CN108913908A - Non-ferrous metal slag passes through pretreated comprehensive recycling process - Google Patents

Non-ferrous metal slag passes through pretreated comprehensive recycling process Download PDF

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Publication number
CN108913908A
CN108913908A CN201810974365.2A CN201810974365A CN108913908A CN 108913908 A CN108913908 A CN 108913908A CN 201810974365 A CN201810974365 A CN 201810974365A CN 108913908 A CN108913908 A CN 108913908A
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China
Prior art keywords
ferrous metal
recycling process
pelletizing
dirt
passes
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CN201810974365.2A
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Chinese (zh)
Inventor
刘步有
孙玉梅
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Qingdao yingkunyuan Mining Technology Co.,Ltd.
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Qingdao Yingkunyuan International Trade Co Ltd
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Priority to CN201810974365.2A priority Critical patent/CN108913908A/en
Publication of CN108913908A publication Critical patent/CN108913908A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006Wet processes
    • C22B7/007Wet processes by acid leaching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes
    • C22B1/08Chloridising roasting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/2406Binding; Briquetting ; Granulating pelletizing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00Obtaining lead
    • C22B13/04Obtaining lead by wet processes
    • C22B13/045Recovery from waste materials
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/12Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/20Electrolytic production, recovery or refining of metals by electrolysis of solutions of noble metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention discloses a kind of non-ferrous metal slags to pass through pretreated comprehensive recycling process, belongs to mineral resources recycling and reusing field, its key points of the technical solution are that including the following steps:The first step, pelletizing:Clinker and chlorinating agent are mixed into combination system ball;Second step, drying:Pelletizing is dried;Third step, high temperature chlorination roasting:Pelletizing is roasted, dry dirt and wet dirt are collected;4th step, acidleach:Dry dirt and wet dirt are poured into acidleach copper-containing solution to impregnate;5th step, filters pressing:It is press-filtered out filtrate and filter residue;6th step leaches:Filter residue is leached, leachate and residue is made;7th step, turbulent flow electrodeposition:Electrodeposition is carried out to filtrate and leachate, solves the problems, such as in mineral tailings that rare element is difficult to separate and produces, achieved the effect that all to extract the valuable element in mineral tailings.

Description

Non-ferrous metal slag passes through pretreated comprehensive recycling process
Technical field
The present invention relates to mineral resources recycling and reusing field, in particular to a kind of non-ferrous metal slag is by pretreated Comprehensive recycling process.
Background technique
A large amount of gold tailing, cyanide residue, sulfate slag, the tailings of copper mine, the tailings of Pb-Zn deposits, tailings red mud of lead factory etc. Deng, these coloured mines produce caused by tailings, i.e., so-called solid waste or dangerous danger object, still containing a certain amount of gold, Silver, copper, lead, zinc and other your dilute elements, there are also contain more iron and other elements.If can will contain in all tailings The elements such as gold, silver, iron carry out sorting recycling, then can either solve current solid waste and dangerous waste handling problems, can also obtain rich Thick income.
The prior art can refer to the Chinese utility model patent that Authorization Notice No. is CN207592409U, and it discloses one kind The system of municipal administration and the difficult solid waste collaboration resource utilization of metallurgy, the system include:1) proportioner:Proportioner includes material Storehouse;2) mixing arrangement:Feed bin is connect by the first mineral aggregate conveying device with mixing arrangement;3) damp mill:Mixing arrangement passes through the Three mineral aggregate conveying devices are connect with damp mill;4) pelletizer:Damp mill is connect by the 4th mineral aggregate conveying device with pelletizer;5) Drying device:Pelletizer is connect by the 5th mineral aggregate conveying device with drying device;6) preheating device:Drying device passes through the 6th Mineral aggregate conveying device is connect with preheating device;7) calciner:Preheating device passes through the 7th mineral aggregate conveying device and calciner Connection.
Although above system is recycled tailings, it can be difficult to the gold, silver, copper, lead, the zinc that contain in tailings It extracts, and carries out separation and produce.
Summary of the invention
The object of the present invention is to provide a kind of non-ferrous metal slags to pass through pretreated comprehensive recycling process, can be by mineral Valuable element in tailings all extracts.
Above-mentioned technical purpose of the invention technical scheme is that:
A kind of non-ferrous metal slag passes through pretreated comprehensive recycling process, which is characterized in that includes the following steps:
The first step, pelletizing:Slag and chlorinating agent are mixed, with pelletizer by the mixture system of slag and chlorinating agent Ball;Second step, drying:Pelletizing obtained is subjected to preheating and drying;
Third step, high temperature chlorination roasting:Dried pelletizing is put into calciner and is roasted, the pelletizing after roasting is received Collection gets up, and the dry dirt of roasting generation and wet dirt are also collected;
4th step, acidleach:Dry dirt and wet dirt are poured into the acid tower equipped with acidleach copper-containing solution and impregnated;
5th step, filters pressing:To the dry dirt and the progress filters pressing of wet dirt, obtained filtrate and filter residue after immersion;
6th step leaches:Filter residue is put into leaching equipment and is leached, leachate and residue is made, by leachate and filtrate Mixing, remaining residue is lead;
7th step, turbulent flow electrodeposition:Electrodeposition is carried out to leachate and filtrate, bronze, silver powder, copper sheet and zine plate are ionized out.
By using above scheme, the pelletizing after roasting can be used as the use such as iron-smelting raw material, last lead, gold obtained Powder, silver powder, copper sheet and zine plate purity are relatively high, can directly use.This technique can by lead remaining in mineral tailings, Gold, silver, copper and zinc extract, and completely handle mineral tailings realization, complete the complete process to solid waste or dangerous waste, discard Object discharge is relatively low, reduces pollution of the mineral products to environment, the withdrawal ratio of various valuable metals is relatively high, and economic well-being of workers and staff is good.
Preferably, the waste water generated after turbulent flow electrodeposition is imported in leaching equipment, reused.
It by using above scheme, is able to carry out waste water and recycles, make full use of metal ion remaining in waste water And leaching solvent, both reduce the discharge of waste, and also reduces processing cost.
It is roasted preferably, calciner is located in closed space.
It floats in air by using above scheme since the dry dirt generated in roasting process can raise, closed space The floating away rear amount lost of dry dirt can be reduced to the greatest extent, both reduced the pollution to environment, and also improved the quantum of output of unit raw material.
Preferably, dry dirt is extracted at wet dirt by exhaust equipment, mix dry dirt with wet dirt.
By using above scheme, dry dirt is directly mixed with wet dirt, facilitates staff is same to transport to next Walk process.
Preferably, raw material iron content is detected before roasting, the iron content for then detecting the pelletizing after roasting before Detection is divided into high-iron-content pellet and low iron ball group.
By using above scheme, high-iron-content pellet can directly send to experienced steel mill and be smelted iron, and low iron ball group can send to Construction site is used as building material, is carried out the sale transport that classification is conducive to the later period to pelletizing, is enable different pelletizings Suitable place is sent to use.
It is dried preferably, the pelletizing made is put into dryer.
By using above scheme, dryer can dry pelletizing with carrying out constant temperature high efficiency, sufficiently carry out to pelletizing pre- Heat, drying effect are got well than traditionally using air-heater drying effect.
Preferably, when leachate is mixed with filtrate, while extractant is added and is extracted.
By using above scheme, valuable metal in leachate can be extracted to organic phase by extraction, quasi- for subsequent electrodeposition For electrolyte, overall recovery efficiency is high.
Preferably, after addition extractant is extracted in leachate and filtrate, then anti-stripping agent is added into mixed liquor, It stirs evenly.
By using above scheme, the valuable metal in leachate and filtrate can be enriched with by anti-stripping agent, can first be returned Receiving portions valuable metal improves recovery efficiency, and since electrolytic deposition process makes regeneration of sulfuric acid, can return to and is used as to be stripped or leach, Sour consumption is reduced, total operation expense is reduced.
Preferably, after slag to be mixed with chlorinating agent to completion, by mixed slag and chlorinating agent pour into damp mill into Row profit mill.
By using above scheme, profit mill can be improved green ball strength, reduces powder rate of dry balls, makes under the fineness of Iron concentrate Drop, bentonite ore ratio reduces, pelletizing grade rises.
Preferably, filter residue enters in next step after the multiple filters pressing of filter press.
By using above scheme, filter press can be greatly reduced in final filter residue obtained by multiple filters pressing containing filter The amount of liquid makes filter residue can be improved leaching efficiency when leaching, and reduces the residual of valuable metal in filter residue.
In conclusion the invention has the advantages that:
1. the pelletizing after roasting can be used as the use such as iron-smelting raw material, finally lead obtained, bronze, silver powder, copper sheet and zine plate are pure It spends relatively high, can directly use.This technique can extract lead remaining in mineral tailings, gold, silver, copper and zinc, Mineral tailings realization is completely handled, the complete process to solid waste or dangerous waste is completed, waste discharge is relatively low, reduces mineral products The withdrawal ratio of pollution to environment, various valuable metals is relatively high, and economic well-being of workers and staff is good;
2. being able to carry out waste water to recycle, metal ion and leaching solvent remaining in waste water are made full use of, was both reduced The discharge of waste, also reduces processing cost;
3. valuable metal in leachate can be extracted to organic phase by extraction, electrolyte is prepared for subsequent electrodeposition, total recycling effect Rate is high;Valuable metal in leachate and filtrate can be enriched with by anti-stripping agent, can first recovery section valuable metal, improve back It produces effects rate, and since electrolytic deposition process makes regeneration of sulfuric acid, can return to and be used as to be stripped or leach, reduce sour consumption, make total operating cost With reduction.
Detailed description of the invention
Fig. 1 is the overall flow figure of embodiment one;
Fig. 2 is the system flow chart of embodiment two;
Fig. 3 is the schematic diagram of prominent return pipe in embodiment two.
In figure, 1, mixing apparatus;11, mineral aggregate transporting equipment;2, damp mill;3, pelletizer;4, dryer;5, roasting dress It sets;6, acid tower;7, filter press;8, leaching equipment;9, turbulent flow electrodeposition pond;91, return pipe;92, water pump.
Specific embodiment
Below in conjunction with attached drawing, invention is further described in detail.The wherein identical appended drawing reference of identical components It indicates.It should be noted that word "front", "rear" used in the following description, "left", "right", "up" and "down" refer to it is attached Direction in figure, word " bottom surface " and " top surface ", "inner" and "outside" are referred respectively to towards or away from geometric center of specific component Direction.
Embodiment one:A kind of non-ferrous metal slag passes through pretreated comprehensive recycling process, as shown in Figure 1, being divided into following Step:
The first step:Non-ferrous metal slag is mixed with chlorinating agent, damp mill 2 is poured into after mixing and carries out profit mill.
Second step:Slag and chlorinating agent after profit is ground pour into and carry out pelletizing in pelletizer 3.
Third step:By pelletizer 3, just pelletizing obtained pours into dryer 4 and is dried, preheats.
4th step:Dry pelletizing is poured into calciner 5 and is roasted, calciner 5 is located in roasting process In enclosure space, the dry dirt for roasting generation is extracted into designated position by exhaust equipment and is collected.Wet dirt can be generated after roasting, It is transported after all dry dirt is mixed with wet dirt.
5th step;Raw material iron content is detected before roasting, the iron content for then detecting the pelletizing after roasting before Detection is divided into high-iron-content pellet and low iron ball group.High-iron-content pellet can directly send to experienced steel mill and be smelted iron, and low iron ball group can send Construction site is gone to use as building material.
6th step:Mixed dry dirt is poured into the acid tower 6 equipped with acidleach copper-containing solution with wet dirt and is impregnated, is made Copper leaching liquid.
7th step:Copper leaching liquid, which pours into, carries out filters pressing in filter press 7, obtain filtrate and filter residue, pressed repeatedly again filter residue Filter reduces remaining filtrate content in filter residue.
8th step:Filter residue is poured into leaching equipment 8, leaching solvent is added, filter residue is leached, residue and leaching is made Liquid out, residue can obtain purer lead after treatment.
9th step:Leachate is mixed with filtrate, obtains mixed solution.
Tenth step:Extract liquor is added in mixed solution, then stirs evenly.Extraction can extract valuable metal in leachate It takes to organic phase, has prepared electrolyte for subsequent electrodeposition.
11st step:A small amount of anti-stripping agent is added in the mixed solution that extract liquor is added, stirs evenly.Anti-stripping agent will Part valuable metal in mixed solution extracts, and first carries out a step recycling.
12nd step:Mixed liquor is subjected to turbulent flow electrodeposition, bronze, silver powder, copper sheet and zine plate is made, by the waste water after electrodeposition It imports in leaching equipment 8.
It is as follows with the detail list after this process according to the sulfate slag of high-speed rail, according to daily 200 tons of siccatives, and return Yield is 0.85 calculating of volatility:
Table one:
Except above-mentioned profit, user can also get the subsidy of solid waste or dangerous waste.Since the price of slag itself is relatively low, So user handles solid waste or dangerous waste to obtain using this technique compares fair margin of profit.
Embodiment two:A kind of non-ferrous metal slag passes through pretreated comprehensive recovery system, as shown in Fig. 2, including by suitable Mixing apparatus 1 that sequence is set gradually, pelletizer 3, dryer 4, calciner 5, acid tower 6, filter press 7, is leached and is set damp mill 2 Standby 8 and turbulent flow electrodeposition pond 9.Mixing apparatus 1, damp mill 2, pelletizer 3, dryer 4, calciner 5, acid tower 6, filter press 7, leaching It is connected between equipment 8 and turbulent flow electrodeposition pond 9 by mineral aggregate transporting equipment 11 out.It is mixed that GHJ series of high efficiency can be used in mixing apparatus 1 Conjunction machine, mixing apparatus 1 mix non-ferrous metal slag and chlorinating agent, by the transport to damp mill 2 of mineral aggregate transporting equipment 11. Damp mill 2 can be used southern exposure heavy type MQR3562 damp mill, damp mill 2 by mixed non-ferrous metal slag and chlorinating agent into Row profit mill, declines the fineness of Iron concentrate, and bentonite ore ratio reduces, pelletizing grade rises.The non-ferrous metal slag that profit mill finishes It is transported by mineral aggregate transporting equipment 11 to pelletizer 3 with chlorinating agent.The Changjiang river pharmacy FCWDA400 model can be used in pelletizer 3 Pelletizing is made in non-ferrous metal slag and chlorinating agent by disc balling machine, pelletizer 3, and pelletizing transports extremely by mineral aggregate transporting equipment 11 In dryer 4.Dryer 4 can select the horizontal large-scale dryer of Sino-German heavy industry, and pelletizing is dried and carried out pre- by dryer 4 Heat, since the drying temperature of dryer 4 is easier control within a certain range, so can be in the drying effect for guaranteeing pelletizing Under the premise of fruit, pre-heat effect is improved.Pelletizing after drying in the transport to calciner 5 of mineral aggregate transporting equipment 11 by being roasted It burns, the hx model roaster of China's letter can be used in calciner 5, and pelletizing is roasted in the enclosed space, made by calciner 5 Chlorinating agent and non-ferrous metal slag generate reaction, generate chloride.The pelletizing roasted is directly collected by staff, Roasting before detect raw material iron content, then by the pelletizing after roasting according to before detect iron content detection be divided into high-iron-content pellet with Low iron ball group, is handled respectively.Calciner 5 can generate dry dirt and wet dirt when being roasted, and dry dirt and wet dirt are blended in It is formed together mixture, mixture in the transport to acid tower 6 of mineral aggregate transporting equipment 11 by being impregnated.Acid tower 6 is provided with acidleach Copper-containing solution, mixture is after the immersion of acidleach copper-containing solution by the transport to filter press 7 of mineral aggregate transporting equipment 11.Filter press 7 can select Jiangsu to dazzle the DY model belt filter press reached, and filter press 7 carries out filters pressing repeatedly to mixture, obtains filtrate and filter Slag, filter residue are transported by mineral aggregate transporting equipment 11 to leaching equipment 8.Leaching solvent, leaching equipment are added in leaching equipment 8 Leachate and residue, lead of the residue Jing Guo the available high-purity of subsequent processing is made in filter residue by 8, and leachate passes through together with filtrate It crosses in the transport to turbulent flow electrodeposition pond 9 of mineral aggregate transporting equipment 11.Leachate is mixed to form in turbulent flow electrodeposition pond 9 with filtrate and mixes Extract liquor is added in liquid in mixed liquor, stirs evenly, and is extracted, and valuable metal in leachate can be extracted to organic by extraction Phase has prepared electrolyte for subsequent electrodeposition.Then a small amount of anti-stripping agent is added in the mixed liquor that extract liquor is added, is stripped Liquid extracts the part valuable metal in mixed solution, first carries out a step recycling.Last turbulent flow electrodeposition pond 9 starts to mixing Liquid carries out electrodeposition, and bronze, silver powder, copper sheet and zine plate is made.
As shown in figure 3, being fixedly connected with return pipe 91 on turbulent flow electrodeposition pond 9,91 other end of return pipe is fixedly connected on On leaching equipment 8, return pipe 91 is connected to turbulent flow electrodeposition pond 9 and leaching equipment 8, and water pump 92 is fixedly connected on return pipe 91. After the completion of turbulent flow electrodeposition pond 9 is to mixed liquor electrodeposition, only it is left waste water in turbulent flow electrodeposition pond 9, water pump 92 will be in turbulent flow electrodeposition pond 9 Waste water drawn back in leaching equipment 8 by return pipe 91.It is able to carry out waste water to recycle, make full use of remaining in waste water Metal ion and leaching solvent had both reduced the discharge of waste, and had also reduced processing cost.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of non-ferrous metal slag passes through pretreated comprehensive recycling process, which is characterized in that include the following steps:
The first step, pelletizing:Slag and chlorinating agent are mixed, with pelletizer (3) by the mixture of slag and chlorinating agent into Row ball processed;
Second step, drying:Pelletizing obtained is subjected to preheating and drying;
Third step, high temperature chlorination roasting:Dried pelletizing is put into calciner (5) and is roasted, by the ball after roasting Group collects, and the dry dirt of roasting generation and wet dirt are also collected;
4th step, acidleach:Dry dirt and wet dirt are poured into the acid tower (6) equipped with acidleach copper-containing solution and impregnated;
5th step, filters pressing:To the dry dirt and the progress filters pressing of wet dirt, obtained filtrate and filter residue after immersion;
6th step leaches:Filter residue is put into leaching equipment (8) and is leached, leachate and residue is made, by leachate and filter Liquid mixing, remaining residue is lead;
7th step, turbulent flow electrodeposition:Electrodeposition is carried out to leachate and filtrate, bronze, silver powder, copper sheet and zine plate are ionized out.
2. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that described 7th step further includes:The waste water generated after turbulent flow electrodeposition is imported in leaching equipment (8), is reused.
3. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that described Third step further includes:Calciner (5), which is located in closed space, to be roasted.
4. non-ferrous metal slag according to claim 3 passes through pretreated comprehensive recycling process, which is characterized in that described Third step further includes:Dry dirt is extracted at wet dirt by exhaust equipment, mixes dry dirt with wet dirt.
5. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that described Step third step further includes:Raw material iron content is detected before roasting, then contains the iron that the pelletizing after roasting detects before Amount detection is divided into high-iron-content pellet and low iron ball group.
6. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that described Second step further includes:The pelletizing made is put into dryer (4) and is dried.
7. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that described 6th step further includes:When leachate is mixed with filtrate, while extractant is added and is extracted.
8. non-ferrous metal slag according to claim 7 passes through pretreated comprehensive recycling process, which is characterized in that described 6th step further includes:After addition extractant is extracted in leachate and filtrate, then anti-stripping agent is added into mixed liquor, stir It mixes uniformly.
9. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that described The first step further includes:After slag to be mixed with chlorinating agent to completion, by mixed slag and chlorinating agent pour into damp mill (2) into Row profit mill.
10. non-ferrous metal slag according to claim 1 passes through pretreated comprehensive recycling process, which is characterized in that institute Stating the 5th step further includes:Filter residue enters in next step after filter press (7) repeatedly filters pressing.
CN201810974365.2A 2018-08-24 2018-08-24 Non-ferrous metal slag passes through pretreated comprehensive recycling process Pending CN108913908A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575500A (en) * 2020-02-01 2020-08-25 吴坤 Method for treating zinc-containing dangerous solid waste and zinc ore by combining chlorination roasting with ammonia process electrodeposition
CN114502752A (en) * 2019-07-11 2022-05-13 公共股份公司矿业和冶金公司诺里尔斯克镍 Method for processing copper sulfide and nickel sulfide materials

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207592409U (en) * 2017-08-25 2018-07-10 中冶长天国际工程有限责任公司 A kind of system of municipal administration and metallurgical difficult solid waste collaboration recycling

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207592409U (en) * 2017-08-25 2018-07-10 中冶长天国际工程有限责任公司 A kind of system of municipal administration and metallurgical difficult solid waste collaboration recycling

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114502752A (en) * 2019-07-11 2022-05-13 公共股份公司矿业和冶金公司诺里尔斯克镍 Method for processing copper sulfide and nickel sulfide materials
CN114502752B (en) * 2019-07-11 2023-10-13 公共股份公司矿业和冶金公司诺里尔斯克镍 Method for processing copper sulfide and nickel sulfide materials
CN111575500A (en) * 2020-02-01 2020-08-25 吴坤 Method for treating zinc-containing dangerous solid waste and zinc ore by combining chlorination roasting with ammonia process electrodeposition

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