CN108913988A - Improve the preparation process of the beryllium-bronze piston ring in elastic service life - Google Patents

Improve the preparation process of the beryllium-bronze piston ring in elastic service life Download PDF

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Publication number
CN108913988A
CN108913988A CN201810546038.7A CN201810546038A CN108913988A CN 108913988 A CN108913988 A CN 108913988A CN 201810546038 A CN201810546038 A CN 201810546038A CN 108913988 A CN108913988 A CN 108913988A
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CN
China
Prior art keywords
piston ring
beryllium
bronze
service life
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810546038.7A
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Chinese (zh)
Inventor
何大林
林上忠
黄光伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI SHANGZHONG PISTON RING CO LTD
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ANHUI SHANGZHONG PISTON RING CO LTD
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Application filed by ANHUI SHANGZHONG PISTON RING CO LTD filed Critical ANHUI SHANGZHONG PISTON RING CO LTD
Priority to CN201810546038.7A priority Critical patent/CN108913988A/en
Publication of CN108913988A publication Critical patent/CN108913988A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)

Abstract

The present invention provides a kind of preparation processes of beryllium-bronze piston ring for improving the elastic service life, which mainly passes through die casting machine die cast, and the piston ring is mixed by beryllium-bronze, steel, silica, inorganic high-temp glue and manganese dioxide.The present invention has rational design, easy to process, can not only improve the structural strength of piston ring entirety, meanwhile, it also can satisfy the purpose for improving the piston ring body elastic service life.

Description

Improve the preparation process of the beryllium-bronze piston ring in elastic service life
Technical field
The invention mainly relates to the technical fields of piston ring processing, and in particular to a kind of beryllium-bronze for improving the elastic service life is living The preparation process of plug ring.
Background technique
Piston ring is the becket for being embedded in inside piston groove, and piston ring is divided into two kinds:Compress ring and machine oil ring, pressure Contracting ring can be used to the burning mixture in sealing combustion room;Machine oil ring is then used to strike off machine oil extra on cylinder, piston ring It is a kind of with the larger metallic elastic ring for expanding outwardly deformation, it is mounted in its corresponding annular groove of section, back and forth With the piston ring of rotary motion, by the pressure difference of gas or liquid, at one of ring periphery and cylinder and ring and annular groove Sealing is formed between side.
During piston ring is used for a long time, piston ring body flexibility decrease can all occur, seriously will appear complete mistake The phenomenon of elasticity is gone, and flexibility decrease will lead to engine poor sealing, collaborate, burn oil, compression ratio (cylinder drops) influences Engine power output.
Summary of the invention
It is above-mentioned to solve invention broadly provides a kind of preparation process of beryllium-bronze piston ring for improving the elastic service life It is proposed in background technique, since piston ring follows the string is exported to engine power the technical issues of impacting.
The present invention solve the technical solution that uses of above-mentioned technical problem for:Main process of the invention is as follows:
Step 1:Weighing apparatus is first passed through, suitable steel and beryllium-bronze is weighed, adds it in high temperature melting furnace, pass through High temperature action is smelted into molten condition;
Step 2:During steel-smelting and beryllium-bronze, by weighing apparatus, suitable silica and titanium dioxide are weighed Manganese is added thereto, and carries out melting;
Step 3:After complete melting, molten liquid is circulated into the compression mod of die casting machine, molten liquid is being circulated into pressure After in casting machine, inorganic high-temp glue is being poured into mold;
Step 4:After die casting machine die cast, piston ring ingredient after molding is transported in cooling chamber carry out it is cold But;
Step 5:After piston ring embryo material is cooling, is being polished using sander the piston ring embryo material, polished Processing both obtains finished product.
Steel is the general designation of the iron-carbon alloy to phosphorus content mass percent between 0.02% to 2.11%.The change of steel Studying point can be with great changes have taken place, and the steel containing only carbon is known as carbon steel (carbon steel) or ordinary steel;In actual production, steel is past Contain different alloying elements toward difference depending on the application, such as:Manganese, nickel, vanadium etc..Application and research history of the mankind to steel It is quite long, but until the Bessemerizing invention of 19th century, steel produce all be a high efficiency at low cost work. Nowadays, steel becomes one of most commonly used material in the world with its cheap price, reliable performance, is construction industry, manufacturing industry With ingredient indispensable in people's daily life.It may be said that steel is the material base of modern society.
Beryllium-bronze, using beryllium as a kind of tin-free bronze of major alloy constituent element.Containing 1.7~2.5% berylliums and a small amount of nickel, The elements such as chromium, titanium, after quenching ageing treatment, strength degree is up to 1250~1500MPa, close to the water of moderate strength steel It is flat.Plasticity is fine under as-quenched, can be processed into various semi-finished product.Beryllium-bronze has very high hardness, elastic limit, tired The labor limit and wearability also have good corrosion resistance, thermal conductivity and electric conductivity, spark are not generated when being hit, is widely used as Important elastic element, wear part and explosion-proof instrument etc..The common trade mark has QBe2, QBe2.5, QBe1.7, QBe1.9 etc..
Silica, the technical terms of chemistry, pure silica is colourless, is solid, chemical formula SiO under room temperature2, do not dissolve in Water.Insoluble in acid, but it is dissolved in hydrofluoric acid and hot concentrated phosphoric acid, can and melt bases and work.There are crystallization dioxies in nature SiClx and two kinds of amorphous silica.Silica have many uses it is general, be mainly used for glass processed, waterglass, pottery, enamel, Refractory material, aerogel blanket, ferrosilicon, molding sand, elemental silicon, cement etc., in ancient times, silica also are used to make the glaze paint of porcelain And carcass.General stone is mainly made of silica, calcium carbonate.
Manganese dioxide (nature presence in the form of pyrolusite).Physical behavior:Black amorphous powder or black iris Body.Dissolubility:It is insoluble in water, weak acid, weak base, nitric acid, cold sulfuric acid, concentrated hydrochloric acid is dissolved under heating state and generates chlorine.
Inorganic high-temp glue is a kind of critically important fine chemical product, and bonding force is strong, fireproof high-temperature resistant, and anti-impact force is good, Nontoxic to volatilize without any substance, application has been deep into the every field of national economy.
During processing, using steel as base-material, it is ensured that the structural strength of piston ring body, meanwhile, pass through dioxy The effect of SiClx, manganese dioxide is, it can be achieved that improve the purpose of piston ring body structural strength;
Further, on existing market, do not occurred being added to the constituent of piston ring using beryllium-bronze as auxiliary material In, and beryllium-bronze not only has good thermally conductive, corrosion resistance, improves the overall efficacy of piston ring, meanwhile, beryllium-bronze is one Kind of the very superior metal material of elastic effect, is added beryllium-bronze in piston ring ingredient, can not only optimization piston ring entirety Structural strength, meanwhile, it is capable to enhance the integrally-built elasticity of piston ring;It further, can by the effect of inorganic high-temp glue The elastic service life of overall improvement piston ring, meanwhile, by the effect of inorganic high-temp glue, molten can be increased in molten condition Under state, intermolecular cohesiveness, and then increase the inner structural strength of piston ring.
Compared with prior art, beneficial effects of the present invention are:The present invention has rational design, easy to process, can not only mention The structural strength of high piston ring entirety, meanwhile, it also can satisfy the purpose for improving the piston ring body elastic service life.
Detailed explanation is carried out to the present invention below with reference to specific embodiment.
Specific embodiment
With reference to embodiment, the present invention is furture elucidated, it should be understood that following specific embodiments are only used for It is bright the present invention rather than limit the scope of the invention, after the present invention has been read, those skilled in the art are to of the invention The modification of various equivalent forms falls within the application range as defined in the appended claims.
Embodiment in the present invention, mainly by following steps produces piston ring:
Step 1:Weighing apparatus is first passed through, suitable steel and beryllium-bronze is weighed, adds it in high temperature melting furnace, pass through High temperature action is smelted into molten condition;
Step 2:During steel-smelting and beryllium-bronze, by weighing apparatus, suitable silica and titanium dioxide are weighed Manganese is added thereto, and carries out melting;
Step 3:After complete melting, molten liquid is circulated into the compression mod of die casting machine, molten liquid is being circulated into pressure After in casting machine, inorganic high-temp glue is being poured into mold;
Step 4:After die casting machine die cast, piston ring ingredient after molding is transported in cooling chamber carry out it is cold But;
Step 5:After piston ring embryo material is cooling, is being polished using sander the piston ring embryo material, polished Processing both obtains finished product.
Now to each component content of piston ring, combined as follows:
Embodiment 1
Ingredient Steel Beryllium-bronze Silica Lithotroph glue Manganese dioxide
Parts by weight 60 11 2 0.6 1
Embodiment 2
Ingredient Steel Beryllium-bronze Silica Lithotroph glue Manganese dioxide
Parts by weight 65 12 2.3 0.7 1.2
Embodiment 3
Ingredient Steel Beryllium-bronze Silica Lithotroph glue Manganese dioxide
Parts by weight 70 13 2.5 0.8 1.5
Embodiment 4
Ingredient Steel Beryllium-bronze Silica Lithotroph glue Manganese dioxide
Parts by weight 75 14 2.7 0.7 1.7
Embodiment 5
Ingredient Steel Beryllium-bronze Silica Lithotroph glue Manganese dioxide
Parts by weight 80 15 3 1.0 2
In order to embody superiority of the invention, now take out multiple identical piston rings, respectively with above-mentioned multiple embodiments into Row elasticity service life and stryctyrak test comparison, specific test process are as follows;
The piston ring that identical 50 prior arts process first is taken out, is divided into five groups, in the above-described embodiments, Each group of embodiment all takes out ten piston rings, and it is small to be designed with ten with above-mentioned existing Piston volume tube at five big groups, in each big group Group carries out anti-strength test;
Anti- strength test one
In each big group, optional five group, by the piston ring in five groups chosen, on pressure detector, respectively Apply identical pressure, control the pressing times of piston ring, after a period of time, remove, observe the extent of damage of piston ring, and remembers Record, it is as follows:
Apply the first great Zu Neige of 5kg pressure group experimental record
Apply the second largest Zu Neige group experimental record of 5kg pressure
Apply the third-largest Zu Neige group experimental record of 5kg pressure
Apply the fourth-largest Zu Neige group experimental record of 5kg pressure
Apply the fifth-largest Zu Neige group experimental record of 5kg pressure
Anti- strength test two
In each big group, the remaining five group's piston rings that do not tested of selection are placed on pressure detector, to work Plug ring applies different pressure, and the pressing times for controlling piston ring are identical, after a period of time, removes, and observes the impaired of piston ring Degree, and record, it is as follows:
First great Zu Neige group experimental record after pressure 10min
Second largest Zu Neige group experimental record after pressure 10min
The third-largest Zu Neige group experimental record after pressure 10min
The fourth-largest Zu Neige group experimental record after pressure 10min
The fifth-largest Zu Neige group experimental record after pressure 10min
According to the comparison of above-mentioned multiple experimental results, we are it is not difficult to find that the piston ring that the present invention makes, in compression strength On the piston ring that produces compared with the prior art, compression strength is superior, under uniform pressure effect, is produced using the present invention Piston ring, effective resistance to compression failure is more permanent.
Elastic life tests
The piston ring that identical 25 prior arts process is taken out, is divided into five groups, in the above-described embodiments, often One group of embodiment all takes out five piston rings, with above-mentioned existing Piston volume tube at five big groups, is designed with five groups in each big group, Carry out elastic life test;
The own opening of ring, is firmly closed, is unclamping, holding by the piston ring and existing piston ring that the present invention is produced It after continuous different time, is unclamping, is measuring deformation quantity, obtain following data statistic;
Difference closing time Xia Ge group experimental record in first big group
Difference closing time Xia Ge group experimental record in second largest group
Difference closing time Xia Ge group experimental record in the third-largest group
Difference closing time Xia Ge group experimental record in the fourth-largest group
Difference closing time Xia Ge group experimental record in the fifth-largest group
It is compared by above-mentioned multiple experimental datas, it can be deduced that, the piston ring developed according to the present invention, in its bullet In the property service life, compared to existing piston ring, the elastic service life is more superior.
Certain embodiment of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (4)

1. improving the preparation process of the beryllium-bronze piston ring in elastic service life, which is characterized in that the piston ring mainly passes through die casting machine Die cast, and the piston ring is mixed by beryllium-bronze, steel, silica, inorganic high-temp glue and manganese dioxide.
2. the preparation process of the beryllium-bronze piston ring according to claim 1 for improving the elastic service life, which is characterized in that described In piston ring, each material content is as follows:The steel of 60-80 parts by weight, the beryllium-bronze of 11-15 parts by weight, 2-3 parts by weight titanium dioxide Silicon SiO2, the inorganic high-temp glue of 0.6-1.0 parts by weight and the manganese dioxide MnO of 1-2 parts by weight2
3. the preparation process of the beryllium-bronze piston ring according to claim 1 for improving the elastic service life, which is characterized in that the work Specific processing technology is as follows for plug ring:
Step 1:Weighing apparatus is first passed through, suitable steel and beryllium-bronze is weighed, adds it in high temperature melting furnace, pass through high temperature Effect, is smelted into molten condition;
Step 2:During steel-smelting and beryllium-bronze, by weighing apparatus, suitable silica and manganese dioxide are weighed, It is added thereto, carries out melting;
Step 3:After complete melting, molten liquid is circulated into the compression mod of die casting machine, molten liquid is being circulated into die casting machine After interior, inorganic high-temp glue is being poured into mold;
Step 4:After die casting machine die cast, piston ring ingredient after molding is transported in cooling chamber and is cooled down;
Step 5:After piston ring embryo material is cooling, polished, at polishing using sander the piston ring embryo material Reason both obtains finished product.
4. the preparation process of the beryllium-bronze piston ring according to claim 1 for improving the elastic service life, which is characterized in that described Inorganic high-temp glue is any one of phenolic resin glue and urea-formaldehyde resin adhesive.
CN201810546038.7A 2018-05-25 2018-05-25 Improve the preparation process of the beryllium-bronze piston ring in elastic service life Pending CN108913988A (en)

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Application Number Priority Date Filing Date Title
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103469115A (en) * 2013-08-07 2013-12-25 安徽蓝博旺机械集团合诚机械有限公司 Fork-lift truck steering knuckle cast steel material and preparation method thereof
CN104815973A (en) * 2015-05-05 2015-08-05 韦守记 Engine hydraulic steering pump production process
CN106086628A (en) * 2016-07-29 2016-11-09 安庆市德奥特汽车零部件制造有限公司 A kind of preparation method of high lubrication composite coating piston ring for combustion engines

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103469115A (en) * 2013-08-07 2013-12-25 安徽蓝博旺机械集团合诚机械有限公司 Fork-lift truck steering knuckle cast steel material and preparation method thereof
CN104815973A (en) * 2015-05-05 2015-08-05 韦守记 Engine hydraulic steering pump production process
CN106086628A (en) * 2016-07-29 2016-11-09 安庆市德奥特汽车零部件制造有限公司 A kind of preparation method of high lubrication composite coating piston ring for combustion engines

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Application publication date: 20181130