CN108929550A - A kind of vegetable fiber environmental protection material and preparation method thereof - Google Patents

A kind of vegetable fiber environmental protection material and preparation method thereof Download PDF

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Publication number
CN108929550A
CN108929550A CN201810930679.2A CN201810930679A CN108929550A CN 108929550 A CN108929550 A CN 108929550A CN 201810930679 A CN201810930679 A CN 201810930679A CN 108929550 A CN108929550 A CN 108929550A
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China
Prior art keywords
parts
environmental protection
vegetable
protection material
silk
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CN201810930679.2A
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Chinese (zh)
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崔飚
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Henan Dong Gui Electronic Technology Co Ltd
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Henan Dong Gui Electronic Technology Co Ltd
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Priority to CN201810930679.2A priority Critical patent/CN108929550A/en
Publication of CN108929550A publication Critical patent/CN108929550A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention discloses a kind of vegetable fiber environmental protection materials and preparation method thereof, it is related to environment-friendly materials technical field, in parts by mass, the vegetable fiber environmental protection material include 8-10 parts of butadiene-styrene copolymer, 2-4 parts of styrene, 12-18 parts of vegetable silk, 0.5-1 parts of zinc stearate, 8-12 parts of sodium bentonite, 3-4 parts of starch, 6-10 parts of carbon dust, 5-15 parts of calcium carbonate, 2-5 parts of oil, sawdust 1-5 parts thin, 10-20 parts of epoxy resin, 1-3 parts of toughener, 10-15 parts of K resin, it is flax silk 5-10 parts thin, 30-50 parts of clean water.Heat-resisting, wear-resisting property is good using vegetable fiber environmental protection material of the invention, toughness is strong, long service life.Suitable for promoting, by adding vegetable silk in raw material, so that material is more environmentally-friendly, and vegetable fiber environmental protection material has the effect of that intensity is high.

Description

A kind of vegetable fiber environmental protection material and preparation method thereof
Technical field
The present invention relates to environment-friendly materials fields, and in particular to a kind of vegetable fiber environmental protection material and preparation method thereof.
Background technique
Electric wire is made of one or a few soft conducting wire, and outer bread is with light and soft sheath;Cable is by one or several Root insulating bag conducting wire composition, outside is wrapped again with metal or tough and tensile outer layer made of rubber.Cable and electric wire are generally all by core wire, insulation Three component part compositions of foreskin and protection crust.The characteristic of common cable is as follows: the ethylene propylene rubber insulated neoprene shield of CEF-- Set, flame retardant power cable for ship.CVV-- polyvinyl chloride insulation, insulated polyvinyl-chloride-sheathed marine flame-proof power cable.
There is not environmentally friendly enough, production processing technology is cumbersome, cost is excessively high for the covering material that prior art uses Problem, therefore, it is necessary to design a kind of vegetable fiber environmental protection material and preparation method thereof for being able to solve problem above.
Summary of the invention
The problem to be solved by the invention is to provide a kind of vegetable fiber environmental protection materials and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of vegetable fiber environmental protection material, in parts by mass, the vegetable fiber environmental protection material include butadiene-styrene 8-10 parts of copolymer, 2-4 parts of styrene, 12-18 parts of vegetable silk, 0.5-1 parts of zinc stearate, sodium bentonite 8-12 Part, 3-4 parts of starch, 6-10 parts of carbon dust, 5-15 parts of calcium carbonate, 2-5 parts of oil, sawdust 1-5 parts thin, 10-20 parts of epoxy resin, toughening 1-3 parts of agent, 10-15 parts of K resin, it is flax silk 5-10 parts thin, 30-50 parts of clean water.
Further, the vegetable fiber environmental protection material includes 10 parts of butadiene-styrene copolymer, styrene 3 part, thread 15 parts of shape plant fiber, 0.8 part of zinc stearate, 10 parts of sodium bentonite, 4 parts of starch, 8 parts of carbon dust, 10 parts of calcium carbonate, oil 3 parts, Thin 3 parts of sawdust, 15 parts of epoxy resin, 2 parts of toughener, 12 parts of K resin, 8 parts of thin flax silk, 40 parts of clean water.
A method of preparing vegetable fiber environmental protection material described in claim 1-2 any one, the preparation method Specifically includes the following steps:
Step 1: preparing butadiene-styrene copolymer 8-10 parts, 2-4 parts of styrene, vegetable silk as requested 12-18 parts, 0.5-1 parts of zinc stearate, 8-12 parts of sodium bentonite, 3-4 parts of starch, 6-10 parts of carbon dust, 5-15 parts of calcium carbonate, oil 2-5 parts, sawdust 1-5 parts thin, 10-20 parts of epoxy resin, flax silk 5-10 parts thin, 1-3 parts of toughener, 10-15 parts of K resin, cleaning 30-50 parts of water;
Step 2: calcium carbonate, oil, thin sawdust, epoxy resin, thin flax silk are mixed, in addition clean water stirs 5-8 minutes To mixture a;
Step 3: the styrene of the amount, vegetable silk, zinc stearate, K resin are first carried out ball milling, then send close In mill or kneader at 65 DEG C -75 DEG C mixing or mediate 15-20 minute, finally discharge, it is cooling, broken, obtain mixture b;
Step 4: mixture b is transposed in reactor, butadiene-benzene is slowly added into after being warming up to 105 DEG C -115 DEG C Ethylene copolymer stirs with being kneaded 12-18 minutes, obtains mixture c;
Step 5: after starch, carbon dust, sodium bentonite, toughener are mixed, be added the obtained mixture a of step 2 and The mixture c that step 4 obtains;
Step 6: being stirred evenly after the mixture addition clean water obtained to step 5 with blender, the speed of stirring is 1800r/min stirs 8-10min;
It is squeezed Step 7: carrying out melting at 110 DEG C -115 DEG C into the mixture investment extruder that step 6 stirs evenly Out, the vegetable fiber environmental protection material is obtained after drying.
Further, the oil is the mixture of one of paraffin oil, naphthenic oil or both.
Further, the plant fiber is cotton fiber, silk fiber, bamboo fibre, tossa, one in ramee Kind.
Further, the temperature melted in extruder described in step 7 is 110 DEG C.
Further, first stage injection pressure is 90bar, second stage injection pressure in extruder described in step 7 Power is 80bar, and phase III injection pressure is 70bar.
Further, the pressure kept in the step 7 is 80bar, and being kept for the time of pressure is 4 seconds, when described cooling Between be 20 seconds.
Using technical solution of the present invention, preparation step is reasonable, and convenient for operation, process is free from environmental pollution, and prepares Synthesis vegetable fiber environmental protection material out is heat-resisting, wear-resisting property is good, and toughness is strong, long service life.Suitable for promoting, by former material Vegetable silk is added in material, so that material is more environmentally-friendly, and vegetable fiber environmental protection material has the effect of that intensity is high.
Specific embodiment
To be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, below with reference to Specific embodiment, the present invention is further explained.
Embodiment 1:
A kind of vegetable fiber environmental protection material, in parts by mass, the vegetable fiber environmental protection material include butadiene-styrene 8 parts of copolymer, 2 parts of styrene, 12 parts of vegetable silk, 0.5 part of zinc stearate, 8 parts of sodium bentonite, 3 parts of starch, carbon dust 6 parts, 5 parts of calcium carbonate, 2 parts of oil, 1 part of thin sawdust, 10 parts of epoxy resin, 1 part of toughener, 10 parts of K resin, 5 parts of thin flax silk, cleaning 30 parts of water.
A method of preparing above-mentioned vegetable fiber environmental protection material, the preparation method specifically includes the following steps:
Step 1: as requested prepare 8 parts of butadiene-styrene copolymer, 2 parts of styrene, 12 parts of vegetable silk, 0.5 part of zinc stearate, 8 parts of sodium bentonite, 3 parts of starch, 6 parts of carbon dust, 5 parts of calcium carbonate, oily 2 parts, 1 part of thin sawdust, asphalt mixtures modified by epoxy resin 10 parts of rouge, 1 part of toughener, 10 parts of K resin, 5 parts of thin flax silk, 30 parts of clean water;
Step 2: calcium carbonate, oil, thin sawdust, epoxy resin, thin flax silk are mixed, obtained in addition clean water stirs 5 minutes Mixture a;
Step 3: the styrene of the amount, vegetable silk, zinc stearate, K resin are first carried out ball milling, then send close In mill or kneader at 65 DEG C mixing or mediate 15 minutes, finally discharging, it is cooling, broken, obtain mixture b;
Step 4: mixture b is transposed in reactor, it is total that butadiene-styrene is slowly added into after being warming up to 105 DEG C Polymers stirs with being kneaded 12 minutes, obtains mixture c;
Step 5: after starch, carbon dust, sodium bentonite, toughener are mixed, be added the obtained mixture a of step 2 and The mixture c that step 4 obtains;
Step 6: being stirred evenly after the mixture addition clean water obtained to step 5 with blender, the speed of stirring is 1800r/min stirs 8min;
Step 7: melting extrusion is carried out at 110 DEG C into the mixture investment extruder that step 6 stirs evenly, it is dry After obtain the vegetable fiber environmental protection material.
Further, the oil is the mixture of one of paraffin oil, naphthenic oil or both.
Further, the plant fiber is cotton fiber, silk fiber, bamboo fibre, tossa, one in ramee Kind.
Further, the temperature melted in extruder described in step 7 is 110 DEG C.
Further, first stage injection pressure is 90bar, second stage injection pressure in extruder described in step 7 Power is 80bar, and phase III injection pressure is 70bar.
Embodiment 2:
A kind of vegetable fiber environmental protection material, in parts by mass, the vegetable fiber environmental protection material include butadiene-styrene 0 part of copolymer 1,4 parts of styrene, 18 parts of vegetable silk, 1 part of zinc stearate, 12 parts of sodium bentonite, 4 parts of starch, carbon dust 10 parts, 15 parts of calcium carbonate, oil 5 parts, 5 parts of thin sawdust, 20 parts of epoxy resin, 3 parts of toughener, 15 parts of K resin, 10 parts of thin flax silk, 50 parts of clean water.
A method of preparing above-mentioned vegetable fiber environmental protection material, the preparation method specifically includes the following steps:
Step 1: preparing 10 parts of butadiene-styrene copolymer, 4 parts of styrene, vegetable silk 18 as requested Part, 1 part of zinc stearate, 12 parts of sodium bentonite, 4 parts of starch, 10 parts of carbon dust, 15 parts of calcium carbonate, oily 5 parts, 5 parts of thin sawdust, ring 20 parts of oxygen resin, 3 parts of toughener, 15 parts of K resin, 10 parts of thin flax silk, 50 parts of clean water;
Step 2: calcium carbonate, oil, thin sawdust, epoxy resin, thin flax silk are mixed, obtained in addition clean water stirs 8 minutes Mixture a;
Step 3: the styrene of the amount, vegetable silk, zinc stearate, K resin are first carried out ball milling, then send close In mill or kneader at 75 DEG C mixing or mediate 20 minutes, finally discharging, it is cooling, broken, obtain mixture b;
Step 4: mixture b is transposed in reactor, it is total that butadiene-styrene is slowly added into after being warming up to 115 DEG C Polymers stirs with being kneaded 18 minutes, obtains mixture c;
Step 5: after starch, carbon dust, sodium bentonite, toughener are mixed, be added the obtained mixture a of step 2 and The mixture c that step 4 obtains;
Step 6: being stirred evenly after the mixture addition clean water obtained to step 5 with blender, the speed of stirring is 1800r/min stirs 10min;
Step 7: melting extrusion is carried out at 115 DEG C into the mixture investment extruder that step 6 stirs evenly, it is dry After obtain the vegetable fiber environmental protection material.
Further, the oil is the mixture of one of paraffin oil, naphthenic oil or both.
Further, the plant fiber is cotton fiber, silk fiber, bamboo fibre, tossa, one in ramee Kind.
Further, the temperature melted in extruder described in step 7 is 110 DEG C.
Further, first stage injection pressure is 90bar, second stage injection pressure in extruder described in step 7 Power is 80bar, and phase III injection pressure is 70bar.
Further, the pressure kept in the step 7 is 80bar, and being kept for the time of pressure is 4 seconds, when described cooling Between be 20 seconds.
Embodiment 3:
A kind of vegetable fiber environmental protection material, in parts by mass, the vegetable fiber environmental protection material include butadiene-styrene 9 parts of copolymer, 3 parts of styrene, 15 parts of vegetable silk, 0.6 part of zinc stearate, 9 parts of sodium bentonite, 3.5 parts of starch, carbon It is 8 parts of powder, 9 parts of calcium carbonate, 4 parts of oil, 3 parts of thin sawdust, 15 parts of epoxy resin, 2 parts of toughener, 13 parts of K resin, 7 parts of thin flax silk, clear 45 parts of clean water.
A method of preparing above-mentioned vegetable fiber environmental protection material, the preparation method specifically includes the following steps:
Step 1: as requested prepare 9 parts of butadiene-styrene copolymer, 3 parts of styrene, 15 parts of vegetable silk, 0.6 part of zinc stearate, 9 parts of sodium bentonite, 3.5 parts of starch, 8 parts of carbon dust, 9 parts of calcium carbonate, oily 4 parts, 3 parts of thin sawdust, epoxy 15 parts of resin, 2 parts of toughener, 13 parts of K resin, 7 parts of thin flax silk, 45 parts of clean water;
Step 2: calcium carbonate, oil, thin sawdust, epoxy resin, thin flax silk are mixed, obtained in addition clean water stirs 7 minutes Mixture a;
Step 3: the styrene of the amount, vegetable silk, zinc stearate, K resin are first carried out ball milling, then send close In mill or kneader at 70 DEG C mixing or mediate 18 minutes, finally discharging, it is cooling, broken, obtain mixture b;
Step 4: mixture b is transposed in reactor, it is total that butadiene-styrene is slowly added into after being warming up to 110 DEG C Polymers stirs with being kneaded 16 minutes, obtains mixture c;
Step 5: after starch, carbon dust, sodium bentonite, toughener are mixed, be added the obtained mixture a of step 2 and The mixture c that step 4 obtains;
Step 6: being stirred evenly after the mixture addition clean water obtained to step 5 with blender, the speed of stirring is 1800r/min stirs 9min;
Step 7: melting extrusion is carried out at 113 DEG C into the mixture investment extruder that step 6 stirs evenly, it is dry After obtain the vegetable fiber environmental protection material.
Further, the oil is the mixture of one of paraffin oil, naphthenic oil or both.
Further, the plant fiber is cotton fiber, silk fiber, bamboo fibre, tossa, one in ramee Kind.
Further, the temperature melted in extruder described in step 7 is 110 DEG C.
Further, first stage injection pressure is 80bar, second stage injection pressure in extruder described in step 7 Power is 80bar, and phase III injection pressure is 70bar.
Further, the pressure kept in the step 7 is 80bar, and being kept for the time of pressure is 6 seconds, when described cooling Between be 20 seconds.
Using technical solution of the present invention, preparation step is reasonable, and convenient for operation, process is free from environmental pollution, and prepares Synthesis vegetable fiber environmental protection material out is heat-resisting, wear-resisting property is good, and toughness is strong, long service life.Suitable for promoting, by former material Vegetable silk is added in material, so that material is more environmentally-friendly, and vegetable fiber environmental protection material has the effect of that intensity is high.
Obviously present invention specific implementation is not subject to the restrictions described above, as long as using method concept and skill of the invention The improvement for the various unsubstantialities that art scheme carries out, or not improved the conception and technical scheme of the invention are directly applied to it Its occasion, it is within the scope of the present invention.

Claims (8)

1. a kind of vegetable fiber environmental protection material, which is characterized in that in parts by mass, the vegetable fiber environmental protection material includes fourth two Alkene -8-10 parts of styrol copolymer, 2-4 parts of styrene, 12-18 parts of vegetable silk, 0.5-1 parts of zinc stearate, sodium base are swollen Moisten 8-12 parts of soil, 3-4 parts of starch, 6-10 parts of carbon dust, 5-15 parts of calcium carbonate, 2-5 parts of oil, sawdust 1-5 parts thin, epoxy resin 10- 20 parts, 1-3 parts of toughener, 10-15 parts of K resin, it is flax silk 5-10 parts thin, 30-50 parts of clean water.
2. a kind of vegetable fiber environmental protection material according to claim 1, it is characterised in that: in parts by mass, the plant Fiber environmental material includes 10 parts of butadiene-styrene copolymer, 3 parts of styrene, 15 parts of vegetable silk, zinc stearate 0.8 part, 10 parts of sodium bentonite, 4 parts of starch, 8 parts of carbon dust, 10 parts of calcium carbonate, oil 3 parts, 3 parts of thin sawdust, 15 parts of epoxy resin, 2 parts of toughener, 12 parts of K resin, 8 parts of thin flax silk, 40 parts of clean water.
3. a kind of method for preparing vegetable fiber environmental protection material described in claim 1-2 any one, which is characterized in that described Preparation method specifically includes the following steps:
Step 1: preparing butadiene-styrene copolymer 8-10 parts, 2-4 parts of styrene, vegetable silk 12- as requested 18 parts, 0.5-1 parts of zinc stearate, 8-12 parts of sodium bentonite, 3-4 parts of starch, 6-10 parts of carbon dust, 5-15 parts of calcium carbonate, oil 2-5 Part, sawdust 1-5 parts thin, 10-20 parts of epoxy resin, flax silk 5-10 parts thin, 1-3 parts of toughener, 10-15 parts of K resin, clean water 30-50 parts;
Step 2: calcium carbonate, oil, thin sawdust, epoxy resin, thin flax silk are mixed, mixed in addition clean water stirs 5-8 minutes Close object a;
Step 3: first carrying out ball milling, then sending mixer the styrene of the amount, vegetable silk, zinc stearate, K resin In kneader at 65 DEG C -75 DEG C mixing or mediate 15-20 minute, finally discharge, it is cooling, broken, obtain mixture b;
Step 4: mixture b is transposed in reactor, butadiene-styrene is slowly added into after being warming up to 105 DEG C -115 DEG C Copolymer stirs with being kneaded 12-18 minutes, obtains mixture c;
Step 5: the mixture a and step that step 2 obtains is added after starch, carbon dust, sodium bentonite, toughener are mixed Four obtained mixture c;
Step 6: being stirred evenly after the mixture addition clean water obtained to step 5 with blender, the speed of stirring is 1800r/min stirs 8-10min;
Step 7: carrying out melting extrusion at 110 DEG C -115 DEG C into the mixture investment extruder that step 6 stirs evenly, do The vegetable fiber environmental protection material is obtained after dry.
4. a kind of vegetable fiber environmental protection material according to claim 1, it is characterised in that: the oil is paraffin oil, cycloalkanes The mixture of one of oil or both.
5. a kind of vegetable fiber environmental protection material according to claim 1, it is characterised in that: the vegetable silk is cotton One of flower fiber, silk fiber, bamboo fibre, tossa, ramee.
6. a kind of preparation method of vegetable fiber environmental protection material according to claim 3, it is characterised in that: institute in step 7 The temperature melted in the extruder stated is 110 DEG C.
7. a kind of preparation method for synthesizing vegetable fiber environmental protection material according to claim 6, it is characterised in that: step 7 Described in extruder in first stage injection pressure be 90bar, second stage injection pressure be 80bar, the phase III injection Pressure is 70bar.
8. a kind of preparation method for synthesizing vegetable fiber environmental protection material according to claim 6, it is characterised in that: the step The pressure kept in rapid seven is 80bar, and being kept for the time of pressure is 4 seconds, and the cooling time is 20 seconds.
CN201810930679.2A 2018-08-15 2018-08-15 A kind of vegetable fiber environmental protection material and preparation method thereof Pending CN108929550A (en)

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Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001051548A2 (en) * 2000-01-10 2001-07-19 Clopay Plastic Products Company, Inc. Antibacterial microporous film and method of making
CN101747644A (en) * 2008-12-16 2010-06-23 金发科技股份有限公司 Plant powder modified thermoplastic wood-plastic composite and preparation method and application
CN106867174A (en) * 2017-03-22 2017-06-20 合肥浦尔菲电线科技有限公司 A kind of environment-friendly materials and preparation method thereof
CN106883492A (en) * 2017-03-22 2017-06-23 合肥浦尔菲电线科技有限公司 A kind of synthesizing environment-friendly material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001051548A2 (en) * 2000-01-10 2001-07-19 Clopay Plastic Products Company, Inc. Antibacterial microporous film and method of making
CN101747644A (en) * 2008-12-16 2010-06-23 金发科技股份有限公司 Plant powder modified thermoplastic wood-plastic composite and preparation method and application
CN106867174A (en) * 2017-03-22 2017-06-20 合肥浦尔菲电线科技有限公司 A kind of environment-friendly materials and preparation method thereof
CN106883492A (en) * 2017-03-22 2017-06-23 合肥浦尔菲电线科技有限公司 A kind of synthesizing environment-friendly material and preparation method thereof

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Application publication date: 20181204