problem of existing simultaneously is, the harmful substance that different fuel burning generates will affect the quality of lime, such as H2O、SO2, charcoal Black, NOxEtc..In addition, these harmful substances can also contact simultaneously with the lime stone (main component is calcium oxide) calcined in kiln It chemically reacts, generates non-lime substance (e.g., CaSO4), to influence the overall quality of lime.Therefore, it is connect using flame The lime that touch is sintered into, generally will be to the processing of blocky lime sur-face peeling just when producing medical or food-grade calcium carbonate It can use, and can only manually remove.
As it can be seen that existing lime calcining mode had not only polluted environment but also had caused the very big wasting of resources and energy waste, simultaneously Lime surface impurity residual is uncontrollable, directly affects medical or food-grade calcium carbonate quality.Application No. is 2014102641325 Chinese patent disclose " a kind of muffle calcination lime burner ", the limekiln using muffle mode to lime stone carry out heating forge It burns, it can be with the quality of effective guarantee lime.But the utilization efficiency of heat energy in the limekiln is lower, the waste heat being emitted into atmosphere More, there is also biggish rooms for improvement.
Summary of the invention
In view of the above problems, the present invention proposes a kind of furnace atmosphere circulation formula lime stone muffle calcination system, the system is using more Grade heat exchange mode, and furnace atmosphere circulation is run, it can be improved the utilization efficiency of thermal energy.
To achieve the above object, the technical solution adopted by the present invention is that:
A kind of furnace atmosphere circulation formula lime stone muffle calcination system comprising the circulatory system and heating system, the circulatory system packet The cryogenic heat exchanger, high-temperature heat-exchanging and calcining furnace for being sequentially connected with and constituting loop are included, the road of working off one's feeling vent one's spleen of the calcining furnace is logical It crosses triple valve and is connected with gas exhaust piping, the injector for driving gas to recycle is additionally provided in the circulatory system loop, it is described Injector is connected with driving blower;The heating system includes combustion chamber and the air preheat that is connected respectively with combustion chamber Device, gas preheater and regenerator, the outlet of the combustion chamber by pipeline sequentially with high-temperature heat-exchanging, cryogenic heat exchanger, sky Air preheater is connected to the dielectric cavity of gas preheater, and the dielectric cavity of the regenerator is connected in the gas exhaust piping.
Optionally, the first dust-extraction unit and first positioned at the regenerator downstream is also arranged in sequence in the gas exhaust piping Carbon dioxide capture device.
Optionally, the downstream of the gas preheater dielectric cavity also passes through pipeline the second dust-extraction unit and second is arranged in sequence Carbon dioxide capture device.
It optionally, further include control module, the triple valve is electrically-controlled valve, and the calcining furnace is equipped with pressure sensor, The control module is connect with triple valve and pressure sensor respectively;The control module is used in calcining furnace pressure be more than to set Gas exhaust piping is opened by triple valve when definite value.
Beneficial effect by adopting the above technical scheme is:
1, the present invention devises two sets of air-channel systems, all the way for comprising the circulatory system including calcining furnace, another way is to pass through combustion The heating system for generating heat is burnt, two systems are isolated from each other, and heat is passed to circulation from heating system by heat exchange mode System.This calcination system can effectively avoid combustion product gases from contacting with the direct of lime stone, to prevent lime stone from calcining Non- lime substance is generated in the process, and then promotes the quality of lime.
2, the present invention is provided with many places heat exchange facilities and can sufficiently be recycled in whole system using multi-stage heat exchanger mode Waste heat avoids energy waste and waste heat from polluting, and the design of entire calcination system is very ingenious, has the characteristics that energy conservation and environmental protection.
3, the present invention uses two sets of air-channel systems, thus high-purity CO that calcining is generated2The flue gas generated with burning is isolated It comes.Meanwhile the gas in the circulatory system can make CO by iterative cycles2Reach high concentration, to be conducive to CO2 Recycling.The CO of recycling2It can be used as the raw material of junior's industry, therefore, this system not only contributes to reduce the discharge of greenhouse gases, Additional economic benefit can also be created.
In short, the design of calcination system of the present invention is very ingenious, the quality of lime product can be improved, and be attached to production CO2, bring new economic benefit.Meanwhile the heat utilization efficiency of this system is higher, has the characteristics that environmental protection and energy saving, pushes away convenient for market Extensively, it has broad application prospects.
Detailed description of the invention
Fig. 1 is a kind of structural block diagram of furnace atmosphere circulation formula lime stone muffle calcination system in the embodiment of the present invention.
Specific embodiment
With reference to the accompanying drawing and specific embodiment the present invention will be further described.
As shown in Figure 1, a kind of furnace atmosphere circulation formula lime stone muffle calcination system comprising the circulatory system and heating system, The circulatory system includes the cryogenic heat exchanger, high-temperature heat-exchanging and calcining furnace for being sequentially connected with and constituting loop, the calcining furnace Road of working off one's feeling vent one's spleen gas exhaust piping is connected with by triple valve, be additionally provided in the circulatory system loop for driving gas to recycle Injector, the injector is connected with driving blower;The heating system includes combustion chamber and is connected respectively with combustion chamber Air preheater, gas preheater and the regenerator connect, the outlet of the combustion chamber by pipeline sequentially with high-temperature heat-exchanging, low Warm heat exchanger, air preheater are connected to the dielectric cavity of gas preheater, and the dielectric cavity of the regenerator is connected to the exhaust In pipeline.
In the system, injector may be provided at the inlet of cryogenic heat exchanger, may also be arranged on the entrance of high-temperature heat-exchanging Place, this depends on the temperature of used driving blower blow gas.
Calcining furnace can use existing Conventional calcination furnace, but usage mode is unlike the prior art.It is in the prior art Directly fuel gas is sent into calcining furnace, and is burnt in calcining furnace.This system then utilizes the original gas circuit entrance of calcining furnace The recyclegas of high temperature is sent into, is not burnt in furnace.
Cryogenic heat exchanger, high-temperature heat-exchanging, air preheater, gas preheater and regenerator in the system are heat exchange Device can select in the prior art suitable type directly to use, can also be customized as needed.
Optionally, still see Fig. 1, the first dedusting dress positioned at the regenerator downstream is also arranged in sequence in the gas exhaust piping It sets and the first carbon dioxide capture device.
Optionally, still see Fig. 1, the downstream of the gas preheater dielectric cavity also passes through pipeline and the second dedusting dress is arranged in sequence It sets and the second carbon dioxide capture device.
It optionally, further include control module, the triple valve is electrically-controlled valve, and the calcining furnace is equipped with pressure sensor, The control module is connect with triple valve and pressure sensor respectively;The control module is used in calcining furnace pressure be more than to set Gas exhaust piping is opened by triple valve when definite value, excessive gas is discharged to maintain the balance of furnace gas and ensures gas Normal circulation.The control target of control module is as previously mentioned, the specific implementation of control algolithm is those skilled in the art Common knowledge, details are not described herein again.
Working principle of the present invention is as follows:
Lime stone is calcined in calcining furnace, and the exhaust gas of generation is discharged out of furnace.The exhaust gas of discharge is divided into two parts: a part For exhaust, another part is circulating air.
Exhaust recycles heat by regenerator, using bag filter dedusting, finally by Collecting carbonic anhydride device After trapping, residual gas is discharged into atmosphere.
Circulating air first passes around cryogenic heat exchanger, and the temperature of circulating air is promoted to 300~400 DEG C, high temperature is entered back into and changes Its temperature is promoted to 1100 DEG C or so, finally enters in calcining furnace, directly heat lime stone by hot device.
The heat source of entire calciner plant is an independent combustion chamber, and combustion chamber needs to input combustion air, main air And fuel.Wherein, combustion air is heated by regenerator, thus the heat of recovery of circulatory system discharge exhaust gas;Main combustion is empty Gas is heated by air preheater, to recycle a part of heat of heating system discharge flue gas;Fuel is pre- by combustion gas Hot device continues to heat, thus a part of heat of recycling heating system discharge flue gas.
Enter in combustion chamber after the above three parts gas preheating and burn, 1300 DEG C or so high-temperature flue gas of generation initially enter High-temperature heat-exchanging enters back into cryogenic heat exchanger.700 DEG C or so are cooled to after high-temperature flue gas and circulating air heat exchange, enters back into air Preheater and main air exchange heat, and temperature is down to 400 DEG C or so.Finally, flue gas enters gas preheater, dropped after exchanging heat with fuel Down to 150 DEG C or so.Low-temperature flue gas is discharged into atmosphere using smoke duster and Collecting carbonic anhydride device, last residual gas.
The high-temperature flue gas heat cycles gas that this furnace atmosphere circulation formula lime stone muffle calcination system is generated by burning, then by The flue gas that burning generates is isolated with lime stone, efficiently avoids the harmful components in flue gas by circulating air heating lime stone Pollution to lime improves the purity of lime.In addition, the system is additionally provided with Collecting carbonic anhydride device, all discharges are trapped Carbon dioxide in gas reduces carbon emission.Multiple heat exchangers in system can also sufficiently recycle the heat in exhaust and flue gas Amount, improves capacity usage ratio, reduces environmental pollution.
Lime stone is during production, and the form and chemical component of fuel are not fixed very much and relative complex, the cigarette for generation of burning Gas ingredient has many uncertain factors, in the flue gas impurity that the production method of conventional lime kiln generates burning with regard to inevitable It is mixed into lime finished product, causes " pollution " of finished product lime.This furnace atmosphere circulation formula lime stone muffle calcination system during production, The flue gas that fuel combustion generates transfers heat to the circulatory system by heat exchange equipment, and heat is supplied lime stone again by the circulatory system Reaction, i.e., the flue gas of fuel combustion does not contact directly with production material directly, this has just prevented band due to fuel impurity problem The pollution come provides a kind of more reliable method for production high-purity lime.
In this furnace atmosphere circulation formula lime stone muffle calcination system, limestone calcination during institute's calorific requirement from low temperature, Heat is only passed to the circulatory system from combustion chamber high temperature flue gas by high-temperature heat exchanger, exchanger.Therefore the cyclic system of this system There is no flue gas (flue gas after combustion chambers burn) ingredient, the only carbon dioxide of lime stone reaction generation in the exhaust gas of system discharge. Meanwhile the iterative cycles of recyclegas make gas concentration lwevel therein quite high, in this way, the exhaust gas of discharge is due to its dioxy It is higher to change carbon purity, thus can be by relatively easy and utilize again at low cost.Also, it reasonably collects and utilizes this part Carbon dioxide can also reduce the discharge of greenhouse gases.As it can be seen that this system is a kind of very environmentally friendly production facility, it is not only able to Reduce the discharge of greenhouse gases, additionally it is possible to provide more good raw material for next stage industry (deep processing of carbon dioxide), create Make additional economic benefit.
In short, the design of calcination system of the present invention is very ingenious, the quality of lime product can be improved, and be attached to production CO2, bring new economic benefit.Meanwhile the heat utilization efficiency of this system is higher, has the characteristics that environmental protection and energy saving, pushes away convenient for market Extensively, it has broad application prospects.
It should be pointed out that the above specific embodiment is the specific case of this patent implementation, without also can not All implementations of this patent can be covered, therefore the restriction to the scope of this patent cannot be regarded as;All and above case Belong to the implementation of same idea or the assembled scheme of above-mentioned several schemes, within the protection domain of this patent..

Claims (4)

1. a kind of furnace atmosphere circulation formula lime stone muffle calcination system, it is characterised in that: described including the circulatory system and heating system The circulatory system includes the cryogenic heat exchanger, high-temperature heat-exchanging and calcining furnace for being sequentially connected with and constituting loop, and the calcining furnace goes out Implication road passes through triple valve and is connected with gas exhaust piping, and the spray for driving gas to recycle is additionally provided in the circulatory system loop Emitter, the injector are connected with driving blower;The heating system includes combustion chamber and is connected respectively with combustion chamber The outlet of air preheater, gas preheater and regenerator, the combustion chamber is sequentially changed with high-temperature heat-exchanging, low temperature by pipeline Hot device, air preheater are connected to the dielectric cavity of gas preheater, and the dielectric cavity of the regenerator is connected to the gas exhaust piping In.
2. furnace atmosphere circulation formula lime stone muffle calcination system according to claim 1, it is characterised in that: the gas exhaust piping In the first dust-extraction unit and the first carbon dioxide capture device positioned at the regenerator downstream is also arranged in sequence.
3. furnace atmosphere circulation formula lime stone muffle calcination system according to claim 1, it is characterised in that: the gas-preheating The downstream of device dielectric cavity also passes through pipeline and the second dust-extraction unit and the second carbon dioxide capture device is arranged in sequence.
4. furnace atmosphere circulation formula lime stone muffle calcination system according to claim 1, it is characterised in that: further include control mould Block, the triple valve be electrically-controlled valve, the calcining furnace be equipped with pressure sensor, the control module respectively with triple valve and pressure Force snesor connection;The control module is used to beat gas exhaust piping by triple valve when calcining furnace pressure and being more than setting value It opens.
CN201810948922.3A 2018-08-20 2018-08-20 Furnace gas circulation type limestone flame-proof calcining system Active CN108947280B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960696A (en) * 2020-06-29 2020-11-20 福建省气柜设备安装有限公司 Lime kiln for directly burning high-temperature coal gas hot delivery of gasification furnace
CN112919468A (en) * 2021-03-10 2021-06-08 广西大学 Method for recovering carbon dioxide by calcining limestone with oxygen-enriched combustion-supporting effect

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CN102211884A (en) * 2011-02-27 2011-10-12 赵军政 High-efficiency, energy-saving and environment-friendly lime manufacturing unit
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CN205170895U (en) * 2015-06-01 2016-04-20 李正福 Rotary kiln CO2 and argon gas are used for controlling means of converter smelting
CN108314336A (en) * 2018-05-09 2018-07-24 王长春 A kind of lime kiln device using circulating air

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960696A (en) * 2020-06-29 2020-11-20 福建省气柜设备安装有限公司 Lime kiln for directly burning high-temperature coal gas hot delivery of gasification furnace
CN111960696B (en) * 2020-06-29 2022-04-05 中琉科技有限公司 Lime kiln for directly burning high-temperature coal gas hot delivery of gasification furnace
CN112919468A (en) * 2021-03-10 2021-06-08 广西大学 Method for recovering carbon dioxide by calcining limestone with oxygen-enriched combustion-supporting effect

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