CN108929106A - A kind of compound heat-insulation Ceramic Tiles - Google Patents
A kind of compound heat-insulation Ceramic Tiles Download PDFInfo
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- CN108929106A CN108929106A CN201811015014.5A CN201811015014A CN108929106A CN 108929106 A CN108929106 A CN 108929106A CN 201811015014 A CN201811015014 A CN 201811015014A CN 108929106 A CN108929106 A CN 108929106A
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- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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Abstract
The present invention relates to a kind of compound heat-insulation Ceramic Tiles, belong to building ceramics field.The present invention is using lignite as raw material, lignite is pyrolyzed under the high temperature conditions can produce tar and coke ingredient, fill sintered brick body internal void effectively, nano aluminium oxide is positively charged, with the negatively charged carry out antagonism of institute in soybean lecithin, the dispersion effect of system component is greatly improved, also can provide good thermal stability, improves heat insulation；It is ground by raw material of vermiculite, surfactant intercalated processing, open its interlamellar spacing, form organic-pillared vermiculite, filling is formed by skeleton with composite modified vermiculite, influences with temperature suffered by system and the metal salt in system, and whisker increases, part is reunited, and can further enhance whole heat-proof quality.The present invention solves the problems, such as that the heat-proof quality of common Ceramic Tiles at present is bad.
Description
Technical field
The present invention relates to a kind of compound heat-insulation Ceramic Tiles, belong to building ceramics field.
Background technique
Ceramic Tiles are by clay, quartz sand and other inorganic non-metallic raw materials, through ingredient, ball milling, powder processed, molding, burning
The plate or Bulk ceramic product of the techniques such as knot production are widely used in the metope and ground of decoration with protection building, structures
Face.With the rapid development of real estate, so that the production and consumption of ceramic tile is all got a larger development, while to ceramic tile
Performance requirement is also higher and higher.However Ceramic Tiles thermal coefficient currently on the market is higher, heat insulating effect is poor, is not used to
Heat preservation and decoration of outer wall.
Summary of the invention
The technical problems to be solved by the invention: it for the bad problem of the heat-proof quality of current common Ceramic Tiles, provides
A kind of compound heat-insulation Ceramic Tiles.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of compound heat-insulation Ceramic Tiles, according to the mass fraction, including following component: 2 ~ 5 parts of brighteners, 20 ~ 40 parts of potassium feldspars, 10
~ 15 parts of lithium carbonates, further includes: 20 ~ 40 parts of compound heat-insulation ingredient A, 30 ~ 50 parts of compound heat-insulation ingredient B.
The preparation method of the compound heat-insulation ingredient A, includes the following steps:
(1) it taking lignite to pulverize and sieve, obtains brown coal powder, brown coal powder is taken to be passed through nitrogen, heat preservation pyrolysis, heating, heat preservation pyrolysis is cooling,
Discharging, must be pyrolyzed material, in 180 ~ 200 DEG C, according to parts by weight, take 20 ~ 40 parts of pyrolysis material, 8 ~ 12 parts of Petropols, 4 ~ 6 parts of terpenes
Olefine resin is stirred, cooling, and heat preservation obtains insulation material, takes insulation material 10:1 ~ 2:3:1 in mass ratio that microcrystalline cellulose, cream is added
Sugar, mannitol mixing, are added zirconium oxide ball milling pearl by ball 20 ~ 30:1 of material mass ratio, ball milling obtains ball milling material；
(2) based on quality portioning number, 40 ~ 60 parts of ball milling material, 15 ~ 30 parts of nano aluminium oxides, 3 ~ 8 parts of adjuvants, 6 ~ 10 portions of soybean are taken
Lecithin, 20 ~ 40 parts of ethanol solutions are mixed, and are evaporated under reduced pressure to get compound heat-insulation ingredient A.
Petropols in the step (1): any one in Petropols C5, C9.
Adjuvant in the step (2): 5:1 ~ 2 take hydroxyapatite, Os Sus domestica powder mixing to get adjuvant in mass ratio.
The preparation method of the compound heat-insulation ingredient B, includes the following steps:
S1. it takes vermiculite to pulverize and sieve, takes sieving particle 1:4 in mass ratio ~ 8 that water mixed grinding is added, abrasive is obtained, in 75 ~ 90
DEG C, take abrasive 1:10 ~ 15:3 in mass ratio ~ 5 that reagent, surfactant mixing, heat-insulation soaking is added, filtering takes filter
Cake washing, it is dry, PERFORMANCE OF MODIFIED VERMICULITE is obtained, takes PERFORMANCE OF MODIFIED VERMICULITE 3:40 ~ 60:1 in mass ratio ~ 2:0.01 that water, dispersing agent, dimethyl is added
Silicone oil mixing, shearing dispersion, high pressure homogenization obtains composite modified vermiculite, spare；
S2. 1:10 ~ 15 take carbide slag, water to be mixed in mass ratio, are evaporated under reduced pressure, and roast, cooling, obtain roasting material, take roasting
Expect that sodium carbonate liquor mixing is added in 1:5 in mass ratio ~ 10, obtains suspension, 1:10 ~ 15 in mass ratio take flyash, NaOH solution
It is mixed, obtains mixed liquid, take mixed liquid to filter, filtrate is taken to stand, take supernatant 1:2 in mass ratio ~ 5 that suspension is added in 50 ~ 70
DEG C mixing, heat preservation obtains slurry, takes slurries filtration, filter cake is taken to wash, dry, obtains carbide slag-flyash processed material；
S3. 5:1 ~ 3:0.1:15 ~ 20 take composite modified vermiculite, carbide slag-flyash processed material, polyvinylpyrrolidine in mass ratio
Ketone, water mixing, obtain mixed slurry, in 60 ~ 80 DEG C, take mixed slurry 10:1 in mass ratio ~ 2 that foaming agent is added and are mixed, i.e.,
Obtain compound heat-insulation ingredient B.
Reagent in the step S1: 6:1 ~ 2 take PBS buffer solution, dopamine mixing to get reagent in mass ratio.
Surfactant in the step S1: 5:1:1 ~ 2 take cetyl trimethylammonium bromide, laruyl alcohol in mass ratio
Polyethers sodium sulfovinate, sodium secondary alkyl sulfonate mixing are to get surfactant.
Dispersing agent in the step S1: 4:1 ~ 2:1 in mass ratio takes zinc stearate, polyethylene wax, titanium dioxide mixing, i.e.,
Obtain dispersing agent.
Foaming agent in the step S3: 4:1 ~ 2:0.01 in mass ratio takes rosin, wooden sodium sulfonate, kopol mixed
It closes to get foaming agent.
The brightener: in mass ratio 5:1:1 ~ 2 take propoxylation propilolic alcohol, sodium hypophosphite, sodium tungstate mixing to get
Brightener.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention is using lignite as raw material, and lignite is pyrolyzed under the high temperature conditions can produce tar and coke ingredient, and tar can be in brick
Play the role of bonding each powder in base pressing process, and during the sintering process, can be used as inside mobile phase enhancing system
Mobility fills sintered brick body internal void effectively, and nano aluminium oxide is positively charged, with institute in soybean lecithin
Negatively charged carry out antagonism, itself aluminium oxide itself have water imbibition, just with the lecithin of partially hydrophobic, in charge
It attracts each other under effect, reaching both to absorb water has reprimand hydraulic action, can play the role of controlling its internal minor amount of water when use, reach and mention
High inner Join power absorbs the effect of heat, the ultra-fine grain size of nano aluminium oxide and the control of distribution, greatly improves system
The dispersion effect of component also can provide good thermal stability, improve heat insulation；
(2) present invention is ground by raw material of vermiculite, and surfactant intercalated processing opens its interlamellar spacing, forms organic-pillared leech
Stone can form ceramic tile system skeleton, facilitate Multiple components under the action of the interaction of a variety of dispersing agents and physical mechanical power
Filling, composite modified vermiculite obtained preferably reduces its thermal coefficient, and when meeting high temperature action, microdilatancy effect can be fine
Reach heat insulation, using carbide slag, flyash as raw material, first to carbide slag carry out water logging, evaporation, baking operation, flyash
Dipping by lye processing, finally carries out hydrothermal synthesis method, and the calcium silicate whisker of system is one equidirectional for double three section linear chain structures
On metasilicic acid chain and 1 pass through Ca2+And OH-The CaO connected8Octahedral double three pitch chains are constituted, flat in length direction
Row is in b axis, and without intermediary water, only 2 hydroxyls are connected with the oxygen atom of oxygen-octahedron, filling and composite modified vermiculite institute shape
At skeleton, influenced with temperature suffered by system and the metal salt in system, whisker increases, part reunion, and can be further
The whole heat-proof quality of enhancing.
Specific embodiment
Petropols: any one in Petropols C5, C9.
Reagent: 6:1 ~ 2 take PBS buffer solution, dopamine that pH is 7.2 ~ 7.8 to mix to get reagent in mass ratio.
Dispersing agent: 4:1 ~ 2:1 in mass ratio takes zinc stearate, polyethylene wax, titanium dioxide mixing to get dispersing agent.
Adjuvant: 5:1 ~ 2 take hydroxyapatite, Os Sus domestica powder mixing to get adjuvant in mass ratio.
Surfactant: in mass ratio 5:1:1 ~ 2 take cetyl trimethylammonium bromide, laureth sodium sulfovinate,
Sodium secondary alkyl sulfonate mixes to get surfactant.
Foaming agent: 4:1 ~ 2:0.01 in mass ratio takes rosin, wooden sodium sulfonate, kopol mixing to get foaming agent.
Brightener: 5:1:1 ~ 2 take propoxylation propilolic alcohol, sodium hypophosphite, sodium tungstate mixing to get light in mass ratio
Agent.
The preparation method of compound heat-insulation ingredient A, includes the following steps:
(1) it takes lignite to sieve with 100 mesh sieve in pulverizer crushing, obtains brown coal powder, take brown coal powder in crucible, move into pyrolysis oven, with 100 ~
160mL/min rate is passed through nitrogen into furnace, and with 6 ~ 10 DEG C/min temperature programming to 550 ~ 650 DEG C, heat preservation 2 ~ 4h of pyrolysis continues
900 ~ 1000 DEG C are warming up to, heat preservation 3 ~ 5h of pyrolysis cools to room temperature with the furnace, discharges, must be pyrolyzed material, in 180 ~ 200 DEG C, by weight
Number meter takes 20 ~ 40 parts of pyrolysis material, 8 ~ 12 parts of Petropols, 4 ~ 6 parts of terpene resins in container, is stirred, naturally cools to
It 140 ~ 150 DEG C, keeps the temperature spare, obtains insulation material, take insulation material 10:1 ~ 2:3:1 in mass ratio that microcrystalline cellulose, lactose, sweet is added
Reveal alcohol in ball grinder mix, by ball 20 ~ 30:1 of material mass ratio addition zirconium oxide ball milling pearl, with 350 ~ 500r/min ball milling 30 ~
50min obtains ball milling material；
(2) based on quality portioning number, 40 ~ 60 parts of ball milling material, 15 ~ 30 parts of nano aluminium oxides, 3 ~ 8 parts of adjuvants, 6 ~ 10 portions of soybean are taken
The ethanol solution that lecithin, 20 ~ 40 parts of volume fractions are 70% is mixed in reaction kettle, 2 ~ 5h is stirred with 500 ~ 800r/min, in 60
~ 80 DEG C be evaporated under reduced pressure to constant weight to get compound heat-insulation ingredient A.
The preparation method of compound heat-insulation ingredient B, includes the following steps:
S1. it takes vermiculite to crushed 200 meshes, takes sieving particle 1:4 in mass ratio ~ 8 that distilled water mixing is added, in dispersion grinding machine
In with 2000 ~ 3000r/min grind 6 ~ 9h, obtain abrasive, in 75 ~ 90 DEG C, take abrasive 1:10 ~ 15:3 in mass ratio ~ 5 be added
Reagent B, surfactant mixing stir 5 ~ 8h, 2 ~ 5h of heat-insulation soaking with 400 ~ 600r/min, and filtering takes filter cake filter cake matter
After measuring 3 ~ 6 times of distillation water washings, in 65 ~ 80 DEG C of oven dryings to constant weight, PERFORMANCE OF MODIFIED VERMICULITE is obtained, takes PERFORMANCE OF MODIFIED VERMICULITE 3:40 in mass ratio
Distilled water, dispersing agent, dimethicone mixing is added in ~ 60:1 ~ 2:0.01, shears 3 ~ 5h of dispersion in 2000 ~ 3000r/min, high
Homogeneous 5 ~ 10min is pressed, composite modified vermiculite is obtained, it is spare；
S2. 1:10 ~ 15 take carbide slag, water to mix in container in mass ratio, after 400 ~ 600r/min magnetic agitation, 30 ~ 50min,
With 75 ~ 90 DEG C of evaporation under reduced pressure removed moisture to constant weight, Muffle furnace is moved to 500 ~ 600 DEG C of 3 ~ 5h of roasting, cools to room temperature with the furnace,
Roasting material is obtained, takes roasting material 1:5 in mass ratio ~ 10 that the sodium carbonate liquor mixing of mass fraction 20% is added, suspension is obtained, by matter
The NaOH solution mixing for taking flyash, concentration 0.01mol/L than 1:10 ~ 15 is measured, 20 ~ 45min is stirred with 400 ~ 600r/min, is obtained
Mixed liquid, takes mixed liquid to filter, filtrate is taken to be stored at room temperature 1 ~ 3h, takes supernatant 1:2 in mass ratio ~ 5 that suspension is added in 50 ~ 75 DEG C of water
The mixing of thermal response kettle, keeps the temperature 3 ~ 5h, obtains slurry, take slurries filtration, after taking 3 ~ 5 times of filter cake filter cake quality of distillation water washing,
70 ~ 90 DEG C of oven dryings are moved to constant weight, obtain carbide slag-flyash processed material；
S3. 5:1 ~ 3:0.1:15 ~ 20 take composite modified vermiculite, carbide slag-flyash processed material, polyvinylpyrrolidine in mass ratio
Ketone, water mixing, obtain mixed slurry, in 60 ~ 80 DEG C, take mixed slurry 10:1 in mass ratio ~ 2 that foaming agent mixing is added, with 800 ~
3 ~ 6h of 1000r/min insulated and stirred is to get compound heat-insulation ingredient B.
A kind of compound heat-insulation Ceramic Tiles, according to the mass fraction, including following component: 2 ~ 5 parts of brighteners, 20 ~ 40 parts of potassium are long
Stone, 10 ~ 15 parts of lithium carbonates, which is characterized in that further include: 20 ~ 40 parts of compound heat-insulation ingredient A, 30 ~ 50 parts of compound heat-insulation ingredient B.
A kind of preparation method of compound heat-insulation Ceramic Tiles, includes the following steps:
(1) according to the mass fraction, 2 ~ 5 parts of brighteners, 20 ~ 40 parts of potassium feldspars, 10 ~ 15 parts of lithium carbonates, 20 ~ 40 parts of compound heat-insulations are taken
Ingredient A, 30 ~ 50 parts of compound heat-insulation ingredient B；
(2) it in 65 ~ 80 DEG C, takes potassium feldspar, lithium carbonate, compound heat-insulation ingredient B to mix in reaction kettle, homogeneous 10 is rolled with 1 ~ 3MPa
~ 20min, after be cooled to 45 ~ 60 DEG C of addition compound heat-insulation ingredient A, brightener with 400 ~ 600r/min grind 20 ~ 40min, obtain base
Material, take base-material reverse mould brickmaking base, at 70 ~ 90 DEG C be dried in vacuo 20 ~ for 24 hours, obtain dry brick, take dry brick in its part table
After the glazing of face, it is put into liquefied gas kiln with 700 ~ 800 DEG C of 3 ~ 5h of sintering to get compound heat-insulation Ceramic Tiles.
Petropols: Petropols C5.
Reagent: 6:1 in mass ratio takes the PBS buffer solution that pH is 7.2, dopamine to mix to get reagent.
Dispersing agent: 4:1:1 in mass ratio takes zinc stearate, polyethylene wax, titanium dioxide mixing to get dispersing agent.
Adjuvant: 5:1 in mass ratio takes hydroxyapatite, Os Sus domestica powder mixing to get adjuvant.
Surfactant: 5:1:1 in mass ratio takes cetyl trimethylammonium bromide, laureth sodium sulfovinate, secondary
Sodium alkyl sulfonate mixes to get surfactant.
Foaming agent: 4:1:0.01 in mass ratio takes rosin, wooden sodium sulfonate, kopol mixing to get foaming agent.
Brightener: 5:1:1 in mass ratio takes propoxylation propilolic alcohol, sodium hypophosphite, sodium tungstate mixing to get light
Agent.
The preparation method of compound heat-insulation ingredient A, includes the following steps:
(1) it takes lignite to sieve with 100 mesh sieve in pulverizer crushing, obtains brown coal powder, take brown coal powder in crucible, move into pyrolysis oven, with
100mL/min rate is passed through nitrogen into furnace, and with 6 DEG C/min temperature programming to 550 DEG C, heat preservation pyrolysis 2h is continuously heating to 900
DEG C, heat preservation pyrolysis 3h cools to room temperature with the furnace, discharges, must be pyrolyzed material, in 180 DEG C, according to parts by weight, 20 parts of pyrolysis is taken to expect,
8 parts of Petropols, 4 parts of terpene resins are stirred in container, naturally cool to 140 DEG C, and heat preservation is spare, obtains insulation material, goes bail for
Temperature material 10:1:3:1 in mass ratio is added microcrystalline cellulose, lactose, mannitol and mixes in ball grinder, adds by ball material mass ratio 20:1
Enter zirconium oxide ball milling pearl, with 350r/min ball milling 30min, obtains ball milling material；
(2) based on quality portioning number, 40 parts of ball milling material, 15 parts of nano aluminium oxides, 3 parts of adjuvants, 6 ~ part soybean lecithin, 20 parts are taken
The ethanol solution that volume fraction is 70% is mixed in reaction kettle, stirs 2h with 500r/min, is evaporated under reduced pressure in 60 DEG C to constant weight,
Up to compound heat-insulation ingredient A.
The preparation method of compound heat-insulation ingredient B, includes the following steps:
S1. it takes vermiculite to crushed 200 meshes, takes sieving particle 1:4 in mass ratio that distilled water mixing is added, in dispersion grinding machine
6h is ground with 2000r/min, obtains abrasive, in 75 DEG C, takes abrasive 1:10:3 in mass ratio that reagent B, surfactant is added
Mixing stirs 5h, heat-insulation soaking 2h, filtering, after taking 3 times of distillation water washings of filter cake filter cake quality, in 65 DEG C with 400r/min
Oven drying obtains PERFORMANCE OF MODIFIED VERMICULITE, takes PERFORMANCE OF MODIFIED VERMICULITE 3:40:1:0.01 in mass ratio that distilled water, dispersing agent, diformazan is added to constant weight
The mixing of base silicone oil shears dispersion 3h, high pressure homogenization 5min in 2000r/min, obtains composite modified vermiculite, spare；
S2. 1:10 in mass ratio takes carbide slag, water to mix in container, after 400r/min magnetic agitation 30min, is depressurized with 75 DEG C
Evaporative removal moisture moves to Muffle furnace with 500 DEG C of roasting 3h, cools to room temperature with the furnace, obtain roasting material to constant weight, take roasting material by
The sodium carbonate liquor mixing of mass fraction 20% is added in mass ratio 1:5, obtains suspension, 1:10 in mass ratio takes flyash, concentration
The NaOH solution of 0.01mol/L mixes, and stirs 20min with 400r/min, obtains mixed liquid, takes mixed liquid to filter, filtrate is taken to be stored at room temperature
1h takes supernatant 1:2 in mass ratio that suspension is added and mixes in 50 DEG C of hydrothermal reaction kettles, keeps the temperature 3h, obtain slurry, take slurry mistake
Filter, after taking 3 times of filter cake filter cake quality of distillation water washing, moves to 70 DEG C of oven dryings to constant weight, obtains at carbide slag-flyash
Manage object；
S3. 5:1:0.1:15 in mass ratio takes composite modified vermiculite, carbide slag-flyash processed material, polyvinylpyrrolidone, water
Mixing, obtains mixed slurry, in 60 DEG C, takes mixed slurry 10:1 in mass ratio that foaming agent mixing is added, is stirred with 800r/min heat preservation
3h is mixed to get compound heat-insulation ingredient B.
A kind of compound heat-insulation Ceramic Tiles, according to the mass fraction, including following component: 2 parts of brighteners, 20 parts of potassium feldspars, 10
Part lithium carbonate, which is characterized in that further include: 20 parts of compound heat-insulation ingredient A, 30 parts of compound heat-insulation ingredient B.
A kind of preparation method of compound heat-insulation Ceramic Tiles, includes the following steps:
(1) according to the mass fraction, 2 parts of brighteners, 20 parts of potassium feldspars, 10 parts of lithium carbonates, 20 parts of compound heat-insulation ingredient A, 30 parts are taken
Compound heat-insulation ingredient B；
(2) it in 65 DEG C, takes potassium feldspar, lithium carbonate, compound heat-insulation ingredient B to mix in reaction kettle, homogeneous 10min is rolled with 1MPa,
After be cooled to 45 DEG C of addition compound heat-insulation ingredient A, brightener with 400r/min grind 20min, obtain base-material, take base-material reverse mould brickmaking
Base is dried in vacuo 20h at 70 DEG C, obtains dry brick, takes dry brick after its part of the surface glazing, is put into liquefied gas kiln
With 700 DEG C of sintering 3h to get compound heat-insulation Ceramic Tiles.
Petropols: Petropols C9.
Reagent: 6:2 in mass ratio takes the PBS buffer solution that pH is 7.8, dopamine to mix to get reagent.
Dispersing agent: 4:2:1 in mass ratio takes zinc stearate, polyethylene wax, titanium dioxide mixing to get dispersing agent.
Adjuvant: 5:2 in mass ratio takes hydroxyapatite, Os Sus domestica powder mixing to get adjuvant.
Surfactant: 5:1:2 in mass ratio takes cetyl trimethylammonium bromide, laureth sodium sulfovinate, secondary
Sodium alkyl sulfonate mixes to get surfactant.
Foaming agent: 4:2:0.01 in mass ratio takes rosin, wooden sodium sulfonate, kopol mixing to get foaming agent.
Brightener: 5:1:2 in mass ratio takes propoxylation propilolic alcohol, sodium hypophosphite, sodium tungstate mixing to get light
Agent.
The preparation method of compound heat-insulation ingredient A, includes the following steps:
(1) it takes lignite to sieve with 100 mesh sieve in pulverizer crushing, obtains brown coal powder, take brown coal powder in crucible, move into pyrolysis oven, with
160mL/min rate is passed through nitrogen into furnace, and with 10 DEG C/min temperature programming to 650 DEG C, heat preservation pyrolysis 4h is continuously heating to
1000 DEG C, heat preservation pyrolysis 5h cools to room temperature with the furnace, discharges, must be pyrolyzed material, in 200 DEG C, according to parts by weight, take 40 parts of heat
Material, 12 parts of Petropols, 6 parts of terpene resins are solved in container, are stirred, naturally cool to 150 DEG C, heat preservation is spare, must keep the temperature
Material takes insulation material 10:2:3:1 in mass ratio that microcrystalline cellulose, lactose, mannitol is added and mixes in ball grinder, by ball material quality
Zirconium oxide ball milling pearl is added than 30:1, ball milling material is obtained with 500r/min ball milling 50min；
(2) based on quality portioning number, 60 parts of ball milling material, 30 parts of nano aluminium oxides, 8 parts of adjuvants, 10 parts of soybean lecithins, 40 parts are taken
The ethanol solution that volume fraction is 70% is mixed in reaction kettle, stirs 5h with 800r/min, is evaporated under reduced pressure in 80 DEG C to constant weight,
Up to compound heat-insulation ingredient A.
The preparation method of compound heat-insulation ingredient B, includes the following steps:
S1. it takes vermiculite to crushed 200 meshes, takes sieving particle 1:8 in mass ratio that distilled water mixing is added, in dispersion grinding machine
9h is ground with 3000r/min, obtains abrasive, in 90 DEG C, takes abrasive 1:15:5 in mass ratio that reagent B, surfactant is added
Mixing stirs 8h, heat-insulation soaking 5h, filtering, after taking 6 times of distillation water washings of filter cake filter cake quality, in 80 DEG C with 600r/min
Oven drying obtains PERFORMANCE OF MODIFIED VERMICULITE, takes PERFORMANCE OF MODIFIED VERMICULITE 3:60:2:0.01 in mass ratio that distilled water, dispersing agent, diformazan is added to constant weight
The mixing of base silicone oil shears dispersion 5h, high pressure homogenization 10min in 3000r/min, obtains composite modified vermiculite, spare；
S2. 1:15 in mass ratio takes carbide slag, water to mix in container, after 600r/min magnetic agitation 50min, is depressurized with 90 DEG C
Evaporative removal moisture moves to Muffle furnace with 600 DEG C of roasting 5h, cools to room temperature with the furnace, obtain roasting material to constant weight, take roasting material by
The sodium carbonate liquor mixing of mass fraction 20% is added in mass ratio 1:10, obtains suspension, 1:15 in mass ratio takes flyash, concentration
The NaOH solution of 0.01mol/L mixes, and stirs 45min with 600r/min, obtains mixed liquid, takes mixed liquid to filter, filtrate is taken to be stored at room temperature
3h takes supernatant 1:5 in mass ratio that suspension is added and mixes in 75 DEG C of hydrothermal reaction kettles, keeps the temperature 5h, obtain slurry, take slurry mistake
Filter, after taking 5 times of filter cake filter cake quality of distillation water washing, moves to 90 DEG C of oven dryings to constant weight, obtains at carbide slag-flyash
Manage object；
S3. 5:3:0.1:20 in mass ratio takes composite modified vermiculite, carbide slag-flyash processed material, polyvinylpyrrolidone, water
Mixing, obtains mixed slurry, in 80 DEG C, takes mixed slurry 10:2 in mass ratio that foaming agent mixing is added, is stirred with 1000r/min heat preservation
6h is mixed to get compound heat-insulation ingredient B.
A kind of compound heat-insulation Ceramic Tiles, according to the mass fraction, including following component: 5 parts of brighteners, 40 parts of potassium feldspars, 15
Part lithium carbonate, which is characterized in that further include: 40 parts of compound heat-insulation ingredient A, 50 parts of compound heat-insulation ingredient B.
A kind of preparation method of compound heat-insulation Ceramic Tiles, includes the following steps:
(1) according to the mass fraction, 5 parts of brighteners, 40 parts of potassium feldspars, 15 parts of lithium carbonates, 40 parts of compound heat-insulation ingredient A, 50 parts are taken
Compound heat-insulation ingredient B；
(2) it in 80 DEG C, takes potassium feldspar, lithium carbonate, compound heat-insulation ingredient B to mix in reaction kettle, homogeneous 20min is rolled with 3MPa,
After be cooled to 60 DEG C of addition compound heat-insulation ingredient A, brightener with 600r/min grind 40min, obtain base-material, take base-material reverse mould brickmaking
Base is dried in vacuo for 24 hours at 90 DEG C, obtains dry brick, takes dry brick after its part of the surface glazing, is put into liquefied gas kiln
With 800 DEG C of sintering 5h to get compound heat-insulation Ceramic Tiles.
Petropols: Petropols C5.
Reagent: 6:1.5 in mass ratio takes the PBS buffer solution that pH is 7.5, dopamine to mix to get reagent.
Dispersing agent: 4:1.5:1 in mass ratio takes zinc stearate, polyethylene wax, titanium dioxide mixing to get dispersing agent.
Adjuvant: 5:1.5 in mass ratio takes hydroxyapatite, Os Sus domestica powder mixing to get adjuvant.
Surfactant: 5:1:1.5 in mass ratio take cetyl trimethylammonium bromide, laureth sodium sulfovinate,
Sodium secondary alkyl sulfonate mixes to get surfactant.
Foaming agent: 4:1.5:0.01 in mass ratio takes rosin, wooden sodium sulfonate, kopol mixing to get foaming agent.
Brightener: 5:1:1.5 in mass ratio takes propoxylation propilolic alcohol, sodium hypophosphite, sodium tungstate mixing to get light
Agent.
The preparation method of compound heat-insulation ingredient A, includes the following steps:
(1) it takes lignite to sieve with 100 mesh sieve in pulverizer crushing, obtains brown coal powder, take brown coal powder in crucible, move into pyrolysis oven, with
130mL/min rate is passed through nitrogen into furnace, and with 8 DEG C/min temperature programming to 600 DEG C, heat preservation pyrolysis 3h is continuously heating to 950
DEG C, heat preservation pyrolysis 4h cools to room temperature with the furnace, discharges, must be pyrolyzed material, in 190 DEG C, according to parts by weight, 30 parts of pyrolysis is taken to expect,
11 parts of Petropols, 5 parts of terpene resins are stirred in container, naturally cool to 145 DEG C, and heat preservation is spare, obtains insulation material, takes
Insulation material 10:1.5:3:1 in mass ratio is added microcrystalline cellulose, lactose, mannitol and mixes in ball grinder, by ball material mass ratio
25:1 is added zirconium oxide ball milling pearl and obtains ball milling material with 400r/min ball milling 35min；
(2) based on quality portioning number, 50 parts of ball milling material, 17 parts of nano aluminium oxides, 5 parts of adjuvants, 7 parts of soybean lecithins, 25 parts are taken
The ethanol solution that volume fraction is 70% is mixed in reaction kettle, stirs 3h with 600r/min, is evaporated under reduced pressure in 70 DEG C to constant weight,
Up to compound heat-insulation ingredient A.
The preparation method of compound heat-insulation ingredient B, includes the following steps:
S1. it takes vermiculite to crushed 200 meshes, takes sieving particle 1:6 in mass ratio that distilled water mixing is added, in dispersion grinding machine
6 ~ 9h is ground with 2500r/min, obtains abrasive, in 80 DEG C, takes abrasive 1:12:4 in mass ratio that reagent B, surface-active is added
Agent mixing stirs 6h, heat-insulation soaking 3h, filtering, after taking 4 times of distillation water washings of filter cake filter cake quality, in 75 with 500r/min
DEG C oven drying obtains PERFORMANCE OF MODIFIED VERMICULITE to constant weight, take PERFORMANCE OF MODIFIED VERMICULITE 3:45:1.5:0.01 in mass ratio be added distilled water, dispersing agent,
Dimethicone mixing shears dispersion 4h, high pressure homogenization 7min in 2500r/min, obtains composite modified vermiculite, spare；
S2. 1:12 in mass ratio takes carbide slag, water to mix in container, after 500r/min magnetic agitation 40min, is depressurized with 80 DEG C
Evaporative removal moisture moves to Muffle furnace with 550 DEG C of roasting 4h, cools to room temperature with the furnace, obtain roasting material to constant weight, take roasting material by
The sodium carbonate liquor mixing of mass fraction 20% is added in mass ratio 1:7, obtains suspension, 1:13 in mass ratio takes flyash, concentration
The NaOH solution of 0.01mol/L mixes, and stirs 35min with 500r/min, obtains mixed liquid, takes mixed liquid to filter, filtrate is taken to be stored at room temperature
2h takes supernatant 1:3 in mass ratio that suspension is added and mixes in 65 DEG C of hydrothermal reaction kettles, keeps the temperature 4h, obtain slurry, take slurry mistake
Filter, after taking 4 times of filter cake filter cake quality of distillation water washing, moves to 80 DEG C of oven dryings to constant weight, obtains at carbide slag-flyash
Manage object；
S3. 5:2:0.1:17 in mass ratio takes composite modified vermiculite, carbide slag-flyash processed material, polyvinylpyrrolidone, water
Mixing, obtains mixed slurry, in 70 DEG C, takes mixed slurry 10:1.5 in mass ratio that foaming agent mixing is added, is kept the temperature with 900r/min
5h is stirred to get compound heat-insulation ingredient B.
A kind of compound heat-insulation Ceramic Tiles, according to the mass fraction, including following component: 3 parts of brighteners, 30 parts of potassium feldspars, 13
Part lithium carbonate, which is characterized in that further include: 30 parts of compound heat-insulation ingredient A, 35 parts of compound heat-insulation ingredient B.
A kind of preparation method of compound heat-insulation Ceramic Tiles, includes the following steps:
(1) according to the mass fraction, 3 parts of brighteners, 25 parts of potassium feldspars, 13 parts of lithium carbonates, 25 parts of compound heat-insulation ingredient A, 40 parts are taken
Compound heat-insulation ingredient B；
(2) it in 75 DEG C, takes potassium feldspar, lithium carbonate, compound heat-insulation ingredient B to mix in reaction kettle, homogeneous 15min is rolled with 2MPa,
After be cooled to 50 DEG C of addition compound heat-insulation ingredient A, brightener with 500r/min grind 25min, obtain base-material, take base-material reverse mould brickmaking
Base is dried in vacuo 22h at 80 DEG C, obtains dry brick, takes dry brick after its part of the surface glazing, is put into liquefied gas kiln
With 750 DEG C of sintering 4h to get compound heat-insulation Ceramic Tiles.
Comparative example 1: it is essentially identical with the preparation method of embodiment 3, it has only the difference is that lacking compound heat-insulation ingredient A.
Comparative example 2: it is essentially identical with the preparation method of embodiment 3, it has only the difference is that lacking compound heat-insulation ingredient B.
Comparative example 3: the thermal insulation ceramics brick of Yangzhou company production.
The thermal insulation ceramics brick of above-described embodiment and comparative example is detected respectively, thermal coefficient detection: each sample is same
When be placed in insulating box, drying to constant weight at a temperature of 378 scholar 5K moves back to drier and is cooled to room temperature；Open thermal conductivity test instrument
Heating furnace cover, each sample is individually placed in heating furnace position above and below testing element, the surface of sample each as far as possible keeps tighter
Close contact can be tested after shutting heating furnace cover；General supply is connected, control heating furnace automatic temperature control switch disk is allocated to predetermined
Control furnace temperature；Test macro switch is opened, enters normal condition to every test condition；Automatic calibration knob is opened, is corrected
It finishes, by calibrating knob slew test shelves, after microcomputer automatically processes data, liquid crystal display watch starts to show tested sample
Mean temperature and thermal coefficient at this temperature, light thermal property detection: temperature detection part is placed on thermal insulation ceramics brick, is used
In detection Ceramic Tiles temperature change；Laser irradiation is carried out to Ceramic Tiles with laser emitter, realizes heating；In the mistake of laser irradiation
Cheng Zhong, the actual power of testing laser transmitter；According to the temperature data and the practical function of above-mentioned gained obtained to liquid monitoring
Rate judges the light thermal property of determinand, obtains that the results are shown in Table 1.
Table 1:
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Thermal coefficient (Wm.k) | 0.18 | 0.13 | 0.12 | 0.4 | 0.42 | 0.5 |
| Sun heat conversion (%) | 84 | 85 | 88 | 78 | 75 | 40 |
| Infrared reflection rate (%) | 89 | 87 | 90 | 76 | 73 | 45 |
In summary, thermal insulation ceramics brick effect of the invention is more preferable, is worth of widely use.
Claims (10)
1. a kind of compound heat-insulation Ceramic Tiles, according to the mass fraction, including following component: 2 ~ 5 parts of brighteners, 20 ~ 40 parts of potassium feldspars,
10 ~ 15 parts of lithium carbonates, which is characterized in that further include: 20 ~ 40 parts of compound heat-insulation ingredient A, 30 ~ 50 parts of compound heat-insulation ingredient B.
2. a kind of compound heat-insulation Ceramic Tiles according to claim 1, which is characterized in that the preparation of the compound heat-insulation ingredient A
Method includes the following steps:
(1) it taking lignite to pulverize and sieve, obtains brown coal powder, brown coal powder is taken to be passed through nitrogen, heat preservation pyrolysis, heating, heat preservation pyrolysis is cooling,
Discharging, must be pyrolyzed material, in 180 ~ 200 DEG C, according to parts by weight, take 20 ~ 40 parts of pyrolysis material, 8 ~ 12 parts of Petropols, 4 ~ 6 parts of terpenes
Olefine resin is stirred, cooling, and heat preservation obtains insulation material, takes insulation material 10:1 ~ 2:3:1 in mass ratio that microcrystalline cellulose, cream is added
Sugar, mannitol mixing, are added zirconium oxide ball milling pearl by ball 20 ~ 30:1 of material mass ratio, ball milling obtains ball milling material；
(2) based on quality portioning number, 40 ~ 60 parts of ball milling material, 15 ~ 30 parts of nano aluminium oxides, 3 ~ 8 parts of adjuvants, 6 ~ 10 portions of soybean are taken
Lecithin, 20 ~ 40 parts of ethanol solutions are mixed, and are evaporated under reduced pressure to get compound heat-insulation ingredient A.
3. a kind of compound heat-insulation Ceramic Tiles according to claim 2, which is characterized in that the Petropols in the step (1):
Any one in Petropols C5, C9.
4. a kind of compound heat-insulation Ceramic Tiles according to claim 2, which is characterized in that the adjuvant in the step (2): pressing matter
Amount takes hydroxyapatite, Os Sus domestica powder mixing to get adjuvant than 5:1 ~ 2.
5. a kind of compound heat-insulation Ceramic Tiles according to claim 1, which is characterized in that the preparation of the compound heat-insulation ingredient B
Method includes the following steps:
S1. it takes vermiculite to pulverize and sieve, takes sieving particle 1:4 in mass ratio ~ 8 that water mixed grinding is added, abrasive is obtained, in 75 ~ 90
DEG C, take abrasive 1:10 ~ 15:3 in mass ratio ~ 5 that reagent, surfactant mixing, heat-insulation soaking is added, filtering takes filter
Cake washing, it is dry, PERFORMANCE OF MODIFIED VERMICULITE is obtained, takes PERFORMANCE OF MODIFIED VERMICULITE 3:40 ~ 60:1 in mass ratio ~ 2:0.01 that water, dispersing agent, dimethyl is added
Silicone oil mixing, shearing dispersion, high pressure homogenization obtains composite modified vermiculite, spare；
S2. 1:10 ~ 15 take carbide slag, water to be mixed in mass ratio, are evaporated under reduced pressure, and roast, cooling, obtain roasting material, take roasting
Expect that sodium carbonate liquor mixing is added in 1:5 in mass ratio ~ 10, obtains suspension, 1:10 ~ 15 in mass ratio take flyash, NaOH solution
It is mixed, obtains mixed liquid, take mixed liquid to filter, filtrate is taken to stand, take supernatant 1:2 in mass ratio ~ 5 that suspension is added in 50 ~ 70
DEG C mixing, heat preservation obtains slurry, takes slurries filtration, filter cake is taken to wash, dry, obtains carbide slag-flyash processed material；
S3. 5:1 ~ 3:0.1:15 ~ 20 take composite modified vermiculite, carbide slag-flyash processed material, polyvinylpyrrolidine in mass ratio
Ketone, water mixing, obtain mixed slurry, in 60 ~ 80 DEG C, take mixed slurry 10:1 in mass ratio ~ 2 that foaming agent is added and are mixed, i.e.,
Obtain compound heat-insulation ingredient B.
6. a kind of compound heat-insulation Ceramic Tiles according to claim 5, which is characterized in that the reagent in the step S1: pressing matter
Amount takes PBS buffer solution, dopamine mixing to get reagent than 6:1 ~ 2.
7. a kind of compound heat-insulation Ceramic Tiles according to claim 5, which is characterized in that the surface-active in the step S1
Agent: 5:1:1 ~ 2 take cetyl trimethylammonium bromide, laureth sodium sulfovinate, sodium secondary alkyl sulfonate mixing in mass ratio,
Up to surfactant.
8. a kind of compound heat-insulation Ceramic Tiles according to claim 5, which is characterized in that the dispersing agent in the step S1: press
Mass ratio 4:1 ~ 2:1 takes zinc stearate, polyethylene wax, titanium dioxide mixing to get dispersing agent.
9. a kind of compound heat-insulation Ceramic Tiles according to claim 5, which is characterized in that the foaming agent in the step S3: press
Mass ratio 4:1 ~ 2:0.01 takes rosin, wooden sodium sulfonate, kopol mixing to get foaming agent.
10. a kind of compound heat-insulation Ceramic Tiles according to claim 1, which is characterized in that the brightener: 5:1 in mass ratio:
1 ~ 2 takes propoxylation propilolic alcohol, sodium hypophosphite, sodium tungstate mixing to get brightener.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109650832A (en) * | 2019-01-12 | 2019-04-19 | 张永华 | A kind of pressure resistance fired brick |
| CN113248282A (en) * | 2021-07-14 | 2021-08-13 | 广东欧文莱陶瓷有限公司 | Rock plate with comfortable human body touch feeling and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621639A (en) * | 2004-12-28 | 2005-06-01 | 许聪勇 | Heat insulating brick and manufacturing method thereof |
| CN101560111A (en) * | 2009-04-08 | 2009-10-21 | 吴汉阳 | Foamed ceramics energy saving and heat preservation decorative wall brick and manufacture method thereof |
| CN101922201A (en) * | 2009-06-17 | 2010-12-22 | 翁履谦 | Coal ash heat-preserving sintered brick/building block and production technology thereof |
| US20150353415A1 (en) * | 2013-01-21 | 2015-12-10 | Torrecid, S.A. | Digital glaze for high grammage, without the use of anti-settling agents |
| CN106116478A (en) * | 2016-06-16 | 2016-11-16 | 赵兰 | A kind of method utilizing red mud to prepare light heat insulation material |
| CN106554514A (en) * | 2016-10-28 | 2017-04-05 | 上海大学 | A kind of method for modifying boron nitride nanosheet surface with poly-dopamine |
| CN107602070A (en) * | 2017-10-19 | 2018-01-19 | 周夕和 | A kind of preparation method of sewage sludge shale brick |
-
2018
- 2018-08-31 CN CN201811015014.5A patent/CN108929106A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621639A (en) * | 2004-12-28 | 2005-06-01 | 许聪勇 | Heat insulating brick and manufacturing method thereof |
| CN101560111A (en) * | 2009-04-08 | 2009-10-21 | 吴汉阳 | Foamed ceramics energy saving and heat preservation decorative wall brick and manufacture method thereof |
| CN101922201A (en) * | 2009-06-17 | 2010-12-22 | 翁履谦 | Coal ash heat-preserving sintered brick/building block and production technology thereof |
| US20150353415A1 (en) * | 2013-01-21 | 2015-12-10 | Torrecid, S.A. | Digital glaze for high grammage, without the use of anti-settling agents |
| CN106116478A (en) * | 2016-06-16 | 2016-11-16 | 赵兰 | A kind of method utilizing red mud to prepare light heat insulation material |
| CN106554514A (en) * | 2016-10-28 | 2017-04-05 | 上海大学 | A kind of method for modifying boron nitride nanosheet surface with poly-dopamine |
| CN107602070A (en) * | 2017-10-19 | 2018-01-19 | 周夕和 | A kind of preparation method of sewage sludge shale brick |
Non-Patent Citations (3)
| Title |
|---|
| 孙酣经等: "《化工新材料产品及应用手册》", 31 January 2002, 中国石化出版社 * |
| 尹瑞等: "《非制冷红外探测材料技术》", 30 September 2011, 国防工业出版社 * |
| 德格吉呼等编著: "《无机非金属材料的性能研究》", 30 March 2013, 内蒙古大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109650832A (en) * | 2019-01-12 | 2019-04-19 | 张永华 | A kind of pressure resistance fired brick |
| CN113248282A (en) * | 2021-07-14 | 2021-08-13 | 广东欧文莱陶瓷有限公司 | Rock plate with comfortable human body touch feeling and preparation method thereof |
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Application publication date: 20181204 |