CN108929290A - A kind of furfural dehydration device - Google Patents

A kind of furfural dehydration device Download PDF

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Publication number
CN108929290A
CN108929290A CN201810911519.3A CN201810911519A CN108929290A CN 108929290 A CN108929290 A CN 108929290A CN 201810911519 A CN201810911519 A CN 201810911519A CN 108929290 A CN108929290 A CN 108929290A
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CN
China
Prior art keywords
dehydrating tower
pipeline
furfural
dehydration device
storage tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810911519.3A
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Chinese (zh)
Inventor
范子久
贺乾龙
王明志
李荣强
李昆
杜天正
吕印雨
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Henan Gran Energy Ltd By Share Ltd
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Henan Gran Energy Ltd By Share Ltd
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Publication date
Application filed by Henan Gran Energy Ltd By Share Ltd filed Critical Henan Gran Energy Ltd By Share Ltd
Priority to CN201810911519.3A priority Critical patent/CN108929290A/en
Publication of CN108929290A publication Critical patent/CN108929290A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/46Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48Furfural

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of furfural dehydration devices, furfural storage tank and dehydration device, it is characterized by: dehydration device includes taking out aldehyde pump, dehydrator and raw material storage tank, dehydrator includes dehydrating tower one and dehydrating tower two, inorganic filler layer is filled with inside dehydrating tower one and dehydrating tower two, furfural storage tank is connected by pipeline with aldehyde pump is taken out, aldehyde pump is taken out to be connected by pipeline with one lower end of dehydrating tower, the upper end of dehydrating tower one is connected by pipeline with the lower end of dehydrating tower two, the upper end of dehydrating tower two is connected by pipeline with raw material storage tank, structure of the invention is reasonable, it is easy to use, the method absorbed by the dehydration of inorganic filler physics, the reduction furfural moisture being simple and efficient, improve furfural content, the inorganic filler repeated reproducibility of dehydration is set to utilize by filler regenerating unit simultaneously, in the product matter for improving furfural It measures while effectively reducing production cost.

Description

A kind of furfural dehydration device
Technical field
The present invention relates to furfural production technical fields, and in particular to a kind of furfural dehydration device.
Background technique
During furfural production, hair aldehyde purification, it is necessary first under vacuum conditions, be carried out using the difference of each component boiling point Dehydration, the principle for recycling furfural-water to form azeotropic is further dehydrated, by continuously flowing back, to obtain qualified chaff Aldehyde product, therefore the water content of furfural is to evaluate the important indicator of furfural grade, water content is fewer, and the higher grade of furfural, and By existing increasing reflux ratio, extending the techniques such as purification production time can improve the water content of a reduction furfural, but this work The loss of skill furfural can increase, and influence refining rate, and increase production cost.
Summary of the invention
The technical problem to be solved in the present invention is to provide furfurals a kind of easy to use, that dehydration efficiency is high and input cost is few Dehydration device.
To realize above-mentioned target, the technical solution of the present invention is as follows: a kind of furfural dehydration device, including furfural storage tank and de- Water installations, it is characterised in that: dehydration device includes that pumping aldehyde pump, dehydrator and raw material storage tank, dehydrator include one He of dehydrating tower Inorganic filler layer is filled with inside dehydrating tower two, dehydrating tower one and dehydrating tower two, furfural storage tank pumps phase with aldehyde is taken out by pipeline Connection takes out aldehyde pump and is connected by pipeline with one lower end of dehydrating tower, and the upper end of dehydrating tower one passes through pipeline and dehydrating tower two Lower end be connected, the upper end of dehydrating tower two is connected by pipeline with raw material storage tank.
Further, dehydration device further includes having the second dehydrator, and the second dehydrator includes dehydrating tower three and dehydrating tower four, It is filled with inorganic filler layer inside dehydrating tower three and dehydrating tower four, takes out aldehyde pump and is connected by pipeline with three lower end of dehydrating tower, The upper end of dehydrating tower three is connected by pipeline with the lower end of dehydrating tower four, and the upper end of dehydrating tower four passes through pipeline and original Material storage tank is connected.
Further, the height between furfural storage tank and ground is greater than the height between dehydration device and ground.
Further, it takes out the pipeline between the pipeline between aldehyde pump and dehydrating tower one, dehydrating tower one and dehydrating tower two, be dehydrated Between pipeline, pumping aldehyde pump between tower two and raw material storage tank and the pipeline between dehydrating tower three, dehydrating tower three and dehydrating tower four Pipeline, be respectively arranged with control valve on the pipeline between dehydrating tower four and raw material storage tank.
Further, inorganic filler layer is to be respectively arranged in dehydrating tower one, dehydrating tower two, dehydrating tower three and dehydrating tower four The sieve plate of portion's upper/lower terminal and the inorganic filler being set between sieve plate.
Further, inorganic filler is made of the silica gel and active carbon that mixed proportion is 1:1.
Further, dehydration device further includes having filler regenerating unit, and filler regenerating unit includes gas source, surge tank, wind Machine and gas heater, gas source are connected to by pipeline with surge tank item, and exhaust fan is added with surge tank and gas respectively by pipeline Hot device is connected, gas heater by be provided with the pipeline of pipeline valve respectively with blower, the bottom of dehydrating tower one, dehydrating tower Two bottom, the bottom of dehydrating tower three are connected with four bottom of dehydrating tower, dehydrating tower one, dehydrating tower two, dehydrating tower three and dehydration It is respectively arranged with outlet pipe at the top of tower four, the first control valve is provided on outlet pipe.
Further, it is provided with second pipe valve on the pipeline between pipeline valve and heated gas heats device, buffers Tank is connected by the pipeline being provided between the pipeline of third pipeline valve and pipeline valve and second pipe valve.
Structure of the invention is reasonable, easy to use, and the method absorbed by the dehydration of inorganic filler physics can effectively reduce The moisture of furfural, corresponding to furfural aldehyde contenting amount can increase on the basis of the original, and the reduction furfural moisture that is simple and efficient mentions High furfural content, while so that the inorganic filler repeated reproducibility of dehydration is utilized by filler regenerating unit, improving chaff The product quality of aldehyde effectively reduces production cost simultaneously.
Detailed description of the invention
Fig. 1 the structural representation of present invention.
Drawing explanation: 1, furfural storage tank, 2, take out aldehyde pump, 3, raw material storage tank, 4, dehydrating tower one, 5, dehydrating tower two, 6, Dehydrating tower three, 7, dehydrating tower four, 8, control valve, 9, surge tank, 10, blower, 11, gas heater, 12, pipeline valve, 13, Two pipeline valves, 14, third pipeline valve, the 15, first control valve.
Specific embodiment
In the description of the present invention, it is to be understood that, term " longitudinal direction ", " transverse direction ", "upper", "lower", "front", "rear", The orientation or positional relationship of the instructions such as "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is based on attached drawing institute The orientation or positional relationship shown is merely for convenience of the description present invention, rather than the device or element of indication or suggestion meaning must There must be specific orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.
In conjunction with attached drawing, the technical schemes of the invention are described in detail, a kind of furfural dehydration device, including furfural storage tank 1 and de- Water installations, dehydration device include that pumping aldehyde pump 2, dehydrator and raw material storage tank 3, dehydrator include dehydrating tower 1 and dehydrating tower two 5, inorganic filler layer is filled with inside dehydrating tower one and dehydrating tower two, furfural storage tank is connected by pipeline with aldehyde pump is taken out, pumping Aldehyde pump is connected by pipeline with one lower end of dehydrating tower, and the upper end of dehydrating tower one passes through the lower end of pipeline and dehydrating tower two It is connected, the upper end of dehydrating tower two is connected by pipeline with raw material storage tank, when needing to further decrease in furfural stoste Moisture, when being further processed to furfural stoste, furfural stoste in furfural storage tank is pumped by taking out aldehyde and is pumped into furfural stoste The height being greater than the height between furfural storage tank and ground between dehydration device and ground may be selected in one bottom of dehydrating tower at this time Degree, makes furfural storage tank position integrally be higher than dehydration device, using gravitational effects, the pumping aldehyde of smaller power can be used to pump to furfural Stoste is extracted, and when furfural stoste enters inorganic filler layer, the moisture contained in furfural stoste is passed through by inorganic filler layer Physical method absorption, the furfural stoste after dehydrated is flowed out from the upper end of dehydrating tower one, in order to further decrease furfural Moisture in stoste enters the bottom with the concatenated dehydrating tower two of dehydrating tower one from the furfural stoste in dehydrating tower one, and furfural is former Liquid is using the inorganic filler layer second dehydration in dehydrating tower two, and furfural stoste after second dehydration is from the upper of dehydrating tower two It finally flows into after the outflow of end into raw material storage tank, furfural stoste further reduced chaff by the twice dehydration of dehydrator The content of moisture in aldehyde.
When in dehydrator inorganic filler layer using after a certain period of time water suction reach saturation, can not continue to furfural stoste into Row dehydration, at this time in order not to stop production while again can to furfural stoste carry out uninterruptedly be dehydrated, can be dehydrated dress Set the second dehydrator of middle installation, the second dehydrator includes dehydrating tower 36 and dehydrating tower 47, inside dehydrating tower three and dehydrating tower four Filled with inorganic filler layer, takes out aldehyde pump and be connected by pipeline with three lower end of dehydrating tower, the upper end of dehydrating tower three passes through pipe Road is connected with the lower end of dehydrating tower four, and the upper end of dehydrating tower four is connected by pipeline with raw material storage tank, works as dehydration Inorganic filler layer adsorption saturation in device one can not stop the supply to the furfural stoste of dehydrator, at this time when continuing absorption It is dehydrated in the dehydrating tower three and dehydrating tower four that furfural stoste can be each led into the second dehydrator, the chaff after final dewatering Aldehyde enters in raw material storage tank, when the second dehydrator is dehydrated furfural stoste, can carry out to the inorganic filler layer in dehydrator Replacement is dehydrated by the alternating of dehydrator and the second dehydrator, has achieved the purpose that furfural stoste is uninterruptedly dehydrated, inorganic filler Layer can be to be respectively arranged at dehydrating tower one, the sieve plate of four inside upper/lower terminal of dehydrating tower two, dehydrating tower three and dehydrating tower and setting Inorganic filler between sieve plate facilitates the replacement of filler.
During being dehydrated to furfural stoste, facilitate the direction of feed of control furfural stoste and later to the maintenance of equipment Maintenance, and achieve the purpose that dehydrator and the second dehydrator are used alternatingly, the pipe between aldehyde pump and dehydrating tower one can taken out at this time Pipeline, dehydrating tower two between road, dehydrating tower one and dehydrating tower two and the pipeline between raw material storage tank take out aldehyde pump and dehydrating tower Divide on pipeline between pipeline, dehydrating tower three between three and the pipeline between dehydrating tower four, dehydrating tower four and raw material storage tank It is not provided with control valve 8, when dehydrator can close the control valve taken out between aldehyde pump and dehydrating tower three on pipeline in the process of running, When dehydrator two can close the control valve taken out between aldehyde pump and dehydrating tower one on pipeline in the process of running, realize dehydrator and The purpose that second dehydrator is used alternatingly.
It is not available then, needs replacing, replacement inorganic filler will increase after inorganic filler is to furfural stoste dehydration saturation Production cost reaches the recycling of inorganic filler to reduce production cost, can install filler additional again in dehydration device at this time Generating apparatus, filler regenerating unit include gas source, surge tank 9, blower 10 and gas heater 11, and gas source passes through pipeline and surge tank Item connection, exhaust fan are connected with surge tank and gas heater respectively by pipeline, and gas heater is by being provided with pipeline The pipeline of valve 12 respectively with blower, the bottom of dehydrating tower one, the bottom of dehydrating tower two, the bottom of dehydrating tower three and dehydrating tower four Bottom is connected, and is respectively arranged with outlet pipe, escape pipe at the top of dehydrating tower one, dehydrating tower two, dehydrating tower three and dehydrating tower four It is provided with the first control valve 15 on road, stops working after the inorganic filler in dehydrator reaches water suction saturation, at dehydrator two In the dehydrating operation state to furfural stoste, gas source is passed through surge tank at this time, gas source preferred property is stable, without dangerous and source Extensive nitrogen, while opening blower, dehydrating tower one, the pipeline valve on dehydrating tower two and dehydrating tower one and the top of dehydrating tower two First control valve of the outlet pipe in portion, the gas in surge tank are pumped into gas heater by blower, and gas heater will It is respectively enterd in dehydrating tower one and dehydrating tower two after gas heating from pipeline valve, the high-temperature gas heated by heater is by nothing Moisture in machine filler is heated into vapor, and the vapor after separating with inorganic filler passes through two top of dehydrating tower one and dehydrating tower Outlet pipe in be discharged, the regeneration of inorganic filler is realized, when needing to dehydrating tower three in the second dehydrator and de- When inorganic filler in water tower four is regenerated, the regenerated usage mode of inorganic filler in dehydrator is repeated, it is de- to second Hydrophone is dehydrated, and inorganic filler is regenerated, and after filler natural cooling, can carry out the work being dehydrated to furfural stoste.
During cooling after filler regeneration, because high-temperature gas is cold by needing to carry out dehydrator behind dehydrator inside But, often cooling time is longer, influences efficiency, and during cooling, in filler moisture become after vapor because the time compared with Length can become again water adsorption in inorganic filler, and the effect for causing inorganic filler to be dehydrated absorption again is poor, at this time in pipe Second pipe valve 13 is provided on pipeline between road valve and heated gas heats device, surge tank is by being provided with third pipe Pipeline between the pipeline of road valve 14 and pipeline valve and second pipe valve is connected, in the cooling process of inorganic filler In, the second pipe valve in gas heater is closed, and is stopped the gas of conveying heating, and open third pipeline valve, is made to delay It rushes the gas at normal temperature in tank to be directly blown into dehydrator or the second dehydrator, by gas at normal temperature respectively to dehydrating tower one, de- Water tower two, dehydrating tower three and dehydrating tower four brush, and accelerate the cooling of inorganic filler, reduce the cooling of inorganic filler Time, the cooling efficiency of inorganic filler is improved, while improving the reproduction quality of inorganic filler.
Because of inorganic oxide substance of the furfural stoste in entering dehydrator or the second dehydrator dehydration, in inorganic filler Chemically reacted with furfural stoste, furfural caused to darken, influence the quality of furfural, in order to avoid or reduce because of oxide Darken caused by being chemically reacted with furfural, thus inorganic filler may be selected by mixed proportion be 1:1 silica gel and The inorganic filler of active carbon composition makes furfural color not change.
Basic principle of the invention, main feature and advantage has been shown and described above, do not depart from spirit of that invention and Under the premise of range, there are also various changes and modifications, these changes and improvements to both fall within claimed invention by the present invention Range.

Claims (8)

1. a kind of furfural dehydration device, including furfural storage tank and dehydration device, it is characterised in that: dehydration device includes taking out aldehyde Pump, dehydrator and raw material storage tank, dehydrator include dehydrating tower one and dehydrating tower two, are filled inside dehydrating tower one and dehydrating tower two There is inorganic filler layer, furfural storage tank is connected by pipeline with aldehyde pump is taken out, and is taken out aldehyde pump and is passed through pipeline and one lower end of dehydrating tower It is connected, the upper end of dehydrating tower one is connected by pipeline with the lower end of dehydrating tower two, and the upper end of dehydrating tower two passes through Pipeline is connected with raw material storage tank.
2. a kind of furfural dehydration device according to claim 1, it is characterised in that: dehydration device further includes having the second dehydration Device, the second dehydrator include dehydrating tower three and dehydrating tower four, are filled with inorganic filler layer inside dehydrating tower three and dehydrating tower four, take out Aldehyde pump is connected by pipeline with three lower end of dehydrating tower, and the upper end of dehydrating tower three passes through the lower end of pipeline and dehydrating tower four It is connected, the upper end of dehydrating tower four is connected by pipeline with raw material storage tank.
3. a kind of furfural dehydration device according to claim 1 or 2, it is characterised in that: between furfural storage tank and ground Height be greater than height between dehydration device and ground.
4. a kind of furfural dehydration device according to claim 2, it is characterised in that: take out the pipe between aldehyde pump and dehydrating tower one Pipeline, dehydrating tower two between road, dehydrating tower one and dehydrating tower two and the pipeline between raw material storage tank take out aldehyde pump and dehydrating tower Divide on pipeline between pipeline, dehydrating tower three between three and the pipeline between dehydrating tower four, dehydrating tower four and raw material storage tank Control valve is not provided with it.
5. a kind of furfural dehydration device according to claim 2, it is characterised in that: inorganic filler layer is de- to be respectively arranged at Water tower one, four inside upper/lower terminal of dehydrating tower two, dehydrating tower three and dehydrating tower sieve plate and be set between sieve plate inorganic fill out Material.
6. a kind of furfural dehydration device according to claim 5, it is characterised in that: inorganic filler is 1:1 by mixed proportion Silica gel and active carbon composition.
7. a kind of furfural dehydration device according to claim 2, it is characterised in that: dehydration device further includes having filler regeneration Device, filler regenerating unit include gas source, surge tank, blower and gas heater, and gas source is connected to by pipeline with surge tank item, Exhaust fan is connected with surge tank and gas heater respectively by pipeline, and gas heater is by being provided with the pipe of pipeline valve Road is connected with blower, the bottom of dehydrating tower one, the bottom of dehydrating tower two, the bottom of dehydrating tower three and four bottom of dehydrating tower respectively It is logical, it is respectively arranged with outlet pipe at the top of dehydrating tower one, dehydrating tower two, dehydrating tower three and dehydrating tower four, is arranged on outlet pipe There is the first control valve.
8. a kind of furfural dehydration device according to claim 2, it is characterised in that: pipeline valve and heated gas heats device Between pipeline on be provided with second pipe valve, surge tank by be provided with third pipeline valve pipeline and pipeline valve and Pipeline between second pipe valve is connected.
CN201810911519.3A 2018-08-12 2018-08-12 A kind of furfural dehydration device Pending CN108929290A (en)

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CN201810911519.3A CN108929290A (en) 2018-08-12 2018-08-12 A kind of furfural dehydration device

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CN201810911519.3A CN108929290A (en) 2018-08-12 2018-08-12 A kind of furfural dehydration device

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202030684U (en) * 2011-03-23 2011-11-09 昌图县糠醛厂 Continuous refining device for furfural
CN104128015A (en) * 2014-08-19 2014-11-05 衡水中科信能源有限公司 Furfural continuous rectification device and process
CN204307379U (en) * 2014-12-04 2015-05-06 子洲县元嘉糠醛生产销售有限公司 A kind of furfuryl alcohol dewater unit
CN105461669A (en) * 2015-12-28 2016-04-06 山西恒宇生物科技有限公司 Dehydration and deacidification device for refining furfural and refining process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202030684U (en) * 2011-03-23 2011-11-09 昌图县糠醛厂 Continuous refining device for furfural
CN104128015A (en) * 2014-08-19 2014-11-05 衡水中科信能源有限公司 Furfural continuous rectification device and process
CN204307379U (en) * 2014-12-04 2015-05-06 子洲县元嘉糠醛生产销售有限公司 A kind of furfuryl alcohol dewater unit
CN105461669A (en) * 2015-12-28 2016-04-06 山西恒宇生物科技有限公司 Dehydration and deacidification device for refining furfural and refining process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘迎新 等: "果糖脱水制备5-羟甲基糠醛及分离纯化" *

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Application publication date: 20181204