CN108943945A - Build flooring Multifunctional sound insulation vibration damping composite material and its production technology - Google Patents

Build flooring Multifunctional sound insulation vibration damping composite material and its production technology Download PDF

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Publication number
CN108943945A
CN108943945A CN201810916078.6A CN201810916078A CN108943945A CN 108943945 A CN108943945 A CN 108943945A CN 201810916078 A CN201810916078 A CN 201810916078A CN 108943945 A CN108943945 A CN 108943945A
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layer
sound insulation
glue
vibration damping
composite material
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Inventor
董文兵
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Nanjing Shiwale New Material Technology Co.,Ltd.
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Nanjing Nelson Energy Saving Technology Co Ltd Of Chinese Academy Of Sciences
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Priority to CN201810916078.6A priority Critical patent/CN108943945A/en
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    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/06Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions for securing layers together; for attaching the product to another member, e.g. to a support, or to another product, e.g. groove/tongue, interlocking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/08Interconnection of layers by mechanical means
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1253Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives curable adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/025Polyolefin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a kind of building flooring Multifunctional sound insulation vibration damping composite materials, including softer, elastic damping layer and the basal layer for being placed in softer, elastic damping layer two sides, hollow glass microbead superposed layer is provided between each basal layer and damping layer, hollow glass microbead superposed layer is that several hollow glass microbeads are uniform curing in the glue-line that adhesive is formed.Since hollow glass microbead includes the gases such as nitrogen, carbon dioxide, density is small, light, adhesive force is strong, is easy to smear, and low thermally conductive, physical and chemical performance is stablized, very easy dispersion is suspended in the organic materials such as glue, coating, and framework is excellent sound-insulating and heat-insulating insulating layer.

Description

Build flooring Multifunctional sound insulation vibration damping composite material and its production technology
Technical field:
The invention belongs to new building material technical field, in particular to a kind of building flooring Multifunctional sound insulation vibration damping composite wood Material, further relates to the production technology of the material.
Background technique:
It is well known that sound source, in the vibration of object, vibration propagates be formed sound wave in air, and when sound wave incident arrives When wall or floor, wall or floor will be made also to generate vibration and to external radiation.Noise is then that sounding body does random vibration The sound issued when dynamic.In daily life, most common is exactly that resident upstairs walks about (especially hard footwear is with such as high-heeled shoes), child Son play it is noisy run, behavior usual in the life such as household is moved, give one impact force of floor, this impact force is enough to produce floor Raw vibration.If the effectiveness in vibration suppression of floor is bad, sound will be transmitted in the family of resident downstairs by floor, wall, be caused Either large or small noise and make troubles to other people, Building Indoor Environment is frequently subjected to the interference of this noise like." green building is commented Price card is quasi- " GB/T50378, " Code for sound insulation design of civil buildings " GB50118 be to house, school, hospital, hotel, office and quotient Noise control in the six classes building such as industry building is put forward new requirements, the air-borne sound sound insulation of floor and strike note sound insulation property All done specified in more detail again, wherein residential housing bedroom, living room point family floor weighted hit a sound pressure level and should be not more than 75dB.In general, Reinforced Concrete Materials has good air-borne sound sound insulation property, the typical armored concrete of 120mm thickness Floor air-borne sound oise insulation factor is about 45dB, and it is about 80- that the weighted of 120mm thickness armored concrete point family floor, which hits sound pressure level, The requirement of relevant criterion is not achieved in 82dB.
Building enclosure energy conservation is the basis of building energy conservation.And in energy-saving design in construction building enclosure, build the heat of dissipation By flooring heat bridge heat transfer loss occurs for (cold) amount, has seriously affected the implementation result of building energy conservation.Flooring is as people The part directly contacted when daily life, work and production, thermal property also have the comfort and health of people most important Influence.Excessive temperature differentials between neighbouring households heating and non-heating (refrigeration), and a point family floor thermal resistance is not achieved minimum thermal resistance and wants It asks, so that point family floor inner surface is generated moisture condensation, hygienic requirements is not achieved.Housing heat-transfer is excessive, can also further increase adjacent The burden of resident's heating (refrigeration) equipment.Heat transfer for neighbor to be reduced also should be appropriate while improving peripheral structure thermal resistance Improve the thermal and insulating performance for dividing family floor.
The material that China is used to build flooring sound insulation vibration damping at present has a single function mostly, and the present invention provides one kind can The noise transmission interference up and down of building flooring is effectively solved, and can be reduced heat transfer and loss between point family while can also improve The Multifunctional sound insulation vibration damping thermal insulation material of fire retardant performance.
The information disclosed in the background technology section is intended only to increase the understanding to general background of the invention, without answering When being considered as recognizing or imply that the information constitutes the prior art already known to those of ordinary skill in the art in any form.
Summary of the invention:
The purpose of the present invention is to provide a kind of building flooring Multifunctional sound insulation vibration damping composite materials, to overcome above-mentioned existing There is the defects of technology.
To achieve the above object, the present invention provides a kind of building flooring Multifunctional sound insulation vibration damping composite material, packets It includes softer, elastic damping layer and the basal layer for being placed in softer, elastic damping layer two sides, is provided between basal layer and damping layer Empty glass microballoon superposed layer, the hollow glass microbead superposed layer is that several hollow glass microbeads are uniform curing to be formed in adhesive Glue-line in.It is understood that softer, elastic damping layer can also be arranged in the two sides of basal layer.
Hollow glass microbead is a kind of small, hollow spherical shape glass powder, in cavity filled with inert gas or Carbon dioxide.
The technical solution that the present invention further limits are as follows:
Preferably, in above-mentioned technical proposal, film surface has viscosity, and the glue-line is bonded between basal layer and buffer layer.
Preferably, in above-mentioned technical proposal, film surface is laid on basal layer and buffer layer without viscosity, the glue-line Between, basal layer and buffer layer are mutually bonded.
Preferably, in above-mentioned technical proposal, glue-line can be formed with pre-production or by premix hollow glass microbead glue The both side surface that glutinous agent is coated in damping layer is formed.
Preferably, in above-mentioned technical proposal, the adhesive surface of damping layer is smooth surface or has concaveconvex structure, when the vibration damping When the adhesive surface of layer has concaveconvex structure, the adhesive for premixing hollow glass microbead is coated in damping layer and flows into concaveconvex structure Form that a upper surface is smooth, lower surface is non-smooth glue-line, this be in order to increase the thickness of glue-line and increase heat reflection and The effect of sound wave reflection.
Preferably, in above-mentioned technical proposal, there are two types of these concaveconvex structures, and one is the artificial later periods to form, such as surface Precreping formed groove or foamed material cut after section open-celled structure, another kind be material itself carry, such as Tissue space between loose fiber class material.
Preferably, in above-mentioned technical proposal, hollow glass microbead specification be 10-250 μm of diameter, 1-2 μm of wall thickness, accumulation it is close Spend 0.1-0.25 grams/cm3.
Preferably, in above-mentioned technical proposal, basal layer is polystyrene foam plastics insulation board, polyurethane foam plastics guarantor One of warm plate, phenolic-aldehyde heat-insulation board, rubber and plastic insulation board, thickness 5-30mm.
Preferably, in above-mentioned technical proposal, the softer, elastic damping layer is rubber based elastic sheet material, polyethylene foam class One of elastic sheet material, polyesters foaming elastic sheet material, loose fiber class elastic sheet material, with a thickness of 2-10mm.
Preferably, in above-mentioned technical proposal, the similar structure of hollow glass microbead structure can also play similar effect Fruit, such as substituted by nanoporous aerogel powder, micron order fly ash float, hollow ceramic microspheres.
Preferably, in above-mentioned technical proposal, adhesive is polyurethanes glue, and phenolic glue, acrylic compounds glue has Machine silicon class glue, rubber glue, polyvinyl alcohol glue, silicone (or modified) class glue, cellulose family glue.
Preferably, in above-mentioned technical proposal, for beautiful or increase and earth material contact area, sound insulation vibration damping is multiple The exposed two sides of condensation material is suppressed with pattern or decorative pattern or three-dimensional contouring.
A kind of production technology for building flooring Multifunctional sound insulation vibration damping composite material, carries out in accordance with the following steps:
Prefabricated functional form mixed liquor: S1 hollow glass microbead is added in pressure sensitive adhesive according to the ratio of 5%-30% and is stirred and evenly mixed It is spare afterwards;
The both side surface that the mixed liquor that S1 is prepared is coated in damping layer is ensured to be formed the glue film of 1-5mm surfacing by S2;
S3 is heating and curing to the damping layer after coating according to the condition of cure of pressure sensitive adhesive;
The damping layer being cured and basal layer pressing are pasted and can be obtained into this product by S4.
The technical solution that the present invention further limits are as follows:
Preferably, in above-mentioned technical proposal, in step S1, after the mixing speed of pressure sensitive adhesive reaches predetermined value, hollow glass microbead It mixes in batches.
Preferably, in above-mentioned technical proposal, in step S1, dispersing agent 0.3%, defoaming agent 0.7% need to be added.
Preferably, in above-mentioned technical proposal, before carrying out step S2, the preparation of softer, elastic damping material layer is according to material Selection lower section any one:
(1) the smooth elastic sheet material in surface or coiled material are embossed in factory process, and being formed has rectangular, diamond shape, triangle, polygon The functional form regular pattern with the linear equidistant groove of longitude and latitude or several equidistant circular grooves such as shape, rectangle, depth of groove 1- 5mm;
(2) foaming kind or rubber based elastic sheet material itself are closed-cell foam structure, by special mechanical by elastic sheet material or volume Material is splitted, and split surface becomes aperture state, several grooves of self-assembling formation;
In carrying out step S2, if it is loose fiber class elastic sheet material, entire sheet material is immersed in adhesive.
Preferably, in above-mentioned technical proposal, prefabricated functional form mixed liquor: by 10-250 μm of diameter, 1-2 μm of wall thickness, accumulation 0.1-0.25 grams of density/cm3 hollow glass microbead is added in water-borne pressure sensitive adhesive according to the ratio of 5%-30%, and dispersion is added Agent 0.3%, defoaming agent 0.7% are uniformly mixed, and stirring rate is no more than 100r/min and component mixes in batches and puddles 5- 10min;Equipment complex plastic roll slot is uniformly poured into after standing 30min after puddling.
The preparation of softer, elastic damping material layer: by crosslinked polyethylene foaming coiled by engraving in advance on dedicated embossing machine Good figure is suppressed, formed have rectangular, diamond shape, triangle, polygon, rectangle etc. with the linear equidistant groove of longitude and latitude or The non-burnishing surface functional form regular pattern of several equidistant circular grooves, depth of groove 1-5mm(are adjusted with the thickness of damping layer It is whole), longitude and latitude line width 1-20mm.Finished crosslinked polyethylene foaming coiled is penetrated into equipment complex unreeling machine.
Crosslinked polyethylene roll position and distance are adjusted, adjustment rubber roller gap 1-5mm(presses coil thickness), start the rolling of roller machine It applies.Pulse 2000 is glued, pulse 1600, rubber roller speed 20m/min are translated.It is required that mixed liquor uniformly inserts groove, one layer is formed At least glue film of 1-5mm.
Enter baking oven hot wind by transmission belt to solidify, 40-70 DEG C of oven temperature, 20 m/min of rate.
The crosslinked polyethylene solidified is bonded with polystyrene thermal insulation plate by transmission belt, is cold-pressed, concora crush roll-in is bonded Power 0 arrives 0.8MPa, is cold-pressed plate pressure 2-6kg, 20 m/min of rate.
By transmission belt by compound good sound insulation damping block deburring, cut (20 meters/min of rate) (disk saw, band saw, deep cutting, Thermo-fuse), it can be used within stacking offline still aging 10 hours or more.
Compared with prior art, the invention has the following beneficial effects:
1, since hollow glass microbead, nanoporous aerogel powder, hollow ceramic microspheres, fly ash float include nitrogen, titanium dioxide The gases such as carbon, density is small, light, adhesive force is strong, is easy to smear, and low thermally conductive, physical and chemical performance is stablized, and dispersion is very easy to It is suspended in the organic materials such as glue, coating, framework is excellent insulating.Such special object is added by composite material The front and back of matter compares, and thermal coefficient can be promoted by original 0.045W/ (mK) to the left and right 0.030W/ (mK), is greatly improved The thermal resistance of composite material, thermal-insulation energy-conservation better effect.
2, hollow glass microbead, nanoporous aerogel powder, hollow ceramic microspheres, fly ash float are fast in a low voice due to itself Characteristic or a kind of ideal acoustical delay acoustic material.Using four probe acoustic impedance pipes to the sound insulation value of composite material into The acoustic impedance variable range of row test, composite material increases, and strike note 20-30dB can be effectively reduced.It is answered by floating build floor method Building flooring is used, when upstairs article falls, vibration of floor is obviously reduced, and effectiveness in vibration suppression is promoted between floor, noise pair in building The transmitting of contiguous floors is effectively suppressed, and provides more comfortable inhabitation and working environment.
3, other heat preserving and insulating materials, hollow glass microbead, nanoporous aerogel powder, fly ash float hollow ceramic are compared Microballon belongs to inorganic material, and fusing point is greater than more than 1000 degree, does not decompose, be unlikely to deform under high temperature, excellent fire protecting performance is derived from it Physics heat-blocking action, itself is not non-ignitable also combustion-supporting.Its excellent hollow heat insulation structure proposes the heat resistance of composite material Height stably reaches B1 grades of fire-protection rating, and flame retardant effect is also improved.
Detailed description of the invention:
Fig. 1 is the cross-sectional view of composite material;
Fig. 2 is the cross-sectional view of composite material;
Fig. 3 is the cross-sectional view of composite material;
Fig. 4 is the cross-sectional view of composite material;
Fig. 5 is 3 embossed surface schematic diagram of damping layer;
Fig. 6 is that the schematic diagram after gelling agent is coated on Fig. 3 basal layer;
Fig. 7 is the schematic diagram after damping layer flat coating;
Fig. 8 is after foamed material is embossed through weft and groove schematic diagram;
Fig. 9 is floor crashing oise insulation factor frequency characteristic;
Figure 10 is floor crashing oise insulation factor frequency characteristic.
In figure: basal layer 1, hollow glass microbead superposed layer 2, damping layer 3, hollow glass microbead 2-1, damping layer fin 3- 1, damping layer groove 3-2.
Specific embodiment:
Specific embodiments of the present invention will be described in detail below, it is to be understood that protection scope of the present invention is not had The limitation of body embodiment.
Unless otherwise explicitly stated, otherwise in entire disclosure and claims, term " includes " or its change Changing such as "comprising" or " including " etc. will be understood to comprise stated element or component, and not exclude other members Part or other component parts.
A kind of building flooring Multifunctional sound insulation vibration damping composite material, including basal layer 1 and it is placed in basal layer two sides table The softer, elastic damping layer 3 in face is provided with hollow glass microbead superposed layer 2, hollow glass between basal layer and the damping layer of two sides Glass microballon superposed layer is several hollow glass microbead 2-1 uniform curing in the glue-line that pressure sensitive adhesive is formed.Hollow glass microbead is outstanding It floats in pressure sensitive adhesive, since hollow glass microbead 2-1 quality is light, it will not settle or arbitrarily run, just as being suspended in glue, An excellent sound-insulating layer is just formed after waiting glue solidification.Pressure sensitive adhesive surface after solidification has viscosity, passes through cold pressing Directly paste basal layer.
It is to be understood that using softer, elastic damping layer 3 and 3 both side surface of softer, elastic damping layer can also be placed in Basal layer 1, this reversed order is in the field of business to belong to more typical application method.
If the film surface of selection, without viscosity, glue-line is laid on the surface of basal layer or buffer layer, basal layer and Buffer layer, which is mutually bonded, can be realized the compound of material.
Glue-line can be formed with pre-production or be coated in basis by the adhesive of liquid premix hollow glass microbead Layer or vibration damping layer surface are formed.
Basal layer or the adhesive surface of damping layer are that smooth surface is perhaps viscous when basal layer or damping layer with concaveconvex structure When veneer has concaveconvex structure, the adhesive for premixing hollow glass microbead is coated in basal layer or damping layer and flows into concave-convex knot Form that a upper surface is smooth, lower surface is non-smooth glue-line in structure, this is to increase the thickness of glue-line and to increase heat anti- Penetrate the effect of harmony wave reflection.
There are two types of these concaveconvex structures, and one is the artificial later periods to form, such as the groove that surface precreping is formed, such as subtracts Shake layer fin 3-1, the open-celled structure of section after damping layer groove 3-2 or foamed material are cut, another kind be material itself from Band, such as the tissue space between loose fiber class material.
It is 10-250 μm of diameter, 1-2 μm of wall thickness, bulk density 0.1- through the preferred hollow glass microbead specification of overtesting 0.25 gram/cm3.
Basal layer is polystyrene foam plastics insulation board, polyurethane foam plastics insulation board, phenolic-aldehyde heat-insulation board, rubber and plastic guarantor One of warm plate, optimal thickness is 5-30mm.
Softer, elastic damping layer is rubber based elastic sheet material, polyethylene foam class elastic sheet material, polyesters foaming elastic piece One of material, loose fiber class elastic sheet material, optimal thickness is 2-10mm.
The similar structure of hollow glass microbead structure can also play similar effect, for example, by nanoporous aerogel powder, Micron order fly ash float, hollow ceramic microspheres substitution.
For beautiful or increase and earth material contact area, the exposed two sides of sound insulation vibration damping composite material can be suppressed There are pattern or decorative pattern or three-dimensional contouring.
A kind of production technology for building flooring Multifunctional sound insulation vibration damping composite material, carries out in accordance with the following steps:
Prefabricated functional form mixed liquor: by 10-250 μm of diameter, 1-2 μm of wall thickness, the hollow glass of 0.1-0.25 grams of bulk density/cm3 Glass microballon is added in water-borne pressure sensitive adhesive according to the ratio of 5%-30%, and dispersing agent 0.3%, defoaming agent 0.7% is added and carries out uniformly Mixing, stirring rate is no more than 100r/min and component mixes in batches and puddles 5-10min;It is uniformly fallen after standing 30min after puddling Enter equipment complex plastic roll slot.
The preparation of softer, elastic damping material layer: by crosslinked polyethylene foaming coiled by engraving in advance on dedicated embossing machine Good figure is suppressed, formed have rectangular, diamond shape, triangle, polygon, rectangle etc. with the linear equidistant groove of longitude and latitude or The non-burnishing surface functional form regular pattern of several equidistant circular grooves, depth of groove 1-5mm(are adjusted with the thickness of damping layer It is whole), longitude and latitude line width 1-20mm.Finished crosslinked polyethylene foaming coiled is penetrated into equipment complex unreeling machine.
Crosslinked polyethylene roll position and distance are adjusted, adjustment rubber roller gap 1-5mm(presses coil thickness), start the rolling of roller machine It applies.Pulse 2000 is glued, pulse 1600, rubber roller speed 20m/min are translated.It is required that mixed liquor uniformly inserts groove, one layer is formed At least glue film of 1-5mm.
Enter baking oven hot wind by transmission belt to solidify, 40-70 DEG C of oven temperature, 20 m/min of rate.
The crosslinked polyethylene solidified is bonded with polystyrene thermal insulation plate by transmission belt, is cold-pressed, concora crush roll-in is bonded Power 0 arrives 0.8MPa, is cold-pressed plate pressure 2-6kg, 20 m/min of rate.
By transmission belt by compound good sound insulation damping block deburring, cut (20 meters/min of rate) (disk saw, band saw, deep cutting, Thermo-fuse), it can be used within stacking offline still aging 10 hours or more.
Hollow glass microbead additive amount is 12%, 20%, the testing result such as building Fig. 9 and 10:120mm thickness armored concrete Fen Hu The sound insulation improvement amount of plate is that 29dB and 37dB(is detected by GB/T50121-2005), effectively increase the specification of common point family floor Change strike note improvement amount, requirement of the green building relevant criterion for indoor acoustical environment can be met.
The aforementioned description to specific exemplary embodiment of the invention is in order to illustrate and illustration purpose.These are retouched It states and is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can much be changed Become and changes.The purpose of selecting and describing the exemplary embodiment is that explaining specific principle of the invention and its actually answering With so that those skilled in the art can be realized and utilize a variety of different exemplary implementation schemes of the invention and Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (17)

1. a kind of building flooring Multifunctional sound insulation vibration damping composite material, including softer, elastic damping layer and it is placed in softer, elastic The basal layer of damping layer two sides, which is characterized in that hollow glass microbead suspension is provided between each basal layer and damping layer Layer, the hollow glass microbead superposed layer are that several hollow glass microbeads are uniform curing in the glue-line that adhesive is formed.
2. building flooring Multifunctional sound insulation vibration damping composite material according to claim 1, which is characterized in that the glue Layer surface has viscosity, and the glue-line is bonded between basal layer and buffer layer.
3. building flooring Multifunctional sound insulation vibration damping composite material according to claim 1, which is characterized in that the glue Layer surface is laid between basal layer and buffer layer without viscosity, the glue-line, and basal layer and buffer layer are mutually bonded.
4. special according to building flooring Multifunctional sound insulation vibration damping composite material described in claim 2 any claim Sign is that the glue-line can be formed with pre-production or be coated in the two of damping layer by the adhesive of premix hollow glass microbead Side surface is formed.
5. building flooring Multifunctional sound insulation vibration damping composite material according to claim 4, which is characterized in that described to subtract The adhesive surface of vibration layer is smooth surface or has concaveconvex structure, when the adhesive surface of the damping layer has concaveconvex structure, in premix The adhesive of empty glass microballoon, which is coated in damping layer and flows into concaveconvex structure, forms that a upper surface is smooth, lower surface is non-flat Whole glue-line.
6. building flooring Multifunctional sound insulation vibration damping composite material according to claim 4, which is characterized in that described recessed Male structure is the open-celled structure or loose fiber class material of section after the groove that surface precreping is formed or foamed material incision Tissue space between material.
7. building flooring Multifunctional sound insulation vibration damping composite material described in -5 any claims according to claim 1, It is characterized in that, the hollow glass microbead specification is 10-250 μm of diameter, 1-2 μm of wall thickness, 0.1-0.25 grams of bulk density/cm3.
8. a kind of building flooring Multifunctional sound insulation vibration damping composite wood described in -5 any claims according to claim 1 Material, which is characterized in that the basal layer is polystyrene foam plastics insulation board, polyurethane foam plastics insulation board, phenolic aldehyde guarantor One of warm plate, rubber and plastic insulation board, thickness 5-30mm.
9. a kind of building flooring Multifunctional sound insulation vibration damping composite wood described in -5 any claims according to claim 1 Material, which is characterized in that the softer, elastic damping layer is rubber based elastic sheet material, polyethylene foam class elastic sheet material, polyesters Foam one of elastic sheet material, loose fiber class elastic sheet material, with a thickness of 2-10mm.
10. a kind of building flooring Multifunctional sound insulation vibration damping composite material according to claim 1, which is characterized in that Hollow glass microbead can also be substituted by nanoporous aerogel powder, micron order fly ash float, hollow ceramic microspheres.
11. a kind of building flooring Multifunctional sound insulation vibration damping composite material according to claim 1, which is characterized in that Adhesive is polyurethanes glue, phenolic glue, acrylic compounds glue, organic silicon glue, rubber glue, polyvinyl alcohol Class glue, silicone (or modified) class glue, cellulose family glue.
12. a kind of building flooring Multifunctional sound insulation vibration damping composite material according to claim 1, which is characterized in that Plane is in the exposed two sides of sound insulation vibration damping composite material or is suppressed with pattern or decorative pattern or three-dimensional contouring.
13. a kind of production technology for building flooring Multifunctional sound insulation vibration damping composite material, it is characterised in that: according to following step It is rapid to carry out:
Prefabricated functional form mixed liquor: S1 hollow glass microbead is added in pressure sensitive adhesive according to the ratio of 5%-30% and is stirred and evenly mixed It is spare afterwards;
The both side surface that the mixed liquor that S1 is prepared is coated in damping layer is ensured to be formed the glue film of 1-5mm surfacing by S2;
S3 is heating and curing to the damping layer after coating according to the condition of cure of pressure sensitive adhesive;
The damping layer being cured and basal layer pressing are pasted and can be obtained into this product by S4.
14. the production technology of building flooring Multifunctional sound insulation vibration damping composite material according to claim 13, special Sign is: in step S1, after the mixing speed of pressure sensitive adhesive reaches predetermined value, hollow glass microbead being mixed in batches.
15. production technology of the building flooring according to claim 13 with Multifunctional sound insulation vibration damping composite material, step In S1, dispersing agent 0.3%, defoaming agent 0.7% need to be added.
16. it is according to claim 13 building flooring Multifunctional sound insulation vibration damping composite material production technology, into Before row step S2, the preparation of softer, elastic damping material layer according to material selection lower section any one:
(1) the smooth elastic sheet material in surface is embossed in factory process, and being formed has rectangular, diamond shape, triangle, polygon, rectangle Deng the functional form regular pattern with the linear equidistant groove of longitude and latitude or several equidistant circular grooves, depth of groove 1-5mm;
(2) foaming kind or rubber based elastic sheet material or coiled material itself are closed-cell foam structure, by special mechanical by elastic piece Material or coiled material are splitted, and split surface becomes aperture state, several grooves of self-assembling formation;
In carrying out step S2, if it is loose fiber class elastic sheet material, adhesive is immersed in sheet material.
17. the production technology of building flooring Multifunctional sound insulation vibration damping composite material according to claim 13, special Sign is:
Prefabricated functional form mixed liquor: by 10-250 μm of diameter, 1-2 μm of wall thickness, the hollow glass of 0.1-0.25 grams of bulk density/cm3 Glass microballon is added in water-borne pressure sensitive adhesive according to the ratio of 5%-30%, and dispersing agent 0.3%, defoaming agent 0.7% is added and carries out uniformly Mixing, stirring rate is no more than 100r/min and component mixes in batches and puddles 5-10min;It is uniformly fallen after standing 30min after puddling Enter equipment complex plastic roll slot;
The preparation of softer, elastic damping material layer: by crosslinked polyethylene foaming coiled by having carved in advance on the dedicated embossing machine Figure is suppressed, and being formed has rectangular, diamond shape, triangle, polygon, rectangle etc. with the linear equidistant groove or several of longitude and latitude The non-burnishing surface functional form regular pattern of equidistant circular groove, depth of groove 1-5mm, longitude and latitude line width 1-20mm;
Finished crosslinked polyethylene foaming coiled is penetrated into equipment complex unreeling machine;
Crosslinked polyethylene roll position and distance are adjusted, rubber roller gap 1-5mm is adjusted, starts roller machine roller coating;
Pulse 2000 is glued, pulse 1600, rubber roller speed 20m/min are translated;
It is required that mixed liquor uniformly inserts groove, one layer of at least glue film of 1-5mm is formed;
Enter baking oven hot wind by transmission belt to solidify, 40-70 DEG C of oven temperature, 20 m/min of rate;
The crosslinked polyethylene solidified is bonded with polystyrene thermal insulation plate by transmission belt, is cold-pressed, fitting concora crush roller pressure 0 arrives 0.8MPa is cold-pressed plate pressure 2-6kg, 20 m/min of rate;
By transmission belt by compound good sound insulation damping block deburring, cut 20 meters/min of rate, stacking offline still aging 10 is small When more than can be used.
CN201810916078.6A 2018-08-13 2018-08-13 Build flooring Multifunctional sound insulation vibration damping composite material and its production technology Pending CN108943945A (en)

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CN113085318A (en) * 2021-05-13 2021-07-09 河南理工大学 Physical improvement method for thermal stability of high-temperature-resistant enhanced rubber component
CN113910710A (en) * 2021-09-24 2022-01-11 上海工程技术大学 Building material with sound insulation function and preparation method thereof

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CN209633956U (en) * 2018-08-13 2019-11-15 中科院南京耐尔思节能科技有限公司 Build flooring Multifunctional sound insulation vibration damping composite material

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CN206335913U (en) * 2016-11-30 2017-07-18 深圳中凝科技有限公司 Sound-insulating and heat-insulating composite structure
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