CN108914095A - A kind of method of ceramics mirror spray coating - Google Patents

A kind of method of ceramics mirror spray coating Download PDF

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Publication number
CN108914095A
CN108914095A CN201810765201.9A CN201810765201A CN108914095A CN 108914095 A CN108914095 A CN 108914095A CN 201810765201 A CN201810765201 A CN 201810765201A CN 108914095 A CN108914095 A CN 108914095A
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CN
China
Prior art keywords
mirror
spray coating
ceramic
spraying plating
ceramics
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Pending
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CN201810765201.9A
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Chinese (zh)
Inventor
陈建陵
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HUNAN YINHE CERAMICS INDUSTRY Co Ltd
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HUNAN YINHE CERAMICS INDUSTRY Co Ltd
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Priority to CN201810765201.9A priority Critical patent/CN108914095A/en
Publication of CN108914095A publication Critical patent/CN108914095A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/42Coating with noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1635Composition of the substrate
    • C23C18/1639Substrates other than metallic, e.g. inorganic or organic or non-conductive
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1655Process features
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1689After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1851Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
    • C23C18/1872Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
    • C23C18/1875Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment only one step pretreatment
    • C23C18/1882Use of organic or inorganic compounds other than metals, e.g. activation, sensitisation with polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00Other substrates
    • B05D2203/30Other inorganic substrates, e.g. ceramics, silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemically Coating (AREA)

Abstract

The invention discloses a kind of method of ceramic mirror spray coating, specific process steps are as follows:A. to ceramic surface processing, then water cleaning ceramic surface is dusted its surface, handles clean grease stain and dust;B. ceramics are sprayed;C. the plate for having sprayed priming paint is dried;D. spraying plating, surfactant spray gun adjust surface tension;E. 1 st pure water cleans, and the complete substrate of spray gun and spraying plating is thoroughly cleaned, extra surfactant is removed;F. mirror spray coating reacts, and prepares reaction solution and spray torch, carries out spraying plating to the ceramics after cleaning, 0.05-0.3 microns of plating thickness, spraying plating is completed to form uniform mirror;G. secondary cleaning is thoroughly cleaned the complete ceramics of spray gun and spraying plating;H. stabilizer sprays;I. it dries up.Ceramics mirror spray coating of the invention has excellent adhesive force, anti-impact force, corrosion resistance, against weather, wearability and marresistance, develops novel glaze colours for glass-ceramic product.

Description

A kind of method of ceramics mirror spray coating
Technical field
The present invention relates to ceramic spray technique field, especially a kind of method of ceramic mirror spray coating.
Background technique
Spraying plating is also known as thermal spraying, with the sprayed on material of molten condition, with a power device spray to metal, alloy, plastics, The workpiece surfaces such as ceramics form the technology of a complete coating.Sprayed on material can be metal or nonmetallic, using heat source by its Fusing or softening, lean on heat source self power or additional compressed air stream, are atomized or push molten grain at the grain beam of injection molten drop, with one Constant speed degree is ejected into matrix surface and forms coating.The heat source used has gas burning flame, gas discharge heat, electric heating and laser. Workpiece passes through spray treatment, its anti-corrosive properties, heat resistance and wearability can be improved, increase its thickness or repair size etc.
Ceramic mirror spray coating is a kind of environmentally friendly process for treating surface, is electroplated instead of tradition.In Surface Processing Industry, plating is One of the technique of environmental pollution most serious is caused, to avoid a series of waste liquid waste water caused by the process of surface treatment such as plating useless Gas disposal, pollution of the harmful heavy metal to environment, the harm to human body, technical staff develop ceramic mirror spray coating technology, it is Using special equipment and advanced material, applied chemistry principle makes to be sprayed-on body surface presentation by way of direct spraying The various DE Specular Lighting effects such as gold, silver, chromium and various colours (reddish yellow purple is turquoise).
For above, herein it is proposed that a kind of method of ceramics mirror spray coating.
Summary of the invention
The present invention is to solve above-mentioned technical deficiency, using modified technical solution, a kind of method of ceramics mirror spray coating, and tool Body process steps are as follows:
A. to ceramic surface processing, then water cleaning ceramic surface is dusted its surface, handles clean grease stain and ash Dirt;
B. ceramics are sprayed, ceramics is stamped into priming paint, 20-25 μm of the thickness control thickness of priming paint, surface requirements height Planarization and cleanliness;
C. the plate for having sprayed priming paint is dried, and puts it into dryer inner, and drying temperature controls at 110 DEG C, continues Dry 30min, priming paint is thoroughly dried;
D. spraying plating, surfactant spray gun adjust surface tension, provide condition to form uniform silver mirror;
E. 1 st pure water cleans, and the complete substrate of spray gun and spraying plating is thoroughly cleaned, extra surfactant is removed;
F. mirror spray coating reacts, and prepares reaction solution and spray torch, carries out spraying plating, plating thickness to the substrate after cleaning 0.05-0.3 microns, spraying plating is completed to form uniform mirror;
The complete substrate of spray gun and spraying plating is thoroughly cleaned, removes extra reaction solution by g. secondary cleaning;
H. stabilizer sprays, and to the substrate and performance height spraying stabilizer after spraying plating reaction, enhances the anti-oxidant of metal layer Ability;
I. it dries up, using wind blowing gun, surface area water is removed to it, processing is completed without ponding in silver mirror surface.
As present invention further optimization mode, in step d, the surfactant includes following sodium alkyl sulfonate 36 Part, 25 parts of sodium alkyl benzene sulfonate, 15 parts of Teepol and 24 parts of soap powder.
As present invention further optimization mode, in step g, sodium chloride solution that concentration is 15% and 25% can use Sodium hydroxide solution, according to volume ratio 10:After 4 pour into container and are sufficiently stirred, then spray gun and substrate are carried out adequately clear It washes.
As present invention further optimization mode, step h, silver plating solution is unstable, and the service life is short, and stabilizer is added, and prevents Only solution is muddy and decomposes, and the stabilizer includes gelatin, and iodide contain Gu, Ni, CO, Hg, Pb inorganic salts, cystine and half Cystine is mixed.
As present invention further optimization mode, the priming paint is set as acrylic primer or epoxy resin primer.
As present invention further optimization mode, in step f, the reaction solution is molten by a small amount of silver nitrate first when making Be added a small amount of ammonium hydroxide in liquid, be precipitated dark brown silver oxide precipitates, then plus excessive ammonium hydroxide form silver-colored amine complex and make to aoxidize Silver dissolution, participates in chemical reaction
2AgNO3+2NH4OH====Ag2O+2NH4NO3+H2O
Ag2O+4NH4OH====2Ag (NH3)2OH+3H2O
Ag (NH3) 2OH+NH4NO3====Ag (NH3)2NO3+NH4Silver-colored mixture in OH solution generates reaction and sinks Product goes out silver.
The invention discloses a kind of methods of ceramic mirror spray coating to be answered using special equipment and advanced nanometer materials Reach mirror effect by way of direct spraying with the principles of chemistry, ceramics is made to have the effect of mirror spray coating, is for ceramics Develop novel glaze colours spray technique.Advantage compared with traditional vacuum plating:With environmental protection, harmful heavy metal is free of;Small investment at This low, safe operation is suitble to automation, mass production.The color of ceramic mirror spray coating can achieve the bright-coloured multiplicity of bloom Property color, not by volumetric constraint recoverable.
Specific embodiment
Below in conjunction in the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution:A kind of method of ceramics mirror spray coating, specific process steps are as follows:
A. to ceramic surface processing, then water cleaning ceramic surface is dusted its surface, handles clean grease stain and ash Dirt;
B. ceramics are sprayed, ceramics is stamped into priming paint, 20-25 μm of the thickness control thickness of priming paint, surface requirements height Planarization and cleanliness;
C. the plate for having sprayed priming paint is dried, and puts it into dryer inner, and drying temperature controls at 110 DEG C, continues Dry 30min, priming paint is thoroughly dried;
D. spraying plating, surfactant spray gun adjust surface tension, provide condition to form uniform silver mirror;
E. 1 st pure water cleans, and the complete substrate of spray gun and spraying plating is thoroughly cleaned, extra surfactant is removed;
F. mirror spray coating reacts, and prepares reaction solution and spray torch, carries out spraying plating, plating thickness to the substrate after cleaning 0.05-0.3 microns, spraying plating is completed to form uniform mirror;
The complete substrate of spray gun and spraying plating is thoroughly cleaned, removes extra reaction solution by g. secondary cleaning;
H. stabilizer sprays, and to the substrate and performance height spraying stabilizer after spraying plating reaction, enhances the anti-oxidant of metal layer Ability;
I. it dries up, using wind blowing gun, surface area water is removed to it, processing is completed without ponding in silver mirror surface.
In step d, the surfactant includes 36 parts of following sodium alkyl sulfonate, 25 parts of sodium alkyl benzene sulfonate, secondary alkyl 15 parts and 24 parts of soap powder of sodium sulphate.
In step g, can use concentration is 15% sodium chloride solution and 25% sodium hydroxide solution, according to volume ratio 10:4 It pours into container after being sufficiently stirred, is then adequately cleaned spray gun and substrate.
Step h, silver plating solution is unstable, and the service life is short, and stabilizer is added, and prevents solution muddy and decomposes, the stabilizer Including gelatin, iodide contain Gu, Ni, CO, and Hg, Pb inorganic salts, cystine and cysteine are mixed.
The priming paint is set as acrylic primer or epoxy resin primer.
In step f, a small amount of ammonium hydroxide will be added in the reaction solution first in a small amount of silver nitrate solution when making, and is precipitated dark brown Color silver oxide precipitates, then plus excessive ammonium hydroxide form silver-colored amine complex and dissolve silver oxide, participate in chemical reaction 2AgNO3+ 2NH4OH====Ag2O+2NH4NO3+H2O
Ag2O+4NH4OH====2Ag (NH3)2OH+3H2O
Ag (NH3) 2OH+NH4NO3====Ag (NH3)2NO3+NH4Silver-colored mixture in OH solution generates reaction and sinks Product goes out silver.
To sum up, the invention discloses a kind of methods of ceramic mirror spray coating, using special equipment and advanced nanoscale material Material, applied chemistry principle reach mirror effect by way of direct spraying, so that ceramics is had the effect of mirror spray coating, are to be directed to Ceramics develop novel glaze colours spray technique.Advantage compared with traditional vacuum plating:With environmental protection, harmful heavy metal is free of;Investment Few at low cost, safe operation, is suitble to automation, mass production.It is bright-coloured that the color of ceramic mirror spray coating can achieve bloom Multiple colors, not by volumetric constraint recoverable.
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (6)

1. a kind of method of ceramics mirror spray coating, which is characterized in that specific process steps are as follows:
A. to ceramic surface processing, then water cleaning ceramic surface is dusted its surface, handles clean grease stain and dust;
B. ceramics are sprayed, ceramics is stamped into priming paint, 20-25 μm of the thickness control thickness of priming paint, surface requirements height is smooth Property and cleanliness;
C. the plate for having sprayed priming paint is dried, and puts it into dryer inner, and drying temperature is controlled at 110 DEG C, continued drying out 30min is thoroughly dried priming paint;
D. spraying plating, surfactant spray gun adjust surface tension, provide condition to form uniform silver mirror;
E. 1 st pure water cleans, and the complete substrate of spray gun and spraying plating is thoroughly cleaned, extra surfactant is removed;
F. mirror spray coating reacts, and prepares reaction solution and spray torch, carries out spraying plating, plating thickness 0.05-0.3 to the substrate after cleaning Micron, spraying plating are completed to form uniform mirror;
The complete substrate of spray gun and spraying plating is thoroughly cleaned, removes extra reaction solution by g. secondary cleaning;
H. stabilizer sprays, and to the substrate and performance height spraying stabilizer after spraying plating reaction, enhances the oxidation resistance of metal layer;
I. it dries up, using wind blowing gun, surface area water is removed to it, processing is completed without ponding in silver mirror surface.
2. a kind of method of ceramic mirror spray coating according to claim 1, which is characterized in that in step d, the surface is living Agent includes 36 parts of following sodium alkyl sulfonate, 25 parts of sodium alkyl benzene sulfonate, 15 parts of Teepol and 24 parts of soap powder.
3. a kind of method of ceramic mirror spray coating according to claim 1, which is characterized in that in step g, desirable concentration is 15% sodium chloride solution and 25% sodium hydroxide solution, according to volume ratio 10:After 4 pour into container and are sufficiently stirred, then Spray gun and substrate are adequately cleaned.
4. a kind of method of ceramic mirror spray coating according to claim 1, which is characterized in that step h, silver plating solution are unstable Fixed, the service life is short, and stabilizer is added, and prevents solution muddy and decomposes, and the stabilizer includes gelatin, and iodide contain Gu, Ni, CO, Hg, Pb inorganic salts, cystine and cysteine are mixed.
5. a kind of method of ceramic mirror spray coating according to claim 1, which is characterized in that the priming paint is set as acrylic acid Priming paint or epoxy resin primer.
6. a kind of method of ceramic mirror spray coating according to claim 1, which is characterized in that in step f, the reaction solution A small amount of ammonium hydroxide will be added when production in a small amount of silver nitrate solution first, dark brown silver oxide precipitates, then plus excess of ammonia are precipitated Water forms silver-colored amine complex and dissolves silver oxide, participates in chemical reaction 2AgNO3+2NH4OH====Ag2O+2NH4NO3+ H2O
Ag2O+4NH4OH====2Ag (NH3)2OH+3H2O
Ag (NH3) 2OH+NH4NO3====Ag (NH3)2NO3+NH4Silver-colored mixture in OH solution generates reaction and deposits Silver.
CN201810765201.9A 2018-07-12 2018-07-12 A kind of method of ceramics mirror spray coating Pending CN108914095A (en)

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Application Number Priority Date Filing Date Title
CN201810765201.9A CN108914095A (en) 2018-07-12 2018-07-12 A kind of method of ceramics mirror spray coating

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550619A (en) * 2019-01-09 2019-04-02 永兴县鸿福金属有限公司 A kind of multi-function metal coloring means

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944710A (en) * 2006-10-11 2007-04-11 方宏亮 Nano mirror spray coating
CN101200350A (en) * 2007-12-18 2008-06-18 张家港雅博纳米材料科技有限公司 Method for processing silver mirror coating
CN101469427A (en) * 2007-12-28 2009-07-01 汪正红 Nano spray plating technique for silver mirror
CN101773904A (en) * 2010-02-09 2010-07-14 林文友 Method for performing nano-plating on mirror surface
CN102127760A (en) * 2011-02-14 2011-07-20 刘洋 Nano mirror spray coating method
CN102327857A (en) * 2011-05-31 2012-01-25 厦门建霖工业有限公司 Method for jet-plating antimicrobial coating on nano mirror surface
CN108192567A (en) * 2018-01-17 2018-06-22 石峰 A kind of anti-skidding mixture in stadium floor

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944710A (en) * 2006-10-11 2007-04-11 方宏亮 Nano mirror spray coating
CN101200350A (en) * 2007-12-18 2008-06-18 张家港雅博纳米材料科技有限公司 Method for processing silver mirror coating
CN101469427A (en) * 2007-12-28 2009-07-01 汪正红 Nano spray plating technique for silver mirror
CN101773904A (en) * 2010-02-09 2010-07-14 林文友 Method for performing nano-plating on mirror surface
CN102127760A (en) * 2011-02-14 2011-07-20 刘洋 Nano mirror spray coating method
CN102327857A (en) * 2011-05-31 2012-01-25 厦门建霖工业有限公司 Method for jet-plating antimicrobial coating on nano mirror surface
CN108192567A (en) * 2018-01-17 2018-06-22 石峰 A kind of anti-skidding mixture in stadium floor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550619A (en) * 2019-01-09 2019-04-02 永兴县鸿福金属有限公司 A kind of multi-function metal coloring means

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Application publication date: 20181130