CN108928076A - A kind of recycled plastic floor and its forming method - Google Patents
A kind of recycled plastic floor and its forming method Download PDFInfo
- Publication number
- CN108928076A CN108928076A CN201811055236.XA CN201811055236A CN108928076A CN 108928076 A CN108928076 A CN 108928076A CN 201811055236 A CN201811055236 A CN 201811055236A CN 108928076 A CN108928076 A CN 108928076A
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- base material
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- composite base
- plastic floor
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses a kind of recycled plastic floor and its forming methods, it includes at least a composite base material layer and printing layer and wearing layer on compound laminar substrate, composite base material layer includes the first base material layer and the second substrate layer being arranged from top to bottom, first base material layer is made by PP or PE material, and the second substrate layer is made by mixing by PET and PE or PET and PP material.The recycled plastic floor plastic floor produced is halogen-free, and when burning will not generate bioxin, helps to reduce air pollution;The present invention can use recycled PET or PET, the macromolecules thermoplastic material such as PE, PP, TPU and EVA is cooperated to form composite base material layer again, again according to required characteristic, composite print layer and wearing layer on composite base material layer, the recyclable plastic floor of environmental protection is formed, and the plastic floor can be recycled to form regenerated resources and recycle.
Description
Technical field:
It is especially a kind of recycled plastic floor and its forming method the present invention relates to floor field.
Background technique:
The substrate of traditional plastic cement bottom largely uses polyvinyl chloride (PVC) to be made, then cooperates wearing layer and printing
Layer forms plastic floor, which uses till today always.But the plastic floor of this class formation can not recycle and need Expenses Cost
Processing is buried, and generating bioxin through burning would seriously pollute the environment.
Summary of the invention:
The technical problem to be solved by the invention is to provide the recyclable modelings of a kind of recyclable and Ke Xunhuanliyong environmental protection
Adhesive floor.
The technical solution of the invention is as follows, provides a kind of recycled plastic floor, includes at least a composite base material layer
With the printing layer and wearing layer being set on compound laminar substrate, composite base material layer includes the first base material layer being arranged from top to bottom and the
Two substrate layers, first base material layer are made by PP or PE material, and the second substrate layer is mixed by PET with PE or PET with PP material
It is made.
Preferably, composite base material layer further includes third substrate layer, third substrate layer is located at the second substrate layer lower surface simultaneously
Setting is bonded with it, third substrate layer is that macromolecular thermoplastic substrate is made.
Preferably, be also mixed with wood powder in first base material layer, be also mixed in the second substrate layer calcium carbonate, talcum powder or
Wood powder.The hardness and rigidity, the shrinking percentage, linear expansion coefficient, the croop property that reduce plastic products of composite base material layer are improved, and it is easy
In processing, the heat resistance of plastic floor can be more improved.
Preferably, third substrate layer is the macromolecular thermoplastic substrate of TPU or EVA.
Preferably, composite base material layer lower surface is also compounded with extra play, extra play is eva film, PE film, TPU thin
Any one of film, foam or cork.
Preferably, printing layer is digital spray printing on composite base material layer or printing layer is PET printing layer, PET printing layer
Fit in composite base material layer upper surface and Chong Die with composite base material layer;Wearing layer is PTU transparent wear or PTE transparent wear
Layer, wearing layer fit in printing layer upper surface.
The present invention also provides a kind of forming method on recycled plastic floor, the second substrate layer of composite base material layer is squeezed with single
Machine produces out, is generated EVA, PE in the second substrate layer surface in a manner of being cast after the production of the second substrate layer, is formed as composite base
The first base material layer and third substrate layer of material layer.
Preferably, composite base material layer binds by co-extrusion and be cut into sheet, then printing layer and wearing layer are sequentially placed
Above composite base material layer, plastic floor then is formed using press hot pressing.When composite base material layer coextrusion mold, recycled with PET
Material is used as material, it is possible to reduce the pollution to environment.
It is compound with hyaline membrane and after embossing and being bonded preferably, printing layer is with PET openpore, using adhesive bonds in multiple
Close on substrate layer or printing layer with PET cloth using adhesive bonds on composite base material, then by digital spray printing by pattern spray printing
In printing layer.
Preferably, printing layer is protected pattern spray printing in a manner of digital spray printing on composite base material layer, then with UV or PU
Shield and embossing.
Preferably, composite base material layer produces foaming body or makes composite base material layer using foaming agent by addition gas
Foaming forms foaming body.
Preferably, being also compounded with strengthening layer on composite base material layer, strengthening layer is formed by papery through printing melamine
Reinforced plastic floor.
Preferably, volume send equipment include with wearing layer unreeling structure, printing layer unreeling structure, wearing layer fit body,
Printing layer fit body and guide mechanism, wearing layer are delivered to roll-in using wearing layer unreeling structure cooperation wearing layer fit body
Unit, printing layer are delivered to roll-in unit using printing layer unreeling structure cooperation printing layer fit body and guide mechanism.
Preferably, roll-in unit is four-roll calender comprising rack, and be set in sequence from lower to upper on the rack
The first conveying roller, the second conveying roller, mirror roller and patterned roll, composite base material layer leads via the first conveying roller and the second conveying roller
Enter, then along the second conveying roller upwardly through between mirror roller and patterned roll, at the same time, printing layer and wearing layer are in composite base
Before material layer passes through between mirror roller and patterned roll, the conveying of equipment is sent using volume, printing layer is enabled to be stacked on composite base material layer, is resistance to
Mill stacking is set in printing layer so that composite base material layer, printing layer and the wearing layer that ought be stacked up and down by mirror roller and
When between patterned roll, binded by roll-in integral.
Further, PET material selects recycled PET material.Recycled PET and PET, PE, PP and EVA are combined into compoundly
Plate makes filler of the PET material as plastic floor, increases plastic floor thickness with recycled PET material, makes PET circulation benefit
With more environmentally-friendly.
Using after above scheme compared with prior art, the invention has the following advantages that selected raw material is that can return
The polyolefin elastomer of receipts, plastic floor produced are halogen-free, and when burning will not generate bioxin, help to reduce air
Pollution;The present invention can use recycled PET or PET, then the macromolecules thermoplastic material such as cooperate PE, PP, TPU and EVA formed it is compound
Substrate layer, then according to required characteristic, composite print layer and wearing layer on composite base material layer, with forming the recyclable plastic cement of environmental protection
Plate, and the plastic floor can be recycled to form regenerated resources and recycle.
Detailed description of the invention:
The structural schematic diagram of the position Fig. 1 two-layer compound substrate layer of the invention.
Fig. 2 is the structural schematic diagram of three layers of composite base material layer of the invention.
Fig. 3 is the structural schematic diagram of another embodiment of composite base material layer of the invention.
Fig. 4 is a kind of structural schematic diagram of plastic floor embodiment of the invention.
Fig. 5 is the structural schematic diagram of plastic floor molding equipment of the present invention.
Specific embodiment:
With regard to specific embodiment, the invention will be further described below:
Embodiment 1
A kind of recycled plastic floor comprising a composite base material layer and printing layer on compound laminar substrate and wear-resisting
Layer, wherein 10 its structure of composite base material layer as shown in Figure 1 can be as follows, including 102 He of first base material layer being arranged from top to bottom
Second substrate layer 101, first base material layer 102 are made by PP or PE material, the second substrate layer 101 by PET and PE or PET with
PP material is made by mixing.
Composite base material layer 10 binds by co-extrusion and is cut into sheet, then printing layer and wearing layer are sequentially placed in composite base
Above material layer, plastic floor then is formed using press hot pressing.Also, wood powder can also be added in first base material layer 102, second
Calcium carbonate, talcum powder or wood powder can also be added in substrate layer 101, and foaming body is formed by physical blowing or chemical blowing,
Specifically, physical blowing can add gas to produce foaming body, chemical blowing then makes composite base material layer foam using foaming agent
Formed foaming body, thus make composite base material layer have dilation and material it is light.
Embodiment 2
Composite base material layer 10 can also be gone back with as shown in Fig. 2, on the basis of first base material layer 102 and the second substrate layer 101
Including third substrate layer 103, wherein first base material layer 102 is made by PP or PE material, and the second substrate layer 101 can be
PET is mixed with PE, or PET is made by mixing with PP material, and third substrate layer 103 is located at the second substrate layer
101 lower surfaces are simultaneously bonded setting with it, and third substrate layer 103 is that macromolecular thermoplastic substrate is made, specifically, third base
Material layer 103 is the macromolecular thermoplastic substrate of TPU or EVA.Also, PET can select recycled PET to be made use again.Equally, it is
Raising performance improves the hardness and rigidity, the shrinking percentages for reducing plastic products, linear expansion coefficient, creep properties of composite base material layer
Can, and it is easy to process, while the heat resistance of plastic floor is improved, wood powder, the second substrate layer are also mixed in first base material layer 102
Calcium carbonate, talcum powder or wood powder are also mixed in 101.
Embodiment 3
As shown in figure 3, composite base material layer 10 is including first base material layer 102, the second substrate layer 101 and third substrate layer
On the basis of 103,103 lower surface of third substrate layer is also compounded with extra play, extra play be eva film, PE film, TPU film,
Any one of foam or cork, so that composite base material layer bottom is soft layer, convenient for being used in rough hard ground,
It illustrates, cement floor at the injustice that can fill up ground when being laid with, enables whole composite base material layer smooth by its soft characteristic,
Furthermore it is also possible to as needed, decorative pattern be designed on extra play, to play the effect of on-slip, noise control.Wherein, in this implementation
In example, first base material layer 102 and third substrate layer 103 are that PE material is formed, and the second substrate layer 101 is that PET material is formed, and are added
Layer is compound with hot pressing or bonding mode and 103 lower surface of third substrate layer.
Embodiment 4
The composite base material layer of above-described embodiment is the main body of plastic floor, also referred to as plastic cement filler, in order to reinforce it
Unique and wearability, as shown in figure 4, carrying out the roller of printing layer 21 and wearing layer 22 together when composite base material layer 10 forms
Pressure, to form final plastic floor.Among these, printing layer 21 can be digital spray printing on composite base material layer 10 or printing layer
21 be PET printing layer, and PET printing layer fits in composite base material layer upper surface and Chong Die with composite base material layer;Wearing layer 22 is PTU
Transparent wear or PTE transparent wear, wearing layer 22 fit in printing layer upper surface.In specific operation process, when compound
Substrate layer on line coextrusion mold when, PET printing layer can be affixed on above composite base material layer on line, be in upper and lower overlapping bonding
One;And printing layer is made to be formed in the composite base material layer upper limb, surface printing has preset pattern or lines, wearing layer
It is formed in the printing layer.The composite base material layer send equipment to distinguish after coextrusion mold, with the printing layer and wearing layer using volume
It is transported to roll-in unit, composite base material layer, printing layer and wearing layer roll-in bonding are fixed as one using the roll-in unit, at
For the plastic floor of environmental protection.The great efficiency of its forming method and environmental protection, and the roll-in unit can be one or more groups of combinations.
In addition, the second substrate layer of the composite base material layer of the plastic floor is produced with single extruder, the second substrate layer is with list
EVA, PE are generated in the second substrate layer surface in a manner of being cast after the production of the second substrate layer, are formed as compound by extruder production
The first base material layer and third substrate layer of substrate layer.
In addition, the forming method of the plastic floor, sheet can not only can be more cut into using co-extrusion in compound on line, and with
Composite base material layer is cut into sheet by hot pressing mode, sequentially puts PRT printing layer and wearing layer above it, recycles press hot pressing
Molding.
About the combination of printing layer, back up is carried out with PET hyaline layer, recycles macromolecule to be coated with the back side, makes
It is with preferable stickiness, and the printing layer can also be the plastic cement high abrasion material such as TPU, or after printing formable layer,
Will be by pattern spray printing in printing layer in the way of digital spray printing, then with UV or PU protects and emboss.Alternatively, printing layer with
Digital spray printing mode forms pattern spray printing on composite base material layer, then is protected and embossed with UV or PU.
In order to realize that the reinforcing of plastic floor is promoted, it is also compounded with strengthening layer on composite base material layer, strengthening layer is passed through by papery
It prints melamine and forms reinforced plastic floor.It can effectively prolong the service life with wear-resisting scratch resistance characteristic.
Reclaimed materials can be used in PET in above-described embodiment.
Volume involved in above-mentioned forming plastic cement floor board method send equipment, structure as shown in figure 5, volume send equipment 3 include with
Wearing layer unreeling structure 31, printing layer unreeling structure 32, wearing layer fit body 33, printing layer fit body 34 and guide mechanism
35, wearing layer 22 cooperates wearing layer fit body 33 to be delivered to roll-in unit 4,21 benefit of printing layer using wearing layer unreeling structure 31
Printing layer fit body 33 and guide mechanism 35 is cooperated to be delivered to roll-in unit 4 with printing layer unreeling structure 32.
Roll-in unit 4 be four-roll calender comprising rack 41, and be set in sequence from lower to upper on the rack first
Conveying roller 42A, the second conveying roller 42B, mirror roller 43 and patterned roll 44, composite base material layer 10 is via the first conveying roller 42A and
Two conveying roller 42B are imported, then at the same time, are printed along the second conveying roller 42B upwardly through between mirror roller 43 and patterned roll 44
Brush layer 21 and wearing layer 22 send the defeated of equipment 3 before composite base material layer 10 passes through between mirror roller 43 and patterned roll 44, using volume
It send, enables printing layer 21 be stacked on composite base material layer 10, wearing layer 22 is stacked in printing layer 21, so that ought be stacked up and down
Composite base material layer 10, printing layer 21 and wearing layer 22 pass through between mirror roller 43 and patterned roll 44 when, by roll-in bind at one
Body.
The made plastic floor of the present invention has the advantage that
Firstly, recycled PET can be used as raw material processed again, not only by resource recycling, and it is at low cost, it is produced
Finished product, do not contain bioxin, effectively reduce the destruction to environment.Secondly, base of the present invention using recycled PET as plastic floor
Material, need to overcome the compatibility of unlike material, therefore be mixed with PP, PE, PET, as the medium of co-extrusion fusion, and become composite base
Material layer does not use PVC completely, relatively more environmentally friendly.In addition, printing layer and wearing layer of the invention can need to adjust according to user
Whole formula is ratio, not only can have decorative pattern, pattern, with more anti-UV, wear-resisting, scratch resistance, durable, shock-absorbing, heat-resisting and use
The advantages that service life is long.
In conclusion the present invention can recycle a large amount of PET, and cooperates addition PP, PE and support plastic cement bottom
Composite base material layer, the traditional material using PVC of technological break-through can support the environment friendly plastic rubber without plasticizing with polyolefin material
Floor, especially overcomes the bonding problem of unlike material, so that PET, PP, PE are fitted closely into composite base material layer, can solve
Environmentally a large amount of Secondary PET, while increasing the applying value of industry.
Only the preferred embodiment of the present invention has been described above, but is not to be construed as limiting the scope of the invention.It is all
The equivalent structure or equivalent flow shift done using description of the invention, be included in scope of patent protection of the invention it
It is interior.
Claims (15)
1. a kind of recycled plastic floor, a composite base material layer and printing layer on compound laminar substrate and resistance to are included at least
Grind layer, it is characterised in that: composite base material layer includes the first base material layer and the second substrate layer being arranged from top to bottom, first base material layer
It is made by PP or PE material, the second substrate layer is made by mixing by PET and PE or PET and PP material.
2. recycled plastic floor according to claim 1, it is characterised in that: composite base material layer further includes third substrate
Layer, third substrate layer are located at the second substrate layer lower surface and are bonded setting with it, and third substrate layer is macromolecular thermoplastic substrate
It is made.
3. recycled plastic floor according to claim 1 or 2, it is characterised in that: be also mixed with wood in first base material layer
Powder is also mixed with calcium carbonate, talcum powder or wood powder in the second substrate layer.
4. recycled plastic floor according to claim 2, it is characterised in that: third substrate layer is the high score of TPU or EVA
Sub- thermoplastic matrix.
5. recycled plastic floor according to claim 1 or 2, it is characterised in that: composite base material layer lower surface is also compound
There is extra play, extra play is any one of eva film, PE film, TPU film, foam or cork.
6. recycled plastic floor according to claim 1, it is characterised in that: printing layer is digital spray printing in composite base material
On layer or printing layer is PET printing layer, and PET printing layer fits in composite base material layer upper surface and Chong Die with composite base material layer;It is resistance to
Grinding layer is PTU transparent wear or PTE transparent wear, and wearing layer fits in printing layer upper surface.
7. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: the second substrate layer with
Single extruder production, is generated EVA, PE in the second substrate layer surface in a manner of being cast after the production of the second substrate layer, is formed as multiple
Close the first base material layer and third substrate layer of substrate layer.
8. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: composite base material layer is logical
It crosses co-extrusion and binds and be cut into sheet, then printing layer and wearing layer are sequentially placed in above composite base material layer, then utilize press
Hot pressing forms plastic floor.
9. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: printing layer is white with PET
Base, it is compound with hyaline membrane and after embossing and being bonded, using adhesive bonds on composite base material layer or printing layer is with the utilization of PET cloth
Adhesive bonds on composite base material, then by digital spray printing by pattern spray printing in printing layer.
10. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: printing layer is with number
Spray printing mode forms pattern spray printing on composite base material layer, then is protected and embossed with UV or PU.
11. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: composite base material layer is logical
Addition gas is crossed to produce foaming body or make composite base material layer foam to form foaming body using foaming agent.
12. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: on composite base material layer
It is also compounded with strengthening layer, strengthening layer forms reinforced plastic floor through printing melamine by papery.
13. it is a kind of produce as claimed in claim 1 or 22 described in the volume on recycled plastic floor send equipment, it is characterised in that: volume send equipment
Including with wearing layer unreeling structure, printing layer unreeling structure, wearing layer fit body, printing layer fit body and guide mechanism,
Wearing layer is delivered to roll-in unit using wearing layer unreeling structure cooperation wearing layer fit body, and printing layer is unreeled using printing layer
Mechanism cooperation printing layer fit body and guide mechanism are delivered to roll-in unit.
14. it is a kind of produce as claimed in claim 1 or 22 described in recycled plastic floor roll-in unit, it is characterised in that: roll-in list
Member is four-roll calender comprising rack, and the first conveying roller on the rack, the second conveying are set in sequence from lower to upper
Roller, mirror roller and patterned roll, composite base material layer are imported via the first conveying roller and the second conveying roller, then along the second conveying roller to
It is upper by between mirror roller and patterned roll, at the same time, printing layer and wearing layer pass through mirror roller and decorative pattern in composite base material layer
Before between roller, the conveying of equipment is sent using volume, enables that printing layer is stacked on composite base material layer, wearing layer is stacked in printing layer,
So that when composite base material layer, printing layer and the wearing layer being stacked up and down pass through between mirror roller and patterned roll, by roll-in
Bonding is integral.
15. the forming method on recycled plastic floor according to claim 1 or 2, it is characterised in that: PET material is selected
Reclaimed materials.
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CN201811055236.XA CN108928076A (en) | 2018-09-11 | 2018-09-11 | A kind of recycled plastic floor and its forming method |
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CN109944411A (en) * | 2019-02-25 | 2019-06-28 | 浙江晶通塑胶有限公司 | A kind of PET plastic floor and its forming method |
CN109968783A (en) * | 2019-04-10 | 2019-07-05 | 深圳市贤俊龙彩印有限公司 | PVC floor production method |
CN110029796A (en) * | 2019-03-29 | 2019-07-19 | 浙江晶通塑胶有限公司 | A kind of floor Environment-friendlywear-resistant wear-resistant scratch resistance PET |
CN110116537A (en) * | 2019-03-29 | 2019-08-13 | 浙江晶通塑胶有限公司 | A kind of recyclable PET carpet of environmental protection |
CN112793286A (en) * | 2020-12-31 | 2021-05-14 | 浙江晶通塑胶有限公司 | Production method of flame-retardant PE wallboard |
CN113291013A (en) * | 2021-04-22 | 2021-08-24 | 无锡同力塑胶贸易有限公司 | Light wear-resistant plastic floor and preparation method thereof |
CN114571821A (en) * | 2022-03-30 | 2022-06-03 | 浙江海利得地板有限公司 | PET floor and preparation method thereof |
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CN109944411A (en) * | 2019-02-25 | 2019-06-28 | 浙江晶通塑胶有限公司 | A kind of PET plastic floor and its forming method |
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CN110116537A (en) * | 2019-03-29 | 2019-08-13 | 浙江晶通塑胶有限公司 | A kind of recyclable PET carpet of environmental protection |
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CN112793286B (en) * | 2020-12-31 | 2023-11-07 | 浙江晶通新材料集团有限公司 | Production method of flame-retardant PE wallboard |
CN113291013A (en) * | 2021-04-22 | 2021-08-24 | 无锡同力塑胶贸易有限公司 | Light wear-resistant plastic floor and preparation method thereof |
CN114571821A (en) * | 2022-03-30 | 2022-06-03 | 浙江海利得地板有限公司 | PET floor and preparation method thereof |
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